A seed crystal is a small piece of
single crystal
In materials science, a single crystal (or single-crystal solid or monocrystalline solid) is a material in which the crystal lattice of the entire sample is continuous and unbroken to the edges of the sample, with no grain boundaries.RIWD. "Re ...
or
polycrystal
A crystallite is a small or even microscopic crystal which forms, for example, during the cooling of many materials. Crystallites are also referred to as grains.
Bacillite is a type of crystallite. It is rodlike with parallel longulites.
Stru ...
material from which a large
crystal
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...
of typically the same material is grown in a laboratory. Used to replicate material, the use of seed crystal to promote growth avoids the otherwise slow randomness of natural crystal growth and allows manufacture on a scale suitable for industry.
Crystal enlargement
The large crystal can be
grown by dipping the seed into a
supersaturated solution
In physical chemistry, supersaturation occurs with a solution when the concentration of a solute exceeds the concentration specified by the value of solubility at equilibrium. Most commonly the term is applied to a solution of a solid in a liqu ...
, into molten material that is then cooled, or by growth on the seed face by passing vapor of the material to be grown over it.
Theory
The theory behind this effect is thought to derive from the physical intermolecular interaction that occurs between compounds in a supersaturated
solution
Solution may refer to:
* Solution (chemistry), a mixture where one substance is dissolved in another
* Solution (equation), in mathematics
** Numerical solution, in numerical analysis, approximate solutions within specified error bounds
* Soluti ...
(or possibly vapor). In solution, liberated (soluble) molecules (
solute
In chemistry, a solution is a special type of homogeneous mixture composed of two or more substances. In such a mixture, a solute is a substance dissolved in another substance, known as a solvent. If the attractive forces between the solvent ...
) are free to move about in random flow. This random flow permits for the possibility of two or more molecular compounds to interact. This interaction can potentiate intermolecular forces between the separate molecules and form a basis for a
crystal lattice
In geometry and crystallography, a Bravais lattice, named after , is an infinite array of discrete points generated by a set of discrete translation operations described in three dimensional space by
: \mathbf = n_1 \mathbf_1 + n_2 \mathbf_2 + n ...
. The placement of a seed crystal into solution allows the
recrystallization process to expedite by eliminating the need for random molecular collision or interaction. By introducing an already pre-formed basis of the target crystal to act upon, the intermolecular interactions are formed much more easily or readily, than relying on random flow. Often, this phase transition from solute in a solution to a
crystal lattice
In geometry and crystallography, a Bravais lattice, named after , is an infinite array of discrete points generated by a set of discrete translation operations described in three dimensional space by
: \mathbf = n_1 \mathbf_1 + n_2 \mathbf_2 + n ...
will be referred to as
nucleation
In thermodynamics, nucleation is the first step in the formation of either a new thermodynamic phase or structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically defined to be the process that deter ...
. Seeding is therefore said to decrease the necessary amount of time needed for nucleation to occur in a recrystallization process.
Uses
One example where a seed crystal is used to grow large
boules
''Boules'' () is a collective name for a wide range of games similar to bowls and bocce (In French: jeu or jeux, in Croatian: boćanje and in Italian: gioco or giochi) in which the objective is to throw or roll heavy balls (called in France, ...
or
ingot
An ingot is a piece of relatively pure material, usually metal, that is cast into a shape suitable for further processing. In steelmaking, it is the first step among semi-finished casting products. Ingots usually require a second procedure of sh ...
s of a single crystal is the
semiconductor
A semiconductor is a material which has an electrical resistivity and conductivity, electrical conductivity value falling between that of a electrical conductor, conductor, such as copper, and an insulator (electricity), insulator, such as glas ...
industry where methods such as the
Czochralski process or
Bridgman technique are employed.
Also during the process of
tempering chocolate
Chocolate is a food made from roasted and ground cacao seed kernels that is available as a liquid, solid, or paste, either on its own or as a flavoring agent in other foods. Cacao has been consumed in some form since at least the Olmec civil ...
, seed crystals can be used to promote the growth of favorable type V crystals
See also
*
Crystal structure
In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystal, crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric pat ...
*
Crystallization
Crystallization is the process by which solid forms, where the atoms or molecules are highly organized into a structure known as a crystal. Some ways by which crystals form are precipitating from a solution, freezing, or more rarely deposi ...
*
Laser heated pedestal growth
*
Micro-pulling-down The micro-pulling-down (μ-PD) method is a crystal growth technique based on continuous transport of the melted substance through micro-channel(s) made in a crucible bottom. Continuous solidification of the melt is progressed on a liquid/solid inte ...
*
Polycrystal
A crystallite is a small or even microscopic crystal which forms, for example, during the cooling of many materials. Crystallites are also referred to as grains.
Bacillite is a type of crystallite. It is rodlike with parallel longulites.
Stru ...
*
Single crystal
In materials science, a single crystal (or single-crystal solid or monocrystalline solid) is a material in which the crystal lattice of the entire sample is continuous and unbroken to the edges of the sample, with no grain boundaries.RIWD. "Re ...
*
Wafer (electronics)
In electronics, a wafer (also called a slice or substrate) is a thin slice of semiconductor, such as a crystalline silicon
Crystalline silicon or (c-Si) Is the crystalline forms of silicon, either polycrystalline silicon (poly-Si, consisting o ...
*
Disappearing polymorphs
References
Crystals
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