![Saphir gisements](https://upload.wikimedia.org/wikipedia/commons/a/a4/Saphir_gisements.jpg)
Sapphire is a precious
gemstone
A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rocks (such as lapis lazuli, opal, ...
, a variety of the mineral
corundum
Corundum is a crystalline form of aluminium oxide () typically containing traces of iron, titanium, vanadium and chromium. It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the pres ...
, consisting of
aluminium oxide () with trace amounts of elements such as
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
,
titanium
Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...
,
chromium
Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal.
Chromium metal is valued for its high corrosion resistance and hardne ...
,
vanadium
Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( pas ...
, or
magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
. The name sapphire is derived via the Latin "sapphirus" from the Greek "sappheiros", which referred to
lapis lazuli
Lapis lazuli (; ), or lapis for short, is a deep-blue metamorphic rock used as a semi-precious stone that has been prized since antiquity for its intense color.
As early as the 7th millennium BC, lapis lazuli was mined in the Sar-i Sang mines, ...
. It is typically blue, but natural "fancy" sapphires also occur in yellow, purple, orange, and green colors; "parti sapphires" show two or more colors. Red corundum stones also occur, but are called
rubies
A ruby is a pinkish red to blood-red colored gemstone, a variety of the mineral corundum ( aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sap ...
rather than sapphires.
Pink-colored corundum may be classified either as
ruby
A ruby is a pinkish red to blood-red colored gemstone, a variety of the mineral corundum ( aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sa ...
or sapphire depending on locale. Commonly, natural sapphires are cut and polished into gemstones and worn in
jewelry
Jewellery ( UK) or jewelry (U.S.) consists of decorative items worn for personal adornment, such as brooches, rings, necklaces, earrings, pendants, bracelets, and cufflinks. Jewellery may be attached to the body or the clothes. From a western ...
. They also may be created synthetically in laboratories for industrial or decorative purposes in large
crystal boules. Because of the remarkable
hardness
In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard ...
of sapphires 9 on the
Mohs scale
The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material.
The scale was introduced in 1812 by th ...
(the third hardest mineral, after
diamond
Diamond is a Allotropes of carbon, solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Another solid form of carbon known as graphite is the Chemical stability, chemically stable form of car ...
at 10 and
moissanite
Moissanite () is naturally occurring silicon carbide and its various crystalline polymorphs. It has the chemical formula SiC and is a rare mineral, discovered by the French chemist Henri Moissan in 1893. Silicon carbide is useful for commercial ...
at 9.5) sapphires are also used in some non-ornamental applications, such as
infrared
Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from around ...
optical
Optics is the branch of physics that studies the behaviour and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behaviour of visible, ultraviole ...
components, high-durability
window
A window is an opening in a wall, door, roof, or vehicle that allows the exchange of light and may also allow the passage of sound and sometimes air. Modern windows are usually glazed or covered in some other transparent or translucent materia ...
s,
wristwatch
A watch is a portable timepiece intended to be carried or worn by a person. It is designed to keep a consistent movement despite the motions caused by the person's activities. A wristwatch is designed to be worn around the wrist, attached by ...
crystals and movement bearings, and very thin
electronic wafers, which are used as the
insulating substrates of special-purpose
solid-state electronics
Solid-state electronics means semiconductor electronics: electronic equipment using semiconductor devices such as transistors, diodes and integrated circuits (ICs). The term is also used as an adjective for devices in which semiconductor electr ...
such as integrated circuits and
GaN
The word Gan or the initials GAN may refer to:
Places
*Gan, a component of Hebrew placenames literally meaning "garden"
China
* Gan River (Jiangxi)
* Gan River (Inner Mongolia),
* Gan County, in Jiangxi province
* Gansu, abbreviated ''Gā ...
-based blue
LEDs
A light-emitting diode (LED) is a semiconductor device that emits light when current flows through it. Electrons in the semiconductor recombine with electron holes, releasing energy in the form of photons. The color of the light (cor ...
. Sapphire is the
birthstone
A birthstone is a gemstone
A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rock ...
for September and the gem of the 45th
anniversary
An anniversary is the date on which an event took place or an institution was founded in a previous year, and may also refer to the commemoration or celebration of that event. The word was first used for Catholic feasts to commemorate saints ...
. A
sapphire jubilee
In 2017, the term sapphire jubilee or blue sapphire jubilee was coined for the celebrations to mark the 65th anniversary of the reign of Queen Elizabeth II (see Sapphire Jubilee of Queen Elizabeth II). Previously, the sapphire wedding anniversary w ...
occurs after 65 years.
Natural sapphires
![LgYellowSapphire](https://upload.wikimedia.org/wikipedia/commons/c/c4/LgYellowSapphire.jpg)
Sapphire is one of the two gem-varieties of
corundum
Corundum is a crystalline form of aluminium oxide () typically containing traces of iron, titanium, vanadium and chromium. It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the pres ...
, the other being
ruby
A ruby is a pinkish red to blood-red colored gemstone, a variety of the mineral corundum ( aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sa ...
(defined as corundum in a shade of red). Although blue is the best-known sapphire color, they occur in other colors, including gray and black, and also can be colorless. A pinkish orange variety of sapphire is called
padparadscha
Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide () with trace amounts of elements such as iron, titanium, chromium, vanadium, or magnesium. The name sapphire is derived via the Latin "sapphir ...
.
Significant sapphire deposits are found in
Australia
Australia, officially the Commonwealth of Australia, is a Sovereign state, sovereign country comprising the mainland of the Australia (continent), Australian continent, the island of Tasmania, and numerous List of islands of Australia, sma ...
,
Afghanistan
Afghanistan, officially the Islamic Emirate of Afghanistan,; prs, امارت اسلامی افغانستان is a landlocked country located at the crossroads of Central Asia and South Asia. Referred to as the Heart of Asia, it is bordere ...
,
Cambodia
Cambodia (; also Kampuchea ; km, កម្ពុជា, UNGEGN: ), officially the Kingdom of Cambodia, is a country located in the southern portion of the Indochinese Peninsula in Southeast Asia, spanning an area of , bordered by Thailand t ...
,
Cameroon
Cameroon (; french: Cameroun, ff, Kamerun), officially the Republic of Cameroon (french: République du Cameroun, links=no), is a country in west-central Africa. It is bordered by Nigeria to the west and north; Chad to the northeast; the C ...
,
China
China, officially the People's Republic of China (PRC), is a country in East Asia. It is the world's most populous country, with a population exceeding 1.4 billion, slightly ahead of India. China spans the equivalent of five time zones and ...
(
Shandong
Shandong ( , ; ; alternately romanized as Shantung) is a coastal province of the People's Republic of China and is part of the East China region.
Shandong has played a major role in Chinese history since the beginning of Chinese civilizati ...
),
Colombia
Colombia (, ; ), officially the Republic of Colombia, is a country in South America with insular regions in North America—near Nicaragua's Caribbean coast—as well as in the Pacific Ocean. The Colombian mainland is bordered by the Car ...
,
Ethiopia
Ethiopia, , om, Itiyoophiyaa, so, Itoobiya, ti, ኢትዮጵያ, Ítiyop'iya, aa, Itiyoppiya officially the Federal Democratic Republic of Ethiopia, is a landlocked country in the Horn of Africa. It shares borders with Eritrea to the ...
,
India
India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the seventh-largest country by area, the second-most populous country, and the most populous democracy in the world. Bounded by the Indian Ocean on the so ...
(
Kashmir
Kashmir () is the northernmost geographical region of the Indian subcontinent. Until the mid-19th century, the term "Kashmir" denoted only the Kashmir Valley between the Great Himalayas and the Pir Panjal Range. Today, the term encompas ...
),
Kenya
)
, national_anthem = "Ee Mungu Nguvu Yetu"()
, image_map =
, map_caption =
, image_map2 =
, capital = Nairobi
, coordinates =
, largest_city = Nairobi
, ...
,
Laos
Laos (, ''Lāo'' )), officially the Lao People's Democratic Republic ( Lao: ສາທາລະນະລັດ ປະຊາທິປະໄຕ ປະຊາຊົນລາວ, French: République démocratique populaire lao), is a socialist ...
,
Madagascar
Madagascar (; mg, Madagasikara, ), officially the Republic of Madagascar ( mg, Repoblikan'i Madagasikara, links=no, ; french: République de Madagascar), is an island country in the Indian Ocean, approximately off the coast of East Africa ...
,
Malawi
Malawi (; or aláwi Tumbuka: ''Malaŵi''), officially the Republic of Malawi, is a landlocked country in Southeastern Africa that was formerly known as Nyasaland. It is bordered by Zambia to the west, Tanzania to the north and northeast ...
,
Mozambique
Mozambique (), officially the Republic of Mozambique ( pt, Moçambique or , ; ny, Mozambiki; sw, Msumbiji; ts, Muzambhiki), is a country located in southeastern Africa bordered by the Indian Ocean to the east, Tanzania to the north, Malawi ...
,
Myanmar
Myanmar, ; UK pronunciations: US pronunciations incl. . Note: Wikipedia's IPA conventions require indicating /r/ even in British English although only some British English speakers pronounce r at the end of syllables. As John C. Wells, Joh ...
(
Burma
Myanmar, ; UK pronunciations: US pronunciations incl. . Note: Wikipedia's IPA conventions require indicating /r/ even in British English although only some British English speakers pronounce r at the end of syllables. As John Wells explai ...
),
Nigeria
Nigeria ( ), , ig, Naìjíríyà, yo, Nàìjíríà, pcm, Naijá , ff, Naajeeriya, kcg, Naijeriya officially the Federal Republic of Nigeria, is a country in West Africa. It is situated between the Sahel to the north and the Gulf o ...
,
Rwanda
Rwanda (; rw, u Rwanda ), officially the Republic of Rwanda, is a landlocked country in the Great Rift Valley of Central Africa, where the African Great Lakes region and Southeast Africa converge. Located a few degrees south of the Equator ...
,
Sri Lanka
Sri Lanka (, ; si, ශ්රී ලංකා, Śrī Laṅkā, translit-std=ISO (); ta, இலங்கை, Ilaṅkai, translit-std=ISO ()), formerly known as Ceylon and officially the Democratic Socialist Republic of Sri Lanka, is an ...
,
Tanzania
Tanzania (; ), officially the United Republic of Tanzania ( sw, Jamhuri ya Muungano wa Tanzania), is a country in East Africa within the African Great Lakes region. It borders Uganda to the north; Kenya to the northeast; Comoro Islands and ...
,
Thailand
Thailand ( ), historically known as Siam () and officially the Kingdom of Thailand, is a country in Southeast Asia, located at the centre of the Indochinese Peninsula, spanning , with a population of almost 70 million. The country is bo ...
,
United States
The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territorie ...
(
Montana
Montana () is a state in the Mountain West division of the Western United States. It is bordered by Idaho to the west, North Dakota and South Dakota to the east, Wyoming to the south, and the Canadian provinces of Alberta, British Columbi ...
) and
Vietnam
Vietnam or Viet Nam ( vi, Việt Nam, ), officially the Socialist Republic of Vietnam,., group="n" is a country in Southeast Asia, at the eastern edge of mainland Southeast Asia, with an area of and population of 96 million, making i ...
.
Sapphire and rubies are often found in the same geographical settings, but they generally have different geological formations. For example, both ruby and sapphire are found in Myanmar's Mogok Stone Tract, but the rubies form in marble, while the sapphire forms in granitic pegmatites or corundum syenites.
[
Every sapphire mine produces a wide range of quality, and origin is not a guarantee of quality. For sapphire, ]Kashmir
Kashmir () is the northernmost geographical region of the Indian subcontinent. Until the mid-19th century, the term "Kashmir" denoted only the Kashmir Valley between the Great Himalayas and the Pir Panjal Range. Today, the term encompas ...
receives the highest premium, although Burma, Sri Lanka, and Madagascar also produce large quantities of fine quality gems.[
The cost of natural sapphires varies depending on their color, clarity, size, ]cut
Cut may refer to:
Common uses
* The act of cutting, the separation of an object into two through acutely-directed force
** A type of wound
** Cut (archaeology), a hole dug in the past
** Cut (clothing), the style or shape of a garment
** Cut (e ...
, and overall quality. Sapphires that are completely untreated are worth far more than those that have been treated. Geographical origin also has a major impact on price. For most gems of one carat or more, an independent report from a respected laboratory such as GIA
''Gia'' is a 1998 American biographical drama television film about the life and times of one of the first supermodels, Gia Carangi. The film stars Angelina Jolie as Gia and Faye Dunaway as Wilhelmina Cooper, with Mercedes Ruehl and Elizabeth M ...
, Lotus Gemology
Lotus Gemology is a gemology laboratory located in Bangkok, Thailand. It was founded in 2014 by Richard W. Hughes and Wimon Manorotkul and their daughter, E. Billie Hughes.
Richard Hughes and Wimon Manorotkul began their gemological careers ...
, or SSEF
The Swiss Gemmological Institute (SSEF) is a gemmology laboratory located in Basel, Switzerland. It is a part of the Schweizerische Stiftung für Edelstein Forschung (SSEF, Swiss Foundation for Gemstone Research). It was founded on an independen ...
, is often required by buyers before they will make a purchase.
Colors
Sapphires in colors other than blue are called "fancy" or "parti-colored" sapphires.
Fancy sapphires are often found in yellow, orange, green, brown, purple and violet hues.
Blue sapphire
Gemstone color can be described in terms of hue
In color theory, hue is one of the main properties (called Color appearance model#Color appearance parameters, color appearance parameters) of a color, defined technically in the CIECAM02 model as "the degree to which a Stimulus (physiology ...
, saturation
Saturation, saturated, unsaturation or unsaturated may refer to:
Chemistry
* Saturation, a property of organic compounds referring to carbon-carbon bonds
**Saturated and unsaturated compounds
** Degree of unsaturation
**Saturated fat or fatty aci ...
, and tone. Hue is commonly understood as the "color
Color (American English) or colour (British English) is the visual perceptual property deriving from the spectrum of light interacting with the photoreceptor cells of the eyes. Color categories and physical specifications of color are associ ...
" of the gemstone. Saturation refers to the vividness or brightness of the hue, and tone is the lightness to darkness of the hue.[ Blue sapphire exists in various mixtures of its primary (blue) and secondary hues, various tonal levels (shades) and at various levels of saturation (vividness).
Blue sapphires are evaluated based upon the purity of their blue hue. ]Violet
Violet may refer to:
Common meanings
* Violet (color), a spectral color with wavelengths shorter than blue
* One of a list of plants known as violet, particularly:
** ''Viola'' (plant), a genus of flowering plants
Places United States
* Viol ...
, and green
Green is the color between cyan and yellow on the visible spectrum. It is evoked by light which has a dominant wavelength of roughly 495570 Nanometre, nm. In subtractive color systems, used in painting and color printing, it is created by ...
are the most common secondary hues found in blue sapphires.[ The highest prices are paid for gems that are pure blue and of vivid saturation. Gems that are of lower saturation, or are too dark or too light in tone are of less value. However, color preferences are a personal taste, like a flavor of ice cream.][
The ]Logan sapphire
The Logan Sapphire is a sapphire from Sri Lanka. One of the largest blue faceted sapphires in the world, it was owned by Sir Victor Sassoon and then purchased by M. Robert Guggenheim as a gift for his wife, Rebecca Pollard Guggenheim, who donat ...
in the National Museum of Natural History
The National Museum of Natural History is a natural history museum administered by the Smithsonian Institution, located on the National Mall in Washington, D.C., United States. It has free admission and is open 364 days a year. In 2021, with 7 ...
, in Washington, D.C.
)
, image_skyline =
, image_caption = Clockwise from top left: the Washington Monument and Lincoln Memorial on the National Mall, United States Capitol, Logan Circle, Jefferson Memorial, White House, Adams Morgan, ...
, is one of the largest facet
Facets () are flat faces on geometric shapes. The organization of naturally occurring facets was key to early developments in crystallography, since they reflect the underlying symmetry of the crystal structure. Gemstones commonly have facets cut ...
ed gem-quality blue sapphires in existence.
The 422.66-ct Siren of Serendip in the Houston Museum of Natural Science
The Houston Museum of Natural Science (abbreviated as HMNS) is a natural history museum located on the northern border of Hermann Park in Houston, Texas, United States. The museum was established in 1909 by the Houston Museum and Scientific Societ ...
is another stunning example of a Sri Lankan sapphire on public display.
Parti sapphires
Particolored sapphires (or bi-color sapphires) are those stones that exhibit two or more colors within a single stone.[ The desirability of particolored or bi-color sapphires is usually judged based on the zoning or location of their colors, the colors’ saturation, and the contrast of their colors.] Australia is the largest source of particolored sapphires; they are not commonly used in mainstream jewelry and remain relatively unknown. Particolored sapphires cannot be created synthetically and only occur naturally. The vast majority of particolored sapphires occur naturally, but it is possible to replicate the appearance of a particolored sapphire in a synthetic sapphire.
Colorless sapphires have historically been used as diamond substitutes in jewelry.[
]
Pink sapphires
Pink sapphires occur in shades from light to dark pink, and deepen in color as the quantity of chromium
Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal.
Chromium metal is valued for its high corrosion resistance and hardne ...
increases. The deeper the pink color, the higher their monetary value. In the United States, a minimum color saturation must be met to be called a ruby
A ruby is a pinkish red to blood-red colored gemstone, a variety of the mineral corundum ( aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sa ...
, otherwise the stone is referred to as a ''pink sapphire''.
Padparadscha
''Padparadscha'' is a delicate, light to medium toned, pink-orange to orange-pink hued corundum
Corundum is a crystalline form of aluminium oxide () typically containing traces of iron, titanium, vanadium and chromium. It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the pres ...
, originally found in Sri Lanka
Sri Lanka (, ; si, ශ්රී ලංකා, Śrī Laṅkā, translit-std=ISO (); ta, இலங்கை, Ilaṅkai, translit-std=ISO ()), formerly known as Ceylon and officially the Democratic Socialist Republic of Sri Lanka, is an ...
, but also found in deposits in Vietnam
Vietnam or Viet Nam ( vi, Việt Nam, ), officially the Socialist Republic of Vietnam,., group="n" is a country in Southeast Asia, at the eastern edge of mainland Southeast Asia, with an area of and population of 96 million, making i ...
and parts of East Africa
East Africa, Eastern Africa, or East of Africa, is the eastern subregion of the African continent. In the United Nations Statistics Division scheme of geographic regions, 10-11-(16*) territories make up Eastern Africa:
Due to the historical ...
. Padparadscha sapphires are rare; the rarest of all is the totally natural variety, with no sign of artificial treatment.
The name is derived from the Sanskrit "padma ranga" (padma = lotus; ranga = color), a color akin to the lotus flower (''Nelumbo nucifera
''Nelumbo nucifera'', also known as sacred lotus, Laxmi lotus, Indian lotus, or simply lotus, is one of two extant species of aquatic plant in the family Nelumbonaceae. It is sometimes colloquially called a water lily, though this more often re ...
'').
Among the fancy (non-blue) sapphires, natural padparadscha fetch the highest prices. Since 2001, more sapphires of this color have appeared on the market as a result of artificial lattice diffusion of beryllium.
Star sapphire
A ''star sapphire'' is a type of sapphire that exhibits a star-like phenomenon known as asterism; red stones are known as "star rubies". Star sapphires contain intersecting needle-like inclusions following the underlying crystal structure
In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystal, crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric pat ...
that causes the appearance of a six-rayed "star"-shaped pattern when viewed with a single overhead light source. The inclusion is often the mineral rutile
Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer Polymorphism (materials science), polymorphs of TiO2 are known, including anatase, akaogiite, and brookite.
Rutile has one of the highest ...
, a mineral composed primarily of titanium dioxide
Titanium dioxide, also known as titanium(IV) oxide or titania , is the inorganic compound with the chemical formula . When used as a pigment, it is called titanium white, Pigment White 6 (PW6), or CI 77891. It is a white solid that is insolubl ...
. The stones are cut ''en cabochon
A cabochon (; ) is a gemstone that has been shaped and polished, as opposed to faceted. The resulting form is usually a convex (rounded) obverse with a flat reverse. Cabochon was the default method of preparing gemstones before gemstone cuttin ...
'', typically with the center of the star near the top of the dome. Occasionally, twelve-rayed stars are found, typically because two different sets of inclusions are found within the same stone, such as a combination of fine needles of rutile with small platelets of hematite
Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
; the first results in a whitish star and the second results in a golden-colored star. During crystallization, the two types of inclusions become preferentially oriented in different directions within the crystal, thereby forming two six-rayed stars that are superimposed upon each other to form a twelve-rayed star. Misshapen stars or 12-rayed stars may also form as a result of twinning.
The inclusions can alternatively produce a cat's eye effect if the girdle plane of the cabochon is oriented parallel to the crystal's c-axis rather than perpendicular to it. To get a cat's eye, the planes of exsolved inclusions must be extremely uniform and tightly packed. If the dome is oriented in between these two directions, an off-center star will be visible, offset away from the high point of the dome.[
At 1404.49 carats, ]The Star of Adam
The Star of Adam is an oval-shaped blue star sapphire, currently the largest star sapphire in the world. It weighs . Prior to its discovery, the Black Star of Queensland, weighing , was the largest star sapphire gem in the world.
Description
T ...
is the largest known blue star sapphire. The gem was mined in the city of Ratnapura, southern Sri Lanka. The Black Star of Queensland
The Black Star of Queensland, named after its nature and place of origin, is a 733-carat (146.6 g) black sapphire, and was the world's largest gem quality star sapphire until The Star of Adam was discovered.
The Black Star sapphire is an oval ...
, the second largest star sapphire in the world, weighs 733 carats. The Star of India mined in Sri Lanka and weighing 563.4 carats is thought to be the third-largest star sapphire, and is currently on display at the American Museum of Natural History
The American Museum of Natural History (abbreviated as AMNH) is a natural history museum on the Upper West Side of Manhattan in New York City. In Theodore Roosevelt Park, across the street from Central Park, the museum complex comprises 26 inter ...
in New York City
New York, often called New York City or NYC, is the List of United States cities by population, most populous city in the United States. With a 2020 population of 8,804,190 distributed over , New York City is also the L ...
. The 182-carat Star of Bombay
The Star of Bombay is a 182- carat (36.4-g) cabochon-cut star sapphire originating in Sri Lanka. The violet-blue gem was given to silent film actress Mary Pickford by her husband, Douglas Fairbanks. She bequeathed it to the Smithsonian Institutio ...
, mined in Sri Lanka and located in the National Museum of Natural History
The National Museum of Natural History is a natural history museum administered by the Smithsonian Institution, located on the National Mall in Washington, D.C., United States. It has free admission and is open 364 days a year. In 2021, with 7 ...
in Washington, D.C.
)
, image_skyline =
, image_caption = Clockwise from top left: the Washington Monument and Lincoln Memorial on the National Mall, United States Capitol, Logan Circle, Jefferson Memorial, White House, Adams Morgan, ...
, is another example of a large blue star sapphire. The value of a star sapphire depends not only on the weight of the stone, but also the body color, visibility, and intensity of the asterism. The color of the stone has more impact on the value than the visibility of the star. Since more transparent stones tend to have better colors, the most expensive star stones are semi-transparent "glass body" stones with vivid colors.[
On 28 July 2021, the world's largest cluster of star sapphires, weighing 510 kg, was unearthed from Ratnapura, Sri Lanka. This star sapphire cluster was named "Serendipity Sapphire".
]
Color-change sapphire
A rare variety of natural sapphire, known as color-change sapphire, exhibits different colors in different light. Color change sapphires are blue in outdoor light and purple under incandescent
Incandescence is the emission of electromagnetic radiation (including visible light) from a hot body as a result of its high temperature. The term derives from the Latin verb ''incandescere,'' to glow white. A common use of incandescence is ...
indoor light, or green to gray-green in daylight and pink to reddish-violet in incandescent light. Color change sapphires come from a variety of locations, including Madagascar
Madagascar (; mg, Madagasikara, ), officially the Republic of Madagascar ( mg, Repoblikan'i Madagasikara, links=no, ; french: République de Madagascar), is an island country in the Indian Ocean, approximately off the coast of East Africa ...
, Myanmar
Myanmar, ; UK pronunciations: US pronunciations incl. . Note: Wikipedia's IPA conventions require indicating /r/ even in British English although only some British English speakers pronounce r at the end of syllables. As John C. Wells, Joh ...
, Sri Lanka
Sri Lanka (, ; si, ශ්රී ලංකා, Śrī Laṅkā, translit-std=ISO (); ta, இலங்கை, Ilaṅkai, translit-std=ISO ()), formerly known as Ceylon and officially the Democratic Socialist Republic of Sri Lanka, is an ...
and Tanzania
Tanzania (; ), officially the United Republic of Tanzania ( sw, Jamhuri ya Muungano wa Tanzania), is a country in East Africa within the African Great Lakes region. It borders Uganda to the north; Kenya to the northeast; Comoro Islands and ...
. Two types exist. The first features the chromium
Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal.
Chromium metal is valued for its high corrosion resistance and hardne ...
chromophore that creates the red color of ruby, combined with the iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
+ titanium
Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...
chromophore that produces the blue color in sapphire. A rarer type, which comes from the Mogok area of Myanmar, features a vanadium
Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( pas ...
chromophore, the same as is used in Verneuil synthetic color-change sapphire.
Virtually all gemstones that show the "alexandrite effect" (color change; a.k.a. ' metamerism') show similar absorption/transmission features in the visible spectrum. This is an absorption band in the yellow (~590 nm), along with valleys of transmission in the blue-green and red. Thus the color one sees depends on the spectral composition of the light source. Daylight is relatively balanced in its spectral power distribution (SPD) and since the human eye is most sensitive to green light, the balance is tipped to the green side. However incandescent light (including candle light) is heavily tilted to the red end of the spectrum, thus tipping the balance to red.
Color-change sapphires colored by the Cr + Fe/Ti chromophores generally change from blue or violetish blue to violet or purple. Those colored by the V chromophore can show a more pronounced change, moving from blue-green to purple.
Certain synthetic color-change sapphires have a similar color change to the natural gemstone alexandrite
The mineral or gemstone chrysoberyl is an aluminate of beryllium with the formula Be Al2 O4. The name chrysoberyl is derived from the Greek words χρυσός ''chrysos'' and βήρυλλος ''beryllos'', meaning "a gold-white spar". Despite ...
and they are sometimes marketed as "alexandrium" or "synthetic alexandrite". However, the latter term is a misnomer: synthetic color-change sapphires are, technically, not synthetic alexandrites but rather alexandrite ''simulants''. This is because genuine alexandrite is a variety of chrysoberyl
The mineral or gemstone chrysoberyl is an aluminate of beryllium with the formula Be Al2 O4. The name chrysoberyl is derived from the Greek words χρυσός ''chrysos'' and βήρυλλος ''beryllos'', meaning "a gold-white spar". Despite ...
: not sapphire, but an entirely different mineral.
Large rubies and sapphires
Large rubies
A ruby is a pinkish red to blood-red colored gemstone, a variety of the mineral corundum ( aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sap ...
and sapphires of poor transparency are frequently used with suspect appraisals that vastly overstate their value. This was the case of the "Life and Pride of America Star Sapphire". Circa 1985, Roy Whetstine claimed to have bought the 1905-ct stone for $10 at the Tucson gem show, but a reporter discovered that L.A. Ward of Fallbrook, CA, who appraised it at the price of $1200/ct, had appraised another stone of the exact same weight several years before Whetstine claimed to have found it.
Bangkok-based Lotus Gemology
Lotus Gemology is a gemology laboratory located in Bangkok, Thailand. It was founded in 2014 by Richard W. Hughes and Wimon Manorotkul and their daughter, E. Billie Hughes.
Richard Hughes and Wimon Manorotkul began their gemological careers ...
maintains an updated listing of world auction records of ruby, sapphire, and spinel
Spinel () is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula in the cubic crystal system. Its name comes from the Latin word , which means ''spine'' in reference to its pointed crystals.
Properties
S ...
. As of November 2019, no sapphire has ever sold at auction for more than $17,295,796.
Cause of color
Rubies
A ruby is a pinkish red to blood-red colored gemstone, a variety of the mineral corundum ( aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sap ...
are corundum
Corundum is a crystalline form of aluminium oxide () typically containing traces of iron, titanium, vanadium and chromium. It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the pres ...
with a dominant red body color. This is generally caused by traces of chromium
Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal.
Chromium metal is valued for its high corrosion resistance and hardne ...
(Cr3+) substituting for the (Al3+) ion in the corundum structure. The color can be modified by both iron and trapped hole color centers.
Unlike localized ("intra-atomic") absorption of light, which causes color for chromium and vanadium impurities, blue color in sapphires comes from intervalence charge transfer, which is the transfer of an electron from one transition-metal ion to another via the conduction
Conductor or conduction may refer to:
Music
* Conductor (music), a person who leads a musical ensemble, such as an orchestra.
* Conductor (album), ''Conductor'' (album), an album by indie rock band The Comas
* Conduction, a type of structured f ...
or valence band
In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of the solid. In nonmetals, the valence band is the highest range of electron energies in w ...
. The iron can take the form Fe2+ or Fe3+, while titanium generally takes the form Ti4+. If Fe2+ and Ti4+ ions are substituted for Al3+, localized areas of charge imbalance are created. An electron transfer from Fe2+ and Ti4+ can cause a change in the valence state of both. Because of the valence change, there is a specific change in energy for the electron, and electromagnetic energy
In physics, electromagnetism is an interaction that occurs between particles with electric charge. It is the second-strongest of the four fundamental interactions, after the strong force, and it is the dominant force in the interactions of a ...
is absorbed. The wavelength
In physics, the wavelength is the spatial period of a periodic wave—the distance over which the wave's shape repeats.
It is the distance between consecutive corresponding points of the same phase on the wave, such as two adjacent crests, tro ...
of the energy absorbed corresponds to yellow light. When this light is subtracted from incident white light, the complementary color blue results. Sometimes when atomic spacing is different in different directions, there is resulting blue-green dichroism
In optics, a dichroic material is either one which causes visible light to be split up into distinct beams of different wavelengths (colours) (not to be confused with dispersion), or one in which light rays having different polarizations are abs ...
.
Purple sapphires contain trace amounts of chromium
Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal.
Chromium metal is valued for its high corrosion resistance and hardne ...
and iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
plus titanium
Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...
and come in a variety of shades. Corundum that contains extremely low levels of chromophores is near colorless. Completely colorless corundum generally does not exist in nature. If trace amounts of iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
are present, a very pale yellow to green color may be seen. However, if both titanium and iron impurities are present together, and in the correct valence states, the result is a blue color.
Intervalence charge transfer is a process that produces a strong colored appearance at a low percentage of impurity. While at least 1% chromium must be present in corundum before the deep red ruby color is seen, sapphire blue is apparent with the presence of only 0.01% of titanium and iron.
The most complete description of the causes of color in corundum extant can be found in Chapter 4 of ''Ruby & Sapphire: A Gemologist's Guide'' (chapter authored by John Emmett, Emily Dubinsky and Richard Hughes).[
]
Treatments
Sapphires can be treated by several methods to enhance and improve their clarity and color.[ It is common practice to heat natural sapphires to improve or enhance their appearance. This is done by heating the sapphires in furnaces to temperatures between for several hours, or even weeks at a time. Different atmospheres may be used. Upon heating, the stone becomes bluer in color, but loses some of the rutile inclusions (silk). When high temperatures (1400 °C+) are used, exsolved rutile silk is dissolved and it becomes clear under magnification. The titanium from the rutile enters solid solution and thus creates with iron the blue color The inclusions in natural stones are easily seen with a ]jeweler's loupe
A loupe ( ) is a simple, small magnification device used to see small details more closely. They generally have higher magnification than a magnifying glass, and are designed to be held or worn close to the eye. A loupe does not have an attached h ...
. Evidence of sapphire and other gemstones being subjected to heating goes back at least to Roman times. Un-heated natural stones are somewhat rare and will often be sold accompanied by a certificate from an independent gemological laboratory attesting to "no evidence of heat treatment".
Yogo sapphire
Yogo sapphires are blue sapphires, a colored variety of corundum, found in Montana, primarily in Yogo Gulch (part of the Little Belt Mountains) in Judith Basin County, Montana. Yogo sapphires are typically cornflower blue, a result of trace amo ...
s do not need heat treating because their cornflower blue color is attractive out of the ground; they are generally free of inclusions, and have high uniform clarity.[ Revised January 2004.] When Intergem Limited began marketing the Yogo in the 1980s as the world's only guaranteed untreated sapphire, heat treatment was not commonly disclosed; by the late 1980s, heat treatment became a major issue. At that time, much of all the world's sapphires were being heated to enhance their natural color. Intergem's marketing of guaranteed untreated Yogos set them against many in the gem industry. This issue appeared as a front-page story in the ''Wall Street Journal
''The Wall Street Journal'' is an American business-focused, international daily newspaper based in New York City, with international editions also available in Chinese and Japanese. The ''Journal'', along with its Asian editions, is published ...
'' on 29 August 1984 in an article by Bill Richards, ''Carats and Schticks: Sapphire Marketer Upsets The Gem Industry''.[ However, the biggest problem the Yogo mine faced was not competition from heated sapphires, but the fact that the Yogo stones could never produce quantities of sapphire above one carat after faceting. As a result, it has remained a niche product, with a market that largely exists in the US.][
Lattice ('bulk') diffusion treatments are used to add impurities to the sapphire to enhance color. This process was originally developed and patented by Linde Air division of Union Carbide and involved diffusing titanium into synthetic sapphire to even out the blue color. It was later applied to natural sapphire. Today, titanium diffusion often uses a synthetic colorless sapphire base. The color layer created by titanium diffusion is extremely thin (less than 0.5 mm). Thus repolishing can and does produce slight to significant loss of color. Chromium diffusion has been attempted, but was abandoned due to the slow diffusion rates of chromium in corundum.
In the year 2000, beryllium diffused "padparadscha" colored sapphires entered the market. Typically ]beryllium
Beryllium is a chemical element with the symbol Be and atomic number 4. It is a steel-gray, strong, lightweight and brittle alkaline earth metal. It is a divalent element that occurs naturally only in combination with other elements to form mi ...
is diffused into a sapphire under very high heat, just below the melting point of the sapphire. Initially (''c.'' 2000) orange sapphires were created, although now the process has been advanced and many colors of sapphire are often treated with beryllium. Due to the small size of the beryllium ion, the color penetration is far greater than with titanium diffusion. In some cases, it may penetrate the entire stone. Beryllium-diffused orange sapphires may be difficult to detect, requiring advanced chemical analysis by gemological labs (''e.g.'', Gübelin, SSEF
The Swiss Gemmological Institute (SSEF) is a gemmology laboratory located in Basel, Switzerland. It is a part of the Schweizerische Stiftung für Edelstein Forschung (SSEF, Swiss Foundation for Gemstone Research). It was founded on an independen ...
, GIA
''Gia'' is a 1998 American biographical drama television film about the life and times of one of the first supermodels, Gia Carangi. The film stars Angelina Jolie as Gia and Faye Dunaway as Wilhelmina Cooper, with Mercedes Ruehl and Elizabeth M ...
, American Gemological Laboratories (AGL), Lotus Gemology
Lotus Gemology is a gemology laboratory located in Bangkok, Thailand. It was founded in 2014 by Richard W. Hughes and Wimon Manorotkul and their daughter, E. Billie Hughes.
Richard Hughes and Wimon Manorotkul began their gemological careers ...
.[
According to United States ]Federal Trade Commission
The Federal Trade Commission (FTC) is an independent agency of the United States government whose principal mission is the enforcement of civil (non-criminal) antitrust law and the promotion of consumer protection. The FTC shares jurisdiction ov ...
guidelines, disclosure is required of any mode of enhancement that has a significant effect on the gem's value.
There are several ways of treating sapphire. Heat-treatment in a reducing or oxidizing atmosphere (but without the use of any other added impurities) is commonly used to improve the color of sapphires, and this process is sometimes known as "heating only" in the gem trade. In contrast, however, heat treatment combined with the deliberate addition of certain specific impurities (e.g. beryllium, titanium, iron, chromium or nickel, which are absorbed into the crystal structure of the sapphire) is also commonly performed, and this process can be known as "diffusion" in the gem trade. However, despite what the terms "heating only" and "diffusion" might suggest, both of these categories of treatment actually involve diffusion processes.
The most complete description of corundum treatments extant can be found in Chapter 6 of ''Ruby & Sapphire: A Gemologist's Guide'' (chapter authored by John Emmett, Richard Hughes and Troy R. Douthit).[
]
Mining
Sapphires are mined from alluvial
Alluvium (from Latin ''alluvius'', from ''alluere'' 'to wash against') is loose clay, silt, sand, or gravel that has been deposited by running water in a stream bed, on a floodplain, in an alluvial fan or beach, or in similar settings. Alluv ...
deposits or from primary underground workings. Commercial mining
Mining is the extraction of valuable minerals or other geological materials from the Earth, usually from an ore body, lode, vein, seam, reef, or placer deposit. The exploitation of these deposits for raw material is based on the economic via ...
locations for sapphire and ruby include (but are not limited to) the following countries: Afghanistan
Afghanistan, officially the Islamic Emirate of Afghanistan,; prs, امارت اسلامی افغانستان is a landlocked country located at the crossroads of Central Asia and South Asia. Referred to as the Heart of Asia, it is bordere ...
, Australia
Australia, officially the Commonwealth of Australia, is a Sovereign state, sovereign country comprising the mainland of the Australia (continent), Australian continent, the island of Tasmania, and numerous List of islands of Australia, sma ...
, Myanmar
Myanmar, ; UK pronunciations: US pronunciations incl. . Note: Wikipedia's IPA conventions require indicating /r/ even in British English although only some British English speakers pronounce r at the end of syllables. As John C. Wells, Joh ...
/Burma
Myanmar, ; UK pronunciations: US pronunciations incl. . Note: Wikipedia's IPA conventions require indicating /r/ even in British English although only some British English speakers pronounce r at the end of syllables. As John Wells explai ...
, Cambodia
Cambodia (; also Kampuchea ; km, កម្ពុជា, UNGEGN: ), officially the Kingdom of Cambodia, is a country located in the southern portion of the Indochinese Peninsula in Southeast Asia, spanning an area of , bordered by Thailand t ...
, China
China, officially the People's Republic of China (PRC), is a country in East Asia. It is the world's most populous country, with a population exceeding 1.4 billion, slightly ahead of India. China spans the equivalent of five time zones and ...
, Colombia
Colombia (, ; ), officially the Republic of Colombia, is a country in South America with insular regions in North America—near Nicaragua's Caribbean coast—as well as in the Pacific Ocean. The Colombian mainland is bordered by the Car ...
, India
India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the seventh-largest country by area, the second-most populous country, and the most populous democracy in the world. Bounded by the Indian Ocean on the so ...
, Kenya
)
, national_anthem = "Ee Mungu Nguvu Yetu"()
, image_map =
, map_caption =
, image_map2 =
, capital = Nairobi
, coordinates =
, largest_city = Nairobi
, ...
, Laos
Laos (, ''Lāo'' )), officially the Lao People's Democratic Republic ( Lao: ສາທາລະນະລັດ ປະຊາທິປະໄຕ ປະຊາຊົນລາວ, French: République démocratique populaire lao), is a socialist ...
, Madagascar
Madagascar (; mg, Madagasikara, ), officially the Republic of Madagascar ( mg, Repoblikan'i Madagasikara, links=no, ; french: République de Madagascar), is an island country in the Indian Ocean, approximately off the coast of East Africa ...
, Malawi
Malawi (; or aláwi Tumbuka: ''Malaŵi''), officially the Republic of Malawi, is a landlocked country in Southeastern Africa that was formerly known as Nyasaland. It is bordered by Zambia to the west, Tanzania to the north and northeast ...
, Nepal
Nepal (; ne, नेपाल ), formerly the Federal Democratic Republic of Nepal ( ne,
सङ्घीय लोकतान्त्रिक गणतन्त्र नेपाल ), is a landlocked country in South Asia. It is mai ...
, Nigeria
Nigeria ( ), , ig, Naìjíríyà, yo, Nàìjíríà, pcm, Naijá , ff, Naajeeriya, kcg, Naijeriya officially the Federal Republic of Nigeria, is a country in West Africa. It is situated between the Sahel to the north and the Gulf o ...
, Pakistan
Pakistan ( ur, ), officially the Islamic Republic of Pakistan ( ur, , label=none), is a country in South Asia. It is the world's List of countries and dependencies by population, fifth-most populous country, with a population of almost 24 ...
, Sri Lanka
Sri Lanka (, ; si, ශ්රී ලංකා, Śrī Laṅkā, translit-std=ISO (); ta, இலங்கை, Ilaṅkai, translit-std=ISO ()), formerly known as Ceylon and officially the Democratic Socialist Republic of Sri Lanka, is an ...
, Tajikistan
Tajikistan (, ; tg, Тоҷикистон, Tojikiston; russian: Таджикистан, Tadzhikistan), officially the Republic of Tajikistan ( tg, Ҷумҳурии Тоҷикистон, Jumhurii Tojikiston), is a landlocked country in Centr ...
, Tanzania
Tanzania (; ), officially the United Republic of Tanzania ( sw, Jamhuri ya Muungano wa Tanzania), is a country in East Africa within the African Great Lakes region. It borders Uganda to the north; Kenya to the northeast; Comoro Islands and ...
, Thailand
Thailand ( ), historically known as Siam () and officially the Kingdom of Thailand, is a country in Southeast Asia, located at the centre of the Indochinese Peninsula, spanning , with a population of almost 70 million. The country is bo ...
, United States, and Vietnam
Vietnam or Viet Nam ( vi, Việt Nam, ), officially the Socialist Republic of Vietnam,., group="n" is a country in Southeast Asia, at the eastern edge of mainland Southeast Asia, with an area of and population of 96 million, making i ...
. Sapphires from different geographic locations may have different appearances or chemical-impurity concentrations, and tend to contain different types of microscopic inclusions. Because of this, sapphires can be divided into three broad categories: classic metamorphic, non-classic metamorphic or magmatic, and classic magmatic.
Sapphires from certain locations, or of certain categories, may be more commercially appealing than others, particularly classic metamorphic sapphires from Kashmir
Kashmir () is the northernmost geographical region of the Indian subcontinent. Until the mid-19th century, the term "Kashmir" denoted only the Kashmir Valley between the Great Himalayas and the Pir Panjal Range. Today, the term encompas ...
, Burma, or Sri Lanka that have not been subjected to heat-treatment.
The Logan sapphire
The Logan Sapphire is a sapphire from Sri Lanka. One of the largest blue faceted sapphires in the world, it was owned by Sir Victor Sassoon and then purchased by M. Robert Guggenheim as a gift for his wife, Rebecca Pollard Guggenheim, who donat ...
, the Star of India, The Star of Adam
The Star of Adam is an oval-shaped blue star sapphire, currently the largest star sapphire in the world. It weighs . Prior to its discovery, the Black Star of Queensland, weighing , was the largest star sapphire gem in the world.
Description
T ...
and the Star of Bombay
The Star of Bombay is a 182- carat (36.4-g) cabochon-cut star sapphire originating in Sri Lanka. The violet-blue gem was given to silent film actress Mary Pickford by her husband, Douglas Fairbanks. She bequeathed it to the Smithsonian Institutio ...
originate from Sri Lankan mines. Madagascar is the world leader in sapphire production (as of 2007) specifically its deposits in and around the town of Ilakaka
Ilakaka is a small town in Ihorombe Region in the south western part of Madagascar. In the early 1990s there were only about 40 residents in the area. After the discovery of one of Earth's largest known alluvial sapphire deposits in the valley of ...
. Prior to the opening of the Ilakaka mines, Australia was the largest producer of sapphires (such as in 1987). In 1991 a new source of sapphires was discovered in Andranondambo, southern Madagascar. That area has been exploited for its sapphires started in 1993, but it was practically abandoned just a few years later—because of the difficulties in recovering sapphires in their bedrock.
In North America
North America is a continent in the Northern Hemisphere and almost entirely within the Western Hemisphere. It is bordered to the north by the Arctic Ocean, to the east by the Atlantic Ocean, to the southeast by South America and the Car ...
, sapphires have been mined mostly from deposits in Montana
Montana () is a state in the Mountain West division of the Western United States. It is bordered by Idaho to the west, North Dakota and South Dakota to the east, Wyoming to the south, and the Canadian provinces of Alberta, British Columbi ...
: fancies along the Missouri River near Helena, Montana
Helena (; ) is the capital city of Montana, United States, and the county seat of Lewis and Clark County.
Helena was founded as a gold camp during the Montana gold rush, and established on October 30, 1864. Due to the gold rush, Helena would ...
, Dry Cottonwood Creek near Deer Lodge, Montana
Deer Lodge is a city in and the county seat of Powell County, Montana, Powell County, Montana, United States. The population was 2,938 at the 2020 United States Census, 2020 census.
Description
The city is perhaps best known as the home of t ...
, and Rock Creek near Philipsburg, Montana
Philipsburg is a town in and the county seat of Granite County, Montana, United States. The population was 841 at the 2020 census. The town was named after the famous mining engineer Philip Deidesheimer, who designed and supervised the constructio ...
. Fine blue Yogo sapphire
Yogo sapphires are blue sapphires, a colored variety of corundum, found in Montana, primarily in Yogo Gulch (part of the Little Belt Mountains) in Judith Basin County, Montana. Yogo sapphires are typically cornflower blue, a result of trace amo ...
s are found at Yogo Gulch west of Lewistown, Montana
Lewistown is a city in and the county seat of Fergus County, Montana, United States. The population was 5,952 at the 2020 census. Lewistown is located in the geographic center of the state, southeast of Great Falls and northwest of Billings. Fir ...
. A few gem-grade sapphires and rubies have also been found in the area of Franklin, North Carolina
Franklin is a town in and the county seat of Macon County, North Carolina, United States. It is situated within the Nantahala National Forest. The population was reported to be 4,175 in the 2020 census, an increase from the total of 3,845 tabula ...
.
The sapphire deposits of Kashmir
Kashmir () is the northernmost geographical region of the Indian subcontinent. Until the mid-19th century, the term "Kashmir" denoted only the Kashmir Valley between the Great Himalayas and the Pir Panjal Range. Today, the term encompas ...
are well known in the gem industry, although their peak production took place in a relatively short period at the end of the nineteenth and early twentieth centuries.[ They have a superior vivid blue hue, coupled with a mysterious and almost sleepy quality, described by some gem enthusiasts as ‘blue velvet”. Kashmir-origin contributes meaningfully to the value of a sapphire, and most corundum of Kashmir origin can be readily identified by its characteristic silky appearance and exceptional hue.] The unique blue appears lustrous under any kind of light, unlike non-Kashmir sapphires which may appear purplish or grayish in comparison. Sotheby's has been in the forefront overseeing record-breaking sales of Kashmir sapphires worldwide. In October 2014, Sotheby's Hong Kong achieved consecutive per-carat price records for Kashmir sapphires – first with the 12.00 carat Cartier sapphire ring at US$193,975 per carat, then with a 17.16 carat sapphire at US$236,404, and again in June 2015 when the per-carat auction record was set at US$240,205. At present, the world record price-per-carat for sapphire at auction is held by a sapphire from Kashmir in a ring, which sold in October 2015 for approximately US$
The United States dollar (symbol: $; code: USD; also abbreviated US$ or U.S. Dollar, to distinguish it from other dollar-denominated currencies; referred to as the dollar, U.S. dollar, American dollar, or colloquially buck) is the official ...
242,000 per carat (HK$
The Hong Kong dollar (, sign: HK$; code: HKD) is the official currency of the Hong Kong Special Administrative Region. It is subdivided into 100 cents or 1000 mils. The Hong Kong Monetary Authority is the monetary authority of Hong Kong and ...
52,280,000 in total, including buyer's premium, or more than US$6.74 million).
Synthetic sapphire
In 1902, the French chemist Auguste Verneuil announced a process for producing synthetic ruby
A ruby is a pinkish red to blood-red colored gemstone, a variety of the mineral corundum ( aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sa ...
crystals. In the flame-fusion (Verneuil process
The Verneuil method (or Verneuil process or Verneuil technique), also called flame fusion, was the first commercially successful method of manufacturing synthetic gemstones, developed in the late 1883 by the French chemist Auguste Verneuil. It ...
), fine alumina powder is added to an oxyhydrogen flame
Oxyhydrogen is a mixture of hydrogen (H2) and oxygen (O2) gases. This gaseous mixture is used for torches to process refractory materials and was the first
gaseous mixture used for welding. Theoretically, a ratio of 2:1 hydrogen:oxygen is enough ...
, and this is directed downward against a ceramic pedestal. Following the successful synthesis of ruby, Verneuil focussed his efforts on sapphire. Synthesis of blue sapphire came in 1909, after chemical analyses of sapphire suggested to Verneuil that iron and titanium were the cause of the blue color. Verneuil patented the process of producing synthetic blue sapphire in 1911.[
The key to the process is that the alumina powder does not melt as it falls through the flame. Instead it forms a sinter cone on the pedestal. When the tip of that cone reaches the hottest part of the flame, the tip melts. Thus the crystal growth is started from a tiny point, ensuring minimal strain.
Next, more oxygen is added to the flame, causing it to burn slightly hotter. This expands the growing crystal laterally. At the same time, the pedestal is lowered at the same rate that the crystal grows vertically. The alumina in the flame is slowly deposited, creating a teardrop shaped " boule" of sapphire material. This step is continued until the desired size is reached, the flame is shut off and the crystal cools. The now elongated crystal contains a lot of strain due to the high thermal gradient between the flame and surrounding air. To release this strain, the now finger-shaped crystal will be tapped with a chisel to split it into two halves.][
Due to the vertical layered growth of the crystal and the curved upper growth surface (which starts from a drop), the crystals will display curved growth lines following the top surface of the boule. This is in contrast to natural corundum crystals, which feature angular growth lines expanding from a single point and following the planar crystal faces.
]
Dopants
Chemical dopant
A dopant, also called a doping agent, is a trace of impurity element that is introduced into a chemical material to alter its original electrical or optical properties. The amount of dopant necessary to cause changes is typically very low. When ...
s can be added to create artificial versions of the ruby, and all the other natural colors of sapphire, and in addition, other colors never seen in geological
Geology () is a branch of natural science concerned with Earth and other astronomical objects, the features or rocks of which it is composed, and the processes by which they change over time. Modern geology significantly overlaps all other Eart ...
samples. Artificial sapphire material is identical to natural sapphire, except it can be made without the flaws that are found in natural stones. The disadvantage of the Verneuil process is that the grown crystals have high internal strains. Many methods of manufacturing sapphire today are variations of the Czochralski process, which was invented in 1916 by Polish chemist Jan Czochralski
Jan Czochralski ( , ; 23 October 1885 – 22 April 1953) was a Polish chemist who invented the Czochralski method, which is used for growing single crystals and in the production of semiconductor wafers. It is still used in over 90 percent of al ...
. In this process, a tiny sapphire seed crystal is dipped into a crucible made of the precious metal iridium
Iridium is a chemical element with the symbol Ir and atomic number 77. A very hard, brittle, silvery-white transition metal of the platinum group, it is considered the second-densest naturally occurring metal (after osmium) with a density of ...
or molybdenum
Molybdenum is a chemical element with the symbol Mo and atomic number 42 which is located in period 5 and group 6. The name is from Neo-Latin ''molybdaenum'', which is based on Ancient Greek ', meaning lead, since its ores were confused with lea ...
, containing molten alumina, and then slowly withdrawn upward at a rate of 1 to 100 mm per hour. The alumina crystallizes on the end, creating long carrot-shaped boules of large size up to 200 kg in mass.
Other growth methods
Synthetic sapphire is also produced industrially from agglomerated aluminum oxide, sintered and fused (such as by hot isostatic pressing
Hot isostatic pressing (HIP) is a manufacturing process, used to reduce the porosity of metals and increase the density of many ceramic materials. This improves the material's mechanical properties and workability.
The process can be used to pro ...
) in an inert atmosphere, yielding a transparent but slightly porous
Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
polycrystalline
A crystallite is a small or even microscopic crystal which forms, for example, during the cooling of many materials. Crystallites are also referred to as grains.
Bacillite is a type of crystallite. It is rodlike with parallel longulites.
Stru ...
product.
In 2003, the world's production of synthetic sapphire was 250 tons (1.25 × 109 carats), mostly by the United States and Russia. The availability of cheap synthetic sapphire unlocked many industrial uses for this unique material.
Applications
Windows
Synthetic sapphire sometimes referred to as ''sapphire glass'' is commonly used as a window material, because it is both highly transparent to wavelengths of light between 150 nm ( UV) and 5500 nm ( IR) (the visible spectrum extends about 380 nm to 750 nm), and extraordinarily scratch-resistant.
The key benefits of sapphire windows are:
* Very wide optical transmission band from UV to near infrared
Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from around ...
(0.15–5.5 µm)
* Significantly stronger than other optical materials or standard glass windows
* Highly resistant to scratching and abrasion (9 on the Mohs scale of mineral hardness
The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material.
The scale was introduced in 1812 by th ...
scale, the 3rd hardest natural substance next to moissanite
Moissanite () is naturally occurring silicon carbide and its various crystalline polymorphs. It has the chemical formula SiC and is a rare mineral, discovered by the French chemist Henri Moissan in 1893. Silicon carbide is useful for commercial ...
and diamonds)
* Extremely high melting temperature (2030 °C)
Some sapphire-glass windows are made from pure sapphire boules that have been grown in a specific crystal orientation, typically along the optical axis, the ''c'' axis, for minimum birefringence
Birefringence is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are said to be birefringent (or birefractive). The birefring ...
for the application.
The boules are sliced up into the desired window thickness and finally polished to the desired surface finish. Sapphire optical windows can be polished to a wide range of surface finishes due to its crystal structure and its hardness. The surface finishes of optical windows are normally called out by the scratch-dig specifications in accordance with the globally adopted MIL-O-13830 specification.
The sapphire windows are used in both high-pressure and vacuum chambers for spectroscopy
Spectroscopy is the field of study that measures and interprets the electromagnetic spectra that result from the interaction between electromagnetic radiation and matter as a function of the wavelength or frequency of the radiation. Matter wa ...
, crystals in various watch
A watch is a portable timepiece intended to be carried or worn by a person. It is designed to keep a consistent movement despite the motions caused by the person's activities. A wristwatch is designed to be worn around the wrist, attached by ...
es, and windows in grocery-store barcode scanner
A barcode reader is an optical scanner that can read printed barcodes, decode the data contained in the barcode to a computer. Like a flatbed scanner, it consists of a light source, a lens and a light sensor for translating optical impulses into e ...
s, since the material's exceptional hardness and toughness makes it very resistant to scratching.[
In 2014 ]Apple
An apple is an edible fruit produced by an apple tree (''Malus domestica''). Apple fruit tree, trees are agriculture, cultivated worldwide and are the most widely grown species in the genus ''Malus''. The tree originated in Central Asia, wh ...
consumed "one-fourth of the world’s supply of sapphire to cover the iPhone’s camera lens and fingerprint reader".
Several attempts have been made to make sapphire screens for smartphones viable. Apple contracted GT Advanced Technologies, Inc. to manufacture sapphire screens for iPhones, the venture failed resulting in the bankruptcy of GTAT. The Kyocera
is a Japanese multinational ceramics and electronics manufacturer headquartered in Kyoto, Japan. It was founded as in 1959 by Kazuo Inamori and renamed in 1982. It manufactures industrial ceramics, solar power generating systems, telecommuni ...
Brigadier was the first production smartphone to feature a sapphire screen.
It is used for end windows on some high-powered laser tubes, as its wide-band transparency and thermal conductivity allow it to handle very high power densities in the infrared and UV spectrum without degrading due to heating.
Along with zirconia
Zirconium dioxide (), sometimes known as zirconia (not to be confused with zircon), is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral baddeleyite. A dopant stabi ...
and aluminum oxynitride, synthetic sapphire is used for shatter-resistant windows in armored vehicles and various military body armor
Body armor, also known as body armour, personal armor or armour, or a suit or coat of armor, is protective clothing designed to absorb or deflect physical attacks. Historically used to protect military personnel, today it is also used by variou ...
suits, in association with composites.
One type of xenon arc lamp
A xenon arc lamp is a highly specialized type of gas discharge lamp, an electric light that produces light by passing electricity through ionized xenon gas at high pressure. It produces a bright white light to simulate sunlight, with applications ...
originally called the "Cermax" and now known generically as the "ceramic-body xenon lamp" uses sapphire crystal output windows. This product tolerates higher thermal loads and thus higher output powers when compared with conventional Xe lamps with pure silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
window.
As substrate for semiconducting circuits
Thin sapphire wafers were the first successful use of an insulating substrate upon which to deposit silicon to make the integrated circuit
An integrated circuit or monolithic integrated circuit (also referred to as an IC, a chip, or a microchip) is a set of electronic circuits on one small flat piece (or "chip") of semiconductor material, usually silicon. Large numbers of tiny ...
s known as silicon on sapphire
Silicon on sapphire (SOS) is a hetero-epitaxial process for metal-oxide-semiconductor (MOS) integrated circuit (IC) manufacturing that consists of a thin layer (typically thinner than 0.6 µm) of silicon grown on a sapphire (Al2O3) wafer. ...
or "SOS"; now other substrates can also be used for the class of circuits known more generally as silicon on insulator
In semiconductor manufacturing, silicon on insulator (SOI) technology is fabrication of silicon semiconductor devices in a layered silicon–insulator–silicon substrate, to reduce parasitic capacitance within the device, thereby improving perfo ...
. Besides its excellent electrical insulating properties, sapphire has high thermal conductivity
The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa.
Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal ...
. CMOS
Complementary metal–oxide–semiconductor (CMOS, pronounced "sea-moss", ) is a type of metal–oxide–semiconductor field-effect transistor (MOSFET) fabrication process that uses complementary and symmetrical pairs of p-type and n-type MOSFE ...
chips on sapphire are especially useful for high-power radio-frequency (RF) applications such as those found in cellular telephones
A mobile phone, cellular phone, cell phone, cellphone, handphone, hand phone or pocket phone, sometimes shortened to simply mobile, cell, or just phone, is a portable telephone that can make and receive telephone call, calls over a radio freq ...
, public-safety band radios, and satellite communication
A communications satellite is an artificial satellite that relays and amplifies radio telecommunication signals via a transponder; it creates a communication channel between a source transmitter and a receiver at different locations on Earth. C ...
systems. "SOS" also allows for the monolithic integration of both digital
Digital usually refers to something using discrete digits, often binary digits.
Technology and computing Hardware
*Digital electronics, electronic circuits which operate using digital signals
**Digital camera, which captures and stores digital i ...
and analog
Analog or analogue may refer to:
Computing and electronics
* Analog signal, in which information is encoded in a continuous variable
** Analog device, an apparatus that operates on analog signals
*** Analog electronics, circuits which use analog ...
circuitry all on one IC chip, and the construction of extremely low power circuits.
In one process, after single crystal sapphire boules are grown, they are core-drilled into cylindrical rods, and wafers are then sliced from these cores.
Wafers of single-crystal sapphire are also used in the semiconductor
A semiconductor is a material which has an electrical resistivity and conductivity, electrical conductivity value falling between that of a electrical conductor, conductor, such as copper, and an insulator (electricity), insulator, such as glas ...
industry as substrates for the growth of devices based on gallium nitride
Gallium nitride () is a binary III/ V direct bandgap semiconductor commonly used in blue light-emitting diodes since the 1990s. The compound is a very hard material that has a Wurtzite crystal structure. Its wide band gap of 3.4 eV affords it ...
(GaN). The use of sapphire significantly reduces the cost, because it has about one-seventh the cost of germanium
Germanium is a chemical element with the symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid in the carbon group that is chemically similar to its group neighbors s ...
. Gallium nitride on sapphire is commonly used in blue light-emitting diodes
A light-emitting diode (LED) is a semiconductor device that emits light when current flows through it. Electrons in the semiconductor recombine with electron holes, releasing energy in the form of photons. The color of the light (cor ...
(LEDs).
In lasers
The first laser
A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word "laser" is an acronym for "light amplification by stimulated emission of radiation". The fir ...
was made in 1960 by Theodore Maiman
Theodore Harold Maiman (July 11, 1927 – May 5, 2007) was an American engineer and physicist who is widely credited with the invention of the laser.Johnson, John Jr. (May 11, 2008). "Theodore H. Maiman, at age 32; scientist created the first LA ...
with a rod of synthetic ruby
A ruby is a pinkish red to blood-red colored gemstone, a variety of the mineral corundum ( aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sap ...
. Titanium-sapphire laser
Ti:sapphire lasers (also known as Ti:Al2O3 lasers, titanium-sapphire lasers, or Ti:sapphs) are tunable lasers which emit red and near-infrared light in the range from 650 to 1100 nanometers. These lasers are mainly used in scientific research beca ...
s are popular due to their relatively rare capacity to be tuned to various wavelengths in the red and near-infrared
Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from around ...
region of the electromagnetic spectrum
The electromagnetic spectrum is the range of frequencies (the spectrum) of electromagnetic radiation and their respective wavelengths and photon energies.
The electromagnetic spectrum covers electromagnetic waves with frequencies ranging from ...
. They can also be easily mode-locked. In these lasers a synthetically produced sapphire crystal
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...
with chromium or titanium
Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...
impurities is irradiated with intense light from a special lamp, or another laser, to create stimulated emission
Stimulated emission is the process by which an incoming photon of a specific frequency can interact with an excited atomic electron (or other excited molecular state), causing it to drop to a lower energy level. The liberated energy transfers to th ...
.
In endoprostheses
Monocrystalline sapphire is fairly biocompatible and the exceptionally low wear of sapphire–metal pairs has led to the introduction (in Ukraine) of sapphire monocrystals for hip
joint endoprostheses.
Historical and cultural references
* Etymologically, the English word "sapphire" derives from French ''saphir'', from Latin ''sapphirus'', ''sappirus'' from Greek σαπφειρος (''sappheiros'') from Hebrew סַפִּיר (''sappir''). Some linguists propose that the Semitic (e.g. Hebrew) terms derive from Sanskrit
Sanskrit (; attributively , ; nominally , , ) is a classical language belonging to the Indo-Aryan branch of the Indo-European languages. It arose in South Asia after its predecessor languages had diffused there from the northwest in the late ...
''Sanipriya'' (शनिप्रिय), from "sani" (शनि) meaning "Saturn
Saturn is the sixth planet from the Sun and the second-largest in the Solar System, after Jupiter. It is a gas giant with an average radius of about nine and a half times that of Earth. It has only one-eighth the average density of Earth; h ...
" and "priyah" (प्रिय), dear, i.e. literally "sacred to Saturn".
* A traditional Hindu
Hindus (; ) are people who religiously adhere to Hinduism.Jeffery D. Long (2007), A Vision for Hinduism, IB Tauris, , pages 35–37 Historically, the term has also been used as a geographical, cultural, and later religious identifier for ...
belief holds that the sapphire causes the planet Saturn (Shani
Shani ( sa, शनि, ), or Shanaishchara ( sa, शनैश्चर, ), refers to the divine personification of the planet Saturn in Hinduism, and is one of the nine heavenly objects (Navagraha) in Hindu astrology. Shani is also a male Hindu ...
) to be favorable to the wearer.
* The Greek term for sapphire quite likely was instead used to refer to lapis lazuli
Lapis lazuli (; ), or lapis for short, is a deep-blue metamorphic rock used as a semi-precious stone that has been prized since antiquity for its intense color.
As early as the 7th millennium BC, lapis lazuli was mined in the Sar-i Sang mines, ...
.[
* During the ]Medieval Ages
In the history of Europe, the Middle Ages or medieval period lasted approximately from the late 5th to the late 15th centuries, similar to the post-classical period of global history. It began with the fall of the Western Roman Empire a ...
, European lapidaries
Lapidary (from the Latin ) is the practice of shaping stone, minerals, or gemstones into decorative items such as cabochons, engraved gems (including cameos), and faceted designs. A person who practices lapidary is known as a lapidarist. A la ...
came to refer to blue corundum crystal by "sapphire", a derivative of the Latin
Latin (, or , ) is a classical language belonging to the Italic branch of the Indo-European languages. Latin was originally a dialect spoken in the lower Tiber area (then known as Latium) around present-day Rome, but through the power of the ...
word for blue: "sapphirus".
* The sapphire is the traditional gift for a 45th wedding anniversary
A wedding anniversary is the anniversary of the date a wedding took place. Couples may take the occasion to celebrate their relationship, either privately or with a larger party. Special celebrations and gifts are often given for particular an ...
.
* A sapphire jubilee
In 2017, the term sapphire jubilee or blue sapphire jubilee was coined for the celebrations to mark the 65th anniversary of the reign of Queen Elizabeth II (see Sapphire Jubilee of Queen Elizabeth II). Previously, the sapphire wedding anniversary w ...
occurs after 65 years. In 2017 Queen Elizabeth II
Elizabeth II (Elizabeth Alexandra Mary; 21 April 1926 – 8 September 2022) was Queen of the United Kingdom and other Commonwealth realms from 6 February 1952 until her death in 2022. She was queen regnant of 32 sovereign states during ...
marked the sapphire jubilee of her accession to the throne.[
* The sapphire is the ]birthstone
A birthstone is a gemstone
A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rock ...
of September.
* An Italian superstition holds that sapphires are amulets against eye problems, and melancholy. Mary, Queen of Scots
Mary, Queen of Scots (8 December 1542 – 8 February 1587), also known as Mary Stuart or Mary I of Scotland, was Queen of Scotland from 14 December 1542 until her forced abdication in 1567.
The only surviving legitimate child of James V of Scot ...
, owned a medicinal sapphire worn as a pendant to rub sore eyes.
* Pope Innocent III
Pope Innocent III ( la, Innocentius III; 1160 or 1161 – 16 July 1216), born Lotario dei Conti di Segni (anglicized as Lothar of Segni), was the head of the Catholic Church and ruler of the Papal States from 8 January 1198 to his death in 16 J ...
decreed that rings of bishops should be made of pure gold, set with an unengraved sapphire, as possessing the virtues and qualities essential to its dignified position as a seal of secrets, for there be many things "that a priest conceals from the senses of the vulgar and less intelligent; which he keeps locked up as it were under seal."
*The sapphire is the official state gem
Leaders of states in the U.S. which have significant mineral deposits often create a state mineral, rock, stone or gemstone to promote interest in their natural resources, history, tourism, etc. Not every state has an official state mineral, rock, ...
of Queensland
)
, nickname = Sunshine State
, image_map = Queensland in Australia.svg
, map_caption = Location of Queensland in Australia
, subdivision_type = Country
, subdivision_name = Australia
, established_title = Before federation
, established_ ...
since August 1985.
Notable sapphires
Extensive tables listing over a hundred important and famous rubies and sapphires can be found in Chapter 10 of ''Ruby & Sapphire: A Gemologist's Guide''.[
]
See also
* Geuda
Geuda (, pronounced gay-yoo-dah) is a form of the mineral corundum, or sapphire, found primarily in Sri Lanka. Around 70%-80% of gems mined in Sri Lanka belong to geuda varieties. Because of its semitransparent and milky appearance due to rutil ...
* Emerald
Emerald is a gemstone and a variety of the mineral beryl (Be3Al2(SiO3)6) colored green by trace amounts of chromium or sometimes vanadium.Hurlbut, Cornelius S. Jr. and Kammerling, Robert C. (1991) ''Gemology'', John Wiley & Sons, New York, p ...
* List of sapphires by size
This is a list of sapphires by size.
Sapphire
Sapphires are a precious gemstone, a variety of the mineral corundum, consisting of aluminum oxide () with trace amounts of elements such as iron, titanium, chromium, copper, or magnesium. It is ...
References
External links
*
Webmineral.com
Webmineral Corundum Page, Webmineral with extensive crystallographic and mineralogical information on Corundum
*
{{Authority control
Oxide minerals
Optical materials
Dielectrics
Transparent materials
Aluminium minerals
Superhard materials
Trigonal minerals
Minerals in space group 167
Corundum gemstones
Crystals