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A still is an apparatus used to distill
liquid A liquid is a nearly incompressible fluid that conforms to the shape of its container but retains a (nearly) constant volume independent of pressure. As such, it is one of the four fundamental states of matter (the others being solid, gas, a ...
mixtures by heating to selectively boil and then cooling to condense the vapor. A still uses the same concepts as a basic distillation apparatus, but on a much larger scale. Stills have been used to produce perfume and medicine, water for injection (WFI) for pharmaceutical use, generally to separate and purify different chemicals, and to produce
distilled beverage Liquor (or a spirit) is an alcoholic drink produced by distillation of grains, fruits, vegetables, or sugar, that have already gone through alcoholic fermentation. Other terms for liquor include: spirit drink, distilled beverage or hard li ...
s containing ethanol.


Application

Since ethanol boils at a much lower temperature than water, simple distillation can separate ethanol from water by applying heat to the mixture. Historically, a copper vessel was used for this purpose, since copper removes undesirable
sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
-based compounds from the alcohol. However, many modern stills are made of stainless steel pipes with copper linings to prevent erosion of the entire vessel and lower copper levels in the waste product (which in large distilleries is processed to become animal feed). Copper is the preferred material for stills because it yields an overall better-tasting spirit. The taste is improved by the chemical reaction between the copper in the still and the sulfur compounds created by the yeast during fermentation. These unwanted and flavor-changing sulfur compounds are chemically removed from the final product resulting in a smoother, better-tasting drink. All copper stills will require repairs about every eight years due to the precipitation of copper-sulfur compounds. The beverage industry was the first to implement a modern distillation apparatus and led the way in developing equipment standards which are now widely accepted in the chemical industry. There is also an increasing usage of the distillation of
gin Gin () is a distilled alcoholic drink that derives its flavour from juniper berries (''Juniperus communis''). Gin originated as a medicinal liquor made by monks and alchemists across Europe, particularly in southern Italy, Flanders and the Ne ...
under glass and
PTFE Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene that has numerous applications. It is one of the best-known and widely applied PFAS. The commonly known brand name of PTFE-based composition is Teflon by Chemour ...
, and even at reduced pressures, to facilitate a fresher product. This is irrelevant to alcohol quality because the process starts with triple distilled grain alcohol, and the distillation is used solely to harvest botanical flavors such as limonene and other terpene like compounds. The ethyl alcohol is relatively unchanged. The simplest standard distillation apparatus is commonly known as a
pot still A pot still is a type of distillation apparatus or still used to distill liquors such as whisky or brandy. In modern (post-1850s) practice, they are not used to produce rectified spirit, because they do not separate congeners from ethanol as eff ...
, consisting of a single heated chamber and a vessel to collect purified alcohol. A pot still incorporates only one
condensation Condensation is the change of the state of matter from the gas phase into the liquid phase, and is the reverse of vaporization. The word most often refers to the water cycle. It can also be defined as the change in the state of water vapor to ...
, whereas other types of distillation equipment have multiple stages which result in higher purification of the more volatile component (alcohol). Pot still distillation gives an incomplete
separation Separation may refer to: Films * ''Separation'' (1967 film), a British feature film written by and starring Jane Arden and directed by Jack Bond * ''La Séparation'', 1994 French film * ''A Separation'', 2011 Iranian film * ''Separation'' (20 ...
, but this can be desirable for the flavor of some distilled beverages. If a purer distillate is desired, a reflux still is the most common solution. Reflux stills incorporate a fractionating column, commonly created by filling copper vessels with glass beads to maximize available
surface area The surface area of a solid object is a measure of the total area that the surface of the object occupies. The mathematical definition of surface area in the presence of curved surfaces is considerably more involved than the definition of arc ...
. As alcohol boils, condenses, and reboils through the column, the effective number of distillations greatly increases. Vodka and
gin Gin () is a distilled alcoholic drink that derives its flavour from juniper berries (''Juniperus communis''). Gin originated as a medicinal liquor made by monks and alchemists across Europe, particularly in southern Italy, Flanders and the Ne ...
and other neutral grain spirits are distilled by this method, then diluted to concentrations appropriate for human consumption. Alcoholic products from home distilleries are common throughout the world but are sometimes in violation of local statutes. The product of illegal stills in the United States is commonly referred to as
moonshine Moonshine is high-proof liquor that is usually produced illegally. The name was derived from a tradition of creating the alcohol during the nighttime, thereby avoiding detection. In the first decades of the 21st century, commercial dist ...
and in Ireland, poitín. However, poitín, although made illegal in 1661, has been legal for export in Ireland since 1997. Note that the term
moonshine Moonshine is high-proof liquor that is usually produced illegally. The name was derived from a tradition of creating the alcohol during the nighttime, thereby avoiding detection. In the first decades of the 21st century, commercial dist ...
itself is often misused as many believe it to be a specific kind of high-
proof Proof most often refers to: * Proof (truth), argument or sufficient evidence for the truth of a proposition * Alcohol proof, a measure of an alcoholic drink's strength Proof may also refer to: Mathematics and formal logic * Formal proof, a con ...
alcohol that was distilled from corn, but the term can refer to any illicitly distilled alcohol.


See also

* Distillation * Distilled water * Retort *
Alembic An alembic (from ar, الإنبيق, al-inbīq, originating from grc, ἄμβιξ, ambix, 'cup, beaker') is an alchemical still consisting of two vessels connected by a tube, used for distillation of liquids. Description The complete disti ...
* Column still *
Pot still A pot still is a type of distillation apparatus or still used to distill liquors such as whisky or brandy. In modern (post-1850s) practice, they are not used to produce rectified spirit, because they do not separate congeners from ethanol as eff ...
* Reflux still * Solar still


References


External links


Moonshine Still
Moonshine Still Ghost from the past - Video * {{Use dmy dates, date=March 2017 Distillation Separation processes Laboratory equipment Chemical equipment Firing techniques