Tar Emulsion
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Tar is a dark brown or black viscous liquid of hydrocarbons and free carbon, obtained from a wide variety of
organic materials Organic matter, organic material, or natural organic matter refers to the large source of carbon-based compounds found within natural and engineered, terrestrial, and aquatic environments. It is matter composed of organic compounds that have c ...
through destructive distillation. Tar can be produced from coal, wood, petroleum, or peat. "a dark brown or black bituminous usually odorous viscous liquid obtained by destructive distillation of organic material (such as wood, coal, or peat)". "tar and pitch, viscous, dark-brown to black substances obtained by the destructive distillation of coal, wood, petroleum, peat and certain other organic materials. " Mineral products resembling tar can be produced from fossil hydrocarbons, such as petroleum. Coal tar is produced from coal as a byproduct of coke production.


Terminology

"Tar" and " pitch" can be used interchangeably; asphalt (naturally occurring pitch) may also be called either "mineral tar" or "mineral pitch". There is a tendency to use "tar" for more liquid substances and "pitch" for more solid ( viscoelastic) substances. Both "tar" and "pitch" are applied to viscous forms of asphalt, such as the asphalt found in naturally occurring tar pits (e.g., the
La Brea Tar Pits La Brea Tar Pits is an active paleontological research site in urban Los Angeles. Hancock Park was formed around a group of tar pits where natural asphalt (also called asphaltum, bitumen, or pitch; ''brea'' in Spanish) has seeped up from the gro ...
in Los Angeles). "Rangoon tar", also known as "Burmese oil" or "Burmese naphtha", is also a form of petroleum. Oil sands, almost exclusively produced in Alberta, Canada, are colloquially referred to as "tar sands" but are in fact composed of asphalt, also called bitumen.


Wood tar

For at least 600 years, wood tar has been used as a water repellent coating for boats, ships, and roofs. In Scandinavia, it was produced as a cash crop. "Peasant Tar" might be named for the district of its production. Wood tar is still used as an additive in the flavoring of
candy Candy, also called sweets (British English) or lollies (Australian English Australian English (AusE, AusEng, AuE, AuEng, en-AU) is the set of varieties of the English language native to Australia. It is the country's common language an ...
,
alcohol Alcohol most commonly refers to: * Alcohol (chemistry), an organic compound in which a hydroxyl group is bound to a carbon atom * Alcohol (drug), an intoxicant found in alcoholic drinks Alcohol may also refer to: Chemicals * Ethanol, one of sev ...
, and other foods. Wood tar is microbicidal. Producing tar from wood was known in ancient Greece and has probably been used in Scandinavia since the Iron Age. Production and trade in pine-derived tar was a major contributor in the economies of
Northern Europe The northern region of Europe has several definitions. A restrictive definition may describe Northern Europe as being roughly north of the southern coast of the Baltic Sea, which is about 54th parallel north, 54°N, or may be based on other g ...
and
Colonial America The colonial history of the United States covers the history of European colonization of North America from the early 17th century until the incorporation of the Thirteen Colonies into the United States after the Revolutionary War. In the ...
. Its main use was in preserving wooden sailing vessels against rot. For centuries, dating back at least to the 14th century, tar was among
Sweden Sweden, formally the Kingdom of Sweden,The United Nations Group of Experts on Geographical Names states that the country's formal name is the Kingdom of SwedenUNGEGN World Geographical Names, Sweden./ref> is a Nordic country located on ...
's most important exports. Sweden exported 13,000 barrels of tar in 1615 and 227,000 barrels in the peak year of 1863. The largest user was the Royal Navy of the United Kingdom. Demand for tar declined with the advent of iron and steel ships. Production nearly stopped in the early 20th century, when other chemicals replaced tar, and wooden ships were replaced by steel ships. Traditional wooden boats are still sometimes tarred. The heating ( dry distilling) of pine wood causes tar and pitch to drip away from the wood and leave behind charcoal. Birch bark is used to make particularly fine tar, known as " Russian oil", suitable for leather protection. The by-products of wood tar are turpentine and
charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, cal ...
. When deciduous tree woods are subjected to destructive distillation, the products are
methanol Methanol (also called methyl alcohol and wood spirit, amongst other names) is an organic chemical and the simplest aliphatic alcohol, with the formula C H3 O H (a methyl group linked to a hydroxyl group, often abbreviated as MeOH). It is a ...
(wood alcohol) and
charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, cal ...
. Tar kilns ( sv, tjärmila, da, tjæremile, no, tjæremile, fi, tervahauta) are dry distillation ovens, historically used in Scandinavia for producing tar from wood. They were built close to the forest, from limestone or from more primitive holes in the ground. The bottom is sloped into an outlet hole to allow the tar to pour out. The wood is split into dimensions of a finger, stacked densely, and finally covered tight with earth and moss. If oxygen can enter, the wood might catch fire, and the production would be ruined. On top of this, a fire is stacked and lit. After a few hours, the tar starts to pour out and continues to do so for a few days.


Uses

Tar was used as seal for roofing
shingles Shingles, also known as zoster or herpes zoster, is a viral disease characterized by a painful skin rash with blisters in a localized area. Typically the rash occurs in a single, wide mark either on the left or right side of the body or face. ...
and tar paper and to seal the hulls of ships and boats. For millennia, wood tar was used to waterproof
sail A sail is a tensile structure—which is made from fabric or other membrane materials—that uses wind power to propel sailing craft, including sailing ships, sailboats, windsurfers, ice boats, and even sail-powered land vehicles. Sails may ...
s and boats, but today, sails made from inherently waterproof synthetic substances have reduced the demand for tar. Wood tar is still used to seal traditional wooden boats and the roofs of historic, shingle-roofed churches, as well as painting exterior walls of log buildings. Tar is also a general disinfectant. Pine tar oil, or wood tar oil, is used for the surface treatment of wooden shingle roofs, boats, buckets, and tubs and in the medicine, soap, and rubber industries. Pine tar has good penetration on the rough wood. An old wood tar oil recipe for the treatment of wood is one-third each genuine wood tar, balsam turpentine, and boiled or raw linseed oil or Chinese tung oil. In Finland, wood tar was once considered a panacea reputed to heal "even those cut in twain through their midriff". A Finnish proverb states that "if sauna, vodka and tar won't help, the disease is fatal." Wood tar is used in traditional Finnish medicine because of its microbicidal properties. Wood tar is also available diluted as
tar water Tar-water was a medieval medicine consisting of pine tar and water. As it was foul-tasting, it slowly dropped in popularity, but was revived in the Victorian era. It is used both as a tonic and as a substitute to get rid of "strong spirits". Both ...
, which has numerous uses: *As a flavoring for candies (e.g.,
Terva Leijona Terva Leijona ("Tar Lion") is a Finnish liquorice candy with tar flavouring. The candy is produced by Cloetta. It is available in traditional flavours like sugarless, licorice, and salmiakki. Leaf has also released a Villi Pohjola (Wild North) ...
) and alcohol (Terva Viina). *As a spice for food, like meat. *As a scent for saunas. Tar water is mixed into water, which is turned into steam in the sauna. *As an anti- dandruff agent in shampoo. *As a component of cosmetics. Mixing tar with
linseed oil Linseed oil, also known as flaxseed oil or flax oil (in its edible form), is a colourless to yellowish oil obtained from the dried, ripened seeds of the flax plant (''Linum usitatissimum''). The oil is obtained by pressing, sometimes followed by ...
varnish Varnish is a clear transparent hard protective coating or film. It is not a stain. It usually has a yellowish shade from the manufacturing process and materials used, but it may also be pigmented as desired, and is sold commercially in various ...
produces tar paint. Tar paint has a translucent brownish hue and can be used to saturate and tone wood and protect it from weather. Tar paint can also be toned with various pigments, producing translucent colors and preserving the wood texture. Tar was once used for public humiliation, known as tarring and feathering. By pouring hot wood tar onto somebody's bare skin and waiting for it to cool, they would remain stuck in one position. From there, people would attach feathers to the tar, which would remain stuck on the tarred person for the duration of the punishment. That person would then become a public example for the rest of the day. Tar was used in 9th-century Baghdad, which had streets paved with tar, derived from petroleum that became accessible from natural fields in the region.


Coal tar

Coal tar was formerly one of the products of gasworks. Tar made from coal or petroleum is considered toxic and carcinogenic because of its high benzene content, though coal tar in low concentrations is used as a topical medicine. Coal and petroleum tar has a pungent odour. Coal tar is listed at number 1999 in the United Nations list of
dangerous goods Dangerous goods, abbreviated DG, are substances that when transported are a risk to health, safety, property or the environment. Certain dangerous goods that pose risks even when not being transported are known as hazardous materials ( syllabi ...
.


See also

* Creosote * Pitch (resin) * Resin *
Rollins Tars The Rollins Tars are the athletic teams that represent Rollins College, located in Winter Park, Florida, in NCAA Division II intercollegiate sports. The Tars—an archaic name for a sailor—compete as members of the Sunshine State Conference (S ...
* Tar Heels * Tar pit *
Tarmac Tarmac may refer to: Engineered surfaces * Tarmacadam, a mainly historical tar-based material for macadamising road surfaces, patented in 1902 * Asphalt concrete, a macadamising material using asphalt instead of tar which has largely superseded ta ...
* Tar (tobacco residue)


References


External links

*
Details history and uses of "Rangoon Tar"
{{Authority control Materials Polymers Chemical mixtures Arab inventions