
Staged combustion is a method used to reduce the emission of
nitrogen oxides
In atmospheric chemistry, is shorthand for nitric oxide () and nitrogen dioxide (), the nitrogen oxides that are most relevant for air pollution.
These gases contribute to the formation of smog and acid rain, as well as affecting tr ...
(
NOx) during
combustion
Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion ...
. There are two methods for staged combustion: air staged supply and fuel staged supply. Applications of staged combustion include
boiler
A boiler is a closed vessel in which fluid (generally water) is heated. The fluid does not necessarily boil. The heated or vaporized fluid exits the boiler for use in various processes or heating applications, including water heating, centra ...
s and
rocket engine
A rocket engine is a reaction engine, producing thrust in accordance with Newton's third law by ejecting reaction mass rearward, usually a high-speed Jet (fluid), jet of high-temperature gas produced by the combustion of rocket propellants stor ...
s.
Air staged supply
Air staging, or two-stage combustion, is generally described as the introduction of over-fire air into a boiler or furnace. Staging the air in the burner (internal air staging) is generally a design feature of low NO
x burners.
Furnace over-fire air (OFA) technology requires the introduction of combustion air to then be separated into primary and secondary flow sections. This achieves complete burnout and encourages the formation of
nitrogen gas
Nitrogen is a chemical element; it has symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at seventh i ...
(
N2) rather than NO
x.
Primary air (70-90%) is mixed with the fuel, producing a relatively low temperature, oxygen-deficient, fuel-rich zone, leading to only moderate amounts of NO
x being formed.
The secondary (10-30%) combustion air is injected above the combustion zone through a special wind-box with air-introducing ports and/or nozzles, which are mounted above the burners.
Combustion
Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion ...
is completed at this increased flame volume. Hence, the relatively low-temperature secondary stage limits the production of thermal NO
x. The location of the injection ports and the mixing of over-fire air is critical to maintaining efficient combustion.
Retrofitting over-fire air on an existing boiler involves water-wall tube modifications to create the ports for the secondary air nozzles and the addition of ducts, dampers, and the wind-box. This technique is currently used in 116 pulverized coal-fired units on a total capacity of 50
gigawatt electrical (GW
e) as a standalone measure.
It is used in combination with other primary measures for NO
x control in 175 coal-fired units on a total capacity of 53
GWe.
Via air staged supply, a NO
x reduction rate from 50-75% is possible. Air staged supply also leverages a simple configuration and is applicable in small-scale combustion.
Fuel staged supply
One form of fuel staged combustion is the procedure known as burner out of service (BOOS). The technique involves shutting off the fuel flow from one burner or more to create fuel-rich and fuel-lean zones, achieving some NO
x emission control (10%). The technique is not widely used in pulverized coal-fired plants (2 units, 350
MWe).
Another method of fuel staged combustion is fuel biasing. In fuel biasing, combustion is staged by diverting fuel from the upper-level burners to the lower ones or from the center to the side burners. The aim is to create a fuel-rich lower or central zone and a fuel-lean upper or side zone in order to achieve complete burnout. The technology lowers the flame temperature and improves the balance of the oxygen concentration in the furnace.
NOx emissions may be reduced by up to 30% using this technology. This technique is used in 13 pulverized coal-fired units on a total capacity of 2.7 GW
e.
Via fuel staged supply, a NO
x reduction rate from 50-75% is also possible, though minor temperature instabilities at the reduction zone can occur and a lower temperature is necessary. While applicable in large-scale combustion, fuel staged combustion uses a more complex constructive configuration.
History
Staged combustion dates back to the
hot bulb engine
The hot-bulb engine, also known as a semi-diesel or Akroyd engine, is a type of internal combustion engine in which fuel Combustion, ignites by coming in contact with a red-hot metal surface inside a bulb, followed by the introduction of air (ox ...
of the 1890s. The first stage of combustion occurred inside a hot bulb, where the hot gases were forced out into the cylinder. Then, when mixed with additional air, the second stage of combustion took place. During those times, staged combustion was used because it was a convenient method of ignition, and, likely, there was not much concern about
air pollution
Air pollution is the presence of substances in the Atmosphere of Earth, air that are harmful to humans, other living beings or the environment. Pollutants can be Gas, gases like Ground-level ozone, ozone or nitrogen oxides or small particles li ...
. A modern application of the principle is the
Stratified charge engine
A stratified charge engine describes a certain type of internal combustion engine, usually spark ignition (SI) engine that can be used in trucks, automobiles, portable and stationary equipment. The term "stratified charge" refers to the working f ...
, in which a spark ignites a rich mixture and the resulting flame-front ignites the weaker mixture elsewhere in the cylinder.
See also
*
Staged combustion cycle (rocket)
References
{{reflist, colwidth=30em
External links
Regenerative Thermal Oxidizer
Combustion
NOx control
Air pollution control systems