Stockholm Convention on Persistent Organic Pollutants is an international
environmental
A biophysical environment is a biotic and abiotic surrounding of an organism or population, and consequently includes the factors that have an influence in their survival, development, and evolution. A biophysical environment can vary in scale f ...
treaty
A treaty is a formal, legally binding written agreement between actors in international law. It is usually made by and between sovereign states, but can include international organizations
An international organization or international o ...
, signed on 22 May 2001 in
Stockholm
Stockholm () is the Capital city, capital and List of urban areas in Sweden by population, largest city of Sweden as well as the List of urban areas in the Nordic countries, largest urban area in Scandinavia. Approximately 980,000 people liv ...
and effective from 17 May 2004, that aims to eliminate or restrict the production and use of
persistent organic pollutant
Persistent organic pollutants (POPs), sometimes known as "forever chemicals", are organic compounds that are resistant to environmental degradation through chemical, biological, and photolytic processes. They are toxic chemicals that adversely ...
s (POPs).
History
In 1995, the Governing Council of the
United Nations Environment Programme
The United Nations Environment Programme (UNEP) is responsible for coordinating responses to environmental issues within the United Nations system. It was established by Maurice Strong, its first director, after the United Nations Conference on th ...
(UNEP) called for global action to be taken on POPs, which it defined as "chemical substances that persist in the environment,
bio-accumulate through the
food web
A food web is the natural interconnection of food chains and a graphical representation of what-eats-what in an ecological community. Another name for food web is consumer-resource system. Ecologists can broadly lump all life forms into one ...
, and pose a risk of causing adverse effects to human health and the environment".
Following this, the Intergovernmental Forum on Chemical Safety (IFCS) and the
International Programme on Chemical Safety The International Programme on Chemical Safety (IPCS) was formed in 1980 and is a collaboration between three United Nations bodies, the World Health Organization, the International Labour Organization and the United Nations Environment Programme, t ...
(IPCS) prepared an assessment of the 12 worst offenders, known as the ''dirty dozen''.
The INC met five times between June 1998 and December 2000 to elaborate the convention, and delegates adopted the Stockholm Convention on POPs at the Conference of the Plenipotentiaries convened from 22 to 23 May 2001 in
Stockholm
Stockholm () is the Capital city, capital and List of urban areas in Sweden by population, largest city of Sweden as well as the List of urban areas in the Nordic countries, largest urban area in Scandinavia. Approximately 980,000 people liv ...
, Sweden.
The negotiations for the convention were completed on 23 May 2001 in Stockholm. The convention entered into force on 17 May 2004 with
ratification
Ratification is a principal's approval of an act of its agent that lacked the authority to bind the principal legally. Ratification defines the international act in which a state indicates its consent to be bound to a treaty if the parties inten ...
by an initial 128 parties and 151 signatories. Co-signatories agree to outlaw nine of the dirty dozen chemicals, limit the use of
DDT
Dichlorodiphenyltrichloroethane, commonly known as DDT, is a colorless, tasteless, and almost odorless crystalline chemical compound, an organochloride. Originally developed as an insecticide, it became infamous for its environmental impacts. ...
to
malaria
Malaria is a mosquito-borne infectious disease that affects humans and other animals. Malaria causes symptoms that typically include fever, tiredness, vomiting, and headaches. In severe cases, it can cause jaundice, seizures, coma, or death. S ...
control, and curtail inadvertent production of
dioxins
Dioxin may refer to:
* 1,2-Dioxin or 1,4-Dioxin, two unsaturated heterocyclic 6-membered rings where two carbon atoms have been replaced by oxygen atoms, giving the molecular formula C4H4O2
*Dibenzo-1,4-dioxin, the parent compound also known as ...
and
furan
Furan is a heterocyclic organic compound, consisting of a five-membered aromatic ring with four carbon atoms and one oxygen atom. Chemical compounds containing such rings are also referred to as furans.
Furan is a colorless, flammable, highly ...
s.
Parties to the convention have agreed to a process by which persistent toxic compounds can be reviewed and added to the convention, if they meet certain criteria for persistence and transboundary threat. The first set of new chemicals to be added to the convention were agreed at a conference in
Geneva
Geneva ( ; french: Genève ) frp, Genèva ; german: link=no, Genf ; it, Ginevra ; rm, Genevra is the List of cities in Switzerland, second-most populous city in Switzerland (after Zürich) and the most populous city of Romandy, the French-speaki ...
on 8 May 2009.
As of September 2022, there are 186 parties to the convention (185 states and the
European Union
The European Union (EU) is a supranational political and economic union of member states that are located primarily in Europe. The union has a total area of and an estimated total population of about 447million. The EU has often been des ...
).
Notable non-ratifying states include the United States, Israel, and Malaysia.
The Stockholm Convention was adopted to
EU legislation in Regulation (EC) No 850/2004. In 2019, the latter was replaced by Regulation (EU) 2019/1021.
Summary of provisions
Key elements of the Convention include the requirement that developed countries provide new and additional financial resources and measures to eliminate production and use of intentionally produced POPs, eliminate unintentionally produced POPs where feasible, and manage and dispose of POPs wastes in an environmentally sound manner. Precaution is exercised throughout the Stockholm Convention, with specific references in the preamble, the objective, and the provision on identifying new POPs.
Persistent Organic Pollutants Review Committee
When adopting the convention, provision was made for a procedure to identify additional POPs and the criteria to be considered in doing so. At the first meeting of the Conference of the Parties (COP1), held in Punta del Este, Uruguay, from 2–6 May 2005, the POPRC was established to consider additional candidates nominated for listing under the convention.
The committee is composed of 31 experts nominated by parties from the five United Nations regional groups and reviews nominated chemicals in three stages. The Committee first determines whether the substance fulfills POP screening criteria detailed in Annex D of the convention, relating to its persistence, bioaccumulation, potential for long-range environmental transport (LRET), and toxicity. If a substance is deemed to fulfill these requirements, the Committee then drafts a risk profile according to Annex E to evaluate whether the substance is likely, as a result of its LRET, to lead to significant adverse human health and/or environmental effects and therefore warrants global action. Finally, if the POPRC finds that global action is warranted, it develops a risk management evaluation, according to Annex F, reflecting socioeconomic considerations associated with possible control measures. Based on this, the POPRC decides to recommend that the COP list the substance under one or more of the annexes to the convention. The POPRC has met annually in Geneva, Switzerland, since its establishment.
The seventh meeting of the Persistent Organic Pollutants Review Committee (POPRC-7) of the Stockholm Convention on Persistent Organic Pollutants (POPs) took place from 10 to 14 October 2011 in Geneva. POPRC-8 was held from 15 to 19 October 2012 in Geneva, POPRC-9 to POPRC-15 were held in Rome, while POPRC-16
needed to be held online.
Listed substances
There were initially twelve distinct chemicals ("dirty dozen") listed in three categories. Two chemicals, hexachlorobenzene and polychlorinated biphenyls, were listed in both categories A and C. Currently, five chemicals are listed in both categories.
Chemicals newly proposed for inclusion in Annexes A, B, C
POPRC-7 considered three proposals for listing in Annexes A, B and/or C of the convention:
chlorinated naphthalenes (CNs),
hexachlorobutadiene
Hexachlorobutadiene, Cl2C=C(Cl)C(Cl)=CCl2, is a colorless liquid at room temperature that has an odor similar to that of turpentine. It is a chlorinated aliphatic diene with niche applications but is most commonly used as a solvent for other chlo ...
(HCBD) and
pentachlorophenol
Pentachlorophenol (PCP) is an organochlorine compound used as a pesticide and a disinfectant. First produced in the 1930s, it is marketed under many trade names. It can be found as pure PCP, or as the sodium salt of PCP, the latter of which diss ...
(PCP), its salts and esters. The proposal is the first stage of the POPRC's work in assessing a substance, and requires the POPRC to assess whether the proposed chemical satisfies the criteria in Annex D of the convention. The criteria for forwarding a proposed chemical to the risk profile preparation stage are persistence, bioaccumulation, potential for long-range environmental transport (LRET), and adverse effects.
POPRC-8 proposed
hexabromocyclododecane
Hexabromocyclododecane (HBCD or HBCDD) is a brominated flame retardant. It consists of twelve carbon, eighteen hydrogen, and six bromine atoms tied to the ring. Its primary application is in extruded (XPS) and expanded (EPS) polystyrene foam that ...
for listing in Annex A, with specific exemptions for production and use in expanded polystyrene and extruded polystyrene in buildings. This proposal was agreed at the sixth Conference of Parties on 28 April-10 May 2013.
POPRC-9 proposed
di-, tri-, tetra-, penta-, hexa-, hepta- and octa-chlorinated napthalenes, and hexachlorobutadiene for listing in Annexes A and C. It also set up further work on pentachlorophenol, its salts and esters, and decabromodiphenyl ether, perfluorooctanesulfonic acid, its salts and perfluorooctane sulfonyl chloride.
POPRC-15 proposed
PFHxS for listing in Annex A without specific exemptions.
Currently,
methoxychlor
Methoxychlor is a synthetic organochloride insecticide, now obsolete.
Usage
Methoxychlor was used to protect crops, ornamentals, livestock, and pets against fleas, mosquitoes, cockroaches, and other insects. It was intended to be a replacement ...
,
dechlorane plus,
UV-328,
chlorpyrifos
Chlorpyrifos (CPS), also known as Chlorpyrifos ethyl, is an organophosphate pesticide that has been used on crops, animals, and buildings, and in other settings, to kill several pests, including insects and worms. It acts on the nervous systems ...
, long-chain
perfluorocarboxylic acid
Perfluoroalkyl carboxylic acids (PFCAs), or perfluorocarboxylic acids are compounds of the formula CnF(2n+1)CO2H that belong to the class of per- and polyfluoroalkyl substances. The simplest example is trifluoroacetic acid. These compounds are o ...
s and medium-chain
chlorinated paraffins are under review.
Controversies
Although some critics have alleged that the treaty is responsible for the continuing death toll from malaria, in reality the treaty specifically permits the public health use of
DDT
Dichlorodiphenyltrichloroethane, commonly known as DDT, is a colorless, tasteless, and almost odorless crystalline chemical compound, an organochloride. Originally developed as an insecticide, it became infamous for its environmental impacts. ...
for the control of
mosquito
Mosquitoes (or mosquitos) are members of a group of almost 3,600 species of small flies within the family Culicidae (from the Latin ''culex'' meaning " gnat"). The word "mosquito" (formed by ''mosca'' and diminutive ''-ito'') is Spanish for "li ...
es (the malaria
vector
Vector most often refers to:
*Euclidean vector, a quantity with a magnitude and a direction
*Vector (epidemiology), an agent that carries and transmits an infectious pathogen into another living organism
Vector may also refer to:
Mathematic ...
). There are also ways to prevent high amounts of DDT consumed by using other malaria vectors such as window screens. As long as there are specific measures taken, such as use of DDT indoors, then the limited amount of DDT can be used in a regulated fashion. From a developing country perspective, a lack of data and information about the sources, releases, and environmental levels of POPs hampers negotiations on specific compounds, and indicates a strong need for research.
Another controversy would be certain POPs (which are continually active, specifically in the Arctic Biota) that were mentioned in the Stockholm Convention, but were not part of the Dirty Dozen such as perfluorooctane sulfonate (PFOS). PFOS have many general uses such as stain repellents but have many properties which can make it a dangerous due to the fact that PFOS can be highly resistant to environmental breakdown. PFOS can be toxic in terms of increased offspring death, decrease in body weight, and the disruption of neurological systems. What makes this compound controversial is the economic and political impact it can have among various countries and businesses.
Related conventions and other ongoing negotiations regarding pollution
*
Rotterdam Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals and Pesticides in International Trade
*
Convention on Long-Range Transboundary Air Pollution
The Convention on Long-Range Transboundary Air Pollution, often abbreviated as Air Convention or CLRTAP, is intended to protect the human environment against air pollution and to gradually reduce and prevent air pollution, including long-range ...
(CLRTAP)
*
*
Minamata Convention on Mercury
The Minamata Convention on Mercury is an international treaty designed to protect human health and the environment from anthropogenic emissions and releases of mercury and mercury compounds. The convention was a result of three years of meetin ...
Ongoing negotiations
* Intergovernmental Forum on Chemical Safety (IFCS)
*
Strategic Approach to International Chemicals Management
The Strategic Approach to International Chemicals Management (SAICM) is a global policy framework to foster the sound management of chemicals. The SAICM Secretariat is hosted by the United Nations Environment Programme.
''"The sound management of ...
(SAICM)
References
Further reading
* Chasek, Pam,
David L. Downie, and J.W. Brown (2013). ''Global Environmental Politics'', 6th Edition, Boulder: Westview Press.
* Downie, D., Krueger, J. and Selin, H. (2005). "Global Policy for Toxic Chemicals", in R. Axelrod, D. Downie and N. Vig (eds.) ''The Global Environment: Institutions, Law & Policy'', 2nd Edition, Washington: CQ Press.
* Downie, David and Jessica Templeton (2013). "Persistent Organic Pollutants." ''The Routledge Handbook of Global Environmental Politics''. New York: Routledge.
*
*
*
* Porta, M., Gasull, M., López, T., Pumarega, J. Distribution of blood concentrations of persistent organic pollutants in representative samples of the general population. United Nations Environment Programme – Regional Activity Centre for Cleaner Production (CP/RAC) Annual Technical Publication 2010, vol. 9, pp. 24–31
PDF.
* Selin, H. (2010). Global Governance of Hazardous Chemicals: Challenges of Multilevel Management, Cambridge: The MIT Press.
*
External links
Stockholm Convention SecretariatText of the ConventionRatifications*
ttp://www.iisd.ca/process/chemical_management-popsintro.html Introduction to the POPs Convention
{{DEFAULTSORT:Stockholm Convention on Persistent Organic Pollutants
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