Thorium Oxyfluoride
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Thorium oxyfluoride is an inorganic compound of
thorium Thorium is a weakly radioactive metallic chemical element with the symbol Th and atomic number 90. Thorium is silvery and tarnishes black when it is exposed to air, forming thorium dioxide; it is moderately soft and malleable and has a high ...
metal, fluorine, and
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as ...
with the chemical formula .


Synthesis

*Thorium oxyfluoride can be prepared from partial hydrolysis of
thorium tetrafluoride Thorium(IV) fluoride ( Th F4) is an inorganic chemical compound. It is a white hygroscopic powder which can be produced by reacting thorium with fluorine gas. At temperatures above 500 °C, it reacts with atmospheric moisture to produce Th ...
in moist air at elevated temperatures, about 1000 °C. ::ThF4 + H2O -> ThOF2 + 2HF * Reaction of
thorium tetrafluoride Thorium(IV) fluoride ( Th F4) is an inorganic chemical compound. It is a white hygroscopic powder which can be produced by reacting thorium with fluorine gas. At temperatures above 500 °C, it reacts with atmospheric moisture to produce Th ...
with
thorium dioxide Thorium dioxide (ThO2), also called thorium(IV) oxide, is a crystalline solid, often white or yellow in colour. Also known as thoria, it is produced mainly as a by-product of lanthanide and uranium production. Thorianite is the name of the minera ...
at 600 °C: ::ThF4 + ThO2 -> 2ThOF2


Physical properties

The compound forms white, insoluble amorphous powder.


Uses

The compound is used as a protective coating on reflective surfaces.


References

{{Fluorine compounds Thorium compounds Oxyfluorides