HOME

TheInfoList



OR:

Soil, also commonly referred to as earth or
dirt Dirt is an unclean matter, especially when in contact with a person's clothes, skin, or possessions. In such cases, they are said to become dirty. Common types of dirt include: * Debris: scattered pieces of waste or remains * Dust: a genera ...
, is a
mixture In chemistry, a mixture is a material made up of two or more different chemical substances which are not chemically bonded. A mixture is the physical combination of two or more substances in which the identities are retained and are mixed in the ...
of
organic matter Organic matter, organic material, or natural organic matter refers to the large source of carbon-based compounds found within natural and engineered, terrestrial, and aquatic environments. It is matter composed of organic compounds that have c ...
,
minerals In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ...
,
gas Gas is one of the four fundamental states of matter (the others being solid, liquid, and plasma). A pure gas may be made up of individual atoms (e.g. a noble gas like neon), elemental molecules made from one type of atom (e.g. oxygen), or ...
es,
liquid A liquid is a nearly incompressible fluid that conforms to the shape of its container but retains a (nearly) constant volume independent of pressure. As such, it is one of the four fundamental states of matter (the others being solid, gas, an ...
s, and
organism In biology, an organism () is any living system that functions as an individual entity. All organisms are composed of cells ( cell theory). Organisms are classified by taxonomy into groups such as multicellular animals, plants, and fung ...
s that together support
life Life is a quality that distinguishes matter that has biological processes, such as signaling and self-sustaining processes, from that which does not, and is defined by the capacity for growth, reaction to stimuli, metabolism, energy trans ...
. Some scientific definitions distinguish ''dirt'' from ''soil'' by restricting the former term specifically to displaced soil. Soil consists of a solid phase of minerals and organic matter (the soil matrix), as well as a
porous Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
phase that holds
gases Gas is one of the four fundamental states of matter (the others being solid, liquid, and plasma). A pure gas may be made up of individual atoms (e.g. a noble gas like neon), elemental molecules made from one type of atom (e.g. oxygen), or ...
(the soil atmosphere) and
water Water (chemical formula ) is an Inorganic compound, inorganic, transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living ...
(the soil solution). Accordingly, soil is a three-
state State may refer to: Arts, entertainment, and media Literature * ''State Magazine'', a monthly magazine published by the U.S. Department of State * ''The State'' (newspaper), a daily newspaper in Columbia, South Carolina, United States * '' Our ...
system of solids, liquids, and gases. Soil is a product of several factors: the influence of
climate Climate is the long-term weather pattern in an area, typically averaged over 30 years. More rigorously, it is the mean and variability of meteorological variables over a time spanning from months to millions of years. Some of the meteorologi ...
, relief (elevation, orientation, and slope of terrain), organisms, and the soil's
parent material Parent material is the underlying geological material (generally bedrock or a superficial or drift deposit) in which soil horizons form. Soils typically inherit a great deal of structure and minerals from their parent material, and, as such, are ...
s (original minerals) interacting over time. It continually undergoes development by way of numerous physical, chemical and biological processes, which include
weathering Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement), ...
with associated
erosion Erosion is the action of surface processes (such as water flow or wind) that removes soil, rock, or dissolved material from one location on the Earth's crust, and then transports it to another location where it is deposited. Erosion is distin ...
. Given its complexity and strong internal
connectedness In mathematics, connectedness is used to refer to various properties meaning, in some sense, "all one piece". When a mathematical object has such a property, we say it is connected; otherwise it is disconnected. When a disconnected object can be ...
, soil ecologists regard soil as an
ecosystem An ecosystem (or ecological system) consists of all the organisms and the physical environment with which they interact. These biotic and abiotic components are linked together through nutrient cycles and energy flows. Energy enters the syst ...
. Most soils have a dry
bulk density Bulk density, also called apparent density or volumetric density, is a property of powders, granules, and other "divided" solids, especially used in reference to mineral components (soil, gravel), chemical substances, (pharmaceutical) ingredients, ...
(density of soil taking into account voids when dry) between 1.1 and 1.6 g/cm3, though the soil particle density is much higher, in the range of 2.6 to 2.7 g/cm3. Little of the soil of
planet Earth Earth is the third planet from the Sun and the only astronomical object known to harbor life. While large volumes of water can be found throughout the Solar System, only Earth sustains liquid surface water. About 71% of Earth's surface ...
is older than the
Pleistocene The Pleistocene ( , often referred to as the ''Ice age'') is the geological epoch that lasted from about 2,580,000 to 11,700 years ago, spanning the Earth's most recent period of repeated glaciations. Before a change was finally confirmed in ...
and none is older than the
Cenozoic The Cenozoic ( ; ) is Earth's current geological era, representing the last 66million years of Earth's history. It is characterised by the dominance of mammals, birds and flowering plants, a cooling and drying climate, and the current configurat ...
, although fossilized soils are preserved from as far back as the
Archean The Archean Eon ( , also spelled Archaean or Archæan) is the second of four geologic eons of Earth's history, representing the time from . The Archean was preceded by the Hadean Eon and followed by the Proterozoic. The Earth during the Archea ...
. The pedosphere interfaces with the
lithosphere A lithosphere () is the rigid, outermost rocky shell of a terrestrial planet or natural satellite. On Earth, it is composed of the crust and the portion of the upper mantle that behaves elastically on time scales of up to thousands of years o ...
, the
hydrosphere The hydrosphere () is the combined mass of water found on, under, and above the surface of a planet, minor planet, or natural satellite. Although Earth's hydrosphere has been around for about 4 billion years, it continues to change in shape. Th ...
, the
atmosphere An atmosphere () is a layer of gas or layers of gases that envelop a planet, and is held in place by the gravity of the planetary body. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A s ...
, and the
biosphere The biosphere (from Greek βίος ''bíos'' "life" and σφαῖρα ''sphaira'' "sphere"), also known as the ecosphere (from Greek οἶκος ''oîkos'' "environment" and σφαῖρα), is the worldwide sum of all ecosystems. It can also be ...
. Collectively, Earth's body of soil, called the
pedosphere The pedosphere (from Greek ''pedon'' "ground" or "earth" and ''sphaira'' "sphere") is the outermost layer of the Earth that is composed of soil and subject to soil formation processes. It exists at the interface of the lithosphere, atmosphere, h ...
, has four important functions: * as a medium for plant growth * as a means of
water storage Water storage is a broad term referring to storage of both potable water for consumption, and non potable water for use in agriculture. In both developing countries and some developed countries found in tropical climates, there is a need to store po ...
, supply and purification * as a modifier of
Earth's atmosphere The atmosphere of Earth is the layer of gases, known collectively as air, retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth protects life on Earth by creating pressure allowing for ...
* as a habitat for organisms All of these functions, in their turn, modify the soil and its properties.
Soil science Soil science is the study of soil as a natural resource on the surface of the Earth including soil formation, classification and mapping; physical, chemical, biological, and fertility properties of soils; and these properties in relation to th ...
has two basic branches of study:
edaphology Edaphology (from Greek , ''edaphos'', "ground",, '' -logia'') is concerned with the influence of soils on living beings, particularly plants. It is one of two main divisions of soil science, the other being pedology. Edaphology includes the stud ...
and
pedology Pedology (from Greek: πέδον, ''pedon'', "soil"; and λόγος, ''logos'', "study") is a discipline within soil science which focuses on understanding and characterizing soil formation, evolution, and the theoretical frameworks for modeling ...
. ''Edaphology'' studies the influence of soils on living things. ''Pedology'' focuses on the formation, description (morphology), and classification of soils in their natural environment. In engineering terms, soil is included in the broader concept of regolith, which also includes other loose material that lies above the bedrock, as can be found on the
Moon The Moon is Earth's only natural satellite. It is the fifth largest satellite in the Solar System and the largest and most massive relative to its parent planet, with a diameter about one-quarter that of Earth (comparable to the width of ...
and other celestial objects.


Processes

Soil is a major component of the
Earth Earth is the third planet from the Sun and the only astronomical object known to harbor life. While large volumes of water can be found throughout the Solar System, only Earth sustains liquid surface water. About 71% of Earth's surface ...
's
ecosystem An ecosystem (or ecological system) consists of all the organisms and the physical environment with which they interact. These biotic and abiotic components are linked together through nutrient cycles and energy flows. Energy enters the syst ...
. The world's ecosystems are impacted in far-reaching ways by the processes carried out in the soil, with effects ranging from
ozone depletion Ozone depletion consists of two related events observed since the late 1970s: a steady lowering of about four percent in the total amount of ozone in Earth's atmosphere, and a much larger springtime decrease in stratospheric ozone (the ozone la ...
and
global warming In common usage, climate change describes global warming—the ongoing increase in global average temperature—and its effects on Earth's climate system. Climate change in a broader sense also includes previous long-term changes to E ...
to
rainforest destruction Rainforests are characterized by a closed and continuous tree canopy, moisture-dependent vegetation, the presence of epiphytes and lianas and the absence of wildfire. Rainforest can be classified as tropical rainforest or temperate rainforest, ...
and
water pollution Water pollution (or aquatic pollution) is the contamination of water bodies, usually as a result of human activities, so that it negatively affects its uses. Water bodies include lakes, rivers, oceans, aquifers, reservoirs and groundwater. Wate ...
. With respect to Earth's
carbon cycle The carbon cycle is the biogeochemical cycle by which carbon is exchanged among the biosphere, pedosphere, geosphere, hydrosphere, and atmosphere of the Earth. Carbon is the main component of biological compounds as well as a major componen ...
, soil acts as an important carbon reservoir, and it is potentially one of the most reactive to human disturbance and climate change. As the planet warms, it has been predicted that soils will add carbon dioxide to the atmosphere due to increased
biological Biology is the scientific study of life. It is a natural science with a broad scope but has several unifying themes that tie it together as a single, coherent field. For instance, all organisms are made up of cells that process hereditary in ...
activity at higher temperatures, a
positive feedback Positive feedback (exacerbating feedback, self-reinforcing feedback) is a process that occurs in a feedback loop which exacerbates the effects of a small disturbance. That is, the effects of a perturbation on a system include an increase in the ...
(amplification). This prediction has, however, been questioned on consideration of more recent knowledge on soil carbon turnover. Soil acts as an engineering medium, a habitat for
soil organisms Soil biology is the study of microbial and faunal activity and ecology in soil. Soil life, soil biota, soil fauna, or edaphon is a collective term that encompasses all organisms that spend a significant portion of their life cycle within a soil ...
, a recycling system for
nutrients A nutrient is a substance used by an organism to survive, grow, and reproduce. The requirement for dietary nutrient intake applies to animals, plants, fungi, and protists. Nutrients can be incorporated into cells for metabolic purposes or excret ...
and
organic waste Biodegradable waste includes any organic matter in waste which can be broken down into carbon dioxide, water, methane or simple organic molecules by micro-organisms and other living things by composting, aerobic digestion, anaerobic digestion ...
s, a regulator of
water quality Water quality refers to the chemical, physical, and biological characteristics of water based on the standards of its usage. It is most frequently used by reference to a set of standards against which compliance, generally achieved through tr ...
, a modifier of atmospheric composition, and a medium for
plant growth Important structures in plant development are buds, shoots, roots, leaves, and flowers; plants produce these tissues and structures throughout their life from meristems located at the tips of organs, or between mature tissues. Thus, a living plant a ...
, making it a critically important provider of
ecosystem services Ecosystem services are the many and varied benefits to humans provided by the natural environment and healthy ecosystems. Such ecosystems include, for example, agroecosystems, forest ecosystem, grassland ecosystems, and aquatic ecosystems. ...
. Since soil has a tremendous range of available niches and
habitat In ecology, the term habitat summarises the array of resources, physical and biotic factors that are present in an area, such as to support the survival and reproduction of a particular species. A species habitat can be seen as the physical ...
s, it contains a prominent part of the Earth's
genetic diversity Genetic diversity is the total number of genetic characteristics in the genetic makeup of a species, it ranges widely from the number of species to differences within species and can be attributed to the span of survival for a species. It is dis ...
. A gram of soil can contain billions of organisms, belonging to thousands of species, mostly microbial and largely still unexplored. Soil has a
mean There are several kinds of mean in mathematics, especially in statistics. Each mean serves to summarize a given group of data, often to better understand the overall value (magnitude and sign) of a given data set. For a data set, the ''arithm ...
prokaryotic A prokaryote () is a single-celled organism that lacks a nucleus and other membrane-bound organelles. The word ''prokaryote'' comes from the Greek πρό (, 'before') and κάρυον (, 'nut' or 'kernel').Campbell, N. "Biology:Concepts & Connec ...
density of roughly 108 organisms per gram, whereas the ocean has no more than 107 prokaryotic organisms per milliliter (gram) of seawater.
Organic carbon Total organic carbon (TOC) is the amount of carbon found in an organic compound and is often used as a non-specific indicator of water quality or cleanliness of pharmaceutical manufacturing equipment. TOC may also refer to the amount of organic c ...
held in soil is eventually returned to the atmosphere through the process of
respiration Respiration may refer to: Biology * Cellular respiration, the process in which nutrients are converted into useful energy in a cell ** Anaerobic respiration, cellular respiration without oxygen ** Maintenance respiration, the amount of cellula ...
carried out by
heterotrophic A heterotroph (; ) is an organism that cannot produce its own food, instead taking nutrition from other sources of organic carbon, mainly plant or animal matter. In the food chain, heterotrophs are primary, secondary and tertiary consumers, but ...
organisms, but a substantial part is retained in the soil in the form of soil organic matter; tillage usually increases the rate of
soil respiration Soil respiration refers to the production of carbon dioxide when soil organisms respire. This includes respiration of plant roots, the rhizosphere, microbes and fauna. Soil respiration is a key ecosystem process that releases carbon from the ...
, leading to the depletion of soil organic matter. Since plant roots need oxygen, aeration is an important characteristic of soil. This ventilation can be accomplished via networks of interconnected soil pores, which also absorb and hold rainwater making it readily available for uptake by plants. Since plants require a nearly continuous supply of water, but most regions receive sporadic rainfall, the water-holding capacity of soils is vital for plant survival. Soils can effectively remove impurities, kill disease agents, and degrade
contaminants Contamination is the presence of a constituent, impurity, or some other undesirable element that spoils, corrupts, infects, makes unfit, or makes inferior a material, physical body, natural environment, workplace, etc. Types of contamination Wi ...
, this latter property being called natural attenuation. Typically, soils maintain a net absorption of
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well ...
and
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on ...
and undergo a net release of carbon dioxide and
nitrous oxide Nitrous oxide (dinitrogen oxide or dinitrogen monoxide), commonly known as laughing gas, nitrous, or nos, is a chemical compound, an oxide of nitrogen with the formula . At room temperature, it is a colourless non-flammable gas, and has a ...
. Soils offer plants physical support, air, water, temperature moderation, nutrients, and protection from toxins. Soils provide readily available nutrients to plants and animals by converting dead organic matter into various nutrient forms.


Composition

A typical soil is about 50% solids (45% mineral and 5% organic matter), and 50% voids (or pores) of which half is occupied by water and half by gas. The percent soil mineral and organic content can be treated as a constant (in the short term), while the percent soil water and gas content is considered highly variable whereby a rise in one is simultaneously balanced by a reduction in the other. The pore space allows for the infiltration and movement of air and water, both of which are critical for life existing in soil. Compaction, a common problem with soils, reduces this space, preventing air and water from reaching plant roots and soil organisms. Given sufficient time, an undifferentiated soil will evolve a
soil profile A soil horizon is a layer parallel to the soil surface whose physical, chemical and biological characteristics differ from the layers above and beneath. Horizons are defined in many cases by obvious physical features, mainly colour and texture. ...
which consists of two or more layers, referred to as soil horizons. These differ in one or more properties such as in their
texture Texture may refer to: Science and technology * Surface texture, the texture means smoothness, roughness, or bumpiness of the surface of an object * Texture (roads), road surface characteristics with waves shorter than road roughness * Texture ( ...
,
structure A structure is an arrangement and organization of interrelated elements in a material object or system, or the object or system so organized. Material structures include man-made objects such as buildings and machines and natural objects such as ...
,
density Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' can also be used. Mathematicall ...
, porosity, consistency, temperature, color, and reactivity. The horizons differ greatly in thickness and generally lack sharp boundaries; their development is dependent on the type of
parent material Parent material is the underlying geological material (generally bedrock or a superficial or drift deposit) in which soil horizons form. Soils typically inherit a great deal of structure and minerals from their parent material, and, as such, are ...
, the processes that modify those parent materials, and the soil-forming factors that influence those processes. The biological influences on soil properties are strongest near the surface, though the geochemical influences on soil properties increase with depth. Mature soil profiles typically include three basic master horizons: A, B, and C. The
solum The solum (plural, sola) in soil science consists of the surface and subsoil layers that have undergone the same soil forming conditions. The base of the solum is the relatively unweathered parent material. Solum and soils are not synonymous. Som ...
normally includes the A and B horizons. The living component of the soil is largely confined to the solum, and is generally more prominent in the A horizon. It has been suggested that the ''pedon'', a column of soil extending vertically from the surface to the underlying parent material and large enough to show the characteristics of all its horizons, could be subdivided in the ''humipedon'' (the living part, where most soil organisms are dwelling, corresponding to the ''humus form''), the ''copedon'' (in intermediary position, where most
weathering Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement), ...
of minerals takes place) and the ''lithopedon'' (in contact with the subsoil). The soil texture is determined by the relative proportions of the individual particles of
sand Sand is a granular material composed of finely divided mineral particles. Sand has various compositions but is defined by its grain size. Sand grains are smaller than gravel and coarser than silt. Sand can also refer to a textural class of s ...
,
silt Silt is granular material of a size between sand and clay and composed mostly of broken grains of quartz. Silt may occur as a soil (often mixed with sand or clay) or as sediment mixed in suspension with water. Silt usually has a floury feel whe ...
, and
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay parti ...
that make up the soil. The interaction of the individual mineral particles with organic matter, water, gases via biotic and
abiotic In biology and ecology, abiotic components or abiotic factors are non-living chemical and physical parts of the environment that affect living organisms and the functioning of ecosystems. Abiotic factors and the phenomena associated with them unde ...
processes causes those particles to flocculate (stick together) to form aggregates or
ped Peds are aggregates of soil particles formed as a result of pedogenic processes; this natural organization of particles forms discrete units separated by pores or voids. The term is generally used for macroscopic (visible; i.e. greater than 1 mm i ...
s. Where these aggregates can be identified, a soil can be said to be developed, and can be described further in terms of color, porosity, consistency, reaction (
acidity In computer science, ACID ( atomicity, consistency, isolation, durability) is a set of properties of database transactions intended to guarantee data validity despite errors, power failures, and other mishaps. In the context of databases, a sequ ...
), etc. Water is a critical agent in soil development due to its involvement in the dissolution, precipitation, erosion, transport, and deposition of the materials of which a soil is composed. The mixture of water and dissolved or suspended materials that occupy the soil
pore space Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
is called the soil solution. Since soil water is never pure water, but contains hundreds of dissolved organic and mineral substances, it may be more accurately called the soil solution. Water is central to the dissolution,
precipitation In meteorology, precipitation is any product of the condensation of atmospheric water vapor that falls under gravitational pull from clouds. The main forms of precipitation include drizzle, rain, Rain and snow mixed, sleet, snow, ice pellets, ...
and leaching of minerals from the
soil profile A soil horizon is a layer parallel to the soil surface whose physical, chemical and biological characteristics differ from the layers above and beneath. Horizons are defined in many cases by obvious physical features, mainly colour and texture. ...
. Finally, water affects the type of vegetation that grows in a soil, which in turn affects the development of the soil, a complex feedback which is exemplified in the dynamics of banded vegetation patterns in semi-arid regions. Soils supply
plants Plants are predominantly photosynthetic eukaryotes of the kingdom Plantae. Historically, the plant kingdom encompassed all living things that were not animals, and included algae and fungi; however, all current definitions of Plantae exclude ...
with
nutrient A nutrient is a substance used by an organism to survive, grow, and reproduce. The requirement for dietary nutrient intake applies to animals, plants, fungi, and protists. Nutrients can be incorporated into cells for metabolic purposes or excrete ...
s, most of which are held in place by particles of
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay parti ...
and organic matter (
colloid A colloid is a mixture in which one substance consisting of microscopically dispersed insoluble particles is suspended throughout another substance. Some definitions specify that the particles must be dispersed in a liquid, while others extend ...
s) The nutrients may be
adsorbed Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a f ...
on clay mineral surfaces, bound within clay minerals ( absorbed), or bound within organic compounds as part of the living
organisms In biology, an organism () is any living system that functions as an individual entity. All organisms are composed of cells ( cell theory). Organisms are classified by taxonomy into groups such as multicellular animals, plants, and fung ...
or dead soil organic matter. These bound nutrients interact with soil water to
buffer Buffer may refer to: Science * Buffer gas, an inert or nonflammable gas * Buffer solution, a solution used to prevent changes in pH * Buffering agent, the weak acid or base in a buffer solution * Lysis buffer, in cell biology * Metal ion buffer ...
the soil solution composition (attenuate changes in the soil solution) as soils wet up or dry out, as plants take up nutrients, as salts are leached, or as acids or alkalis are added. Plant nutrient availability is affected by
soil pH Soil pH is a measure of the acidity or basicity (alkalinity) of a soil. Soil pH is a key characteristic that can be used to make informative analysis both qualitative and quantitatively regarding soil characteristics. pH is defined as the ne ...
, which is a measure of the
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxi ...
ion activity in the soil solution. Soil pH is a function of many soil forming factors, and is generally lower (more acid) where weathering is more advanced. Most plant nutrients, with the exception of
nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at sevent ...
, originate from the minerals that make up the soil parent material. Some nitrogen originates from rain as dilute
nitric acid Nitric acid is the inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but older samples tend to be yellow cast due to decomposition into oxides of nitrogen. Most commercially available nitric ...
and
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous wa ...
, but most of the nitrogen is available in soils as a result of
nitrogen fixation Nitrogen fixation is a chemical process by which molecular nitrogen (), with a strong triple covalent bond, in the air is converted into ammonia () or related nitrogenous compounds, typically in soil or aquatic systems but also in industry. A ...
by bacteria. Once in the soil-plant system, most nutrients are recycled through living organisms, plant and microbial residues (soil organic matter), mineral-bound forms, and the soil solution. Both living soil organisms (microbes, animals and plant roots) and soil organic matter are of critical importance to this recycling, and thereby to
soil formation Soil formation, also known as pedogenesis, is the process of soil genesis as regulated by the effects of place, environment, and history. Biogeochemical processes act to both create and destroy order (anisotropy) within soils. These alterations ...
and
soil fertility Soil fertility refers to the ability of soil to sustain agricultural plant growth, i.e. to provide plant habitat and result in sustained and consistent yields of high quality.
. Microbial soil enzymes may release nutrients from minerals or organic matter for use by plants and other microorganisms, sequester (incorporate) them into living cells, or cause their loss from the soil by volatilisation (loss to the atmosphere as gases) or leaching.


Formation

Soil is said to be formed when organic matter has accumulated and colloids are washed downward, leaving deposits of clay,
humus In classical soil science, humus is the dark organic matter in soil that is formed by the decomposition of plant and animal matter. It is a kind of soil organic matter. It is rich in nutrients and retains moisture in the soil. Humus is the Latin ...
,
iron oxide Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of which ...
,
carbonate A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate g ...
, and
gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywa ...
, producing a distinct layer called the B horizon. This is a somewhat arbitrary definition as mixtures of sand, silt, clay and humus will support biological and agricultural activity before that time. These constituents are moved from one level to another by water and animal activity. As a result, layers (horizons) form in the soil profile. The alteration and movement of materials within a soil causes the formation of distinctive
soil horizons A soil horizon is a layer parallel to the soil surface whose physical, chemical and biological characteristics differ from the layers above and beneath. Horizons are defined in many cases by obvious physical features, mainly colour and texture. ...
. However, more recent definitions of soil embrace soils without any organic matter, such as those
regolith Regolith () is a blanket of unconsolidated, loose, heterogeneous superficial deposits covering solid rock. It includes dust, broken rocks, and other related materials and is present on Earth, the Moon, Mars, some asteroids, and other terrestria ...
s that formed on Mars and analogous conditions in planet Earth deserts. An example of the development of a soil would begin with the weathering of lava flow bedrock, which would produce the purely mineral-based parent material from which the soil texture forms. Soil development would proceed most rapidly from bare rock of recent flows in a warm climate, under heavy and frequent rainfall. Under such conditions, plants (in a first stage
nitrogen-fixing Nitrogen fixation is a chemical process by which molecular nitrogen (), with a strong triple covalent bond, in the air is converted into ammonia () or related nitrogenous compounds, typically in soil or aquatic systems but also in industry. Atmo ...
lichen A lichen ( , ) is a composite organism that arises from algae or cyanobacteria living among filaments of multiple fungi species in a mutualistic relationship.cyanobacteria then
epilithic Lithophytes are plants that grow in or on rocks. They can be classified as either epilithic (or epipetric) or endolithic; epilithic lithophytes grow on the surfaces of rocks, while endolithic lithophytes grow in the crevices of rocks (and are also ...
higher plants) become established very quickly on
basalt Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90% of a ...
ic lava, even though there is very little organic material. Basaltic minerals commonly weather relatively quickly, according to the
Goldich dissolution series The Goldich dissolution series is a method of predicting the relative stability or weathering rate of common igneous minerals on the Earth's surface, with minerals that form at higher temperatures and pressures less stable on the surface than minera ...
. The plants are supported by the porous rock as it is filled with nutrient-bearing water that carries minerals dissolved from the rocks. Crevasses and pockets, local topography of the rocks, would hold fine materials and harbour plant roots. The developing plant roots are associated with mineral-weathering
mycorrhizal fungi   A mycorrhiza (from Greek μύκης ', "fungus", and ῥίζα ', "root"; pl. mycorrhizae, mycorrhiza or mycorrhizas) is a symbiotic association between a fungus and a plant. The term mycorrhiza refers to the role of the fungus in the plant ...
that assist in breaking up the porous lava, and by these means organic matter and a finer mineral soil accumulate with time. Such initial stages of soil development have been described on volcanoes, inselbergs, and glacial moraines. How soil formation proceeds is influenced by at least five classic factors that are intertwined in the evolution of a soil: parent material, climate, topography (relief), organisms, and time. When reordered to climate, relief, organisms, parent material, and time, they form the acronym CROPT.


Physical properties

The physical properties of soils, in order of decreasing importance for ecosystem services such as crop production, are
texture Texture may refer to: Science and technology * Surface texture, the texture means smoothness, roughness, or bumpiness of the surface of an object * Texture (roads), road surface characteristics with waves shorter than road roughness * Texture ( ...
,
structure A structure is an arrangement and organization of interrelated elements in a material object or system, or the object or system so organized. Material structures include man-made objects such as buildings and machines and natural objects such as ...
,
bulk density Bulk density, also called apparent density or volumetric density, is a property of powders, granules, and other "divided" solids, especially used in reference to mineral components (soil, gravel), chemical substances, (pharmaceutical) ingredients, ...
,
porosity Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
, consistency,
temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measurement, measured with a thermometer. Thermometers are calibrated in various Conversion of units of temperature, temp ...
,
colour Color (American English) or colour (British English) is the visual perceptual property deriving from the spectrum of light interacting with the photoreceptor cells of the eyes. Color categories and physical specifications of color are associa ...
and
resistivity Electrical resistivity (also called specific electrical resistance or volume resistivity) is a fundamental property of a material that measures how strongly it resists electric current. A low resistivity indicates a material that readily allows ...
. Soil texture is determined by the relative proportion of the three kinds of soil mineral particles, called soil separates:
sand Sand is a granular material composed of finely divided mineral particles. Sand has various compositions but is defined by its grain size. Sand grains are smaller than gravel and coarser than silt. Sand can also refer to a textural class of s ...
,
silt Silt is granular material of a size between sand and clay and composed mostly of broken grains of quartz. Silt may occur as a soil (often mixed with sand or clay) or as sediment mixed in suspension with water. Silt usually has a floury feel whe ...
, and
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay parti ...
. At the next larger scale, soil structures called
ped Peds are aggregates of soil particles formed as a result of pedogenic processes; this natural organization of particles forms discrete units separated by pores or voids. The term is generally used for macroscopic (visible; i.e. greater than 1 mm i ...
s or more commonly ''soil aggregates'' are created from the soil separates when
iron oxide Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of which ...
s,
carbonate A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate g ...
s, clay,
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
and
humus In classical soil science, humus is the dark organic matter in soil that is formed by the decomposition of plant and animal matter. It is a kind of soil organic matter. It is rich in nutrients and retains moisture in the soil. Humus is the Latin ...
, coat particles and cause them to adhere into larger, relatively
stable A stable is a building in which livestock, especially horses, are kept. It most commonly means a building that is divided into separate stalls for individual animals and livestock. There are many different types of stables in use today; the ...
secondary structures. Soil
bulk density Bulk density, also called apparent density or volumetric density, is a property of powders, granules, and other "divided" solids, especially used in reference to mineral components (soil, gravel), chemical substances, (pharmaceutical) ingredients, ...
, when determined at standardized moisture conditions, is an estimate of
soil compaction In geotechnical engineering, soil compaction is the process in which stress applied to a soil causes densification as air is displaced from the pores between the soil grains. When stress is applied that causes densification due to water (or other ...
. Soil porosity consists of the void part of the soil volume and is occupied by gases or water. Soil consistency is the ability of soil materials to stick together. Soil temperature and colour are self-defining. Resistivity refers to the resistance to conduction of electric currents and affects the rate of corrosion of metal and concrete structures which are buried in soil. These properties vary through the depth of a soil profile, i.e. through
soil horizon A soil horizon is a layer parallel to the soil surface whose physical, chemical and biological characteristics differ from the layers above and beneath. Horizons are defined in many cases by obvious physical features, mainly colour and texture. ...
s. Most of these properties determine the aeration of the soil and the ability of water to infiltrate and to be
held Held may refer to: Places * Held Glacier People Arts and media * Adolph Held (1885–1969), U.S. newspaper editor, banker, labor activist *Al Held (1928–2005), U.S. abstract expressionist painter. * Alexander Held (born 1958), German televis ...
within the soil.


Soil moisture

Soil
water content Water content or moisture content is the quantity of water contained in a material, such as soil (called soil moisture), rock, ceramics, crops, or wood. Water content is used in a wide range of scientific and technical areas, and is expressed as ...
can be measured as volume or
weight In science and engineering, the weight of an object is the force acting on the object due to gravity. Some standard textbooks define weight as a vector quantity, the gravitational force acting on the object. Others define weight as a scalar quan ...
. Soil moisture levels, in order of decreasing water content, are saturation,
field capacity Field capacity is the amount of soil moisture or water content held in the soil after excess water has drained away and the rate of downward movement has decreased. This usually takes place 2–3 days after rain or irrigation in pervious soils of un ...
,
wilting point Permanent wilting point (PWP) or wilting point (WP) is defined as the minimum amount of water in the soil that the plant requires not to wilt. If the soil water content decreases to this or any lower point a plant wilts and can no longer recover ...
, air dry, and oven dry. Field capacity describes a drained wet soil at the point water content reaches equilibrium with gravity. Irrigating soil above field capacity risks percolation losses. Wilting point describes the dry limit for growing plants. Available water capacity is the amount of water held in a soil profile available to plants. As water content drops, plants have to work against increasing forces of
adhesion Adhesion is the tendency of dissimilar particles or surfaces to cling to one another ( cohesion refers to the tendency of similar or identical particles/surfaces to cling to one another). The forces that cause adhesion and cohesion can be ...
and sorptivity to withdraw water. Irrigation scheduling avoids moisture stress by replenishing depleted water before stress is induced.
Capillary action Capillary action (sometimes called capillarity, capillary motion, capillary rise, capillary effect, or wicking) is the process of a liquid flowing in a narrow space without the assistance of, or even in opposition to, any external forces li ...
is responsible for moving groundwater from wet regions of the soil to dry areas.
Subirrigation Subirrigation also known as seepage irrigation, is a method of irrigation where water is delivered to the plant root zone. The excess may be collected for reuse. Subirrigation is used in growing field crops such as tomatoes, peppers, and sugar ...
designs (e.g., wicking beds, sub-irrigated planters) rely on capillarity to supply water to plant roots. Capillary action can result in an evaporative concentration of salts, causing land degradation through salination. Soil moisture measurement — measuring the water content of the soil, as can be expressed in terms of volume or weight — can be based on ''in situ'' probes (e.g., capacitance probes, neutron probes), or
remote sensing Remote sensing is the acquisition of information about an object or phenomenon without making physical contact with the object, in contrast to in situ or on-site observation. The term is applied especially to acquiring information about Earth ...
methods.


Soil gas

The atmosphere of soil, or
soil gas Soil gases (soil atmosphere) are the gases found in the air space between soil components. The spaces between the solid soil particles, if they do not contain water, are filled with air. The primary soil gases are nitrogen, carbon dioxide and oxygen ...
, is very different from the atmosphere above. The consumption of oxygen by microbes and plant roots, and their release of carbon dioxide, decreases oxygen and increases carbon dioxide concentration. Atmospheric CO2 concentration is 0.04%, but in the soil pore space it may range from 10 to 100 times that level, thus potentially contributing to the inhibition of root respiration. Calcareous soils regulate CO2 concentration by
carbonate A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate g ...
buffering, contrary to acid soils in which all CO2 respired accumulates in the soil pore system. At extreme levels, CO2 is toxic. This suggests a possible
negative feedback Negative feedback (or balancing feedback) occurs when some function of the output of a system, process, or mechanism is fed back in a manner that tends to reduce the fluctuations in the output, whether caused by changes in the input or by othe ...
control of soil CO2 concentration through its inhibitory effects on root and microbial respiration (also called
soil respiration Soil respiration refers to the production of carbon dioxide when soil organisms respire. This includes respiration of plant roots, the rhizosphere, microbes and fauna. Soil respiration is a key ecosystem process that releases carbon from the ...
). In addition, the soil voids are saturated with water vapour, at least until the point of maximal
hygroscopic Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption or adsorption from the surrounding environment, which is usually at normal or room temperature. If water molecules become suspended among the substance ...
ity, beyond which a
vapour-pressure deficit Vapour-pressure deficit, or VPD, is the difference (deficit) between the amount of moisture in the air and how much moisture the air can hold when it is saturated. Once air becomes saturated, water will condense out to form clouds, dew or films o ...
occurs in the soil pore space. Adequate porosity is necessary, not just to allow the penetration of water, but also to allow gases to diffuse in and out. Movement of gases is by
diffusion Diffusion is the net movement of anything (for example, atoms, ions, molecules, energy) generally from a region of higher concentration to a region of lower concentration. Diffusion is driven by a gradient in Gibbs free energy or chemical p ...
from high concentrations to lower, the
diffusion coefficient Diffusivity, mass diffusivity or diffusion coefficient is a proportionality constant between the molar flux due to molecular diffusion and the gradient in the concentration of the species (or the driving force for diffusion). Diffusivity is enco ...
decreasing with
soil compaction In geotechnical engineering, soil compaction is the process in which stress applied to a soil causes densification as air is displaced from the pores between the soil grains. When stress is applied that causes densification due to water (or other ...
. Oxygen from above atmosphere diffuses in the soil where it is consumed and levels of carbon dioxide in excess of above atmosphere diffuse out with other gases (including
greenhouse gases A greenhouse gas (GHG or GhG) is a gas that absorbs and emits radiant energy within the thermal infrared range, causing the greenhouse effect. The primary greenhouse gases in Earth's atmosphere are water vapor (), carbon dioxide (), meth ...
) as well as water.
Soil texture Soil texture is a classification instrument used both in the field and laboratory to determine soil classes based on their physical texture. Soil texture can be determined using qualitative methods such as texture by feel, and quantitative methods ...
and
structure A structure is an arrangement and organization of interrelated elements in a material object or system, or the object or system so organized. Material structures include man-made objects such as buildings and machines and natural objects such as ...
strongly affect soil porosity and gas diffusion. It is the total pore space (
porosity Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
) of soil, not the pore size, and the degree of pore interconnection (or conversely pore sealing), together with water content, air
turbulence In fluid dynamics, turbulence or turbulent flow is fluid motion characterized by chaotic changes in pressure and flow velocity. It is in contrast to a laminar flow, which occurs when a fluid flows in parallel layers, with no disruption between ...
and temperature, that determine the rate of diffusion of gases into and out of soil. Platy soil structure and soil compaction (low porosity) impede gas flow, and a deficiency of oxygen may encourage anaerobic bacteria to reduce (strip oxygen) from nitrate NO3 to the gases N2, N2O, and NO, which are then lost to the atmosphere, thereby depleting the soil of nitrogen, a detrimental process called
denitrification Denitrification is a microbially facilitated process where nitrate (NO3−) is reduced and ultimately produces molecular nitrogen (N2) through a series of intermediate gaseous nitrogen oxide products. Facultative anaerobic bacteria perform denitr ...
. Aerated soil is also a net sink of methane (CH4) but a net producer of methane (a strong heat-absorbing
greenhouse gas A greenhouse gas (GHG or GhG) is a gas that absorbs and emits radiant energy within the thermal infrared range, causing the greenhouse effect. The primary greenhouse gases in Earth's atmosphere are water vapor (), carbon dioxide (), methane ...
) when soils are depleted of oxygen and subject to elevated temperatures. Soil atmosphere is also the seat of emissions of
volatiles Volatiles are the group of chemical elements and chemical compounds that can be readily vaporized. In contrast with volatiles, elements and compounds that are not readily vaporized are known as refractory substances. On planet Earth, the term ...
other than carbon and nitrogen oxides from various soil organisms, e.g. roots, bacteria, fungi, animals. These volatiles are used as chemical cues, making soil atmosphere the seat of interaction networks playing a decisive role in the stability, dynamics and evolution of soil ecosystems. Biogenic soil volatile organic compounds are exchanged with the aboveground atmosphere, in which they are just 1–2 orders of magnitude lower than those from aboveground vegetation. Humans can get some idea of the soil atmosphere through the well-known 'after-the-rain' scent, when infiltering rainwater flushes out the whole soil atmosphere after a drought period, or when soil is excavated, a bulk property attributed in a
reductionist Reductionism is any of several related philosophical ideas regarding the associations between phenomena which can be described in terms of other simpler or more fundamental phenomena. It is also described as an intellectual and philosophical po ...
manner to particular biochemical compounds such as petrichor or
geosmin Geosmin ( ) is an irregular sesquiterpenoid, produced from the universal sesquiterpene precursor farnesyl pyrophosphate (also known as farnesyl diphosphate), in a two-step -dependent reaction. Geosmin, along with the irregular monoterpene 2-me ...
.


Solid phase (soil matrix)

Soil particles can be classified by their chemical composition (
mineralogy Mineralogy is a subject of geology specializing in the scientific study of the chemistry, crystal structure, and physical (including optical) properties of minerals and mineralized artifacts. Specific studies within mineralogy include the proc ...
) as well as their size. The particle size distribution of a soil, its texture, determines many of the properties of that soil, in particular
hydraulic conductivity Hydraulic conductivity, symbolically represented as (unit: m/s), is a property of porous materials, soils and rocks, that describes the ease with which a fluid (usually water) can move through the pore space, or fractures network. It depends on th ...
and
water potential Water potential is the potential energy of water per unit volume relative to pure water in reference conditions. Water potential quantifies the tendency of water to move from one area to another due to osmosis, gravity, mechanical pressure and matr ...
, but the mineralogy of those particles can strongly modify those properties. The mineralogy of the finest soil particles, clay, is especially important.


Chemistry

The chemistry of a soil determines its ability to supply available plant nutrients and affects its physical properties and the health of its living population. In addition, a soil's chemistry also determines its corrosivity, stability, and ability to absorb
pollutants A pollutant or novel entity is a substance or energy introduced into the environment that has undesired effects, or adversely affects the usefulness of a resource. These can be both naturally forming (i.e. minerals or extracted compounds like o ...
and to filter water. It is the surface chemistry of mineral and organic
colloids A colloid is a mixture in which one substance consisting of microscopically dispersed insoluble particles is suspended throughout another substance. Some definitions specify that the particles must be dispersed in a liquid, while others extend ...
that determines soil's chemical properties. A colloid is a small, insoluble particle ranging in size from 1
nanometer 330px, Different lengths as in respect to the molecular scale. The nanometre (international spelling as used by the International Bureau of Weights and Measures; SI symbol: nm) or nanometer (American and British English spelling differences#-re, ...
to 1 micrometer, thus small enough to remain suspended by
Brownian motion Brownian motion, or pedesis (from grc, πήδησις "leaping"), is the random motion of particles suspended in a medium (a liquid or a gas). This pattern of motion typically consists of random fluctuations in a particle's position ins ...
in a fluid medium without settling. Most soils contain organic colloidal particles called humus as well as the inorganic colloidal particles of
clays Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay parti ...
. The very high
specific surface area Specific surface area (SSA) is a property of solids defined as the total surface area of a material per unit of mass, (with units of m2/kg or m2/g) or solid or bulk volume (units of m2/m3 or m−1). It is a physical value that can be used to dete ...
of colloids and their net
electrical charge Electricity is the set of physical phenomena associated with the presence and motion of matter that has a property of electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by ...
s give soil its ability to hold and release
ions An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
. Negatively charged sites on colloids attract and release cations in what is referred to as
cation exchange Ion exchange is a reversible interchange of one kind of ion present in an insoluble solid with another of like charge present in a solution surrounding the solid with the reaction being used especially for softening or making water demineralised, ...
.
Cation-exchange capacity Cation-exchange capacity (CEC) is a measure of how many cations can be retained on soil particle surfaces. Negative charges on the surfaces of soil particles bind positively-charged atoms or molecules (cations), but allow these to exchange with ot ...
is the amount of exchangeable
cations An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
per unit weight of dry soil and is expressed in terms of milliequivalents of positively charged ions per 100 grams of soil (or centimoles of positive charge per kilogram of soil; cmolc/kg). Similarly, positively charged sites on colloids can attract and release
anions An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
in the soil, giving the soil anion exchange capacity.


Cation and anion exchange

The cation exchange, that takes place between colloids and soil water, buffers (moderates) soil pH, alters soil structure, and purifies percolating water by adsorbing cations of all types, both useful and harmful. The negative or positive charges on colloid particles make them able to hold cations or anions, respectively, to their surfaces. The charges result from four sources. # Isomorphous substitution occurs in clay during its formation, when lower-valence cations substitute for higher-valence cations in the crystal structure. Substitutions in the outermost layers are more effective than for the innermost layers, as the
electric charge Electric charge is the physical property of matter that causes charged matter to experience a force when placed in an electromagnetic field. Electric charge can be ''positive'' or ''negative'' (commonly carried by protons and electrons respectiv ...
strength drops off as the square of the distance. The net result is oxygen atoms with net negative charge and the ability to attract cations. # Edge-of-clay oxygen atoms are not in balance ionically as the tetrahedral and octahedral structures are incomplete. #
Hydroxyl In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry, alcohols and carboxylic acids contain one or more hydroxy g ...
s may substitute for oxygens of the silica layers, a process called
hydroxylation In chemistry, hydroxylation can refer to: *(i) most commonly, hydroxylation describes a chemical process that introduces a hydroxyl group () into an organic compound. *(ii) the ''degree of hydroxylation'' refers to the number of OH groups in a ...
. When the hydrogens of the clay hydroxyls are ionised into solution, they leave the oxygen with a negative charge (anionic clays). # Hydrogens of humus hydroxyl groups may also be ionised into solution, leaving, similarly to clay, an oxygen with a negative charge. Cations held to the negatively charged colloids resist being washed downward by water and are out of reach of plant roots, thereby preserving the fertility of soils in areas of moderate rainfall and low temperatures. There is a hierarchy in the process of cation exchange on colloids, as cations differ in the strength of adsorption by the colloid and hence their ability to replace one another (
ion exchange Ion exchange is a reversible interchange of one kind of ion present in an insoluble solid with another of like charge present in a solution surrounding the solid with the reaction being used especially for softening or making water demineralised, ...
). If present in equal amounts in the soil water solution: Al3+ replaces H+ replaces Ca2+ replaces Mg2+ replaces K+ same as replaces Na+ If one cation is added in large amounts, it may replace the others by the sheer force of its numbers. This is called
law of mass action In chemistry, the law of mass action is the proposition that the rate of the chemical reaction is directly proportional to the product of the activities or concentrations of the reactants. It explains and predicts behaviors of solutions in dyn ...
. This is largely what occurs with the addition of cationic fertilisers ( potash,
lime Lime commonly refers to: * Lime (fruit), a green citrus fruit * Lime (material), inorganic materials containing calcium, usually calcium oxide or calcium hydroxide * Lime (color), a color between yellow and green Lime may also refer to: Botany ...
). As the soil solution becomes more acidic (low pH, meaning an abundance of H+), the other cations more weakly bound to colloids are pushed into solution as hydrogen ions occupy exchange sites (
protonation In chemistry, protonation (or hydronation) is the adding of a proton (or hydron, or hydrogen cation), (H+) to an atom, molecule, or ion, forming a conjugate acid. (The complementary process, when a proton is removed from a Brønsted–Lowry acid, i ...
). A low pH may cause the hydrogen of hydroxyl groups to be pulled into solution, leaving charged sites on the colloid available to be occupied by other cations. This
ionisation Ionization, or Ionisation is the process by which an atom or a molecule acquires a negative or positive charge by gaining or losing electrons, often in conjunction with other chemical changes. The resulting electrically charged atom or molecule i ...
of
hydroxy group In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry, alcohols and carboxylic acids contain one or more hydroxy ...
s on the surface of soil colloids creates what is described as pH-dependent surface charges. Unlike permanent charges developed by isomorphous substitution, pH-dependent charges are variable and increase with increasing pH. Freed cations can be made available to plants but are also prone to be leached from the soil, possibly making the soil less fertile. Plants are able to excrete H+ into the soil through the synthesis of
organic acid An organic acid is an organic compound with acidic properties. The most common organic acids are the carboxylic acids, whose acidity is associated with their carboxyl group –COOH. Sulfonic acids, containing the group –SO2OH, are re ...
s and by that means, change the pH of the soil near the root and push cations off the colloids, thus making those available to the plant.


Cation exchange capacity (CEC)

Cation exchange capacity Cation-exchange capacity (CEC) is a measure of how many cations can be retained on soil particle surfaces. Negative charges on the surfaces of soil particles bind positively-charged atoms or molecules (cations), but allow these to exchange with ot ...
is the soil's ability to remove cations from the soil water solution and sequester those to be exchanged later as the plant roots release hydrogen ions to the solution. CEC is the amount of exchangeable hydrogen cation (H+) that will combine with 100 grams dry weight of soil and whose measure is one milliequivalents per 100 grams of soil (1 meq/100 g). Hydrogen ions have a single charge and one-thousandth of a gram of hydrogen ions per 100 grams dry soil gives a measure of one milliequivalent of hydrogen ion. Calcium, with an atomic weight 40 times that of hydrogen and with a valence of two, converts to = 20 milliequivalents of hydrogen ion per 100 grams of dry soil or 20 meq/100 g. The modern measure of CEC is expressed as centimoles of positive charge per kilogram (cmol/kg) of oven-dry soil. Most of the soil's CEC occurs on clay and humus colloids, and the lack of those in hot, humid, wet climates (such as
tropical rainforest Tropical rainforests are rainforests that occur in areas of tropical rainforest climate in which there is no dry season – all months have an average precipitation of at least 60 mm – and may also be referred to as ''lowland equatori ...
s), due to leaching and decomposition, respectively, explains the apparent sterility of tropical soils. Live plant roots also have some CEC, linked to their specific surface area.


Anion exchange capacity (AEC)

Anion exchange capacity is the soil's ability to remove anions (such as
nitrate Nitrate is a polyatomic ion with the chemical formula . Salts containing this ion are called nitrates. Nitrates are common components of fertilizers and explosives. Almost all inorganic nitrates are soluble in water. An example of an insolubl ...
,
phosphate In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid . The phosphate or orthophosphate ion is derived from phospho ...
) from the soil water solution and sequester those for later exchange as the plant roots release carbonate anions to the soil water solution. Those colloids which have low CEC tend to have some AEC. Amorphous and sesquioxide clays have the highest AEC, followed by the iron oxides. Levels of AEC are much lower than for CEC, because of the generally higher rate of positively (versus negatively) charged surfaces on soil colloids, to the exception of variable-charge soils. Phosphates tend to be held at anion exchange sites. Iron and aluminum hydroxide clays are able to exchange their hydroxide anions (OH) for other anions. The order reflecting the strength of anion adhesion is as follows: : replaces replaces replaces Cl The amount of exchangeable anions is of a magnitude of tenths to a few milliequivalents per 100 g dry soil. As pH rises, there are relatively more hydroxyls, which will displace anions from the colloids and force them into solution and out of storage; hence AEC decreases with increasing pH (alkalinity).


Reactivity (pH)

Soil reactivity is expressed in terms of pH and is a measure of the
acid In computer science, ACID ( atomicity, consistency, isolation, durability) is a set of properties of database transactions intended to guarantee data validity despite errors, power failures, and other mishaps. In the context of databases, a sequ ...
ity or alkalinity of the soil. More precisely, it is a measure of
hydronium In chemistry, hydronium (hydroxonium in traditional British English) is the common name for the aqueous cation , the type of oxonium ion produced by protonation of water. It is often viewed as the positive ion present when an Arrhenius acid is d ...
concentration in an aqueous solution and ranges in values from 0 to 14 (acidic to basic) but practically speaking for soils, pH ranges from 3.5 to 9.5, as pH values beyond those extremes are toxic to life forms. At 25 °C an aqueous solution that has a pH of 3.5 has 10−3.5 moles H3O+ (hydronium ions) per litre of solution (and also 10−10.5 moles per litre OH). A pH of 7, defined as neutral, has 10−7 moles of hydronium ions per litre of solution and also 10−7 moles of OH per litre; since the two concentrations are equal, they are said to neutralise each other. A pH of 9.5 has 10−9.5 moles hydronium ions per litre of solution (and also 10−2.5 moles per litre OH). A pH of 3.5 has one million times more hydronium ions per litre than a solution with pH of 9.5 ( or 106) and is more acidic. The effect of pH on a soil is to remove from the soil or to make available certain ions. Soils with high acidity tend to have toxic amounts of
aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It has ...
and
manganese Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy u ...
. As a result of a trade-off between toxicity and requirement most nutrients are better available to plants at moderate pH, although most minerals are more soluble in acid soils. Soil organisms are hindered by high acidity, and most agricultural crops do best with mineral soils of pH 6.5 and organic soils of pH 5.5. Given that at low pH toxic metals (e.g. cadmium, zinc, lead) are positively charged as cations and organic pollutants are in non-ionic form, thus both made more available to organisms, it has been suggested that plants, animals and microbes commonly living in acid soils are pre-adapted to every kind of pollution, whether of natural or human origin. In high rainfall areas, soils tend to acidify as the basic cations are forced off the soil colloids by the mass action of hydronium ions from usual or unusual rain acidity against those attached to the colloids. High rainfall rates can then wash the nutrients out, leaving the soil inhabited only by those organisms which are particularly efficient to uptake nutrients in very acid conditions, like in
tropical rainforests Tropical rainforests are rainforests that occur in areas of tropical rainforest climate in which there is no dry season – all months have an average precipitation of at least 60 mm – and may also be referred to as ''lowland equatori ...
. Once the colloids are saturated with H3O+, the addition of any more hydronium ions or aluminum hydroxyl cations drives the pH even lower (more acidic) as the soil has been left with no buffering capacity. In areas of extreme rainfall and high temperatures, the clay and humus may be washed out, further reducing the buffering capacity of the soil. In low rainfall areas, unleached calcium pushes pH to 8.5 and with the addition of exchangeable sodium, soils may reach pH 10. Beyond a pH of 9, plant growth is reduced. High pH results in low micro-nutrient mobility, but water-soluble
chelates Chelation is a type of bonding of ions and molecules to metal ions. It involves the formation or presence of two or more separate coordinate bonds between a polydentate (multiple bonded) ligand and a single central metal atom. These ligands ar ...
of those nutrients can correct the deficit. Sodium can be reduced by the addition of gypsum (calcium sulphate) as calcium adheres to clay more tightly than does sodium causing sodium to be pushed into the soil water solution where it can be washed out by an abundance of water.


Base saturation percentage

There are acid-forming cations (e.g. hydronium, aluminium, iron) and there are base-forming cations (e.g. calcium, magnesium, sodium). The fraction of the negatively-charged soil colloid exchange sites (CEC) that are occupied by base-forming cations is called
base saturation Cation-exchange capacity (CEC) is a measure of how many cations can be retained on soil particle surfaces. Negative charges on the surfaces of soil particles bind positively-charged atoms or molecules (cations), but allow these to exchange with ot ...
. If a soil has a CEC of 20 meq and 5 meq are aluminium and hydronium cations (acid-forming), the remainder of positions on the colloids () are assumed occupied by base-forming cations, so that the base saturation is (the compliment 25% is assumed acid-forming cations). Base saturation is almost in direct proportion to pH (it increases with increasing pH). It is of use in calculating the amount of lime needed to neutralise an acid soil (lime requirement). The amount of lime needed to neutralize a soil must take account of the amount of acid forming ions on the colloids (exchangeable acidity), not just those in the soil water solution (free acidity). The addition of enough lime to neutralize the soil water solution will be insufficient to change the pH, as the acid forming cations stored on the soil colloids will tend to restore the original pH condition as they are pushed off those colloids by the calcium of the added lime.


Buffering

The resistance of soil to change in pH, as a result of the addition of acid or basic material, is a measure of the buffering capacity of a soil and (for a particular soil type) increases as the CEC increases. Hence, pure sand has almost no buffering ability, though soils high in colloids (whether mineral or organic) have high buffering capacity. Buffering occurs by cation exchange and neutralisation. However, colloids are not the only regulators of soil pH. The role of
carbonates A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate g ...
should be underlined, too. More generally, according to pH levels, several buffer systems take precedence over each other, from calcium carbonate buffer range to iron buffer range. The addition of a small amount of highly basic aqueous ammonia to a soil will cause the ammonium to displace hydronium ions from the colloids, and the end product is water and colloidally fixed ammonium, but little permanent change overall in soil pH. The addition of a small amount of
lime Lime commonly refers to: * Lime (fruit), a green citrus fruit * Lime (material), inorganic materials containing calcium, usually calcium oxide or calcium hydroxide * Lime (color), a color between yellow and green Lime may also refer to: Botany ...
, Ca(OH)2, will displace hydronium ions from the soil colloids, causing the fixation of calcium to colloids and the evolution of CO2 and water, with little permanent change in soil pH. The above are examples of the buffering of soil pH. The general principal is that an increase in a particular cation in the soil water solution will cause that cation to be fixed to colloids (buffered) and a decrease in solution of that cation will cause it to be withdrawn from the colloid and moved into solution (buffered). The degree of buffering is often related to the CEC of the soil; the greater the CEC, the greater the buffering capacity of the soil.


Redox

Soil chemical reactions involve some combination of proton and electron transfer. Oxidation occurs if there is a loss of electrons in the transfer process while reduction occurs if there is a gain of electrons.
Reduction potential Redox potential (also known as oxidation / reduction potential, ''ORP'', ''pe'', ''E_'', or E_) is a measure of the tendency of a chemical species to acquire electrons from or lose electrons to an electrode and thereby be reduced or oxidised resp ...
is measured in volts or millivolts. Soil microbial communities develop along
electron transport chain An electron transport chain (ETC) is a series of protein complexes and other molecules that transfer electrons from electron donors to electron acceptors via redox reactions (both reduction and oxidation occurring simultaneously) and couples thi ...
s, forming electrically conductive
biofilms A biofilm comprises any syntrophic consortium of microorganisms in which cells stick to each other and often also to a surface. These adherent cells become embedded within a slimy extracellular matrix that is composed of extracellular po ...
, and developing networks of
bacterial nanowires Bacterial nanowires (also known as microbial nanowires) are electrically conductive appendages produced by a number of bacteria most notably from (but not exclusive to) the '' Geobacter'' and ''Shewanella'' genera. Conductive nanowires have also ...
. Redox factors in soil development, where formation of redoximorphic color features provides critical information for soil interpretation. Understanding the redox gradient is important to managing carbon sequestration, bioremediation, wetland delineation, and soil-based microbial fuel cells.


Nutrients

Seventeen elements or nutrients are essential for plant growth and reproduction. They are carbon (C), hydrogen (H), oxygen (O), nitrogen (N),
phosphorus Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Ea ...
(P),
potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosp ...
(K),
sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
(S),
calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar ...
(Ca),
magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ...
(Mg),
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in fr ...
(Fe),
boron Boron is a chemical element with the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the ''boron group'' it has th ...
(B), manganese (Mn), copper (Cu),
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic ta ...
(Zn),
molybdenum Molybdenum is a chemical element with the symbol Mo and atomic number 42 which is located in period 5 and group 6. The name is from Neo-Latin ''molybdaenum'', which is based on Ancient Greek ', meaning lead, since its ores were confused with l ...
(Mo),
nickel Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow to ...
(Ni) and
chlorine Chlorine is a chemical element with the symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is ...
(Cl). Nutrients required for plants to complete their life cycle are considered
essential nutrients A nutrient is a substance used by an organism to survive, grow, and reproduce. The requirement for dietary nutrient intake applies to animals, plants, fungi, and protists. Nutrients can be incorporated into cells for metabolic purposes or excret ...
. Nutrients that enhance the growth of plants but are not necessary to complete the plant's life cycle are considered non-essential. With the exception of carbon, hydrogen and oxygen, which are supplied by carbon dioxide and water, and nitrogen, provided through nitrogen fixation, the nutrients derive originally from the mineral component of the soil. The Law of the Minimum expresses that when the available form of a nutrient is not in enough proportion in the soil solution, then other nutrients cannot be taken up at an optimum rate by a plant. A particular nutrient ratio of the soil solution is thus mandatory for optimizing plant growth, a value which might differ from nutrient ratios calculated from plant composition. Plant uptake of nutrients can only proceed when they are present in a plant-available form. In most situations, nutrients are absorbed in an ionic form from (or together with) soil water. Although minerals are the origin of most nutrients, and the bulk of most nutrient elements in the soil is held in crystalline form within primary and secondary minerals, they weather too slowly to support rapid plant growth. For example, the application of finely ground minerals,
feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldspa ...
and
apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of OH−, F− and Cl− ions, respectively, in the crystal. The formula of the admixture of the three most common ...
, to soil seldom provides the necessary amounts of potassium and phosphorus at a rate sufficient for good plant growth, as most of the nutrients remain bound in the crystals of those minerals. The nutrients adsorbed onto the surfaces of clay colloids and soil organic matter provide a more accessible reservoir of many plant nutrients (e.g. K, Ca, Mg, P, Zn). As plants absorb the nutrients from the soil water, the soluble pool is replenished from the surface-bound pool. The decomposition of soil organic matter by microorganisms is another mechanism whereby the soluble pool of nutrients is replenished – this is important for the supply of plant-available N, S, P, and B from soil. Gram for gram, the capacity of humus to hold nutrients and water is far greater than that of clay minerals, most of the soil cation exchange capacity arising from charged
carboxylic In organic chemistry, a carboxylic acid is an organic acid that contains a carboxyl group () attached to an R-group. The general formula of a carboxylic acid is or , with R referring to the alkyl, alkenyl, aryl, or other group. Carboxylic ...
groups on organic matter. However, despite the great capacity of humus to retain water once water-soaked, its high
hydrophobicity In chemistry, hydrophobicity is the physical property of a molecule that is seemingly repelled from a mass of water (known as a hydrophobe). In contrast, hydrophiles are attracted to water. Hydrophobic molecules tend to be nonpolar and, t ...
decreases its
wettability Wetting is the ability of a liquid to maintain contact with a solid surface, resulting from intermolecular interactions when the two are brought together. This happens in presence of a gaseous phase or another liquid phase not miscible with t ...
. All in all, small amounts of humus may remarkably increase the soil's capacity to promote plant growth.


Soil organic matter

The organic material in soil is made up of
organic compounds In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The s ...
and includes plant, animal and microbial material, both living and dead. A typical soil has a biomass composition of 70% microorganisms, 22% macrofauna, and 8% roots. The living component of an acre of soil may include 900 lb of earthworms, 2400 lb of fungi, 1500 lb of bacteria, 133 lb of protozoa and 890 lb of arthropods and algae. A few percent of the soil organic matter, with small
residence time The residence time of a fluid parcel is the total time that the parcel has spent inside a control volume (e.g.: a chemical reactor, a lake, a human body). The residence time of a set of parcels is quantified in terms of the frequency distribution ...
, consists of the microbial biomass and
metabolites In biochemistry, a metabolite is an intermediate or end product of metabolism. The term is usually used for small molecules. Metabolites have various functions, including fuel, structure, signaling, stimulatory and inhibitory effects on enzymes, c ...
of bacteria, molds, and actinomycetes that work to break down the dead organic matter. Were it not for the action of these micro-organisms, the entire carbon dioxide part of the atmosphere would be sequestered as organic matter in the soil. However, in the same time soil microbes contribute to
carbon sequestration Carbon sequestration is the process of storing carbon in a carbon pool. Carbon dioxide () is naturally captured from the atmosphere through biological, chemical, and physical processes. These changes can be accelerated through changes in lan ...
in the topsoil through the formation of stable humus. In the aim to sequester more carbon in the soil for alleviating the
greenhouse effect The greenhouse effect is a process that occurs when energy from a planet's host star goes through the planet's atmosphere and heats the planet's surface, but greenhouse gases in the atmosphere prevent some of the heat from returning directly ...
it would be more efficient in the long-term to stimulate
humification In classical soil science, humus is the dark organic matter in soil that is formed by the decomposition of plant and animal matter. It is a kind of soil organic matter. It is rich in nutrients and retains moisture in the soil. Humus is the Latin ...
than to decrease litter
decomposition Decomposition or rot is the process by which dead organic substances are broken down into simpler organic or inorganic matter such as carbon dioxide, water, simple sugars and mineral salts. The process is a part of the nutrient cycle and is ...
. The main part of soil organic matter is a complex assemblage of small organic molecules, collectively called humus or
humic Humic substances (HS) are organic compounds that are important components of humus, the major organic fraction of soil, peat, and coal (and also a constituent of many upland streams, dystrophic lakes, and ocean water). For a long era in the 19th ...
substances. The use of these terms, which do not rely on a clear chemical classification, has been considered as obsolete. Other studies showed that the classical notion of molecule is not convenient for humus, which escaped most attempts done over two centuries to resolve it in unit components, but still is chemically distinct from polysaccharides, lignins and proteins. Most living things in soils, including plants, animals, bacteria, and fungi, are dependent on organic matter for nutrients and/or energy. Soils have organic compounds in varying degrees of decomposition which rate is dependent on temperature, soil moisture, and aeration. Bacteria and fungi feed on the raw organic matter, which are fed upon by
protozoa Protozoa (singular: protozoan or protozoon; alternative plural: protozoans) are a group of single-celled eukaryotes, either free-living or parasitic, that feed on organic matter such as other microorganisms or organic tissues and debris. Histo ...
, which in turn are fed upon by
nematodes The nematodes ( or grc-gre, Νηματώδη; la, Nematoda) or roundworms constitute the phylum Nematoda (also called Nemathelminthes), with plant- parasitic nematodes also known as eelworms. They are a diverse animal phylum inhabiting a bro ...
,
annelids The annelids (Annelida , from Latin ', "little ring"), also known as the segmented worms, are a large phylum, with over 22,000 extant species including ragworms, earthworms, and leeches. The species exist in and have adapted to various ecolog ...
and
arthropod Arthropods (, (gen. ποδός)) are invertebrate animals with an exoskeleton, a segmented body, and paired jointed appendages. Arthropods form the phylum Arthropoda. They are distinguished by their jointed limbs and cuticle made of chitin, o ...
s, themselves able to consume and transform raw or humified organic matter. This has been called the
soil food web The soil food web is the community of organisms living all or part of their lives in the soil. It describes a complex living system in the soil and how it interacts with the environment, plants, and animals. Food webs describe the transfer of en ...
, through which all organic matter is processed as in a
digestive system The human digestive system consists of the gastrointestinal tract plus the accessory organs of digestion (the tongue, salivary glands, pancreas, liver, and gallbladder). Digestion involves the breakdown of food into smaller and smaller compon ...
. Organic matter holds soils open, allowing the infiltration of air and water, and may hold as much as twice its weight in water. Many soils, including desert and rocky-gravel soils, have little or no organic matter. Soils that are all organic matter, such as
peat Peat (), also known as turf (), is an accumulation of partially decayed vegetation or organic matter. It is unique to natural areas called peatlands, bogs, mires, moors, or muskegs. The peatland ecosystem covers and is the most efficient ...
(
histosols In both the World Reference Base for Soil Resources (WRB) and the USDA soil taxonomy, a Histosol is a soil consisting primarily of organic materials. They are defined as having or more of organic soil material in the upper . Organic soil materia ...
), are infertile. In its earliest stage of decomposition, the original organic material is often called raw organic matter. The final stage of decomposition is called humus. In
grassland A grassland is an area where the vegetation is dominated by grasses (Poaceae). However, sedge ( Cyperaceae) and rush (Juncaceae) can also be found along with variable proportions of legumes, like clover, and other herbs. Grasslands occur natu ...
, much of the organic matter added to the soil is from the deep, fibrous, grass root systems. By contrast, tree leaves falling on the forest floor are the principal source of soil organic matter in the forest. Another difference is the frequent occurrence in the grasslands of fires that destroy large amounts of aboveground material but stimulate even greater contributions from roots. Also, the much greater acidity under any forests inhibits the action of certain soil organisms that otherwise would mix much of the surface litter into the mineral soil. As a result, the soils under grasslands generally develop a thicker
A horizon A soil horizon is a layer parallel to the soil surface whose physical, chemical and biological characteristics differ from the layers above and beneath. Horizons are defined in many cases by obvious physical features, mainly colour and texture. ...
with a deeper distribution of organic matter than in comparable soils under forests, which characteristically store most of their organic matter in the forest floor ( O horizon) and thin A horizon.


Humus

Humus refers to organic matter that has been decomposed by soil microflora and fauna to the point where it is resistant to further breakdown. Humus usually constitutes only five percent of the soil or less by volume, but it is an essential source of nutrients and adds important textural qualities crucial to
soil health Soil health is a state of a soil meeting its range of ecosystem functions as appropriate to its environment. In more colloquial terms, the health of soil arises from favorable interactions of all soil components (living and non-living) that belong ...
and plant growth. Humus also feeds arthropods,
termites Termites are small insects that live in colonies and have distinct castes (eusocial) and feed on wood or other dead plant matter. Termites comprise the infraorder Isoptera, or alternatively the epifamily Termitoidae, within the order Blattod ...
and
earthworms An earthworm is a terrestrial invertebrate that belongs to the phylum Annelida. They exhibit a tube-within-a-tube body plan; they are externally segmented with corresponding internal segmentation; and they usually have setae on all segments. T ...
which further improve the soil. The end product, humus, is suspended in
colloidal A colloid is a mixture in which one substance consisting of microscopically dispersed insoluble particles is suspended throughout another substance. Some definitions specify that the particles must be dispersed in a liquid, while others extend ...
form in the soil solution and forms a
weak acid Acid strength is the tendency of an acid, symbolised by the chemical formula HA, to dissociate into a proton, H+, and an anion, A-. The dissociation of a strong acid in solution is effectively complete, except in its most concentrated solutio ...
that can attack silicate minerals by
chelating Chelation is a type of bonding of ions and molecules to metal ions. It involves the formation or presence of two or more separate coordinate bonds between a polydentate (multiple bonded) ligand and a single central metal atom. These ligands ar ...
their iron and aluminum atoms. Humus has a high cation and anion exchange capacity that on a dry weight basis is many times greater than that of clay colloids. It also acts as a buffer, like clay, against changes in pH and soil moisture.
Humic acid Humic substances (HS) are organic compounds that are important components of humus, the major organic fraction of soil, peat, and coal (and also a constituent of many upland streams, dystrophic lakes, and ocean water). For a long era in the 19th an ...
s and
fulvic acid Humic substances (HS) are organic compounds that are important components of humus, the major organic fraction of soil, peat, and coal (and also a constituent of many upland streams, dystrophic lakes, and ocean water). For a long era in the 19t ...
s, which begin as raw organic matter, are important constituents of humus. After the death of plants, animals, and microbes, microbes begin to feed on the residues through their production of extra-cellular soil enzymes, resulting finally in the formation of humus. As the residues break down, only molecules made of
aliphatic In organic chemistry, hydrocarbons ( compounds composed solely of carbon and hydrogen) are divided into two classes: aromatic compounds and aliphatic compounds (; G. ''aleiphar'', fat, oil). Aliphatic compounds can be saturated, like hexane, o ...
and
aromatic In chemistry, aromaticity is a chemical property of cyclic ( ring-shaped), ''typically'' planar (flat) molecular structures with pi bonds in resonance (those containing delocalized electrons) that gives increased stability compared to satu ...
hydrocarbons, assembled and stabilized by oxygen and hydrogen bonds, remain in the form of complex molecular assemblages collectively called humus. Humus is never pure in the soil, because it reacts with metals and clays to form complexes which further contribute to its stability and to soil structure. Although the structure of humus has in itself few nutrients (with the exception of constitutive metals such as calcium, iron and aluminum) it is able to attract and link, by weak bonds, cation and anion nutrients that can further be released into the soil solution in response to selective root uptake and changes in soil pH, a process of paramount importance for the maintenance of fertility in tropical soils.
Lignin Lignin is a class of complex organic polymers that form key structural materials in the support tissues of most plants. Lignins are particularly important in the formation of cell walls, especially in wood and bark, because they lend rigidity a ...
is resistant to breakdown and accumulates within the soil. It also reacts with
proteins Proteins are large biomolecules and macromolecules that comprise one or more long chains of amino acid residues. Proteins perform a vast array of functions within organisms, including catalysing metabolic reactions, DNA replication, respo ...
, which further increases its resistance to decomposition, including enzymatic decomposition by microbes.
Fat In nutrition, biology, and chemistry, fat usually means any ester of fatty acids, or a mixture of such compounds, most commonly those that occur in living beings or in food. The term often refers specifically to triglycerides (triple est ...
s and
wax Waxes are a diverse class of organic compounds that are lipophilic, malleable solids near ambient temperatures. They include higher alkanes and lipids, typically with melting points above about 40 °C (104 °F), melting to give low ...
es from plant matter have still more resistance to decomposition and persist in soils for thousand years, hence their use as tracers of past vegetation in buried soil layers. Clay soils often have higher organic contents that persist longer than soils without clay as the organic molecules adhere to and are stabilised by the clay. Proteins normally decompose readily, to the exception of scleroproteins, but when bound to clay particles they become more resistant to decomposition. As for other proteins clay particles absorb the enzymes exuded by microbes, decreasing
enzyme activity Enzyme assays are laboratory methods for measuring enzymatic activity. They are vital for the study of enzyme kinetics and enzyme inhibition. Enzyme units The quantity or concentration of an enzyme can be expressed in molar amounts, as with any ...
while protecting extracellular enzymes from degradation. The addition of organic matter to clay soils can render that organic matter and any added nutrients inaccessible to plants and microbes for many years. A study showed increased soil fertility following the addition of mature compost to a clay soil. High soil
tannin Tannins (or tannoids) are a class of astringent, polyphenolic biomolecules that bind to and precipitate proteins and various other organic compounds including amino acids and alkaloids. The term ''tannin'' (from Anglo-Norman ''tanner'', ...
content can cause nitrogen to be sequestered as resistant tannin-protein complexes. Humus formation is a process dependent on the amount of plant material added each year and the type of base soil. Both are affected by climate and the type of organisms present. Soils with humus can vary in nitrogen content but typically have 3 to 6 percent nitrogen. Raw organic matter, as a reserve of nitrogen and phosphorus, is a vital component affecting
soil fertility Soil fertility refers to the ability of soil to sustain agricultural plant growth, i.e. to provide plant habitat and result in sustained and consistent yields of high quality.
. Humus also absorbs water, and expands and shrinks between dry and wet states to a higher extent than clay, increasing soil porosity. Humus is less stable than the soil's mineral constituents, as it is reduced by microbial decomposition, and over time its concentration diminishes without the addition of new organic matter. However, humus in its most stable forms may persist over centuries if not millennia.
Charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, cal ...
is a source of highly stable humus, called
black carbon Chemically, black carbon (BC) is a component of fine particulate matter (PM ≤ 2.5  µm in aerodynamic diameter). Black carbon consists of pure carbon in several linked forms. It is formed through the incomplete combustion of fossil fuel ...
, which had been used traditionally to improve the fertility of nutrient-poor tropical soils. This very ancient practice, as ascertained in the genesis of Amazonian dark earths, has been renewed and became popular under the name of
biochar Biochar is the lightweight black residue, made of carbon and ashes, remaining after the pyrolysis of biomass. Biochar is defined by the International Biochar Initiative as "the solid material obtained from the thermochemical conversion ...
. It has been suggested that biochar could be used to sequester more carbon in the fight against the greenhouse effect.


Climatological influence

The production, accumulation and degradation of organic matter are greatly dependent on climate. For example, when a thawing event occurs, the flux of soil gases with atmospheric gases is significantly influenced. Temperature, soil moisture and
topography Topography is the study of the forms and features of land surfaces. The topography of an area may refer to the land forms and features themselves, or a description or depiction in maps. Topography is a field of geoscience and planetary scien ...
are the major factors affecting the accumulation of organic matter in soils. Organic matter tends to accumulate under wet or cold conditions where
decomposer Decomposers are organisms that break down dead or decaying organisms; they carry out decomposition, a process possible by only certain kingdoms, such as fungi. Like herbivores and predators, decomposers are heterotrophic, meaning that they use ...
activity is impeded by low temperature or excess moisture which results in anaerobic conditions. Conversely, excessive rain and high temperatures of tropical climates enables rapid decomposition of organic matter and leaching of plant nutrients. Forest ecosystems on these soils rely on efficient recycling of nutrients and plant matter by the living plant and microbial biomass to maintain their productivity, a process which is disturbed by human activities. Excessive slope, in particular in the presence of cultivation for the sake of agriculture, may encourage the erosion of the top layer of soil which holds most of the raw organic material that would otherwise eventually become humus.


Plant residue

Cellulose Cellulose is an organic compound with the formula , a polysaccharide consisting of a linear chain of several hundred to many thousands of β(1→4) linked D-glucose units. Cellulose is an important structural component of the primary cell wall ...
and
hemicellulose A hemicellulose (also known as polyose) is one of a number of heteropolymers (matrix polysaccharides), such as arabinoxylans, present along with cellulose in almost all terrestrial plant cell walls.Scheller HV, Ulvskov Hemicelluloses.// Annu Rev ...
undergo fast decomposition by fungi and bacteria, with a half-life of 12–18 days in a temperate climate. Brown rot fungi can decompose the cellulose and hemicellulose, leaving the lignin and phenolic compounds behind.
Starch Starch or amylum is a polymeric carbohydrate consisting of numerous glucose units joined by glycosidic bonds. This polysaccharide is produced by most green plants for energy storage. Worldwide, it is the most common carbohydrate in human diets ...
, which is an
energy storage Energy storage is the capture of energy produced at one time for use at a later time to reduce imbalances between energy demand and energy production. A device that stores energy is generally called an accumulator or battery. Energy comes in ...
system for plants, undergoes fast decomposition by bacteria and fungi. Lignin consists of
polymers A polymer (; Greek '' poly-'', "many" + '' -mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and ...
composed of 500 to 600 units with a highly branched, amorphous structure, linked to cellulose, hemicellulose and
pectin Pectin ( grc, πηκτικός ': "congealed" and "curdled") is a heteropolysaccharide, a structural acid contained in the primary lamella, in the middle lamella, and in the cell walls of terrestrial plants. The principal, chemical component o ...
in plant cell walls. Lignin undergoes very slow decomposition, mainly by
white rot A wood-decay or xylophagous fungus is any species of fungus that digests moist wood, causing it to rot. Some species of wood-decay fungi attack dead wood, such as brown rot, and some, such as '' Armillaria'' (honey fungus), are parasitic and co ...
fungi and actinomycetes; its half-life under temperate conditions is about six months.


Horizons

A horizontal layer of the soil, whose physical features, composition and age are distinct from those above and beneath, is referred to as a soil horizon. The naming of a horizon is based on the type of material of which it is composed. Those materials reflect the duration of specific processes of soil formation. They are labelled using a shorthand notation of letters and numbers which describe the horizon in terms of its colour, size, texture, structure, consistency, root quantity, pH, voids, boundary characteristics and presence of nodules or concretions. No soil profile has all the major horizons. Some, called
entisols Entisols are soils defined in USDA soil taxonomy that do not show any profile development other than an A horizon. An entisol has no diagnostic horizons, and most are basically unaltered from their parent material, which can be unconsolidated sed ...
, may have only one horizon or are currently considered as having no horizon, in particular incipient soils from unreclaimed
mining waste In mining, tailings are the materials left over after the process of separating the valuable fraction from the uneconomic fraction (gangue) of an ore. Tailings are different to overburden, which is the waste rock or other material that overli ...
deposits,
moraines A moraine is any accumulation of unconsolidated debris (regolith and rock), sometimes referred to as glacial till, that occurs in both currently and formerly glaciated regions, and that has been previously carried along by a glacier or ice she ...
, volcanic cones
sand dunes A dune is a landform composed of wind- or water-driven sand. It typically takes the form of a mound, ridge, or hill. An area with dunes is called a dune system or a dune complex. A large dune complex is called a dune field, while broad, fl ...
or alluvial terraces. Upper soil horizons may be lacking in truncated soils following wind or water ablation, with concomitant downslope burying of soil horizons, a natural process aggravated by agricultural practices such as tillage. The growth of trees is another source of disturbance, creating a micro-scale heterogeneity which is still visible in soil horizons once trees have died. By passing from a horizon to another, from the top to the bottom of the soil profile, one goes back in time, with past events registered in soil horizons like in
sediment Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sand a ...
layers. Sampling
pollen Pollen is a powdery substance produced by seed plants. It consists of pollen grains (highly reduced microgametophytes), which produce male gametes (sperm cells). Pollen grains have a hard coat made of sporopollenin that protects the gametophy ...
, testate amoebae and plant remains in soil horizons may help to reveal environmental changes (e.g. climate change,
land use Land use involves the management and modification of natural environment or wilderness into built environment such as settlements and semi-natural habitats such as arable fields, pastures, and managed woods. Land use by humans has a long his ...
change) which occurred in the course of soil formation. Soil horizons can be dated by several methods such as
radiocarbon Carbon-14, C-14, or radiocarbon, is a radioactive isotope of carbon with an atomic nucleus containing 6 protons and 8 neutrons. Its presence in organic materials is the basis of the radiocarbon dating method pioneered by Willard Libby and co ...
, using pieces of charcoal provided they are of enough size to escape pedoturbation by earthworm activity and other mechanical disturbances. Fossil soil horizons from
paleosols In the geosciences, paleosol (''palaeosol'' in Great Britain and Australia) is an ancient soil that formed in the past. The precise definition of the term in geology and paleontology is slightly different from its use in soil science. In geolo ...
can be found within
sedimentary rock Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles t ...
sequences, allowing the study of past environments. The exposure of parent material to favourable conditions produces mineral soils that are marginally suitable for plant growth, as is the case in eroded soils. The growth of vegetation results in the production of organic residues which fall on the ground as litter for plant aerial parts (leaf litter) or are directly produced belowground for subterranean plant organs (root litter), and then release
dissolved organic matter Dissolved organic carbon (DOC) is the fraction of organic carbon operationally defined as that which can pass through a filter with a pore size typically between 0.22 and 0.7 micrometers. The fraction remaining on the filter is called partic ...
. The remaining surficial organic layer, called the O horizon, produces a more active soil due to the effect of the organisms that live within it. Organisms colonise and break down organic materials, making available nutrients upon which other plants and animals can live. After sufficient time, humus moves downward and is deposited in a distinctive organic-mineral surface layer called the A horizon, in which organic matter is mixed with mineral matter through the activity of burrowing animals, a process called pedoturbation. This natural process does not go to completion in the presence of conditions detrimental to soil life such as strong acidity, cold climate or pollution, stemming in the accumulation of undecomposed organic matter within a single organic horizon overlying the mineral soil and in the juxtaposition of humified organic matter and mineral particles, without intimate mixing, in the underlying mineral horizons.


Classification

One of the first soil classification systems was developed by Russian scientist
Vasily Dokuchaev Vasily Vasilyevich Dokuchaev (russian: Васи́лий Васи́льевич Докуча́ев; 1 March 1846 – 8 November 1903) was a Russian geologist and geographer who is credited with laying the foundations of soil science. The U ...
around 1880. It was modified a number of times by American and European researchers and was developed into the system commonly used until the 1960s. It was based on the idea that soils have a particular morphology based on the materials and factors that form them. In the 1960s, a different classification system began to emerge which focused on
soil morphology Soil morphology is the study of the formation and description of soil types within various soil horizons. C.F. Marbut championed reliance on soil morphology instead of on theories of pedogenesis for soil classification because theories of soil gen ...
instead of parental materials and soil-forming factors. Since then, it has undergone further modifications. The
World Reference Base for Soil Resources The World Reference Base for Soil Resources (WRB) is an international soil classification system for naming soils and creating legends for soil maps. The currently valid version is the fourth edition 2022. It is edited by a working group of the Int ...
aims to establish an international reference base for soil classification.


Uses

Soil is used in agriculture, where it serves as the anchor and primary nutrient base for plants. The types of soil and available moisture determine the species of plants that can be cultivated.
Agricultural soil science Agricultural soil science is a branch of soil science that deals with the study of edaphic conditions as they relate to the production of food and fiber. In this context, it is also a constituent of the field of agronomy and is thus also descr ...
was the primeval domain of soil knowledge, long time before the advent of
pedology Pedology (from Greek: πέδον, ''pedon'', "soil"; and λόγος, ''logos'', "study") is a discipline within soil science which focuses on understanding and characterizing soil formation, evolution, and the theoretical frameworks for modeling ...
in the 19th century. However, as demonstrated by
aeroponics Aeroponics is the process of growing plants in the air or mist environment without soil or an aggregate medium. The word "aeroponic" is derived from the Greek meanings of ''aer'' ("air") and ''ponos'' ("labour"). It is a subset of hydroponics ...
,
aquaponics Aquaponics is a food production system that couples aquaculture (raising aquatic animals such as fish, crayfish, snails or prawns in tanks) with hydroponics (cultivating plants in water) whereby the nutrient-rich aquaculture water is fed to hyd ...
and
hydroponics Hydroponics is a type of horticulture and a subset of hydroculture which involves growing plants, usually crops or medicinal plants, without soil, by using water-based mineral nutrient solutions in aqueous solvents. Terrestrial or aquatic plant ...
, soil material is not an absolute essential for agriculture, and soilless cropping systems have been claimed as the future of agriculture for an endless growing mankind. Soil material is also a critical component in mining, construction and landscape development industries. Soil serves as a foundation for most construction projects. The movement of massive volumes of soil can be involved in
surface mining Surface mining, including strip mining, open-pit mining and mountaintop removal mining, is a broad category of mining in which soil and rock overlying the mineral deposit (the overburden) are removed, in contrast to underground mining, in which ...
,
road building A road is a linear way for the conveyance of traffic that mostly has an improved surface for use by vehicles (motorized and non-motorized) and pedestrians. Unlike streets, the main function of roads is transportation. There are many types o ...
and
dam A dam is a barrier that stops or restricts the flow of surface water or underground streams. Reservoirs created by dams not only suppress floods but also provide water for activities such as irrigation, human consumption, industrial use, a ...
construction.
Earth sheltering An earth shelter, also called an earth house, earth bermed house, or underground house, is a structure (usually a house) with earth (soil) against the walls, on the roof, or that is entirely buried underground. Earth acts as thermal mass, making ...
is the architectural practice of using soil for external
thermal mass In building design, thermal mass is a property of the mass of a building that enables it to store heat and provide inertia against temperature fluctuations. It is sometimes known as the thermal flywheel effect. The thermal mass of heavy structura ...
against building walls. Many
building material Building material is material used for construction. Many naturally occurring substances, such as clay, rocks, sand, wood, and even twigs and leaves, have been used to construct buildings. Apart from naturally occurring materials, many man-ma ...
s are soil based. Loss of soil through urbanization is growing at a high rate in many areas and can be critical for the maintenance of
subsistence agriculture Subsistence agriculture occurs when farmers grow food crops to meet the needs of themselves and their families on smallholdings. Subsistence agriculturalists target farm output for survival and for mostly local requirements, with little or no ...
. Soil resources are critical to the environment, as well as to food and fibre production, producing 98.8% of food consumed by humans. Soil provides minerals and water to plants according to several processes involved in plant nutrition. Soil absorbs rainwater and releases it later, thus preventing floods and drought, flood regulation being one of the major ecosystem services provided by soil. Soil cleans water as it percolates through it. Soil is the habitat for many organisms: the major part of known and unknown
biodiversity Biodiversity or biological diversity is the variety and variability of life on Earth. Biodiversity is a measure of variation at the genetic (''genetic variability''), species (''species diversity''), and ecosystem (''ecosystem diversity'') le ...
is in the soil, in the form of earthworms,
woodlice A woodlouse (plural woodlice) is an isopod crustacean from the polyphyleticThe current consensus is that Oniscidea is actually triphyletic suborder Oniscidea within the order Isopoda. They get their name from often being found in old wood. ...
,
millipede Millipedes are a group of arthropods that are characterised by having two pairs of jointed legs on most body segments; they are known scientifically as the class Diplopoda, the name derived from this feature. Each double-legged segment is a res ...
s,
centipede Centipedes (from New Latin , "hundred", and Latin , "foot") are predatory arthropods belonging to the class Chilopoda (Ancient Greek , ''kheilos'', lip, and New Latin suffix , "foot", describing the forcipules) of the subphylum Myriapoda, an a ...
s,
snail A snail is, in loose terms, a shelled gastropod. The name is most often applied to land snails, terrestrial pulmonate gastropod molluscs. However, the common name ''snail'' is also used for most of the members of the molluscan class Gastrop ...
s,
slug Slug, or land slug, is a common name for any apparently shell-less terrestrial gastropod mollusc. The word ''slug'' is also often used as part of the common name of any gastropod mollusc that has no shell, a very reduced shell, or only a smal ...
s,
mite Mites are small arachnids (eight-legged arthropods). Mites span two large orders of arachnids, the Acariformes and the Parasitiformes, which were historically grouped together in the subclass Acari, but genetic analysis does not show clear evid ...
s,
springtail Springtails (Collembola) form the largest of the three lineages of modern hexapods that are no longer considered insects (the other two are the Protura and Diplura). Although the three orders are sometimes grouped together in a class called Ent ...
s, enchytraeids,
nematode The nematodes ( or grc-gre, Νηματώδη; la, Nematoda) or roundworms constitute the phylum Nematoda (also called Nemathelminthes), with plant- parasitic nematodes also known as eelworms. They are a diverse animal phylum inhabiting a bro ...
s,
protist A protist () is any eukaryotic organism (that is, an organism whose cells contain a cell nucleus) that is not an animal, plant, or fungus. While it is likely that protists share a common ancestor (the last eukaryotic common ancestor), the exclu ...
s), bacteria, archaea, fungi and
algae Algae (; singular alga ) is an informal term for a large and diverse group of photosynthesis, photosynthetic eukaryotic organisms. It is a polyphyletic grouping that includes species from multiple distinct clades. Included organisms range from u ...
; and most organisms living above ground have part of them (
plants Plants are predominantly photosynthetic eukaryotes of the kingdom Plantae. Historically, the plant kingdom encompassed all living things that were not animals, and included algae and fungi; however, all current definitions of Plantae exclude ...
) or spend part of their
life cycle Life cycle, life-cycle, or lifecycle may refer to: Science and academia *Biological life cycle, the sequence of life stages that an organism undergoes from birth to reproduction ending with the production of the offspring *Life-cycle hypothesis, ...
(
insects Insects (from Latin ') are pancrustacean hexapod invertebrates of the class Insecta. They are the largest group within the arthropod phylum. Insects have a chitinous exoskeleton, a three-part body (head, thorax and abdomen), three pairs of ...
) below-ground. Above-ground and below-ground biodiversities are tightly interconnected, making soil protection of paramount importance for any
restoration Restoration is the act of restoring something to its original state and may refer to: * Conservation and restoration of cultural heritage ** Audio restoration ** Film restoration ** Image restoration ** Textile restoration *Restoration ecology * ...
or
conservation Conservation is the preservation or efficient use of resources, or the conservation of various quantities under physical laws. Conservation may also refer to: Environment and natural resources * Nature conservation, the protection and manageme ...
plan. The biological component of soil is an extremely important carbon sink since about 57% of the biotic content is carbon. Even in deserts, cyanobacteria,
lichen A lichen ( , ) is a composite organism that arises from algae or cyanobacteria living among filaments of multiple fungi species in a mutualistic relationship.moss Mosses are small, non-vascular flowerless plants in the taxonomic division Bryophyta (, ) ''sensu stricto''. Bryophyta (''sensu lato'', Schimp. 1879) may also refer to the parent group bryophytes, which comprise liverworts, mosses, and hornw ...
es form
biological soil crust Biological soil crusts are communities of living organisms on the soil surface in arid and semi-arid ecosystems. They are found throughout the world with varying species composition and cover depending on topography, soil characteristics, climat ...
s which capture and sequester a significant amount of carbon by
photosynthesis Photosynthesis is a process used by plants and other organisms to convert light energy into chemical energy that, through cellular respiration, can later be released to fuel the organism's activities. Some of this chemical energy is stored in ...
. Poor farming and grazing methods have degraded soils and released much of this sequestered carbon to the atmosphere. Restoring the world's soils could offset the effect of increases in
greenhouse gas emissions Greenhouse gas emissions from human activities strengthen the greenhouse effect, contributing to climate change. Most is carbon dioxide from burning fossil fuels: coal, oil, and natural gas. The largest emitters include coal in China and lar ...
and slow global warming, while improving crop yields and reducing water needs. Waste management often has a soil component.
Septic drain field Septic drain fields, also called leach fields or leach drains, are subsurface wastewater disposal facilities used to remove contaminants and impurities from the liquid that emerges after anaerobic digestion in a septic tank. Organic materials in ...
s treat
septic tank A septic tank is an underground chamber made of concrete, fiberglass, or plastic through which domestic wastewater ( sewage) flows for basic sewage treatment. Settling and anaerobic digestion processes reduce solids and organics, but the treatm ...
effluent using
aerobic Aerobic means "requiring air," in which "air" usually means oxygen. Aerobic may also refer to * Aerobic exercise, prolonged exercise of moderate intensity * Aerobics, a form of aerobic exercise * Aerobic respiration, the aerobic process of cellu ...
soil processes. Land application of
waste water Wastewater is water generated after the use of freshwater, raw water, drinking water or saline water in a variety of deliberate applications or processes. Another definition of wastewater is "Used water from any combination of domestic, industrial ...
relies on
soil biology Soil biology is the study of microbial and faunal activity and ecology in soil. Soil life, soil biota, soil fauna, or edaphon is a collective term that encompasses all organisms that spend a significant portion of their life cycle within a soil ...
to aerobically treat BOD. Alternatively,
landfill A landfill site, also known as a tip, dump, rubbish dump, garbage dump, or dumping ground, is a site for the disposal of waste materials. Landfill is the oldest and most common form of waste disposal, although the systematic burial of the waste ...
s use soil for
daily cover The daily cover on an operational landfill site is the layer of compressed soil or earth which is laid on top of a days deposition of waste. Benefits of using daily cover include: * Reduction of odor and air emissions * Control of disease vecto ...
, isolating waste deposits from the atmosphere and preventing unpleasant smells.
Composting Compost is a mixture of ingredients used as plant fertilizer and to improve soil's physical, chemical and biological properties. It is commonly prepared by decomposing plant, food waste, recycling organic materials and manure. The resulting m ...
is now widely used to treat aerobically solid domestic waste and dried effluents of
settling basin A settling basin, settling pond or decant pond is an earthen or concrete structure using sedimentation to remove settleable matter and turbidity from wastewater. The basins are used to control water pollution in diverse industries such as agricul ...
s. Although compost is not soil, biological processes taking place during composting are similar to those occurring during decomposition and humification of soil organic matter. Organic soils, especially peat, serve as a significant fuel and
horticultural Horticulture is the branch of agriculture that deals with the art, science, technology, and business of plant cultivation. It includes the cultivation of fruits, vegetables, nuts, seeds, herbs, sprouts, mushrooms, algae, flowers, seaweeds and no ...
resource. Peat soils are also commonly used for the sake of agriculture in Nordic countries, because peatland sites, when drained, provide fertile soils for food production. However, wide areas of peat production, such as rain-fed
sphagnum ''Sphagnum'' is a genus of approximately 380 accepted species of mosses, commonly known as sphagnum moss, peat moss, also bog moss and quacker moss (although that term is also sometimes used for peat). Accumulations of ''Sphagnum'' can store wa ...
bogs, also called blanket bogs or
raised bog Raised bogs, also called ombrotrophic bogs, are acidic, wet habitats that are poor in mineral salts and are home to flora and fauna that can cope with such extreme conditions. Raised bogs, unlike fens, are exclusively fed by precipitation (ombrot ...
s, are now protected because of their patrimonial interest. As an example,
Flow Country The Flow Country is a large, rolling expanse of peatland and wetland area of Caithness and Sutherland in the North of Scotland. It is the largest expanse of blanket bog in Europe, and covers about . It is an area of deep peat, dotted with bog ...
, covering 4,000 square kilometres of rolling expanse of blanket bogs in Scotland, is now candidate for being included in the
World Heritage List A World Heritage Site is a landmark or area with legal protection by an international convention administered by the United Nations Educational, Scientific and Cultural Organization (UNESCO). World Heritage Sites are designated by UNESCO for h ...
. Under present-day global warming peat soils are thought to be involved in a self-reinforcing (positive feedback) process of increased emission of greenhouse gases (methane and carbon dioxide) and increased temperature, a contention which is still under debate when replaced at field scale and including stimulated plant growth.
Geophagy Geophagia (), also known as geophagy (), is the intentional practice of eating earth or soil-like substances such as clay, chalk, or termite mounds. It is a behavioural adaptation that occurs in many non-human animals and has been documented i ...
is the practice of eating soil-like substances. Both animals and humans occasionally consume soil for medicinal, recreational, or religious purposes. It has been shown that some
monkeys Monkey is a common name that may refer to most mammals of the infraorder Simiiformes, also known as the simians. Traditionally, all animals in the group now known as simians are counted as monkeys except the apes, which constitutes an incomple ...
consume soil, together with their preferred food (tree
foliage A leaf ( : leaves) is any of the principal appendages of a vascular plant stem, usually borne laterally aboveground and specialized for photosynthesis. Leaves are collectively called foliage, as in "autumn foliage", while the leaves, s ...
and
fruits In botany, a fruit is the seed-bearing structure in flowering plants that is formed from the ovary after flowering. Fruits are the means by which flowering plants (also known as angiosperms) disseminate their seeds. Edible fruits in particula ...
), in order to alleviate tannin toxicity. Soils filter and purify water and affect its chemistry. Rain water and pooled water from ponds, lakes and rivers percolate through the soil horizons and the upper
rock strata In geology and related fields, a stratum ( : strata) is a layer of rock or sediment characterized by certain lithologic properties or attributes that distinguish it from adjacent layers from which it is separated by visible surfaces known as e ...
, thus becoming groundwater.
Pests PESTS was an anonymous American activist group formed in 1986 to critique racism Racism is the belief that groups of humans possess different behavioral traits corresponding to inherited attributes and can be divided based on the superiority ...
(
virus A virus is a submicroscopic infectious agent that replicates only inside the living cells of an organism. Viruses infect all life forms, from animals and plants to microorganisms, including bacteria and archaea. Since Dmitri Ivanovsky's ...
es) and
pollutant A pollutant or novel entity is a substance or energy introduced into the environment that has undesired effects, or adversely affects the usefulness of a resource. These can be both naturally forming (i.e. minerals or extracted compounds like o ...
s, such as persistent organic pollutants (
chlorinated In chemistry, halogenation is a chemical reaction that entails the introduction of one or more halogens into a compound. Halide-containing compounds are pervasive, making this type of transformation important, e.g. in the production of polyme ...
pesticide Pesticides are substances that are meant to control pests. This includes herbicide, insecticide, nematicide, molluscicide, piscicide, avicide, rodenticide, bactericide, insect repellent, animal repellent, microbicide, fungicide, and lampri ...
s,
polychlorinated biphenyl Polychlorinated biphenyls (PCBs) are highly carcinogenic chemical compounds, formerly used in industrial and consumer products, whose production was banned in the United States by the Toxic Substances Control Act in 1979 and internationally by t ...
s), oils (
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ...
s), heavy metals (
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, l ...
, zinc,
cadmium Cadmium is a chemical element with the symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12, zinc and mercury. Like zinc, it demonstrates oxidation state +2 in most of ...
), and excess nutrients (nitrates,
sulfate The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ...
s, phosphates) are filtered out by the soil. Soil organisms
metabolise Metabolism (, from el, μεταβολή ''metabolē'', "change") is the set of life-sustaining chemical reactions in organisms. The three main functions of metabolism are: the conversion of the energy in food to energy available to run cell ...
them or immobilise them in their biomass and necromass, thereby incorporating them into stable humus. The physical integrity of soil is also a prerequisite for avoiding landslides in rugged landscapes.


Degradation

Land degradation Land degradation is a process in which the value of the biophysical environment is affected by a combination of human-induced processes acting upon the land. It is viewed as any change or disturbance to the land perceived to be deleterious ...
is a human-induced or natural process which impairs the capacity of
land Land, also known as dry land, ground, or earth, is the solid terrestrial surface of the planet Earth that is not submerged by the ocean or other bodies of water. It makes up 29% of Earth's surface and includes the continents and various islan ...
to function. Soil degradation involves acidification,
contamination Contamination is the presence of a constituent, impurity, or some other undesirable element that spoils, corrupts, infects, makes unfit, or makes inferior a material, physical body, natural environment, workplace, etc. Types of contamination ...
,
desertification Desertification is a type of land degradation in drylands in which biological productivity is lost due to natural processes or induced by human activities whereby fertile areas become increasingly arid. It is the spread of arid areas caused b ...
,
erosion Erosion is the action of surface processes (such as water flow or wind) that removes soil, rock, or dissolved material from one location on the Earth's crust, and then transports it to another location where it is deposited. Erosion is distin ...
or salination.


Acidification

Soil acidification is beneficial in the case of
alkaline soil Alkali, or Alkaline, soils are clay soils with high pH (greater than 8.5), a poor soil structure and a low infiltration capacity. Often they have a hard calcareous layer at 0.5 to 1 metre depth. Alkali soils owe their unfavorable physico ...
s, but it degrades land when it lowers crop productivity, soil biological activity and increases soil vulnerability to
contamination Contamination is the presence of a constituent, impurity, or some other undesirable element that spoils, corrupts, infects, makes unfit, or makes inferior a material, physical body, natural environment, workplace, etc. Types of contamination ...
and erosion. Soils are initially acid and remain such when their parent materials are low in basic
cation An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...
s (calcium, magnesium, potassium and
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable is ...
). On parent materials richer in weatherable minerals acidification occurs when basic cations are leached from the soil profile by rainfall or exported by the harvesting of forest or agricultural crops. Soil acidification is accelerated by the use of acid-forming nitrogenous fertilizers and by the effects of
acid precipitation Acid rain is rain or any other form of precipitation that is unusually acidic, meaning that it has elevated levels of hydrogen ions (low pH). Most water, including drinking water, has a neutral pH that exists between 6.5 and 8.5, but aci ...
.
Deforestation Deforestation or forest clearance is the removal of a forest or stand of trees from land that is then converted to non-forest use. Deforestation can involve conversion of forest land to farms, ranches, or urban use. The most concentrated ...
is another cause of soil acidification, mediated by increased leaching of soil nutrients in the absence of
tree canopies In biology, the canopy is the aboveground portion of a plant cropping or crop, formed by the collection of individual plant crowns. In forest ecology, canopy also refers to the upper layer or habitat zone, formed by mature tree crowns an ...
.


Contamination

Soil
contamination Contamination is the presence of a constituent, impurity, or some other undesirable element that spoils, corrupts, infects, makes unfit, or makes inferior a material, physical body, natural environment, workplace, etc. Types of contamination ...
at low levels is often within a soil's capacity to treat and assimilate
waste Waste (or wastes) are unwanted or unusable materials. Waste is any substance discarded after primary use, or is worthless, defective and of no use. A by-product, by contrast is a joint product of relatively minor economic value. A waste produ ...
material.
Soil biota Soil biology is the study of microbial and faunal activity and ecology in soil. Soil life, soil biota, soil fauna, or edaphon is a collective term that encompasses all organisms that spend a significant portion of their life cycle within a soil ...
can treat waste by transforming it, mainly through microbial
enzymatic Enzymes () are proteins that act as biological catalysts by accelerating chemical reactions. The molecules upon which enzymes may act are called substrates, and the enzyme converts the substrates into different molecules known as products. ...
activity. Soil organic matter and soil minerals can adsorb the waste material and decrease its
toxicity Toxicity is the degree to which a chemical substance or a particular mixture of substances can damage an organism. Toxicity can refer to the effect on a whole organism, such as an animal, bacterium, or plant, as well as the effect on a su ...
, although when in colloidal form they may transport the adsorbed contaminants to subsurface environments. Many waste treatment processes rely on this natural
bioremediation Bioremediation broadly refers to any process wherein a biological system (typically bacteria, microalgae, fungi, and plants), living or dead, is employed for removing environmental pollutants from air, water, soil, flue gasses, industrial effluent ...
capacity. Exceeding treatment capacity can damage soil biota and limit soil function. Derelict soils occur where industrial contamination or other development activity damages the soil to such a degree that the land cannot be used safely or productively. Remediation of derelict soil uses principles of geology, physics, chemistry and biology to degrade, attenuate, isolate or remove soil contaminants to restore
soil functions Soil functions are general capabilities of soils that are important for various agricultural, environmental, nature protection, landscape architecture and urban applications. Soil can perform many functions and these include functions related to t ...
and values. Techniques include leaching, air sparging,
soil conditioner A soil conditioner is a product which is added to soil to improve the soil’s physical qualities, usually its fertility (ability to provide nutrition for plants) and sometimes its mechanics. In general usage, the term "soil conditioner" is often ...
s,
phytoremediation Phytoremediation technologies use living plants to clean up soil, air and water contaminated with hazardous contaminants. It is defined as "the use of green plants and the associated microorganisms, along with proper soil amendments and agronomi ...
, bioremediation and Monitored Natural Attenuation. An example of diffuse pollution with contaminants is copper accumulation in
vineyard A vineyard (; also ) is a plantation of grape-bearing vines, grown mainly for winemaking, but also raisins, table grapes and non-alcoholic grape juice. The science, practice and study of vineyard production is known as viticulture. Vineyards ...
s and
orchard An orchard is an intentional plantation of trees or shrubs that is maintained for food production. Orchards comprise fruit- or nut-producing trees which are generally grown for commercial production. Orchards are also sometimes a feature of lar ...
s to which fungicides are repeatedly applied, even in
organic farming Organic farming, also known as ecological farming or biological farming,Labelling, article 30 o''Regulation (EU) 2018/848 of the European Parliament and of the Council of 30 May 2018 on organic production and labelling of organic products and re ...
. Microfibres from synthetic textiles are another type of plastic soil contamination, 100% of agricultural soil samples from southwestern China contained plastic particles, 92% of which were microfibres. Sources of microfibres likely included string or twine, as well as irrigation water in which clothes had been washed. The application of biosolids from sewage sludge and compost can introduce microplastics to soils. This adds to the burden of microplastics from other sources (e.g. the atmosphere). Approximately half the sewage sludge in Europe and North America is applied to agricultural land. In Europe it has been estimated that for every million inhabitants 113 to 770 tonnes of microplastics are added to agricultural soils each year.


Desertification

Desertification Desertification is a type of land degradation in drylands in which biological productivity is lost due to natural processes or induced by human activities whereby fertile areas become increasingly arid. It is the spread of arid areas caused b ...
, an environmental process of ecosystem degradation in arid and semi-arid regions, is often caused by badly adapted human activities such as
overgrazing Overgrazing occurs when plants are exposed to intensive grazing for extended periods of time, or without sufficient recovery periods. It can be caused by either livestock in poorly managed agricultural applications, game reserves, or nature res ...
or excess harvesting of
firewood Firewood is any wooden material that is gathered and used for fuel. Generally, firewood is not highly processed and is in some sort of recognizable log or branch form, compared to other forms of wood fuel like pellets or chips. Firewood can ...
. It is a common misconception that
drought A drought is defined as drier than normal conditions.Douville, H., K. Raghavan, J. Renwick, R.P. Allan, P.A. Arias, M. Barlow, R. Cerezo-Mota, A. Cherchi, T.Y. Gan, J. Gergis, D.  Jiang, A.  Khan, W.  Pokam Mba, D.  Rosenfeld, J. Tierney, an ...
causes desertification. Droughts are common in arid and semiarid lands. Well-managed lands can recover from drought when the rains return.
Soil management Soil management is the application of operations, practices, and treatments to protect soil and enhance its performance (such as soil fertility or soil mechanics). It includes soil conservation, soil amendment, and optimal soil health. In agricult ...
tools include maintaining soil nutrient and organic matter levels, reduced tillage and increased cover. These practices help to control erosion and maintain productivity during periods when moisture is available. Continued land abuse during droughts, however, increases
land degradation Land degradation is a process in which the value of the biophysical environment is affected by a combination of human-induced processes acting upon the land. It is viewed as any change or disturbance to the land perceived to be deleterious ...
. Increased population and livestock pressure on marginal lands accelerates desertification. It is now questioned whether present-day climate warming will favour or disfavour desertification, with contradictory reports about predicted rainfall trends associated with increased temperature, and strong discrepancies among regions, even in the same country.


Erosion

Erosion Erosion is the action of surface processes (such as water flow or wind) that removes soil, rock, or dissolved material from one location on the Earth's crust, and then transports it to another location where it is deposited. Erosion is distin ...
of soil is caused by
water Water (chemical formula ) is an Inorganic compound, inorganic, transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living ...
,
wind Wind is the natural movement of air or other gases relative to a planet's surface. Winds occur on a range of scales, from thunderstorm flows lasting tens of minutes, to local breezes generated by heating of land surfaces and lasting a few hou ...
,
ice Ice is water frozen into a solid state, typically forming at or below temperatures of 0 degrees Celsius or Depending on the presence of impurities such as particles of soil or bubbles of air, it can appear transparent or a more or less opaq ...
, and movement in response to gravity. More than one kind of erosion can occur simultaneously. Erosion is distinguished from
weathering Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement), ...
, since erosion also transports eroded soil away from its place of origin (soil in transit may be described as
sediment Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sand a ...
). Erosion is an intrinsic natural process, but in many places it is greatly increased by human activity, especially unsuitable land use practices. These include
agricultural Agriculture or farming is the practice of cultivating plants and livestock. Agriculture was the key development in the rise of sedentary human civilization, whereby farming of domesticated species created food surpluses that enabled people ...
activities which leave the soil bare during times of heavy rain or strong winds,
overgrazing Overgrazing occurs when plants are exposed to intensive grazing for extended periods of time, or without sufficient recovery periods. It can be caused by either livestock in poorly managed agricultural applications, game reserves, or nature res ...
,
deforestation Deforestation or forest clearance is the removal of a forest or stand of trees from land that is then converted to non-forest use. Deforestation can involve conversion of forest land to farms, ranches, or urban use. The most concentrated ...
, and improper construction activity. Improved management can limit erosion. Soil conservation techniques which are employed include changes of land use (such as replacing erosion-prone
crop A crop is a plant that can be grown and harvested extensively for profit or subsistence. When the plants of the same kind are cultivated at one place on a large scale, it is called a crop. Most crops are cultivated in agriculture or hydroponi ...
s with
grass Poaceae () or Gramineae () is a large and nearly ubiquitous family of monocotyledonous flowering plants commonly known as grasses. It includes the cereal grasses, bamboos and the grasses of natural grassland and species cultivated in lawns and ...
or other soil-binding plants), changes to the timing or type of agricultural operations,
terrace Terrace may refer to: Landforms and construction * Fluvial terrace, a natural, flat surface that borders and lies above the floodplain of a stream or river * Terrace, a street suffix * Terrace, the portion of a lot between the public sidewalk ...
building, use of erosion-suppressing cover materials (including
cover crops In agriculture, cover crops are plants that are planted to cover the soil rather than for the purpose of being harvested. Cover crops manage soil erosion, soil fertility, soil quality, water, weeds, pests, diseases, biodiversity and wildlife in ...
and other plants), limiting disturbance during construction, and avoiding construction during erosion-prone periods and in erosion-prone places such as steep slopes. Historically, one of the best examples of large-scale soil erosion due to unsuitable land-use practices is wind erosion (the so-called
dust bowl The Dust Bowl was a period of severe dust storms that greatly damaged the ecology and agriculture of the American and Canadian prairies during the 1930s. The phenomenon was caused by a combination of both natural factors (severe drought) an ...
) which ruined American and Canadian prairies during the 1930s, when immigrant farmers, encouraged by the federal government of both countries, settled and converted the original
shortgrass prairie The shortgrass prairie is an ecosystem located in the Great Plains of North America. The two most dominant grasses in the shortgrass prairie are blue grama (''Bouteloua gracilis'') and buffalograss ('' Bouteloua dactyloides''), the two less domi ...
to agricultural crops and
cattle ranching A ranch (from es, rancho/Mexican Spanish) is an area of land, including various structures, given primarily to ranching, the practice of raising grazing livestock such as cattle and sheep. It is a subtype of a farm. These terms are most often ...
. A serious and long-running water erosion problem occurs in China, on the middle reaches of the
Yellow River The Yellow River or Huang He (Chinese: , Mandarin: ''Huáng hé'' ) is the second-longest river in China, after the Yangtze River, and the sixth-longest river system in the world at the estimated length of . Originating in the Bayan Ha ...
and the upper reaches of the
Yangtze River The Yangtze or Yangzi ( or ; ) is the longest river in Asia, the third-longest in the world, and the longest in the world to flow entirely within one country. It rises at Jari Hill in the Tanggula Mountains (Tibetan Plateau) and flows ...
. From the Yellow River, over 1.6 billion tons of sediment flow each year into the ocean. The sediment originates primarily from water erosion (gully erosion) in the
Loess Plateau The Chinese Loess Plateau, or simply the Loess Plateau, is a plateau in north-central China formed of loess, a clastic silt-like sediment formed by the accumulation of wind-blown dust. It is located southeast of the Gobi Desert and is surround ...
region of northwest China. Soil piping is a particular form of soil erosion that occurs below the soil surface. It causes
levee A levee (), dike (American English), dyke (Commonwealth English), embankment, floodbank, or stop bank is a structure that is usually earthen and that often runs parallel to the course of a river in its floodplain or along low-lying coastlin ...
and dam failure, as well as
sink hole A sinkhole is a depression or hole in the ground caused by some form of collapse of the surface layer. The term is sometimes used to refer to doline, enclosed depressions that are locally also known as ''vrtače'' and shakeholes, and to openi ...
formation. Turbulent flow removes soil starting at the mouth of the
seep A seep or flush is a moist or wet place where water, usually groundwater, reaches the earth's surface from an underground aquifer. Description Seeps are usually not of sufficient volume to be flowing beyond their immediate above-ground location. ...
flow and the
subsoil Subsoil is the layer of soil under the topsoil on the surface of the ground. Like topsoil, it is composed of a variable mixture of small particles such as sand, silt and clay, but with a much lower percentage of organic matter and humus, and it ...
erosion advances up-gradient. The term
sand boil Sand boils or sand volcanoes occur when water under pressure wells up through a bed of sand. The water looks like it is boiling up from the bed of sand, hence the name. Sand volcano A sand volcano or sand blow is a cone of sand formed by the ...
is used to describe the appearance of the discharging end of an active soil pipe.


Salination

Soil salination Soil salinity is the salt content in the soil; the process of increasing the salt content is known as salinization. Salts occur naturally within soils and water. Salination can be caused by natural processes such as mineral weathering or by the ...
is the accumulation of free
salt Salt is a mineral composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of salts; salt in the form of a natural crystalline mineral is known as rock salt or halite. Salt is present in vast quantiti ...
s to such an extent that it leads to degradation of the agricultural value of soils and vegetation. Consequences include
corrosion Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...
damage, reduced plant growth, erosion due to loss of plant cover and soil structure, and
water quality Water quality refers to the chemical, physical, and biological characteristics of water based on the standards of its usage. It is most frequently used by reference to a set of standards against which compliance, generally achieved through tr ...
problems due to
sedimentation Sedimentation is the deposition of sediments. It takes place when particles in suspension settle out of the fluid in which they are entrained and come to rest against a barrier. This is due to their motion through the fluid in response to the ...
. Salination occurs due to a combination of natural and human-caused processes. Arid conditions favour salt accumulation. This is especially apparent when soil parent material is saline.
Irrigation Irrigation (also referred to as watering) is the practice of applying controlled amounts of water to land to help grow crops, landscape plants, and lawns. Irrigation has been a key aspect of agriculture for over 5,000 years and has been develo ...
of arid lands is especially problematic. All irrigation water has some level of salinity. Irrigation, especially when it involves leakage from canals and overirrigation in the field, often raises the underlying
water table The water table is the upper surface of the zone of saturation. The zone of saturation is where the pores and fractures of the ground are saturated with water. It can also be simply explained as the depth below which the ground is saturated. T ...
. Rapid salination occurs when the land surface is within the capillary fringe of saline groundwater.
Soil salinity control Soil salinity control relates to controlling the problem of soil salinity and reclaiming salinized agricultural land. The aim of soil salinity control is to prevent soil degradation by salination and reclamation of already salty (saline) soils ...
involves
watertable control Watertable control is the practice of controlling the height of the water table by drainage. Its main applications are in agricultural land (to improve the crop yield using agricultural drainage systems) and in cities to manage the extensive underg ...
and flushing with higher levels of applied water in combination with
tile drainage Tile drainage is a form of agricultural drainage system that removes excess sub-surface water from fields to allow sufficient air space within the soil, proper cultivation, and access by heavy machinery to tend and harvest crops. While surface wate ...
or another form of
subsurface drainage Drainage is the natural or artificial removal of a surface's water and sub-surface water from an area with excess of water. The internal drainage of most agricultural soils is good enough to prevent severe waterlogging (anaerobic condition ...
.


Reclamation

Soils which contain high levels of particular clays with high swelling properties, such as
smectite A smectite (from ancient Greek ''σμηκτός'' smektos 'lubricated'; ''σμηκτρίς'' smektris 'walker's earth', ' fuller's earth'; rubbing earth; earth that has the property of cleaning) is a mineral mixtures of various swelling sheet si ...
s, are often very fertile. For example, the smectite-rich paddy soils of Thailand's Central Plains are among the most productive in the world. However, the overuse of mineral nitrogen
fertilizer A fertilizer (American English) or fertiliser (British English; see spelling differences) is any material of natural or synthetic origin that is applied to soil or to plant tissues to supply plant nutrients. Fertilizers may be distinct from ...
s and pesticides in
irrigated Irrigation (also referred to as watering) is the practice of applying controlled amounts of water to land to help grow crops, landscape plants, and lawns. Irrigation has been a key aspect of agriculture for over 5,000 years and has been develo ...
intensive
rice production Rice is the seed of the Poaceae, grass species ''Oryza sativa'' (Asian rice) or less commonly ''Oryza glaberrima'' (African rice). The name wild rice is usually used for species of the genera ''Zizania (genus), Zizania'' and ''Porteresia'', bo ...
has endangered these soils, forcing farmers to implement integrated practices based on Cost Reduction Operating Principles. Many farmers in tropical areas, however, struggle to retain organic matter and clay in the soils they work. In recent years, for example, productivity has declined and soil erosion has increased in the low-clay soils of northern Thailand, following the abandonment of
shifting cultivation Shifting cultivation is an agricultural system in which plots of land are cultivated temporarily, then abandoned while post-disturbance fallow vegetation is allowed to freely grow while the cultivator moves on to another plot. The period of cul ...
for a more permanent land use. Farmers initially responded by adding organic matter and clay from termite mound material, but this was
unsustainable Specific definitions of sustainability are difficult to agree on and have varied in the literature and over time. The concept of sustainability can be used to guide decisions at the global, national, and individual levels (e.g. sustainable livi ...
in the long-term because of rarefaction of termite mounds. Scientists experimented with adding
bentonite Bentonite () is an absorbent swelling clay consisting mostly of montmorillonite (a type of smectite) which can either be Na-montmorillonite or Ca-montmorillonite. Na-montmorillonite has a considerably greater swelling capacity than Ca-mon ...
, one of the smectite family of clays, to the soil. In field trials, conducted by scientists from the
International Water Management Institute The International Water Management Institute (IWMI) is a non-profit international water management research organisation under the CGIAR with its headquarters in Colombo, Sri Lanka, and offices across Africa and Asia. Research at the Institute foc ...
(IWMI) in cooperation with
Khon Kaen University Khon Kaen University ( th, มหาวิทยาลัยขอนแก่น) or KKU (มข.) is a public research university, and it is one of the most prestigious universities in Thailand. The university was the first institution of highe ...
and local farmers, this had the effect of helping retain water and nutrients. Supplementing the farmer's usual practice with a single application of 200 kg bentonite per
rai RAI – Radiotelevisione italiana (; commercially styled as Rai since 2000; known until 1954 as Radio Audizioni Italiane) is the national public broadcasting company of Italy, owned by the Ministry of Economy and Finance. RAI operates many terr ...
(6.26 rai = 1 hectare) resulted in an average yield increase of 73%. Other studies showed that applying bentonite to degraded sandy soils reduced the risk of crop failure during drought years. In 2008, three years after the initial trials, IWMI scientists conducted a survey among 250 farmers in northeast Thailand, half of whom had applied bentonite to their fields. The average improvement for those using the clay addition was 18% higher than for non-clay users. Using the clay had enabled some farmers to switch to growing vegetables, which need more fertile soil. This helped to increase their income. The researchers estimated that 200 farmers in northeast Thailand and 400 in Cambodia had adopted the use of clays, and that a further 20,000 farmers were introduced to the new technique. If the soil is too high in clay or salts (e.g. saline sodic soil), adding gypsum, washed river sand and organic matter (e.g.
municipal solid waste Municipal solid waste (MSW), commonly known as trash or garbage in the United States and rubbish in Britain, is a waste type consisting of everyday items that are discarded by the public. "Garbage" can also refer specifically to food waste, ...
) will balance the composition. Adding organic matter, like
ramial chipped wood Ramial chipped wood (RCW), also called BRF (from the French name, bois raméal fragmenté, "chipped branch-wood"), is a type of woodchips made solely from small to medium-sized branches. The adjective "ramial" refers to branches (rami). RCW is a ...
or
compost Compost is a mixture of ingredients used as plant fertilizer and to improve soil's physical, chemical and biological properties. It is commonly prepared by decomposing plant, food waste, recycling organic materials and manure. The resulting m ...
, to soil which is depleted in nutrients and too high in sand will boost its quality and improve production. Special mention must be made of the use of
charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, cal ...
, and more generally
biochar Biochar is the lightweight black residue, made of carbon and ashes, remaining after the pyrolysis of biomass. Biochar is defined by the International Biochar Initiative as "the solid material obtained from the thermochemical conversion ...
to improve nutrient-poor tropical soils, a process based on the higher fertility of anthropogenic
pre-Columbian In the history of the Americas, the pre-Columbian era spans from the original settlement of North and South America in the Upper Paleolithic period through European colonization, which began with Christopher Columbus's voyage of 1492. Usually, t ...
Amazonian Dark Earths, also called
Terra Preta ''Terra preta'' (, locally , literally "black soil" in Portuguese) is a type of very dark, fertile anthropogenic soil ( anthrosol) found in the Amazon Basin. It is also known as "Amazonian dark earth" or "Indian black earth". In Portuguese its ful ...
de Índio, due to interesting physical and chemical properties of soil black carbon as a source of stable humus. However, the uncontrolled application of charred waste products of all kinds may endanger soil life and human health.


History of studies and research

The history of the study of soil is intimately tied to humans' urgent need to provide food for themselves and forage for their animals. Throughout history, civilizations have prospered or declined as a function of the availability and productivity of their soils.


Studies of soil fertility

The Greek historian
Xenophon Xenophon of Athens (; grc, Ξενοφῶν ; – probably 355 or 354 BC) was a Greek military leader, philosopher, and historian, born in Athens. At the age of 30, Xenophon was elected commander of one of the biggest Greek mercenary armies o ...
(450–355 
BCE Common Era (CE) and Before the Common Era (BCE) are year notations for the Gregorian calendar (and its predecessor, the Julian calendar), the world's most widely used calendar era. Common Era and Before the Common Era are alternatives to the o ...
) is credited with being the first to expound upon the merits of green-manuring crops: 'But then whatever weeds are upon the ground, being turned into earth, enrich the soil as much as dung.'
Columella Lucius Junius Moderatus Columella (; Arabic: , 4 – ) was a prominent writer on agriculture in the Roman Empire. His ' in twelve volumes has been completely preserved and forms an important source on Roman agriculture, together with the wo ...
's ''Of husbandry'', circa 60  CE, advocated the use of lime and that
clover Clover or trefoil are common names for plants of the genus ''Trifolium'' (from Latin ''tres'' 'three' + ''folium'' 'leaf'), consisting of about 300 species of flowering plants in the legume or pea family Fabaceae originating in Europe. The genus h ...
and
alfalfa Alfalfa () (''Medicago sativa''), also called lucerne, is a perennial flowering plant in the legume family Fabaceae. It is cultivated as an important forage crop in many countries around the world. It is used for grazing, hay, and silage, as we ...
(
green manure In agriculture, a green manure is a crop specifically produced to be incorporated into the soil while still green. Typically, the green manure's biomass is incorporated with a plow or disk, as is often done with (brown) manure. The primary goal ...
) should be turned under, and was used by 15 generations (450 years) under the
Roman Empire The Roman Empire ( la, Imperium Romanum ; grc-gre, Βασιλεία τῶν Ῥωμαίων, Basileía tôn Rhōmaíōn) was the post-Roman Republic, Republican period of ancient Rome. As a polity, it included large territorial holdings aro ...
until its collapse. From the
fall of Rome The fall of the Western Roman Empire (also called the fall of the Roman Empire or the fall of Rome) was the loss of central political control in the Western Roman Empire, a process in which the Empire failed to enforce its rule, and its vas ...
to the
French Revolution The French Revolution ( ) was a period of radical political and societal change in France that began with the Estates General of 1789 and ended with the formation of the French Consulate in November 1799. Many of its ideas are consider ...
, knowledge of soil and agriculture was passed on from parent to child and as a result, crop yields were low. During the European
Middle Ages In the history of Europe, the Middle Ages or medieval period lasted approximately from the late 5th to the late 15th centuries, similar to the post-classical period of global history. It began with the fall of the Western Roman Empire a ...
, Yahya Ibn al-'Awwam's handbook, with its emphasis on irrigation, guided the people of North Africa, Spain and the
Middle East The Middle East ( ar, الشرق الأوسط, ISO 233: ) is a geopolitical region commonly encompassing Arabia (including the Arabian Peninsula and Bahrain), Asia Minor (Asian part of Turkey except Hatay Province), East Thrace (Europea ...
; a translation of this work was finally carried to the southwest of the United States when under Spanish influence. Olivier de Serres, considered the father of French
agronomy Agronomy is the science and technology of producing and using plants by agriculture for food, fuel, fiber, chemicals, recreation, or land conservation. Agronomy has come to include research of plant genetics, plant physiology, meteorology, and s ...
, was the first to suggest the abandonment of fallowing and its replacement by hay
meadows A meadow ( ) is an open habitat, or field, vegetated by grasses, herbs, and other non-woody plants. Trees or shrubs may sparsely populate meadows, as long as these areas maintain an open character. Meadows may be naturally occurring or artifici ...
within
crop rotation Crop rotation is the practice of growing a series of different types of crops in the same area across a sequence of growing seasons. It reduces reliance on one set of nutrients, pest and weed pressure, and the probability of developing resistant ...
s. He also highlighted the importance of soil (the French
terroir (, ; from ''terre'', "land") is a French term used to describe the environmental factors that affect a crop's phenotype, including unique environment contexts, farming practices and a crop's specific growth habitat. Collectively, these conte ...
) in the management of vineyards. His famous book contributed to the rise of modern,
sustainable agriculture Sustainable agriculture is farming in sustainable ways meeting society's present food and textile needs, without compromising the ability for current or future generations to meet their needs. It can be based on an understanding of ecosystem s ...
and to the collapse of old agricultural practices such as
soil amendment A soil conditioner is a product which is added to soil to improve the soil’s physical qualities, usually its fertility (ability to provide nutrition for plants) and sometimes its mechanics. In general usage, the term "soil conditioner" is often ...
for crops by the lifting of forest litter and
assarting Assarting is the act of clearing forested lands for use in agriculture or other purposes. In English land law, it was illegal to assart any part of a royal forest without permission. This was the greatest trespass that could be committed in a ...
, which ruined the soils of western Europe during the Middle Ages and even later on according to regions. Experiments into what made plants grow first led to the idea that the ash left behind when plant matter was burned was the essential element but overlooked the role of nitrogen, which is not left on the ground after combustion, a belief which prevailed until the 19th century. In about 1635, the Flemish chemist
Jan Baptist van Helmont Jan Baptist van Helmont (; ; 12 January 1580 – 30 December 1644) was a chemist, physiologist, and physician from Brussels. He worked during the years just after Paracelsus and the rise of iatrochemistry, and is sometimes considered to b ...
thought he had proved water to be the essential element from his famous five years' experiment with a willow tree grown with only the addition of rainwater. His conclusion came from the fact that the increase in the plant's weight had apparently been produced only by the addition of water, with no reduction in the soil's weight. John Woodward ( 1728) experimented with various types of water ranging from clean to muddy and found muddy water the best, and so he concluded that earthy matter was the essential element. Others concluded it was humus in the soil that passed some essence to the growing plant. Still others held that the vital growth principal was something passed from dead plants or animals to the new plants. At the start of the 18th century, Jethro Tull demonstrated that it was beneficial to cultivate (stir) the soil, but his opinion that the stirring made the fine parts of soil available for plant absorption was erroneous. As chemistry developed, it was applied to the investigation of soil fertility. The French chemist
Antoine Lavoisier Antoine-Laurent de Lavoisier ( , ; ; 26 August 17438 May 1794),
CNRS (
combust oxygen internally to live. He was able to deduce that most of the weight of van Helmont's willow tree derived from air. It was the French agriculturalist
Jean-Baptiste Boussingault Jean-Baptiste Joseph Dieudonné Boussingault (2 February 1801 – 11 May 1887) was a French chemist who made significant contributions to agricultural science, petroleum science and metallurgy. Biography Jean-Baptiste Boussingault – an agric ...
who by means of experimentation obtained evidence showing that the main sources of carbon, hydrogen and oxygen for plants were air and water, while nitrogen was taken from soil.
Justus von Liebig Justus Freiherr von Liebig (12 May 1803 – 20 April 1873) was a German scientist who made major contributions to agricultural and biological chemistry, and is considered one of the principal founders of organic chemistry. As a professor at the ...
in his book ''Organic chemistry in its applications to agriculture and physiology'' (published 1840), asserted that the chemicals in plants must have come from the soil and air and that to maintain soil fertility, the used minerals must be replaced. Liebig nevertheless believed the nitrogen was supplied from the air. The enrichment of soil with guano by the Incas was rediscovered in 1802, by
Alexander von Humboldt Friedrich Wilhelm Heinrich Alexander von Humboldt (14 September 17696 May 1859) was a German polymath, geographer, naturalist, explorer, and proponent of Romantic philosophy and science. He was the younger brother of the Prussian minister, ...
. This led to its mining and that of Chilean nitrate and to its application to soil in the United States and Europe after 1840. The work of Liebig was a revolution for agriculture, and so other investigators started experimentation based on it. In England John Bennet Lawes and
Joseph Henry Gilbert Sir Joseph Henry Gilbert, Fellow of the Royal Society (1 August 1817 – 23 December 1901) was an English chemist, noteworthy for his long career spent improving the methods of practical agriculture. He was a fellow of the Royal Society. Life He ...
worked in the
Rothamsted Experimental Station Rothamsted Research, previously known as the Rothamsted Experimental Station and then the Institute of Arable Crops Research, is one of the oldest agricultural research institutions in the world, having been founded in 1843. It is located at Harp ...
, founded by the former, and that plants took nitrogen from the soil, and that salts needed to be in an available state to be absorbed by plants. Their investigations also produced the
superphosphate Triple superphosphate is a component of fertilizer that primarily consists of monocalcium phosphate, Ca(H2PO4)2. Triple superphosphate is obtained by treating phosphate rock with phosphoric acid. Traditional routes for extraction of phosphate ro ...
, consisting in the acid treatment of phosphate rock. This led to the invention and use of salts of potassium (K) and nitrogen (N) as fertilizers. Ammonia generated by the production of coke was recovered and used as fertiliser. Finally, the chemical basis of nutrients delivered to the soil in manure was understood and in the mid-19th century chemical fertilisers were applied. However, the dynamic interaction of soil and its life forms was still not understood. In 1856, J. Thomas Way discovered that ammonia contained in fertilisers was transformed into nitrates, and twenty years later
Robert Warington Robert Warington FRS (7 September 1807 – 17 November 1867) was an English chemist considered the driving force behind the creation of the world's first enduring chemistry society, The Chemical Society of London, which later became the Royal Soci ...
proved that this transformation was done by living organisms. In 1890
Sergei Winogradsky Sergei Nikolaievich Winogradsky (or Vinohradsky; published under the name of Sergius Winogradsky or M. S. Winogradsky from Ukrainian Mykolayovych Serhiy; uk, Сергій Миколайович Виноградський; 1 September 1856 – ...
announced he had found the bacteria responsible for this transformation. It was known that certain
legume A legume () is a plant in the family Fabaceae (or Leguminosae), or the fruit or seed of such a plant. When used as a dry grain, the seed is also called a pulse. Legumes are grown agriculturally, primarily for human consumption, for livestock for ...
s could take up nitrogen from the air and fix it to the soil but it took the development of bacteriology towards the end of the 19th century to lead to an understanding of the role played in nitrogen fixation by bacteria. The symbiosis of bacteria and leguminous roots, and the fixation of nitrogen by the bacteria, were simultaneously discovered by the German agronomist
Hermann Hellriegel Hermann Hellriegel (October 21, 1831 – September 24, 1895) was a German agricultural chemist who discovered that leguminous plants assimilate the free nitrogen of the atmosphere. Biography He was born at Mausitz (now part of Zwenkau), in ...
and the Dutch microbiologist
Martinus Beijerinck Martinus Willem Beijerinck (, 16 March 1851 – 1 January 1931) was a Dutch microbiologist and botanist who was one of the founders of virology and environmental microbiology. He is credited with the discovery of viruses, which he called "'' ...
. Crop rotation, mechanisation, chemical and natural fertilisers led to a doubling of wheat yields in western Europe between 1800 and 1900.


Studies of soil formation

The scientists who studied the soil in connection with agricultural practices had considered it mainly as a static substrate. However, soil is the result of evolution from more ancient geological materials, under the action of biotic and abiotic processes. After studies of the improvement of the soil commenced, other researchers began to study soil genesis and as a result also soil types and classifications. In 1860, while in Mississippi, Eugene W. Hilgard (1833–1916) studied the relationship between rock material, climate, vegetation, and the type of soils that were developed. He realised that the soils were dynamic, and considered the classification of soil types. Unfortunately, his work was not continued. At about the same time, Friedrich Albert Fallou was describing soil profiles and relating soil characteristics to their formation as part of his professional work evaluating forest and farm land for the principality of
Saxony Saxony (german: Sachsen ; Upper Saxon: ''Saggsn''; hsb, Sakska), officially the Free State of Saxony (german: Freistaat Sachsen, links=no ; Upper Saxon: ''Freischdaad Saggsn''; hsb, Swobodny stat Sakska, links=no), is a landlocked state of ...
. His 1857 book, (First principles of soil science) established modern soil science. Contemporary with Fallou's work, and driven by the same need to accurately assess land for equitable taxation, Vasily Dokuchaev led a team of soil scientists in Russia who conducted an extensive survey of soils, observing that similar basic rocks, climate and vegetation types lead to similar soil layering and types, and established the concepts for soil classifications. Due to language barriers, the work of this team was not communicated to western Europe until 1914 through a publication in German by
Konstantin Glinka Konstantin Dmitrievich Glinka (russian: Константи́н Дми́триевич Гли́нка) (1867–1927) was a Russian soil scientist. He was Director of the Agricultural College of Leningrad and Experimental Station, and the first dir ...
, a member of the Russian team. Curtis F. Marbut, influenced by the work of the Russian team, translated Glinka's publication into English, and, as he was placed in charge of the U.S.
National Cooperative Soil Survey The National Cooperative Soil Survey Program (NCSS) in the United States is a nationwide partnership of federal, regional, state, and local agencies and institutions. This partnership works together to cooperatively investigate, inventory, docum ...
, applied it to a national soil classification system.


See also


References


Sources


Bibliography

* * * ** ** ** ** **


Further reading


Soil-Net.com
A free schools-age educational site teaching about soil and its importance. * Adams, J.A. 1986. ''Dirt''. College Station, Texas: Texas A&M University Press * Certini, G., Scalenghe, R. 2006. Soils: Basic concepts and future challenges. Cambridge Univ Press, Cambridge. * David R. Montgomery, ''Dirt: The Erosion of Civilizations'', * Faulkner, Edward H. 1943. Plowman's Folly. New York, Grosset & Dunlap.
LandIS Free Soilscapes Viewer
Free interactive viewer for the Soils of England and Wales * Jenny, Hans. 1941
Factors of Soil Formation: A System of Quantitative Pedology
* Logan, W.B. 1995. Dirt: The ecstatic skin of the earth. * Mann, Charles C. September 2008. " Our good earth" ''National Geographic Magazine'' * Photographs of sand boils. * Soil Survey Division Staff. 1999. ''Soil survey manual''. Soil Conservation Service. U.S. Department of Agriculture Handbook 18. * Soil Survey Staff. 1975. ''Soil Taxonomy: A basic system of soil classification for making and interpreting soil surveys.'' USDA-SCS Agric. Handb. 436. United States Government Printing Office, Washington, DC.
Soils (Matching suitable forage species to soil type)
Oregon State University * * Janick, Jules. 2002

Purdue University
LandIS Soils Data for England and Wales
a pay source for GIS data on the soils of England and Wales and soils data source; they charge a handling fee to researchers.


External links

{{Authority control Land management Horticulture Granularity of materials Natural materials Natural resources