Substitute

natural gas Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbo ...

(SNG), or synthetic natural gas, is a fuel gas (predominantly

methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Eart ...

, CH₄) that can be produced from

fossil fuels A fossil fuel is a hydrocarbon-containing material formed naturally in the Earth's crust from the remains of dead plants and animals that is extracted and burned as a fuel. The main fossil fuels are coal, oil, and natural gas. Fossil fuels ...

such as

lignite coal Lignite, often referred to as brown coal, is a soft, brown, combustible, sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35%, and is considered the lowest rank of coal due to its relatively low heat ...

oil shale Oil shale is an organic-rich fine-grained sedimentary rock containing kerogen (a solid mixture of organic chemical compounds) from which liquid hydrocarbons can be produced. In addition to kerogen, general composition of oil shales constitute ...

, or from

biofuel Biofuel is a fuel that is produced over a short time span from biomass, rather than by the very slow natural processes involved in the formation of fossil fuels, such as oil. According to the United States Energy Information Administration (E ...

s (when it is named bio-SNG) or using electricity with

power-to-gas Power-to-gas (often abbreviated P2G) is a technology that uses electric power to produce a gaseous fuel. When using surplus power from wind generation, the concept is sometimes called windgas. Most P2G systems use electrolysis to produce hydrogen ...

systems. SNG in the form of

LNG Liquefied natural gas (LNG) is natural gas (predominantly methane, CH4, with some mixture of ethane, C2H6) that has been cooled down to liquid form for ease and safety of non-pressurized storage or transport. It takes up about 1/600th the volu ...

CNG Compressed natural gas (CNG) is a fuel gas mainly composed of methane (CH4), compressed to less than 1% of the volume it occupies at standard atmospheric pressure. It is stored and distributed in hard containers at a pressure of , usually in cy ...

can be used in road, rail, air and marine transport vehicles as a substitute for costly diesel, petrol, etc. The

carbon footprint A carbon footprint is the total greenhouse gas (GHG) emissions caused by an individual, event, organization, service, place or product, expressed as carbon dioxide equivalent (CO2e). Greenhouse gases, including the carbon-containing gases carbo ...

of SNG derived from coal is comparable to petroleum products. Bio-SNG has a much smaller carbon footprint when compared to petroleum products. LPG can also be produced by synthesising SNG with partial reverse

hydrogenation Hydrogenation is a chemical reaction between molecular hydrogen (H2) and another compound or element, usually in the presence of a Catalysis, catalyst such as nickel, palladium or platinum. The process is commonly employed to redox, reduce or S ...

at high pressure and low temperature. LPG is more easily transportable than SNG, more suitable as fuel in two wheeler or smaller HP vehicles /engines and also fetches higher price in international market due to short supply. Renewable electrical energy can also be used to create SNG (methane) via for example electrolysis of water or via a PEM fuel cell in reverse to create hydrogen which is then reacted with from for example CSS/U Utilisation in the

Sabatier reaction The Sabatier reaction or Sabatier process produces methane and water from a reaction of hydrogen with carbon dioxide at elevated temperatures (optimally 300–400 °C) and pressures (perhaps 3 MPa ) in the presence of a nickel catalyst. It w ...

. : + 4H₂ → CH₄ + 2H₂O

Distribution

It is advantageous to distribute SNG and bio-SNG together with natural gas in a gas grid. In this way, the production of renewable gas can be phased in at the same rate as the production capacity is increased. The gas market and infrastructure the natural gas has contributed with is a condition for large scale introduction of renewable biomethane produced through anaerobic digestion (biogas) or gasification and methanation bio-SNG.

Projects

The Great Plains Synfuels Plant injects approximately 4.1 million m³/day of SNG from lignite coal into the

United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territorie ...

national gas grid. The production process of SNG at the Great Plains plant involves

gasification Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (). This is achieved by reacting ...

, gas cleaning, shift, and

methanation Methanation is the conversion of carbon monoxide and carbon dioxide (COx) to methane (CH4) through hydrogenation. The methanation reactions of COx were first discovered by Sabatier and Senderens in 1902. CO''x'' methanation has many practical ap ...

. China is constructing nearly 30 nos massive SNG production plants from coal / lignite with aggregate annual capacity of 120 billion standard cubic meters of SNG.

References

External links

SGC Rapport 187 Substitute natural gas from biomass gasification

SGC-rapport on gasification and methanation
{{fuel gas Natural gas Synthetic fuel technologies

Distribution

Projects

See also

References

External links