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Spin engineering describes the control and manipulation of
quantum spin Spin is a conserved quantity carried by elementary particles, and thus by composite particles (hadrons) and atomic nuclei. Spin is one of two types of angular momentum in quantum mechanics, the other being ''orbital angular momentum''. The orbita ...
systems to develop devices and materials. This includes the use of the spin
degrees of freedom Degrees of freedom (often abbreviated df or DOF) refers to the number of independent variables or parameters of a thermodynamic system. In various scientific fields, the word "freedom" is used to describe the limits to which physical movement or ...
as a probe for spin based phenomena. Because of the basic importance of quantum spin for physical and chemical processes, spin engineering is relevant for a wide range of scientific and technological applications. Current examples range from
Bose–Einstein condensation Bose–Einstein may refer to: * Bose–Einstein condensate ** Bose–Einstein condensation (network theory) * Bose–Einstein correlations * Bose–Einstein statistics In quantum statistics, Bose–Einstein statistics (B–E statistics) describe ...
to spin-based data storage and reading in state-of-the-art hard disk drives, as well as from powerful analytical tools like
nuclear magnetic resonance Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are perturbed by a weak oscillating magnetic field (in the near field) and respond by producing an electromagnetic signal with a ...
spectroscopy and
electron paramagnetic resonance Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials that have unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but the spin ...
spectroscopy to the development of magnetic molecules as
qubits In quantum computing, a qubit () or quantum bit is a basic unit of quantum information—the quantum version of the classic binary bit physically realized with a two-state device. A qubit is a two-state (or two-level) quantum-mechanical system, ...
and magnetic
nanoparticles A nanoparticle or ultrafine particle is usually defined as a particle of matter that is between 1 and 100 nanometres (nm) in diameter. The term is sometimes used for larger particles, up to 500 nm, or fibers and tubes that are less than 1 ...
. In addition, spin engineering exploits the functionality of spin to design materials with novel properties as well as to provide a better understanding and advanced applications of conventional material systems. Many chemical reactions are devised to create bulk materials or single molecules with well defined spin properties, such as a
single-molecule magnet A single-molecule magnet (SMM) is a metal-organic compound that has superparamagnetic behavior below a certain blocking temperature at the molecular scale. In this temperature range, a SMM exhibits magnetic hysteresis of purely molecular origin.
. The aim of this article is to provide an outline of fields of research and development where the focus is on the properties and applications of quantum spin.


Introduction

As spin is one of the fundamental quantum properties of
elementary particle In particle physics, an elementary particle or fundamental particle is a subatomic particle that is not composed of other particles. Particles currently thought to be elementary include electrons, the fundamental fermions ( quarks, leptons, an ...
s it is relevant for a large range of physical and chemical phenomena. For instance, the spin of the
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no kn ...
plays a key role in the
electron configuration In atomic physics and quantum chemistry, the electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. For example, the electron configuration of the neon atom ...
of atoms which is the basis of the periodic table of elements. The origin of
ferromagnetism Ferromagnetism is a property of certain materials (such as iron) which results in a large observed magnetic permeability, and in many cases a large magnetic coercivity allowing the material to form a permanent magnet. Ferromagnetic materials ...
is also closely related to the magnetic moment associated with the spin and the spin-dependent
Pauli exclusion principle In quantum mechanics, the Pauli exclusion principle states that two or more identical particles with half-integer spins (i.e. fermions) cannot occupy the same quantum state within a quantum system simultaneously. This principle was formulated ...
. Thus, the engineering of ferromagnetic materials like
mu-metal Mu-metal is a nickel–iron soft ferromagnetic alloy with very high permeability, which is used for shielding sensitive electronic equipment against static or low-frequency magnetic fields. It has several compositions. One such composition i ...
s or
Alnico Alnico is a family of iron alloys which in addition to iron are composed primarily of aluminium (Al), nickel (Ni), and cobalt (Co), hence the acronym ''al-ni-co''. They also include copper, and sometimes titanium. Alnico alloys are ferromagnetic, ...
at the beginning of the last century can be considered as early examples of spin engineering, although the concept of spin was not yet known at that time. Spin engineering in its generic sense became possible only after the first experimental characterization of spin in the
Stern–Gerlach experiment The Stern–Gerlach experiment demonstrated that the spatial orientation of angular momentum is quantized. Thus an atomic-scale system was shown to have intrinsically quantum properties. In the original experiment, silver atoms were sent throug ...
in 1922 followed by the development of
relativistic quantum mechanics In physics, relativistic quantum mechanics (RQM) is any Poincaré covariant formulation of quantum mechanics (QM). This theory is applicable to massive particles propagating at all velocities up to those comparable to the speed of light ''c ...
by Paul Dirac. This theory was the first to accommodate the spin of the electron and its magnetic moment. Whereas the physics of spin engineering dates back to the groundbreaking findings of quantum chemistry and physics within the first decades of the 20th century, the chemical aspects of spin engineering have received attention especially within the last twenty years. Today, researchers focus on specialized topics, such as the design and synthesis of molecular magnets or other model systems in order to understand and harness the fundamental principles behind phenomena such as the relation between magnetism and chemical reactivity as well as microstructure related mechanical properties of metals and the biochemical impact of spin (e. g.
photoreceptor protein Photoreceptor proteins are light-sensitive proteins involved in the sensing and response to light in a variety of organisms. Some examples are rhodopsin in the photoreceptor cells of the vertebrate retina, phytochrome in plants, and bacteriorhodo ...
s) and spin transport.


Research fields of spin engineering


Spintronics

Spintronics is the exploitation of both the intrinsic spin of the electron and its fundamental electronic charge in solid-state devices and is thus a part of spin engineering. Spintronics is probably one of the most advanced fields of spin engineering with many important inventions which can be found in end-user devices like the reading heads for magnetic hard disk drives. This section is divided in basic spintronic phenomena and their applications.


Basic spintronic phenomena

* Giant magnetoresistance (GMR), Tunnel magnetoresistance (TMR),
Spin valve A spin valve is a device, consisting of two or more conducting magnetic materials, whose electrical resistance can change between two values depending on the relative alignment of the magnetization in the layers. The resistance change is a result ...
* Spin transfer torque (STT) *Spin injection *Pure spin currents *
Spin pumping Spin pumping is the dynamical generation of pure spin current by the coherent precession of magnetic moments, which can efficiently inject spin from a magnetic material into an adjacent non-magnetic material. The non-magnetic material usually host ...
*
Spin wave A spin wave is a propagating disturbance in the ordering of a magnetic material. These low-lying collective excitations occur in magnetic lattices with continuous symmetry. From the equivalent quasiparticle point of view, spin waves are known as ...
s,
magnonics Magnonics is an emerging field of modern magnetism, which can be considered a sub-field of modern solid state physics. Magnonics combines the study of waves and magnetism. Its main aim is to investigate the behaviour of spin waves in nano-structure ...
* (inverse) Spin Hall effect *Spin calorics, Spin Seebeck effect


Applications of spintronics

this section is devoted to current and possible future applications of spintronics which make use of one or the combination of several basic spintronic phenomena: *
Hard disk drive A hard disk drive (HDD), hard disk, hard drive, or fixed disk is an electro-mechanical data storage device that stores and retrieves digital data using magnetic storage with one or more rigid rapidly rotating platters coated with magnet ...
read heads *
Magnetoresistive random-access memory Magnetoresistive random-access memory (MRAM) is a type of non-volatile random-access memory which stores data in magnetic domains. Developed in the mid-1980s, proponents have argued that magnetoresistive RAM will eventually surpass competing tec ...
(MRAM) *
Racetrack memory Racetrack memory or domain-wall memory (DWM) is an experimental non-volatile memory device under development at IBM's Almaden Research Center by a team led by physicist Stuart Parkin. In early 2008, a 3-bit version was successfully demonstrated. ...
*
Spin transistor The magnetically sensitive transistor (also known as the spin transistor or spintronic transistor—named for spintronics, the technology which this development spawned), originally proposed in 1990 by Supriyo Datta and Biswajit Das, currently sti ...
* Spin quantum computing *
Magnon A magnon is a quasiparticle, a collective excitation of the electrons' spin structure in a crystal lattice. In the equivalent wave picture of quantum mechanics, a magnon can be viewed as a quantized spin wave. Magnons carry a fixed amount of e ...
-based spintronics


Spin Materials

materials which properties are determined or strongly influenced by quantum spin: *Magnetic alloys, i.e.
Heusler compound Heusler compounds are magnetic intermetallics with face-centered cubic crystal structure and a composition of XYZ (half-Heuslers) or X2YZ (full-Heuslers), where X and Y are transition metals and Z is in the p-block. The term derives from the name ...
s *
Graphene Graphene () is an allotrope of carbon consisting of a single layer of atoms arranged in a hexagonal lattice nanostructure.
systems *Organic spin materials *Molecular nanomagnets *Magnetic molecules *Organic radicals *Metamaterials with artificial magnetism


Spin based detection

methods to characterize materials and physical or chemical processes via spin based phenomena: *
Magneto-optic Kerr effect In physics the magneto-optic Kerr effect (MOKE) or the surface magneto-optic Kerr effect (SMOKE) is one of the magneto-optic effects. It describes the changes to light reflected from a magnetized surface. It is used in materials science research ...
(
MOKE Moke may refer to: Places * Moke (Bihar, India), a village * Moke Lake, South Island, New Zealand * Na Mokulua, two small Hawaiian islands known together as "The Mokes" People * Hans Moke Niemann (born 2003), American chess grandmaster * ...
) *
Nuclear magnetic resonance Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are perturbed by a weak oscillating magnetic field (in the near field) and respond by producing an electromagnetic signal with a ...
(
NMR Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are perturbed by a weak oscillating magnetic field (in the near field) and respond by producing an electromagnetic signal with a ...
) *
Neutron scattering Neutron scattering, the irregular dispersal of free neutrons by matter, can refer to either the naturally occurring physical process itself or to the man-made experimental techniques that use the natural process for investigating materials. Th ...
*Spin polarized
photoemission The photoelectric effect is the emission of electrons when electromagnetic radiation, such as light, hits a material. Electrons emitted in this manner are called photoelectrons. The phenomenon is studied in condensed matter physics, and solid sta ...
* Brillouin Light Scattering (BLS) *X-ray magnetic circular dichroism ( XMCD)


References

{{Reflist


External links


Albert Fert (Nobel Prize in Physics (2007)), "The origin, the development and the future of spintronics", Nobel Lecture as pdf at nobelprize.org Peter Grünberg (Nobel Prize in Physics (2007)), "From spinwaves to Giant Magnetoresistance (GMR) and beyond", Nobel Lecture as pdf at nobelprize.org Scientific background of the discovery of the Giant Magnetoresistance, compiled by the Class for Physics of the Royal Swedish Academy of SciencesAlbert Fert (Nobel Prize in Physics (2007)) video answer of the question: "What is spin?"
Quantum chemistry Materials science Applied and interdisciplinary physics Spintronics Organic chemistry Inorganic chemistry