Formation
These tubes form when calcium carbonate or calcium sulfate dissolved in the water comes out of solution and is deposited. In soda straws, as each drop hovers at the tip, it deposits a ring of mineral at its edge. It then falls and a new drop takes its place. Each successive drop of water deposits a little more mineral before falling, and eventually a tube is built up.Outside the cave environment
Straws can also form beneath man-made structures and grow significantly faster than in the natural cave environment.Hill, C A, and Forti, P, (1997). Cave Minerals of the World, (2nd edition). untsville, Alabama: National Speleological Society Inc.pp 217 and 225Smith, G.K., (2016). “Calcite Straw Stalactites Growing From Concrete Structures”, Cave and Karst Science, Vol.43, No.1, P.4-10, (April 2016), British Cave Research Association, . These forms are classified as calthemites as opposed to the speleothems growing in natural environments. Their chemistry differs from those found in caves because they are derived from concrete, lime, mortar or other calcareous material.Macleod, G, Hall, A J and Fallick, A E, (1990). "An applied mineralogical investigation of concrete degradation in a major concrete road bridge". Mineralogical Magazine, Vol.54, 637–644. Calthemite soda straws have been recorded as growing up to per day in length, which is hundreds of times faster than speleothem soda straw growth rates typically averaging 2 mm or less per year. Calthemite straws are on average just 40% the mass per unit length of speleothem straws of equivalent external diameter. This is because calthemite straws have a thinner wall thickness and less-dense calcium carbonate structure compared to speleothem straws.Smith, G.K., (2021). "Comparison of calthemite and speleothem straw stalactites, and environmental conditions influencing straw diameter", Cave and Karst Science, Transactions of the British Cave Research Association, Vol.48(1), 3–11 A calthemite straw can vary in outside diameter as it grows in length. Changes in diameter can take a matter of days or weeks and are due to changes in drip rate over time. Slow dripping calthemite straws tend to be slightly larger in diameter than fast-dripping straws. As a comparison, because of the much "slower growth rate of speleothem (cave) straws, there is more chance that fluctuation in drip rate may be averaged out and the straw external diameter remains reasonably constant."References
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