Freiherr Christian Johann Dietrich Theodor von Grotthuss (20 January 1785 – 26 March 1822) was a

Baltic German Baltic Germans (german: Deutsch-Balten or , later ) were ethnic German inhabitants of the eastern shores of the Baltic Sea, in what today are Estonia and Latvia. Since their coerced resettlement in 1939, Baltic Germans have markedly declined ...

scientist known for establishing the first theory of

electrolysis In chemistry and manufacturing, electrolysis is a technique that uses direct electric current (DC) to drive an otherwise non-spontaneous chemical reaction. Electrolysis is commercially important as a stage in the separation of elements from n ...

in 1806 and formulating the first law of

photochemistry Photochemistry is the branch of chemistry concerned with the chemical effects of light. Generally, this term is used to describe a chemical reaction caused by absorption of ultraviolet (wavelength from 100 to 400 nm), visible light (400–7 ...

in 1817. His theory of

is considered the first description of the so-called

Grotthuss mechanism The Grotthuss mechanism (also known as proton jumping) is the process by which an 'excess' proton or proton defect diffuses through the hydrogen bond network of water molecules or other hydrogen-bonded liquids through the formation and concomitant ...

Life and work

Grotthuss was born in 1785 in

Leipzig Leipzig ( , ; Upper Saxon: ) is the most populous city in the German state of Saxony. Leipzig's population of 605,407 inhabitants (1.1 million in the larger urban zone) as of 2021 places the city as Germany's eighth most populous, as wel ...

Electorate of Saxony The Electorate of Saxony, also known as Electoral Saxony (German: or ), was a territory of the Holy Roman Empire from 1356–1806. It was centered around the cities of Dresden, Leipzig and Chemnitz. In the Golden Bull of 1356, Emperor Charles ...

Holy Roman Empire The Holy Roman Empire was a Polity, political entity in Western Europe, Western, Central Europe, Central, and Southern Europe that developed during the Early Middle Ages and continued until its Dissolution of the Holy Roman Empire, dissolution i ...

, during an extended stay of his parents away from their home in northern

Grand Duchy of Lithuania The Grand Duchy of Lithuania was a European state that existed from the 13th century to 1795, when the territory was partitioned among the Russian Empire, the Kingdom of Prussia, and the Habsburg Empire of Austria. The state was founded by Li ...

. He showed interest in natural sciences and went to study first in

and later in

Paris Paris () is the capital and most populous city of France, with an estimated population of 2,165,423 residents in 2019 in an area of more than 105 km² (41 sq mi), making it the 30th most densely populated city in the world in 2020. S ...

at the

École Polytechnique École may refer to: * an elementary school in the French educational stages normally followed by secondary education establishments (collège and lycée) * École (river), a tributary of the Seine flowing in région Île-de-France * École, Savoi ...

. Several renowned scientists taught at the École Polytechnique at that time, including

Antoine François, comte de Fourcroy Antoine is a French given name (from the Latin ''Antonius'' meaning 'highly praise-worthy') that is a variant of Danton, Titouan, D'Anton and Antonin. The name is used in France, Switzerland, Belgium, Canada, West Greenland, Haiti, French Guiana ...

Claude Louis Berthollet Claude Louis Berthollet (, 9 December 1748 – 6 November 1822) was a Savoyard-French chemist who became vice president of the French Senate in 1804. He is known for his scientific contributions to theory of chemical equilibria via the mech ...

and

Louis Nicolas Vauquelin Prof. Louis Nicolas Vauquelin Royal Society of London, FRS(For) HFRSE (16 May 1763 – 14 November 1829) was a French pharmacist and chemist. He was the discoverer of both chromium and beryllium. Early life Vauquelin was born at Saint-André-d'H ...

. Because of some tensions in the relations between Russia and France, Grotthuss had to leave for

Italy Italy ( it, Italia ), officially the Italian Republic, ) or the Republic of Italy, is a country in Southern Europe. It is located in the middle of the Mediterranean Sea, and its territory largely coincides with the homonymous geographical re ...

where he stayed at Naples for one year. The discovery of the first electric cell in 1800 by

Alessandro Volta Alessandro Giuseppe Antonio Anastasio Volta (, ; 18 February 1745 – 5 March 1827) was an Italian physicist, chemist and lay Catholic who was a pioneer of electricity and power who is credited as the inventor of the electric battery and the ...

provided the scientists a source of electricity which was used in various laboratory experiments around Europe. The electrolysis of water, acids and salt solutions was reported, but a good explanation was missing. Grotthuss actively contributed to this area both in terms of electrolysis experiments and their interpretation. During his stay in Italy, he published his work on electrolysis in 1806. His idea that the charge is not transported by the movement of particles but by breaking and reformation of bonds was the first basically correct concept for the charge transport in

electrolyte An electrolyte is a medium containing ions that is electrically conducting through the movement of those ions, but not conducting electrons. This includes most soluble salts, acids, and bases dissolved in a polar solvent, such as water. Upon dis ...

s; it is still valid for the charge transport in water, and the current proton hopping mechanism is a modified version of the original

. The following two years Grotthuss spent in

Rome , established_title = Founded , established_date = 753 BC , founder = King Romulus (legendary) , image_map = Map of comune of Rome (metropolitan city of Capital Rome, region Lazio, Italy).svg , map_caption ...

, some other Italian cities, and Paris, and then went back to Russia via

Munich Munich ( ; german: München ; bar, Minga ) is the capital and most populous city of the States of Germany, German state of Bavaria. With a population of 1,558,395 inhabitants as of 31 July 2020, it is the List of cities in Germany by popu ...

and

Vienna en, Viennese , iso_code = AT-9 , registration_plate = W , postal_code_type = Postal code , postal_code = , timezone = CET , utc_offset = +1 , timezone_DST ...

. From 1808 on he lived at the estate of his mother in northern Lithuania. There he conducted research on electricity and light with the limited research equipment he could assemble. Grotthuss committed

suicide Suicide is the act of intentionally causing one's own death. Mental disorders (including depression, bipolar disorder, schizophrenia, personality disorders, anxiety disorders), physical disorders (such as chronic fatigue syndrome), and s ...

in the spring of 1822 during a depression caused by health problems.

Life and work

See also

References

Further reading