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Solid fuel refers to various forms of
solid Solid is one of the four fundamental states of matter (the others being liquid, gas, and plasma). The molecules in a solid are closely packed together and contain the least amount of kinetic energy. A solid is characterized by structur ...
material that can be burnt to release energy, providing heat and light through the process of
combustion Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combus ...
. Solid fuels can be contrasted with liquid fuels and
gaseous fuel Fuel gas is any one of a number of fuels that under ordinary conditions are gaseous. Most fuel gases are composed of hydrocarbons (such as methane or propane), hydrogen, carbon monoxide, or mixtures thereof. Such gases are sources energy ...
s. Common examples of solid fuels include
wood Wood is a porous and fibrous structural tissue found in the stems and roots of trees and other woody plants. It is an organic materiala natural composite of cellulose fibers that are strong in tension and embedded in a matrix of lignin ...
,
charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, ...
,
peat Peat (), also known as turf (), is an accumulation of partially Decomposition, decayed vegetation or organic matter. It is unique to natural areas called peatlands, bogs, mires, Moorland, moors, or muskegs. The peatland ecosystem covers and ...
,
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when ...
, hexamine fuel tablets, dry dung, wood pellets,
corn Maize ( ; ''Zea mays'' subsp. ''mays'', from es, maíz after tnq, mahiz), also known as corn (North American and Australian English), is a cereal grain first domesticated by indigenous peoples in southern Mexico about 10,000 years ago. The ...
,
wheat Wheat is a grass widely cultivated for its seed, a cereal grain that is a worldwide staple food. The many species of wheat together make up the genus ''Triticum'' ; the most widely grown is common wheat (''T. aestivum''). The archaeologi ...
, rye, and other grains. Solid fuels are extensively used in rocketry as solid propellants. Solid fuels have been used throughout human history to create fire and solid fuel is still in widespread use throughout the world in the present day.


Types of solid fuels


Wood

Wood fuel can refer to several fuels such as firewood,
charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, ...
, ''wood chips'' sheets, pellets, and sawdust. The particular form used depends upon factors such as source, quantity, quality and application. In many areas, wood is the most easily available form of fuel, requiring no
tool A tool is an object that can extend an individual's ability to modify features of the surrounding environment or help them accomplish a particular task. Although many animals use simple tools, only human beings, whose use of stone tools dates b ...
s in the case of picking up dead wood, or few tools. Today,
burning Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion ...
of wood is the largest use of
energy In physics, energy (from Ancient Greek: ἐνέργεια, ''enérgeia'', “activity”) is the quantitative property that is transferred to a body or to a physical system, recognizable in the performance of work and in the form of ...
derived from a solid fuel
biomass Biomass is plant-based material used as a fuel for heat or electricity production. It can be in the form of wood, wood residues, energy crops, agricultural residues, and waste from industry, farms, and households. Some people use the terms bio ...
. Wood fuel can be used for
cooking Cooking, cookery, or culinary arts is the art, science and craft of using heat to prepare food for consumption. Cooking techniques and ingredients vary widely, from grilling food over an open fire to using electric stoves, to baking in vario ...
and heating, and occasionally for fueling
steam engine A steam engine is a heat engine that performs mechanical work using steam as its working fluid. The steam engine uses the force produced by steam pressure to push a piston back and forth inside a cylinder. This pushing force can be ...
s and steam turbines that generate electricity. Wood may be used indoors in a furnace, stove, or
fireplace A fireplace or hearth is a structure made of brick, stone or metal designed to contain a fire. Fireplaces are used for the relaxing ambiance they create and for heating a room. Modern fireplaces vary in heat efficiency, depending on the desig ...
, or outdoors in a furnace,
campfire A campfire is a fire at a campsite that provides light and warmth, and heat for cooking. It can also serve as a beacon, and an insect and predator deterrent. Established campgrounds often provide a stone or steel fire ring for safety. Campf ...
, or
bonfire A bonfire is a large and controlled outdoor fire, used either for informal disposal of burnable waste material or as part of a celebration. Etymology The earliest recorded uses of the word date back to the late 15th century, with the Catho ...
. As with any
fire Fire is the rapid oxidation of a material (the fuel) in the exothermic chemical process of combustion, releasing heat, light, and various reaction products. At a certain point in the combustion reaction, called the ignition point, flames ...
, burning wood fuel creates numerous by-products, some of which may be useful (heat and steam), and others that are undesirable, irritating or dangerous. There is debate as to whether burning wood can be considered carbon neutral, as technically the wood cannot release more carbon than was sequestered during its growth, although this does not take account of other impacts such as deforestation and rotting has on the
carbon footprint A carbon footprint is the total greenhouse gas (GHG) emissions caused by an individual, event, organization, service, place or product, expressed as carbon dioxide equivalent (CO2e). Greenhouse gases, including the carbon-containing gases carbo ...
. When harvested in a sustainable fashion wood is usually considered to be a renewable solid fuel.


Biomass

Although wood is a form of biomass, the term usually refers to other natural plant material that can be burnt for fuel. Common biomass fuels include waste wheat, straw, nut shells and other fibrous material.


Peat

Peat fuel is an accumulation of partially decayed
vegetation Vegetation is an assemblage of plant species and the ground cover they provide. It is a general term, without specific reference to particular taxa, life forms, structure, spatial extent, or any other specific botanical or geographic charac ...
or organic matter that can be burnt once sufficiently dried. It is used widely in the country districts of
Ireland Ireland ( ; ga, Éire ; Ulster-Scots: ) is an island in the North Atlantic Ocean, in north-western Europe. It is separated from Great Britain to its east by the North Channel, the Irish Sea, and St George's Channel. Ireland is the s ...
and
Scotland Scotland (, ) is a country that is part of the United Kingdom. Covering the northern third of the island of Great Britain, mainland Scotland has a border with England to the southeast and is otherwise surrounded by the Atlantic Ocean to ...
where alternatives are absent or expensive. It has a relatively low
calorific value The heating value (or energy value or calorific value) of a substance, usually a fuel or food (see food energy), is the amount of heat released during the combustion of a specified amount of it. The ''calorific value'' is the total energy releas ...
, even after essential drying.


Coal

Coal is a combustible black or brownish-black
sedimentary rock Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
usually occurring in
rock strata In geology and related fields, a stratum ( : strata) is a layer of rock or sediment characterized by certain lithologic properties or attributes that distinguish it from adjacent layers from which it is separated by visible surfaces known as e ...
in layers or veins called coal beds or coal seams. Throughout history, coal has been used as an energy resource, primarily burned for the production of electricity and heat, and is also used for industrial purposes, such as refining metals. Coal is the largest source of energy for the generation of electricity worldwide, as well as one of the largest worldwide The extraction of coal, its use in energy production and its byproducts are all associated with
environmental A biophysical environment is a biotic and abiotic surrounding of an organism or population, and consequently includes the factors that have an influence in their survival, development, and evolution. A biophysical environment can vary in scal ...
and
health effects Health effects (or health impacts) are changes in health resulting from exposure to a source. Health effects are an important consideration in many areas, such as hygiene, pollution studies, occupational safety and health, ( utrition and health sc ...
. Variations such as smokeless coal can be formed naturally in the form of
anthracite Anthracite, also known as hard coal, and black coal, is a hard, compact variety of coal that has a submetallic luster. It has the highest carbon content, the fewest impurities, and the highest energy density of all types of coal and is the hig ...
, a metamorphosed type of coal with a very high carbon content that gives off a smokeless flame when set alight. It is an important type of
smokeless fuel Smokeless fuel is a type of solid fuel which either does not emit visible smoke, or emits minimal amounts, during combustion. These types of fuel are becoming increasingly popular in areas which ban the use of coal and other fuels such as unseaso ...
.


Coke

Coke is a fuel with few impurities and a high
carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon ma ...
content, usually made from
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when ...
. It is the solid
carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon ma ...
aceous material derived from
destructive distillation Destruction may refer to: Concepts * Destruktion, a term from the philosophy of Martin Heidegger * Destructive narcissism, a pathological form of narcissism * Self-destructive behaviour, a widely used phrase that ''conceptualises'' certain kind ...
of low-ash, low-sulfur
bituminous coal Bituminous coal, or black coal, is a type of coal containing a tar-like substance called bitumen or asphalt. Its coloration can be black or sometimes dark brown; often there are well-defined bands of bright and dull material within the seams. It ...
. Cokes made from coal are grey, hard, and porous. While coke can be formed naturally, the commonly used form is man-made. The form known as
petroleum coke Petroleum coke, abbreviated coke or petcoke, is a final carbon-rich solid material that derives from oil refining, and is one type of the group of fuels referred to as cokes. Petcoke is the coke that, in particular, derives from a final crack ...
, or pet coke, is derived from oil refinery coker units or other cracking processes.


Smokeless fuel

Solid fuels which produce little smoke or volatiles are made from powdered
anthracite Anthracite, also known as hard coal, and black coal, is a hard, compact variety of coal that has a submetallic luster. It has the highest carbon content, the fewest impurities, and the highest energy density of all types of coal and is the hig ...
coal and supplied in the form of briquettes usually for domestic use either in stoves or open fireplaces. The fuel is replacing coal as a fuel for open fires because of the reduction in particulate emissions and its increased efficiency. Smokeless fuel burns at a higher temperature and more slowly than a coal fire. The term also includes
charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, ...
, made by restricted combustion of dry wood, is also widely used for open air
barbecue Barbecue or barbeque (informally BBQ in the UK, US, and Canada, barbie in Australia and braai in South Africa) is a term used with significant regional and national variations to describe various cooking methods that use live fire and smoke ...
s with food cooked on an open fire.


Municipal waste

Municipal solid waste commonly known as trash or garbage in the
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country Continental United States, primarily located in North America. It consists of 50 U.S. state, states, a Washington, D.C., ...
and as rubbish in Britain, is a
waste type Waste comes in many different forms and may be categorized in a variety of ways. The types listed here are not necessarily exclusive and there may be considerable overlap so that one waste entity may fall into one to many types. * Agricultural w ...
consisting of everyday items that are discarded by the public. It can be burnt to create electrical energy by careful control of the waste stream. With the correct technology it can also be gasified and converted to a viable fuel source. However, this is technology heavy and can only be used where the waste is known not to contain toxic materials. ilson and Burgh. (2008). Energizing Our Future: Rational Choices For The 21st Century. New Jersey: John Wiley & Sons, Inc./ref>


Rocket propellant

Solid rocket propellant consists of a solid oxidizer (such as ammonium nitrate) bound with flakes or powders of energy compounds (such as RDX) plus binders, plasticizers, stabilizers, and other additives. Solid propellant is much easier to store and handle than liquid propellant. It also has a higher energy density so it does not require as large of a space for the same amount of stored energy.


Calorific value

The heat available from each type of fuel is very variable, and depends on the
carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon ma ...
and
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-to ...
content, as well as non-combustible or ash and water content. One measure of the heat produced by burning is the
Heat of combustion The heating value (or energy value or calorific value) of a substance, usually a fuel or food (see food energy), is the amount of heat released during the combustion of a specified amount of it. The ''calorific value'' is the total energy rele ...
, an exact measure usually determined using bomb calorimetry and demanding complete combustion to carbon dioxide and water. Gaseous fuels like
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane ...
have higher values than solid fuels like
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when ...
, and
peat Peat (), also known as turf (), is an accumulation of partially Decomposition, decayed vegetation or organic matter. It is unique to natural areas called peatlands, bogs, mires, Moorland, moors, or muskegs. The peatland ecosystem covers and ...
exhibits the lowest value of all common fuels. Thus methane has an HHV (Higher heating value) of 55.50 MJ/kg, the highest value of common fuels.
Diesel fuel Diesel fuel , also called diesel oil, is any liquid fuel specifically designed for use in a diesel engine, a type of internal combustion engine in which fuel ignition takes place without a spark as a result of compression of the inlet air and ...
has an HHV value of 44.80 MJ/kg and
anthracite coal Anthracite, also known as hard coal, and black coal, is a hard, compact variety of coal that has a submetallic luster. It has the highest carbon content, the fewest impurities, and the highest energy density of all types of coal and is the hig ...
a value of 32.50 MJ/kg. Moisture and ash-free firewood has a lower value of 21.70 MJ/kg while dry
peat Peat (), also known as turf (), is an accumulation of partially Decomposition, decayed vegetation or organic matter. It is unique to natural areas called peatlands, bogs, mires, Moorland, moors, or muskegs. The peatland ecosystem covers and ...
has the lowest value of all common fuels of about 15.00 MJ/kg. These are somewhat ideal values and the actual heat realized by any fuel will depend on the
fireplace A fireplace or hearth is a structure made of brick, stone or metal designed to contain a fire. Fireplaces are used for the relaxing ambiance they create and for heating a room. Modern fireplaces vary in heat efficiency, depending on the desig ...
or
combustion chamber A combustion chamber is part of an internal combustion engine in which the fuel/air mix is burned. For steam engines, the term has also been used for an extension of the firebox which is used to allow a more complete combustion process. Intern ...
used and its design for example. But they do give a useful guide to the heat available from any fuel. Dry wood has roughly two thirds the
calorific value The heating value (or energy value or calorific value) of a substance, usually a fuel or food (see food energy), is the amount of heat released during the combustion of a specified amount of it. The ''calorific value'' is the total energy releas ...
of coal so a greater weight is needed to make the same amount of heat.


Benefits and disadvantages

Solid fuels, compared to liquid fuels or gaseous fuels, are often cheaper, easier to extract, more stable to transport and in many places are more readily available.
Coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when ...
, in particular, is utilized in the generation of 38.1% of the world’s
electricity Electricity is the set of physical phenomena associated with the presence and motion of matter that has a property of electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as describe ...
because it is less expensive than its liquid and gas counterparts. However, solid fuels are also heavier to transport, require more destructive methods to extract/burn and often have higher carbon, nitrate and sulphate emissions. With the exception of sustainable wood/biomass solid fuel is normally considered non-renewable as it requires thousands of years to form. Solid fuels are composed of organic materials and can contribute to poor air quality. The burning of solid fuels releases more organic aerosol than
liquefied petroleum gas Liquefied petroleum gas (LPG or LP gas) is a fuel gas which contains a flammable mixture of hydrocarbon gases, specifically propane, propylene, butylene, isobutane and n-butane. LPG is used as a fuel gas in heating appliances, cookin ...
and releases many volatile organic compounds, which can contribute to poor air quality through the formation of secondary pollutants such as ground level ozone and
secondary organic aerosol A secondary organic aerosol (SOA) is a molecule produced via oxidation over several generations of a parent organic molecule. In contrast to primary organic aerosols, which are emitted directly from the biosphere, secondary organic aerosols are eith ...
. The emissions from solid fuels are likely drivers of poor air quality in regions where solid fuels are a dominant
fuel A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work. The concept was originally applied solely to those materials capable of releasing chemical energy b ...
source, with
volatile organic compound Volatile organic compounds (VOCs) are organic compounds that have a high vapour pressure at room temperature. High vapor pressure correlates with a low boiling point, which relates to the number of the sample's molecules in the surrounding air, a ...
emissions from solid fuels significantly more reactive with the hydroxyl radical compared to those from
liquefied petroleum gas Liquefied petroleum gas (LPG or LP gas) is a fuel gas which contains a flammable mixture of hydrocarbon gases, specifically propane, propylene, butylene, isobutane and n-butane. LPG is used as a fuel gas in heating appliances, cookin ...
.


See also

* Bagasse *
Biofuel Biofuel is a fuel that is produced over a short time span from biomass, rather than by the very slow natural processes involved in the formation of fossil fuels, such as oil. According to the United States Energy Information Administration ...
*
Fossil fuel A fossil fuel is a hydrocarbon-containing material formed naturally in the Earth's crust from the remains of dead plants and animals that is extracted and burned as a fuel. The main fossil fuels are coal, oil, and natural gas. Fossil fuels ma ...
* Synthetic fuel *
Nuclear power Nuclear power is the use of nuclear reactions to produce electricity. Nuclear power can be obtained from nuclear fission, nuclear decay and nuclear fusion reactions. Presently, the vast majority of electricity from nuclear power is produced b ...


References


Further reading

* "CO2 Emissions (metric tons per capita)." Data. N.p., n.d. Web. 25 March 2014. * "Coal Facts." Coal Facts. N.p., n.d. Web. 25 March 2014. * "Heating Options for Your Home Buying Guide." Electricity, Gas or Solid Fuel? - CHOICE Reviews Heating Options for Your Home. N.p., n.d. Web. 25 March 2014.


External links

* {{Authority control