A telluroxide is a type of
organotellurium compound Organotellurium chemistry describes the synthesis and properties of chemical compounds containing a carbon-tellurium chemical bond. Organotellurium chemistry is a lightly studied area, in part because of the few applications.
Functional groups
The ...
with the formula R
2TeO. These compounds are analogous to
sulfoxides in some respects. Reflecting the decreased tendency of Te to form
multiple bond
In chemistry, bond order, as introduced by Linus Pauling, is defined as the difference between the number of bonds and anti-bonds.
The bond order itself is the number of electron pairs (covalent bonds) between two atoms. For example, in diat ...
s, telluroxides exist both the monomer and the
polymer
A polymer (; Greek '' poly-'', "many" + ''-mer'', "part")
is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
, which are favored in solution and the solid state, respectively:
[Jens Beckmann, Dainis Dakternieks, Andrew Duthie, François Ribot, Markus Schürmann, and Naomi A. Lewcenko "New Insights into the "Structures of Diorganotellurium Oxides. The First Polymeric Diorganotelluroxane 6H4)2TeO">p-MeOC6H4)2TeOsub>n" Organometallics, 2003, volume 22, 3257–3261. ]
:(R
2TeO)
n {{Eqm n R
2TeO
Telluroxides are prepared from the telluroethers by
halogenation followed by base hydrolysis:
:R
2Te + Br
2 → R
2TeBr
2
:R
2TeBr
2 + 2 NaOH → R
2TeO + 2 NaBr + H
2O
References
Organotellurium compounds
Functional groups