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The Transition Matrix Method (T-matrix method, TMM) is a computational technique of
light scattering Scattering is a term used in physics to describe a wide range of physical processes where moving particles or radiation of some form, such as light or sound, are forced to deviate from a straight trajectory by localized non-uniformities (including ...
by nonspherical particles originally formulated by Peter C. Waterman (1928–2012) in 1965. The technique is also known as null field method and extended boundary condition method (EBCM). In the method, matrix elements are obtained by matching boundary conditions for solutions of
Maxwell equations Maxwell's equations, or Maxwell–Heaviside equations, are a set of coupled partial differential equations that, together with the Lorentz force law, form the foundation of classical electromagnetism, classical optics, and electric circuits. T ...
. It has been greatly extended to incorporate diverse types of linear media occupying the region enclosing the scatterer. T-matrix method proves to be highly efficient and has been widely-used in computing electromagnetic scattering of single and compound particles.


Definition of the T-matrix

The incident and scattered electric field are expanded into spherical vector wave functions (SVWF), which are also encountered in
Mie scattering The Mie solution to Maxwell's equations (also known as the Lorenz–Mie solution, the Lorenz–Mie–Debye solution or Mie scattering) describes the scattering of an electromagnetic plane wave by a homogeneous sphere. The solution takes the ...
. They are the
fundamental solution In mathematics, a fundamental solution for a linear partial differential operator is a formulation in the language of distribution theory of the older idea of a Green's function (although unlike Green's functions, fundamental solutions do not ad ...
s of the vector Helmholtz equation and can be generated from the scalar fundamental solutions in
spherical coordinates In mathematics, a spherical coordinate system is a coordinate system for three-dimensional space where the position of a point is specified by three numbers: the ''radial distance'' of that point from a fixed origin, its ''polar angle'' measu ...
, the spherical
Bessel functions Bessel functions, first defined by the mathematician Daniel Bernoulli and then generalized by Friedrich Bessel, are canonical solutions of Bessel's differential equation x^2 \frac + x \frac + \left(x^2 - \alpha^2 \right)y = 0 for an arbitrary ...
of the first kind and the spherical Hankel functions. Accordingly, there are two linearly independent sets of solutions denoted as \mathbf^1,\mathbf^1 and \mathbf^3,\mathbf^3, respectively. They are also called regular and outgoing SVWFs, respectively. With this, we can write the incident field as :\mathbf_= \sum_^\infty \sum_^n\left( a_ \mathbf^1_+ b_ \mathbf^1_\right). The scattered field is expanded into radiating SVWFs: :\mathbf_= \sum_^\infty \sum_^n\left( f_ \mathbf^3_+ g_ \mathbf^3_\right). The T-matrix relates the expansion coefficients of the incident field to those of the scattered field. :\begin f_\\ g_\end = T \begin a_ \\ b_ \end The T-matrix is determined by the scatterer shape and material and for a given incident field allows one to calculate the scattered field.


Calculation of the T-matrix

The standard way to calculate the T-matrix is the ''null-field method'', which relies on the Stratton–Chu equations. They basically state that the electromagnetic fields outside a given volume can be expressed as integrals over the surface enclosing the volume involving only the tangential components of the fields on the surface. If the observation point is located inside this volume, the integrals vanish. By making use of the boundary conditions for the tangential field components on the scatterer surface, :\mathbf \times (\mathbf_ + \mathbf_) =\mathbf \times \mathbf_ and :\mathbf \times (\mathbf_ + \mathbf_) = \mathbf \times \mathbf_, where \mathbf is the
normal vector In geometry, a normal is an object such as a line, ray, or vector that is perpendicular to a given object. For example, the normal line to a plane curve at a given point is the (infinite) line perpendicular to the tangent line to the curve at ...
to the scatterer surface, one can derive an integral representation of the scattered field in terms of the tangential components of the internal fields on the scatterer surface. A similar representation can be derived for the incident field. By expanding the internal field in terms of SVWFs and exploiting their orthogonality on spherical surfaces, one arrives at an expression for the T-matrix. The T-matrix can also be computed from far field data. This approach avoids numerical stability issues associated with the null-field method. Several numerical codes for the evaluation of the T-matrix can be found onlin

The T matrix can be found with methods other than null field method and extended boundary condition method (EBCM); therefore, the term ``T-matrix method" is infelicitous.


References

{{DEFAULTSORT:T-matrix method Computational physics Electromagnetism Electrodynamics Scattering, absorption and radiative transfer (optics) Computational electromagnetics