Stanislas Sorel (born 1803,
Putanges, France; died 18 March 1871, Paris) was a French
civil engineer
A civil engineer is a person who practices civil engineering – the application of planning, designing, constructing, maintaining, and operating infrastructure while protecting the public and environmental health, as well as improving existing ...
, inventor, and
chemist
A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties. Chemists carefully describe th ...
, raised the son of a poor clock-maker.
[Beach, Alfred Ely (1871). Stanislas Sorel. Sci. Am, 25, 151.]
A poorly known aspect of Sorel early works was the development of heating appliances. In 1833 he invented an apparatus able to regulate the combustion, and therefore the temperature, in an oven. It could be considered as a first rudimentary
thermostat
A thermostat is a regulating device component which senses the temperature of a physical system and performs actions so that the system's temperature is maintained near a desired setpoint.
Thermostats are used in any device or system tha ...
. He applied this principle to a commercial portable stove (‘Le Cordon Bleu’) to facilitate safe and unattended cooking in the home kitchens. From these very first developments, he was intrigued by the properties of different metals, a.o. these of
zinc
Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
to protect
steel
Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant ty ...
against
corrosion
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...
.
[ Spennemann, Dirk H.R. (2017). Advertisements for Stanislas Sorel’s portable stove ‘Le Cordon Bleu’ (1833–1849). A visual data set. Institute for Land, Water and Society Report nº 101. Albury, NSW: Institute for Land, Water and Society, Charles Sturt University. ]
Sorel filed a patent on 10 May 1837 for a "
galvanic" method of protecting
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
from
rust
Rust is an iron oxide, a usually reddish-brown oxide formed by the reaction of iron and oxygen in the catalytic presence of water or air moisture. Rust consists of hydrous iron(III) oxides (Fe2O3·nH2O) and iron(III) oxide-hydroxide (FeO(OH ...
by either coating it in a bath of molten
zinc
Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
or by covering it with galvanic paint (cold galvanizing). This was the precursor of the modern
hot-dip galvanizing
Hot-dip galvanization is a form of galvanization. It is the process of coating iron and steel with zinc, which alloys with the surface of the base metal when immersing the metal in a bath of molten zinc at a temperature of around . When expose ...
. Sorel patent led to the industrial application and to the widespread use of the hot-dip galvanization process invented nearly one century earlier, in 1742, by the French physician and chemist
Paul Jacques Malouin
Paul Jacques Malouin (27 June 1701 – 3 January 1778) was a French physician and chemist.
Career
Born in Caen, Malouin graduated in medicine in 1730 against the wishes of his father (a legal official from Caen) who had sent him to Paris to study ...
.
In 1857, Sorel patented a new type of
paint
Paint is any pigmented liquid, liquefiable, or solid mastic composition that, after application to a substrate in a thin layer, converts to a solid film. It is most commonly used to protect, color, or provide texture. Paint can be made in many ...
based on
zinc oxychloride and much less toxic than the then currently used lead-based paints containing
ceruse
Venetian ceruse, also known as ''blanc de ceruse de Venise'' and Spirits of Saturn, was a 16th-century cosmetic used as a skin whitener. It was in great demand and considered the best available at the time, supposedly containing the best qualit ...
, a basic carbonate of lead.
In 1867, Sorel made a new form of
cement
A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel ( aggregate) together. Cement mix ...
from a combination of
magnesium oxide
Magnesium oxide ( Mg O), or magnesia, is a white hygroscopic solid mineral that occurs naturally as periclase and is a source of magnesium (see also oxide). It has an empirical formula of MgO and consists of a lattice of Mg2+ ions and O2− ions ...
and
magnesium chloride
Magnesium chloride is the family of inorganic compounds with the formula , where x can range from 0 to 12. These salts are colorless or white solids that are highly soluble in water. These compounds and their solutions, both of which occur in natu ...
, which had a remarkable capacity to bond with and contain other materials.
[Stanislas Sorel (1867).]
Sur un nouveau ciment magnésien
. ''Comptes Rendus Hebdomadaires des Séances de l'Académie des Sciences'', volume 65, pages 102–104. Sorel cement
Sorel cement (also known as magnesia cement or magnesium oxychloride) is a non-hydraulic cement first produced by the French chemist Stanislas Sorel in 1867.Sorel Stanislas (1867).Sur un nouveau ciment magnésien. ''Comptes Rendus Hebdomadaires d ...
as it is known has been used for
grindstones, tiles,
artificial stone and even artificial
ivory
Ivory is a hard, white material from the tusks (traditionally from elephants) and teeth of animals, that consists mainly of dentine, one of the physical structures of teeth and tusks. The chemical structure of the teeth and tusks of mammals is ...
(e.g. for
billiard balls
A billiard ball is a small, hard ball used in cue sports, such as carom billiards, pool, and snooker. The number, type, diameter, color, and pattern of the balls differ depending upon the specific game being played. Various particular ball pr ...
). It is stronger than the more usual
Portland cement
Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-specialty grout. It was developed from other types of hydraulic lime in England in the early 19th c ...
.
See also
*
Friedel's salt
Friedel's salt is an anion exchanger mineral belonging to the family of the layered double hydroxides (LDHs). It has affinity for anions as chloride and iodide and is capable of retaining them to a certain extent in its crystallographical stru ...
*
Salt-concrete
Salt-concrete (or ''salzbeton'') is a building material that is used to reduce the water inflow in mining shafts in salt mines. It is composed of 16% cement, 39% halite, 16% limestone powder, 14% water and 15% sand.
History
Salt-concrete was used ...
*
Sorel cement
Sorel cement (also known as magnesia cement or magnesium oxychloride) is a non-hydraulic cement first produced by the French chemist Stanislas Sorel in 1867.Sorel Stanislas (1867).Sur un nouveau ciment magnésien. ''Comptes Rendus Hebdomadaires d ...
*
Magnesium oxychloride
References
Further reading
*
* Sorel S. (1838). Procédé de préparation du fer dit galvanisé pour le préserver de l'oxidation. Archives des découvertes et des inventions nouvelles, 264–266.
* Sorel S. (1858). Peinture à base d'oxychlorure de zinc. Le Génie Industriel, 15(90), 327–328.
* Sorel S. (1858). Note sur un nouveau procédé pour la peinture à l'oxychlorure de zinc. Bulletin de la Société d'Encouragement pour l'Industrie Nationale, 57, 231–232.
* Sorel S. (1857). New chemical compositions producing either house paintings, cement, or plastic paste to be moulded. Being Patent Number: 1710, published 19 June 1857. London: Eyre and Spottiswood; 1857.
* Société Sorel et Laissement (1859). Peinture Sorel à l'oxychlorure de zinc. La Presse, 1859 Jul 20.
1803 births
1871 deaths
19th-century French chemists
19th-century French engineers
{{france-chemist-stub