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A solutional cave, solution cave, or karst cave is a
cave A cave or cavern is a natural void in the ground, specifically a space large enough for a human to enter. Caves often form by the weathering of rock and often extend deep underground. The word ''cave'' can refer to smaller openings such as sea ...
usually formed in the soluble rock
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms w ...
. It is the most frequently occurring type of cave. It can also form in other rocks, including
chalk Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. C ...
,
dolomite Dolomite may refer to: *Dolomite (mineral), a carbonate mineral *Dolomite (rock), also known as dolostone, a sedimentary carbonate rock *Dolomite, Alabama, United States, an unincorporated community *Dolomite, California, United States, an unincor ...
,
marble Marble is a metamorphic rock composed of recrystallized carbonate minerals, most commonly calcite or dolomite. Marble is typically not foliated (layered), although there are exceptions. In geology, the term ''marble'' refers to metamorphose ...
, salt beds, and
gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywa ...
.


Process

Bedrock In geology, bedrock is solid rock that lies under loose material ( regolith) within the crust of Earth or another terrestrial planet. Definition Bedrock is the solid rock that underlies looser surface material. An exposed portion of be ...
is dissolved by natural
acid In computer science, ACID ( atomicity, consistency, isolation, durability) is a set of properties of database transactions intended to guarantee data validity despite errors, power failures, and other mishaps. In the context of databases, a se ...
in
groundwater Groundwater is the water present beneath Earth's surface in rock and Pore space in soil, soil pore spaces and in the fractures of stratum, rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit ...
that seeps through bedding-planes, faults, joints and so on. Over geological epochs these openings expand as the walls are dissolved to become caves or cave systems. The portions of a solutional cave that are below the
water table The water table is the upper surface of the zone of saturation. The zone of saturation is where the pores and fractures of the ground are saturated with water. It can also be simply explained as the depth below which the ground is saturated. T ...
or the local level of the groundwater will be flooded.


Limestone caves

The largest and most abundant solutional caves are located in limestone. Limestone caves are often adorned with calcium carbonate formations produced through slow precipitation. These include
flowstone Flowstones are sheetlike deposits of calcite or other carbonate minerals, formed where water flows down the walls or along the floors of a cave. They are typically found in "solution caves", in limestone, where they are the most common speleot ...
s,
stalactite A stalactite (, ; from the Greek 'stalaktos' ('dripping') via ''stalassein'' ('to drip') is a mineral formation that hangs from the ceiling of caves, hot springs, or man-made structures such as bridges and mines. Any material that is soluble ...
s,
stalagmite A stalagmite (, ; from the Greek , from , "dropping, trickling") is a type of rock formation that rises from the floor of a cave due to the accumulation of material deposited on the floor from ceiling drippings. Stalagmites are typicall ...
s,
helictite A helictite is a speleothem (cave-formed mineral) found in a limestone cave that changes its axis from the vertical at one or more stages during its growth. Helictites have a curving or angular form that looks as if they were grown in zero gra ...
s,
soda straw A soda straw (or simply straw) is a speleothem in the form of a hollow mineral cylindrical tube. They are also known as tubular stalactites. Soda straws grow in places where water leaches slowly through cracks in rock, such as on the roofs of c ...
s, calcite rafts and columns. These secondary mineral deposits in caves are called ''
speleothem A speleothem (; ) is a geological formation by mineral deposits that accumulate over time in natural caves. Speleothems most commonly form in calcareous caves due to carbonate dissolution reactions. They can take a variety of forms, dependi ...
s''.


Carbonic acid dissolution

Limestone dissolves under the action of rainwater and groundwater charged with H2CO3 ( carbonic acid) and naturally occurring
organic acid An organic acid is an organic compound with acidic properties. The most common organic acids are the carboxylic acids, whose acidity is associated with their carboxyl group –COOH. Sulfonic acids, containing the group –SO2OH, are ...
s. The dissolution process produces a distinctive landform known as ''
karst Karst is a topography formed from the dissolution of soluble rocks such as limestone, Dolomite (rock), dolomite, and gypsum. It is characterized by underground drainage systems with sinkholes and caves. It has also been documented for more weathe ...
'', characterized by
sinkhole A sinkhole is a depression or hole in the ground caused by some form of collapse of the surface layer. The term is sometimes used to refer to doline, enclosed depressions that are locally also known as ''vrtače'' and shakeholes, and to openi ...
s and underground drainage. Solutional caves in this landform—topography are often called karst caves.


Sulfuric acid dissolution

Lechuguilla Cave At , Lechuguilla Cave is the eighth-longest explored cave in the world and the second deepest () in the continental United States. It is most famous for its unusual geology, rare formations, and pristine condition. The cave is named for the c ...
in
New Mexico ) , population_demonym = New Mexican ( es, Neomexicano, Neomejicano, Nuevo Mexicano) , seat = Santa Fe, New Mexico, Santa Fe , LargestCity = Albuquerque, New Mexico, Albuquerque , LargestMetro = Albuquerque metropolitan area, Tiguex , Offi ...
and nearby Carlsbad Cavern are now believed to be examples of another type of solutional cave. They were formed by H2S (
hydrogen sulfide Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. The under ...
) gas rising from below, where reservoirs of
petroleum Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crud ...
give off sulfurous fumes. This gas mixes with ground water and forms H2SO4 (
sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular fo ...
). The acid then dissolves the limestone from below, rather than from above, by acidic water percolating from the surface.


Examples


Australia

* Jenolan Caves, New South Wales


Taiwan

*
Black Dwarf Cave Black Dwarf Cave. is a cave and tourist attraction in Tianfu Village on Liuqiu Island, off Pingtung County, Taiwan. Its scenic area includes paths around the surrounding coasts and its ticket includes access to some other nearby attractions such ...
, Pingtung County


United States

*
Jewel Cave National Monument Jewel Cave National Monument contains Jewel Cave, currently the third longest cave in the world, with of mapped passageways. It is located approximately west of the town of Custer in Black Hills of South Dakota. It became a national monument ...
, South Dakota *
Mammoth Cave National Park Mammoth Cave National Park is an American national park in west-central Kentucky, encompassing portions of Mammoth Cave, the longest cave system known in the world. Since the 1972 unification of Mammoth Cave with the even-longer system under F ...
, Kentucky *
Russell Cave National Monument Russell Cave National Monument is a U.S. National Monument in northeastern Alabama, United States, close to the town of Bridgeport. The monument was established on May 11, 1961, when 310 acres (1.3 km2) of land were donated by the Natio ...
, Alabama *
Wind Cave National Park Wind Cave National Park is an American national park located north of the town of Hot Springs in western South Dakota. Established on January 3, 1903 by President Theodore Roosevelt, it was the sixth national park in the U.S. and the first c ...
, South Dakota *
Oregon Caves National Monument and Preserve Oregon Caves National Monument and Preserve is a protected area in the northern Siskiyou Mountains of southwestern Oregon in the United States. The 4,554-acre (1,843 ha) park, including the marble cave, is 20 miles (32 km) east of Ca ...
, Oregon


Vietnam

*
Hang Sơn Đoòng Sơn Đoòng cave ( vi, hang Sơn Đoòng, IPA: ), in Phong Nha-Kẻ Bàng National Park, Bố Trạch District, Quảng Bình Province, Vietnam, is one of the world's largest natural caves. Located near the Laos–Vietnam border, Hang Sơn ...
, Quảng Bình Province


References


Sources

* * *


External links

* {{Authority control Karst caves