Stratospheric sulfate aerosols (geoengineering)

Stratospheric aerosol injection is a proposed method of solar geoengineering (or solar radiation modification) to reduce global warming. This would introduce aerosols into the stratosphere to create a cooling effect via global dimming and increased albedo, which occurs naturally from volcanic eruptions. It appears that stratospheric aerosol injection, at a moderate intensity, could counter most changes to temperature and precipitation, take effect rapidly, have low direct implementation costs, and be reversible in its direct climatic effects. The Intergovernmental Panel on Climate Change concludes that it "is the most-researched olar geoengineeringmethod, with ''high agreement'' that it could limit warming to below 1.5°C." However, like other solar geoengineering approaches, stratospheric aerosol injection would do so imperfectly and other effects are possible, particularly if used in a suboptimal manner.

Various forms of sulfur have been shown to cool the planet after large volcanic eruptions. However, as of 2021, there has been little research and existing natural aerosols in the stratosphere are not well understood. so there is no leading candidate material. Alumina, calcite and salt are also under consideration. The leading proposed method of delivery is custom aircraft.

Methods

Materials

Various forms of sulfur were proposed as the injected substance, as this is in part how volcanic eruptions cool the planet. Precursor gases such as sulfur dioxide and hydrogen sulfide have been considered. According to estimates, "one kilogram of well placed sulfur in the stratosphere would roughly offset the warming effect of several hundred thousand kilograms of carbon dioxide." One study calculated the impact of injecting sulfate particles, or aerosols, every one to four years into the stratosphere in amounts equal to those lofted by the volcanic eruption of Mount Pinatubo in 1991, but did not address the many technical and political challenges involved in potential solar geoengineering efforts. Use of gaseous sulfuric acid appears to reduce the problem of aerosol growth. Materials such as photophoretic particles, titanium dioxide, and diamond are also under consideration.

Delivery

Various techniques have been proposed for delivering the aerosol or precursor gases. The required altitude to enter the stratosphere is the height of the tropopause, which varies from 11 kilometres (6.8 mi/36,000 ft) at the poles to 17 kilometers (11 mi/58,000 ft) at the equator.

* ''Civilian aircraft'' including the Boeing 747–400 and Gulfstream G550/650, C-37A could be modified at relatively low cost to deliver sufficient amounts of required material according to one study, but a later metastudy suggests a new aircraft would be needed but easy to develop.
* ''Military aircraft'' such as the F15-C variant of the F-15 Eagle have the necessary flight ceiling, but limited payload. Military tanker aircraft such as the KC-135 Stratotanker and KC-10 Extender also have the necessary ceiling and have greater payload capacity.
* Modified ''artillery'' might have the necessary capability, but requires a polluting and expensive propellant charge to loft the payload. Railgun artillery could be a non-polluting alternative.
*''High-altitude balloons'' can be used to lift precursor gases, in tanks, bladders or in the balloons' envelope.

Injection system

The latitude and distribution of injection locations has been discussed by various authors. Whilst a near-equatorial injection regime will allow particles to enter the rising leg of the Brewer-Dobson circulation, several studies have concluded that a broader, and higher-latitude, injection regime will reduce injection mass flow rates and/or yield climatic benefits. Concentration of precursor injection in a single longitude appears to be beneficial, with condensation onto existing particles reduced, giving better control of the size distribution of aerosols resulting. The long residence time of carbon dioxide in the atmosphere may require a millennium-timescale commitment to SRM if aggressive emissions abatement is not pursued simultaneously.

Aerosol formation

Primary aerosol formation, also known as homogeneous aerosol formation, results when gaseous combines with oxygen and water to form aqueous sulfuric acid (H₂SO₄). This acidic liquid solution is in the form of a vapor and condenses onto particles of solid matter, either meteoritic in origin or from dust carried from the surface to the stratosphere. Secondary or heterogeneous aerosol formation occurs when H₂SO₄ vapor condenses onto existing aerosol particles. Existing aerosol particles or droplets also run into each other, creating larger particles or droplets in a process known as coagulation. Warmer atmospheric temperatures also lead to larger particles. These larger particles would be less effective at scattering sunlight because the peak light scattering is achieved by particles with a diameter of 0.3 μm.

Advantages of the technique

The advantages of this approach in comparison to other possible means of solar geoengineering are:

* ''Mimics a natural process'': Stratospheric sulfur aerosols are created by existing natural processes (especially volcanoes), whose impacts have been studied via observations. This contrasts with other, more speculative solar geoengineering techniques which do not have natural analogs (e.g., space sunshade).
* ''Technological feasibility'': In contrast to other proposed solar geoengineering techniques, such as marine cloud brightening, much of the required technology is pre-existing: chemical manufacturing, artillery shells, high-altitude aircraft, weather balloons, etc. Unsolved technical challenges include methods to deliver the material in controlled diameter with good scattering properties.
* ''Scalability'': Some solar geoengineering techniques, such as cool roofs and ice protection, can only provide a limited intervention in the climate due to insufficient scale—one cannot reduce the temperature by more than a certain amount with each technique. Research has suggested that this technique may have a high radiative 'forcing potential'.

Uncertainties

It is uncertain how effective any solar geoengineering technique would be, due to the difficulties modeling their impacts and the complex nature of the global climate system. Certain efficacy issues are specific to stratospheric aerosols.

* ''Lifespan of aerosols'': Tropospheric sulfur aerosols are short-lived. Delivery of particles into the lower stratosphere in the arctic will typically ensure that they remain aloft only for a few weeks or months, as air in this region is predominantly descending. To ensure endurance, higher-altitude delivery is needed, ensuring a typical endurance of several years by enabling injection into the rising leg of the Brewer-Dobson circulation above the tropical tropopause. Further, sizing of particles is crucial to their endurance.
* ''Aerosol delivery'': There are two proposals for how to create a stratospheric sulfate aerosol cloud, either through the release of a precursor gas () or the direct release of sulfuric acid () and these face different challenges. If gas is released it will oxidize to form and then condense to form droplets far from the injection site. Releasing would not allow control over the size of the particles that are formed but would not require a sophisticated release mechanism. Simulations suggest that as the release rate is increased there would be diminishing returns on the cooling effect, as larger particles would be formed which have a shorter lifetime and are less effective scatterers of light. If is released directly then the aerosol particles would form very quickly and in principle the particle size could be controlled although the engineering requirements for this are uncertain. Assuming a technology for direct release could be conceived and developed, it would allow control over the particle size to possibly alleviate some of the inefficiencies associated with release.

Cost

Early studies suggest that stratospheric aerosol injection might have a relatively low direct cost. The annual cost of delivering 5 million tons of an albedo enhancing aerosol (sufficient to offset the expected warming over the next century) to an altitude of 20 to 30 km is estimated at US$2 billion to 8 billion. In comparison, the annual cost estimates for climate damage or emission mitigation range from US$200 billion to 2 trillion.

A 2016 study finds the cost per 1 W/m² of cooling to be between 5–50 billion USD/yr. Because larger particles are less efficient at cooling and drop out of the sky faster, the unit-cooling cost is expected to increase over time as increased dose leads to larger, but less efficient, particles by mechanism such as coalescence and Ostwald ripening. Assume RCP8.5, -5.5 W/m² of cooling would be required by 2100 to maintain 2020 climate. At the dose level required to provide this cooling, the net efficiency per mass of injected aerosols would reduce to below 50% compared to low-level deployment (below 1W/m²). At a total dose of -5.5 W/m², the cost would be between 55-550 billion USD/yr when efficiency reduction is also taken into account, bringing annual expenditure to levels comparable to other mitigation alternatives.

Other possible side effects

Solar geoengineering in general poses various problems and risks. However, certain problems are specific to or more pronounced with stratospheric sulfide injection.

* ''Ozone depletion'': is a potential side effect of sulfur aerosols; and these concerns have been supported by modelling. However, this may only occur if high enough quantities of aerosols drift to, or are deposited in, Polar stratospheric clouds before the levels of CFCs and other ozone destroying gases fall naturally to safe levels because stratospheric aerosols, together with the ozone destroying gases, are responsible for ozone depletion. The injection of other aerosols that may be safer such as calcite has therefore been proposed. The injection of non-sulfide aerosols like calcite (limestone) would also have a cooling effect while counteracting ozone depletion and would be expected to reduce other side effects.
* ''Whitening of the sky'': There would be an effect on the appearance of the sky from stratospheric aerosol injection, notably a slight hazing of blue skies and a change in the appearance of sunsets. How stratospheric aerosol injection may affect clouds remains uncertain. According to a study on cleaner air, the reduction of aerosol pollution has led to solar brightening in Europe and North America, which has been responsible for an increase in U.S. corn production over the past 30 years.
* ''Stratospheric temperature change'': Aerosols can also absorb some radiation from the Sun, the Earth, and the surrounding atmosphere. This changes the surrounding air temperature and could potentially impact the stratospheric circulation, which in turn may impact the surface circulation.
*''Deposition and acid rain'': The surface deposition of sulfate injected into the stratosphere may also have an impact on ecosystems. However, the amount and wide dispersal of injected aerosols means that their impact on particulate concentrations and acidity of precipitation would be very small.
*''Ecological consequences'': The consequences of stratospheric aerosol injection on ecological systems are unknown and potentially vary by ecosystem with differing impacts on marine versus terrestrial biomes.
*''Mixed effects on agriculture'': An historical study in 2018 found that stratospheric sulfate aerosols injected by the volcanic eruptions of Chicón (1982) and Mount Pinatubo (1991) had mixed effects on global crop yields of certain major crops.

Outdoors research

Almost all work to date on stratospheric sulfate injection has been limited to modeling and laboratory work. In 2009, a Russian team tested aerosol formation in the lower troposphere using helicopters. In 2015, David Keith and Gernot Wagner described a potential field experiment, the Stratospheric Controlled Perturbation Experiment (SCoPEx), using stratospheric calcium carbonate injection, but as of October 2020 the time and place had not yet been determined.

In 2012, the Bristol University-led Stratospheric Particle Injection for Climate Engineering (SPICE) project planned on a limited field test in order to evaluate a potential delivery system. The group received support from the EPSRC, NERC and STFC to the tune of £2.1 million and was one of the first UK projects aimed at providing evidence-based knowledge about solar radiation management. Although the field testing was cancelled, the project panel decided to continue the lab-based elements of the project. Furthermore, a consultation exercise was undertaken with members of the
public in a parallel project by Cardiff University, with specific exploration of
attitudes to the SPICE test. This research found that almost all of the participants in the poll were willing to allow the field trial to proceed, but very few were comfortable with the actual use of stratospheric aerosols. A campaign opposing geoengineering led by the ETC Group drafted an open letter calling for the project to be suspended until international agreement is reached, specifically pointing to the upcoming convention of parties to the Convention on Biological Diversity in 2012.

Governance

Most of the existing governance of stratospheric sulfate aerosols is from that which is applicable to solar radiation management more broadly. However, some existing legal instruments would be relevant to stratospheric sulfate aerosols specifically. At the international level, the Convention on Long-Range Transboundary Air Pollution (CLRTAP Convention) obligates those countries which have ratified it to reduce their emissions of particular transboundary air pollutants. Notably, both solar radiation management and climate change (as well as greenhouse gases) could satisfy the definition of "air pollution" which the signatories commit to reduce, depending on their actual negative effects. Commitments to specific values of the pollutants, including sulfates, are made through protocols to the CLRTAP Convention. Full implementation or large scale climate response field tests of stratospheric sulfate aerosols could cause countries to exceed their limits. However, because stratospheric injections would be spread across the globe instead of concentrated in a few nearby countries, and could lead to net reductions in the "air pollution" which the CLRTAP Convention is to reduce.

The stratospheric injection of sulfate aerosols would cause the Vienna Convention for the Protection of the Ozone Layer to be applicable due to their possible deleterious effects on stratospheric ozone. That treaty generally obligates its Parties to enact policies to control activities which "have or are likely to have adverse effects resulting from modification or likely modification of the ozone layer." The Montreal Protocol to the Vienna Convention prohibits the production of certain ozone depleting substances, via phase outs. Sulfates are presently not among the prohibited substances.

In the United States, the Clean Air Act might give the United States Environmental Protection Agency authority to regulate stratospheric sulfate aerosols.

Welsbach seeding

Welsbach seeding is a patented climate engineering method, involving seeding the stratosphere with small (10 to 100 micron) metal oxide particles ( thorium dioxide, aluminium oxide). The purpose of the Welsbach seeding would be to "(reduce) atmospheric warming due to the greenhouse effect resulting from a greenhouse gases layer," by converting radiative energy at near-infrared wavelengths into radiation at far-infrared wavelengths, permitting some of the converted radiation to escape into space, thus cooling the atmosphere. The seeding as described would be performed by airplanes at altitudes between 7 and 13 kilometres.

Patent

The method was patented by Hughes Aircraft Company in 1991, US patent 5003186. Quote from the patent:

"Global warming has been a great concern of many environmental scientists. Scientists believe that the greenhouse effect is responsible for global warming. Greatly increased amounts of heat-trapping gases have been generated since the Industrial Revolution. These gases, such as CO₂, CFC, and methane, accumulate in the atmosphere and allow sunlight to stream in freely but block heat from escaping (greenhouse effect). These gases are relatively transparent to sunshine but absorb strongly the long-wavelength infrared radiation released by the earth."

"This invention relates to a method for the reduction of global warming resulting from the greenhouse effect, and in particular to a method which involves the seeding of the earth's stratosphere with Welsbach-like materials."

Feasibility

The method has never been implemented, and is not considered to be a viable option by current geoengineering experts; in fact the proposed mechanism is considered to violate the second law of thermodynamics. Currently proposed atmospheric geoengineering methods would instead use other aerosols, at considerably higher altitudes.

History

Mikhail Budyko is believed to have been the first, in 1974, to put forth the concept of artificial solar radiation management with stratospheric sulfate aerosols if global warming ever became a pressing issue. Such controversial climate engineering proposals for global dimming have sometimes been called a "Budyko Blanket".

See also

* Carl Auer von Welsbach
* Chemtrail conspiracy theory
* Climate change
* Climate engineering
* Cloud seeding
* Global dimming
* Solar geoengineering
* Termination Shock
* Weather Modification Operations and Research Board

References

Further reading

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External links

What can we do about climate change?
Oceanography magazine

Global Warming and Ice Ages: Prospects for Physics-Based Modulation of Global Change
Lawrence Livermore National Laboratory

The Geoengineering Option:A Last Resort Against Global Warming?
Council on Foreign Relations

Geo-Engineering Climate Change with Sulfate Aerosols
Pacific Northwest National Laboratory

Geo-Engineering Research
Parliamentary Office of Science and Technology

Geo-engineering Options for Mitigating Climate Change
Department of Energy and Climate Change

Unilateral Geoengineering
Council on Foreign Relations
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* {{YouTube, id=EnNerOVUOdo, title=As planet warms, scientists explore 'far out' ways to reduce atmospheric CO2 PBS NewsHour published on March 27, 2019 animation of SCoPEx

Climate change policy
Planetary engineering
Climate engineering