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The Transition Matrix Method (T-matrix method, TMM) is a computational technique of
light scattering In physics, scattering is a wide range of physical processes where moving particles or radiation of some form, such as light or sound, are forced to deviate from a straight trajectory by localized non-uniformities (including particles and radia ...
by nonspherical particles originally formulated by Peter C. Waterman (1928–2012) in 1965. The technique is also known as null field method and extended boundary condition method (EBCM). In the method, matrix elements are obtained by matching boundary conditions for solutions of Maxwell equations. It has been greatly extended to incorporate diverse types of linear media occupying the region enclosing the scatterer. T-matrix method proves to be highly efficient and has been widely used in computing electromagnetic scattering of single and compound particles.


Definition of the T-matrix

The incident and scattered
electric field An electric field (sometimes called E-field) is a field (physics), physical field that surrounds electrically charged particles such as electrons. In classical electromagnetism, the electric field of a single charge (or group of charges) descri ...
are expanded into spherical vector wave functions (SVWF), which are also encountered in
Mie scattering In electromagnetism, the Mie solution to Maxwell's equations (also known as the Lorenz–Mie solution, the Lorenz–Mie–Debye solution or Mie scattering) describes the scattering of an electromagnetic plane wave by a homogeneous sphere. The sol ...
. They are the
fundamental solution In mathematics, a fundamental solution for a linear partial differential operator is a formulation in the language of distribution theory of the older idea of a Green's function (although unlike Green's functions, fundamental solutions do not ...
s of the vector
Helmholtz equation In mathematics, the Helmholtz equation is the eigenvalue problem for the Laplace operator. It corresponds to the elliptic partial differential equation: \nabla^2 f = -k^2 f, where is the Laplace operator, is the eigenvalue, and is the (eigen)fun ...
and can be generated from the scalar fundamental solutions in
spherical coordinates In mathematics, a spherical coordinate system specifies a given point in three-dimensional space by using a distance and two angles as its three coordinates. These are * the radial distance along the line connecting the point to a fixed point ...
, the spherical
Bessel functions Bessel functions, named after Friedrich Bessel who was the first to systematically study them in 1824, are canonical solutions of Bessel's differential equation x^2 \frac + x \frac + \left(x^2 - \alpha^2 \right)y = 0 for an arbitrary complex ...
of the first kind and the spherical Hankel functions. Accordingly, there are two linearly independent sets of solutions denoted as \mathbf^1,\mathbf^1 and \mathbf^3,\mathbf^3, respectively. They are also called regular and outgoing SVWFs, respectively. With this, we can write the incident field as :\mathbf_= \sum_^\infty \sum_^n\left( a_ \mathbf^1_+ b_ \mathbf^1_\right). The scattered field is expanded into radiating SVWFs: :\mathbf_= \sum_^\infty \sum_^n\left( f_ \mathbf^3_+ g_ \mathbf^3_\right). The T-matrix relates the expansion coefficients of the incident field to those of the scattered field. :\begin f_\\ g_\end = T \begin a_ \\ b_ \end The T-matrix is determined by the scatterer shape and material and for a given incident field allows one to calculate the scattered field.


Calculation of the T-matrix

The standard way to calculate the T-matrix is the ''null-field method'', which relies on the Stratton–Chu equations. They basically state that the electromagnetic fields outside a given volume can be expressed as integrals over the surface enclosing the volume involving only the tangential components of the fields on the surface. If the observation point is located inside this volume, the integrals vanish. By making use of the
boundary conditions In the study of differential equations, a boundary-value problem is a differential equation subjected to constraints called boundary conditions. A solution to a boundary value problem is a solution to the differential equation which also satis ...
for the tangential field components on the scatterer surface, :\mathbf \times (\mathbf_ + \mathbf_) =\mathbf \times \mathbf_ and :\mathbf \times (\mathbf_ + \mathbf_) = \mathbf \times \mathbf_, where \mathbf is the
normal vector In geometry, a normal is an object (e.g. a line, ray, or vector) that is perpendicular to a given object. For example, the normal line to a plane curve at a given point is the infinite straight line perpendicular to the tangent line to the cu ...
to the scatterer surface, one can derive an integral representation of the scattered field in terms of the tangential components of the internal fields on the scatterer surface. A similar representation can be derived for the incident field. By expanding the internal field in terms of SVWFs and exploiting their orthogonality on spherical surfaces, one arrives at an expression for the T-matrix. The T-matrix can also be computed from far field data. This approach avoids
numerical stability In the mathematical subfield of numerical analysis, numerical stability is a generally desirable property of numerical algorithms. The precise definition of stability depends on the context: one important context is numerical linear algebra, and ...
issues associated with the null-field method. Several numerical codes for the evaluation of the T-matrix can be found onlin

The T matrix can be found with methods other than null field method and extended boundary condition method (EBCM); therefore, the term "T-matrix method" is infelicitous. Improvement of traditional T-matrix includes Invariant-imbedding T-matrix Method (IITM) by B. R. Johnson. The numerical code of IITM is developed by Lei Bi, based on Mishchenko's EBCM code. It is more powerful than EBCM as it is more efficient and increases the upper limit of particle size during the computation.


References

{{DEFAULTSORT:T-matrix method Computational physics Electromagnetism Electrodynamics Scattering, absorption and radiative transfer (optics) Computational electromagnetics