Selenium
Selenium is a chemical element; it has symbol (chemistry), symbol Se and atomic number 34. It has various physical appearances, including a brick-red powder, a vitreous black solid, and a grey metallic-looking form. It seldom occurs in this elem ...
has six natural
isotope
Isotopes are distinct nuclear species (or ''nuclides'') of the same chemical element. They have the same atomic number (number of protons in their Atomic nucleus, nuclei) and position in the periodic table (and hence belong to the same chemica ...
s that occur in significant quantities, along with the trace isotope
79Se, which occurs in minute quantities in
uranium
Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...
ores. Five of these isotopes are
stable
A stable is a building in which working animals are kept, especially horses or oxen. The building is usually divided into stalls, and may include storage for equipment and feed.
Styles
There are many different types of stables in use tod ...
:
74Se,
76Se,
77Se,
78Se, and
80Se. The last three also occur as
fission products
Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the releas ...
, along with
79Se, which has a
half-life Half-life is a mathematical and scientific description of exponential or gradual decay.
Half-life, half life or halflife may also refer to:
Film
* Half-Life (film), ''Half-Life'' (film), a 2008 independent film by Jennifer Phang
* ''Half Life: ...
of 327,000 years,
[The half-life of 79Se](_blank)
and
82Se, which has a very long half-life (~10
20 years, decaying via
double beta decay
In nuclear physics, double beta decay is a type of radioactive decay in which two neutrons are simultaneously transformed into two protons, or vice versa, inside an atomic nucleus. As in single beta decay, this process allows the atom to move cl ...
to
82Kr) and for practical purposes can be considered to be stable. There are 23 other unstable isotopes that have been characterized, the longest-lived being
79Se with a half-life 327,000 years,
75Se with a half-life of 120 days, and
72Se with a half-life of 8.40 days. Of the other isotopes,
73Se has the longest half-life, 7.15 hours; most others have half-lives not exceeding 38 seconds.
List of isotopes
, -id=Selenium-63
, rowspan=3,
63Se
, rowspan=3 style="text-align:right" , 34
, rowspan=3 style="text-align:right" , 29
, rowspan=3, 62.98191(54)#
, rowspan=3, 13.2(39) ms
,
β+,
p (89%)
,
62Ge
, rowspan=3, 3/2−#
, rowspan=3,
, rowspan=3,
, -
, β
+ (11%)
,
63As
, -
, 2p? (<0.5%)
,
61Ge
, -id=Selenium-64
, rowspan=2,
64Se
, rowspan=2 style="text-align:right" , 34
, rowspan=2 style="text-align:right" , 30
, rowspan=2, 63.97117(54)#
, rowspan=2, 22.6(2) ms
, β
+?
,
64As
, rowspan=2, 0+
, rowspan=2,
, rowspan=2,
, -
, β
+, p?
,
63Ge
, -id=Selenium-65
, rowspan=2,
65Se
, rowspan=2 style="text-align:right" , 34
, rowspan=2 style="text-align:right" , 31
, rowspan=2, 64.96455(32)#
, rowspan=2, 34.2(7) ms
, β
+, p (87%)
,
64Ge
, rowspan=2, 3/2−#
, rowspan=2,
, rowspan=2,
, -
, β
+ (13%)
,
65As
, -id=Selenium-66
, rowspan=2,
66Se
, rowspan=2 style="text-align:right" , 34
, rowspan=2 style="text-align:right" , 32
, rowspan=2, 65.95528(22)#
, rowspan=2, 54(4) ms
, β
+
,
66As
, rowspan=2, 0+
, rowspan=2,
, rowspan=2,
, -
, β
+, p?
,
65Ge
, -id=Selenium-67
, rowspan=2,
67Se
, rowspan=2 style="text-align:right" , 34
, rowspan=2 style="text-align:right" , 33
, rowspan=2, 66.949994(72)
, rowspan=2, 133(4) ms
, β
+ (99.5%)
,
67As
, rowspan=2, 5/2−#
, rowspan=2,
, rowspan=2,
, -
, β
+, p (0.5%)
,
66Ge
, -id=Selenium-68
,
68Se
, style="text-align:right" , 34
, style="text-align:right" , 34
, 67.94182524(53)
, 35.5(7) s
, β
+
,
68As
, 0+
,
,
, -id=Selenium-69
, rowspan=2,
69Se
, rowspan=2 style="text-align:right" , 34
, rowspan=2 style="text-align:right" , 35
, rowspan=2, 68.9394148(16)
, rowspan=2, 27.4(2) s
, β
+ (99.95%)
,
69As
, rowspan=2, 1/2−
, rowspan=2,
, rowspan=2,
, -
, β
+, p (.052%)
,
68Ge
, -id=Selenium-69m1
, style="text-indent:1em" ,
69m1Se
, colspan="3" style="text-indent:2em" , 38.85(22) keV
, 2.0(2) μs
,
IT
,
69Se
, 5/2−
,
,
, -id=Selenium-69m2
, style="text-indent:1em" ,
69m2Se
, colspan="3" style="text-indent:2em" , 574.0(4) keV
, 955(16) ns
, IT
,
69Se
, 9/2+
,
,
, -id=Selenium-70
,
70Se
, style="text-align:right" , 34
, style="text-align:right" , 36
, 69.9335155(17)
, 41.1(3) min
, β
+
,
70As
, 0+
,
,
, -id=Selenium-71
,
71Se
, style="text-align:right" , 34
, style="text-align:right" , 37
, 70.9322094(30)
, 4.74(5) min
, β
+
,
71As
, (5/2−)
,
,
, -id=Selenium-71m1
, style="text-indent:1em" ,
71m1Se
, colspan="3" style="text-indent:2em" , 48.79(5) keV
, 5.6(7) μs
, IT
,
71Se
, (1/2−)
,
,
, -id=Selenium-71m2
, style="text-indent:1em" ,
71m2Se
, colspan="3" style="text-indent:2em" , 260.48(10) keV
, 19.0(5) μs
, IT
,
71Se
, (9/2+)
,
,
, -id=Selenium-72
,
72Se
, style="text-align:right" , 34
, style="text-align:right" , 38
, 71.9271405(21)
, 8.40(8) d
,
EC
,
72As
, 0+
,
,
, -id=Selenium-73
,
73Se
, style="text-align:right" , 34
, style="text-align:right" , 39
, 72.9267549(80)
, 7.15(9) h
, β
+
,
73As
, 9/2+
,
,
, -id=Selenium-73m
, rowspan=2 style="text-indent:1em" ,
73mSe
, rowspan=2 colspan="3" style="text-indent:2em" , 25.71(4) keV
, rowspan=2, 39.8(17) min
, IT (72.6%)
,
73Se
, rowspan=2, 3/2−
, rowspan=2,
, rowspan=2,
, -
, β
+ (27.4%)
,
73As
, -id=Selenium-74
,
74Se
, style="text-align:right" , 34
, style="text-align:right" , 40
, 73.922475933(15)
, colspan=3 align=center,
Observationally Stable
Stable nuclides are isotopes of a chemical element whose nucleons are in a configuration that does not permit them the surplus energy required to produce a radioactive emission. The nuclei of such isotopes are not radioactive and unlike radionuc ...
[Theoretically capable of β+β+ decay to 74Ge; half-life is above .]
, 0+
, 0.0086(3)
,
, -id=Selenium-75
,
75Se
, style="text-align:right" , 34
, style="text-align:right" , 41
, 74.922522870(78)
, 119.78(3) d
, EC
,
75As
, 5/2+
,
,
, -id=Selenium-76
,
76Se
, style="text-align:right" , 34
, style="text-align:right" , 42
, 75.919213702(17)
, colspan=3 align=center, Stable
, 0+
, 0.0923(7)
,
, -id=Selenium-77
,
77Se
Fission product
Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the releas ...
, style="text-align:right" , 34
, style="text-align:right" , 43
, 76.919914150(67)
, colspan=3 align=center, Stable
, 1/2−
, 0.0760(7)
,
, -id=Selenium-77m
, style="text-indent:1em" ,
77mSe
, colspan="3" style="text-indent:2em" , 161.9223(10) keV
, 17.36(5) s
, IT
,
77Se
, 7/2+
,
,
, -id=Selenium-78
,
78Se
, style="text-align:right" , 34
, style="text-align:right" , 44
, 77.91730924(19)
, colspan=3 align=center, Stable
, 0+
, 0.2369 (22)
,
, -id=Selenium-79
,
79SeLong-lived fission product
Long-lived fission products (LLFPs) are radioactive materials with a long half-life (more than 200,000 years) produced by nuclear fission of uranium and plutonium. Because of their persistent radiotoxicity, it is necessary to isolate them from hum ...
, style="text-align:right" , 34
, style="text-align:right" , 45
, 78.91849925(24)
, 3.27(28)×10
5 y
, β
−
,
79Br
, 7/2+
,
,
, -id=Selenium-79m
, rowspan=2 style="text-indent:1em" ,
79mSe
, rowspan=2 colspan="3" style="text-indent:2em" , 95.77(3) keV
, rowspan=2, 3.900(18) min
, IT (99.94%)
,
79Se
, rowspan=2, 1/2−
, rowspan=2,
, rowspan=2,
, -
, β
− (0.056%)
,
79Br
, -id=Selenium-80
,
80Se
, style="text-align:right" , 34
, style="text-align:right" , 46
, 79.9165218(10)
, colspan=3 align=center, Observationally Stable
[Theoretically capable of β−β− decay to 80Kr]
, 0+
, 0.4980(36)
,
, -id=Selenium-81
,
81Se
, style="text-align:right" , 34
, style="text-align:right" , 47
, 80.9179930(10)
, 18.45(12) min
, β
−
,
81Br
, 1/2−
,
,
, -id=Selenium-81m
, rowspan=2 style="text-indent:1em" ,
81mSe
, rowspan=2 colspan="3" style="text-indent:2em" , 103.00(6) keV
, rowspan=2, 57.28(2) min
, IT (99.95%)
,
81Se
, rowspan=2, 7/2+
, rowspan=2,
, rowspan=2,
, -
, β
− (0.051%)
,
81Br
, -id=Selenium-82
,
82Se
[ Primordial ]radionuclide
A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess numbers of either neutrons or protons, giving it excess nuclear energy, and making it unstable. This excess energy can be used in one of three ...
, style="text-align:right" , 34
, style="text-align:right" , 48
, 81.91669953(50)
, 8.76(15)×10
19 y
,
β−β−
,
82Kr
, 0+
, 0.0882(15)
,
, -id=Selenium-83
,
83Se
, style="text-align:right" , 34
, style="text-align:right" , 49
, 82.9191186(33)
, 22.25(4) min
, β
−
,
83Br
, 9/2+
,
,
, -id=Selenium-83m
, style="text-indent:1em" ,
83mSe
, colspan="3" style="text-indent:2em" , 228.92(7) keV
, 70.1(4) s
, β
−
,
83Br
, 1/2−
,
,
, -id=Selenium-84
,
84Se
, style="text-align:right" , 34
, style="text-align:right" , 50
, 83.9184668(21)
, 3.26(10) min
, β
−
,
84Br
, 0+
,
,
, -id=Selenium-85
,
85Se
, style="text-align:right" , 34
, style="text-align:right" , 51
, 84.9222608(28)
, 32.9(3) s
, β
−
,
85Br
, (5/2)+
,
,
, -id=Selenium-86
, rowspan=2,
86Se
, rowspan=2 style="text-align:right" , 34
, rowspan=2 style="text-align:right" , 52
, rowspan=2, 85.9243117(27)
, rowspan=2, 14.3(3) s
, β
−
,
86Br
, rowspan=2, 0+
, rowspan=2,
, rowspan=2,
, -
, β
−,
n?
,
85Br
, -id=Selenium-87
, rowspan=2,
87Se
, rowspan=2 style="text-align:right" , 34
, rowspan=2 style="text-align:right" , 53
, rowspan=2, 86.9286886(24)
, rowspan=2, 5.50(6) s
, β
− (99.50%)
,
87Br
, rowspan=2, (3/2+)
, rowspan=2,
, rowspan=2,
, -
, β
−, n (0.60%)
,
86Br
, -id=Selenium-88
, rowspan=2,
88Se
, rowspan=2 style="text-align:right" , 34
, rowspan=2 style="text-align:right" , 54
, rowspan=2, 87.9314175(36)
, rowspan=2, 1.53(6) s
, β
− (99.01%)
,
88Br
, rowspan=2, 0+
, rowspan=2,
, rowspan=2,
, -
, β
−, n (0.99%)
,
87Br
, -id=Selenium-89
, rowspan=2,
89Se
, rowspan=2 style="text-align:right" , 34
, rowspan=2 style="text-align:right" , 55
, rowspan=2, 88.9366691(40)
, rowspan=2, 430(50) ms
, β
− (92.2%)
,
89Br
, rowspan=2, 5/2+#
, rowspan=2,
, rowspan=2,
, -
, β
−, n (7.8%)
,
88Br
, -id=Selenium-90
, rowspan=2,
90Se
, rowspan=2 style="text-align:right" , 34
, rowspan=2 style="text-align:right" , 56
, rowspan=2, 89.94010(35)
, rowspan=2, 210(80) ms
, β
−
,
90Br
, rowspan=2, 0+
, rowspan=2,
, rowspan=2,
, -
, β
−, n?
,
89Br
, -id=Selenium-91
, rowspan=3,
91Se
, rowspan=3 style="text-align:right" , 34
, rowspan=3 style="text-align:right" , 57
, rowspan=3, 90.94570(47)
, rowspan=3, 270(50) ms
, β
− (79%)
,
91Br
, rowspan=3, 1/2+#
, rowspan=3,
, rowspan=3,
, -
, β
−, n (21%)
,
90Br
, -
, β
−, 2n?
,
89Br
, -id=Selenium-92
, rowspan=3,
92Se
, rowspan=3 style="text-align:right" , 34
, rowspan=3 style="text-align:right" , 58
, rowspan=3, 91.94984(43)#
, rowspan=3, 90# ms
300 ns, β
−?
,
92Br
, rowspan=3, 0+
, rowspan=3,
, rowspan=3,
, -
, β
−, n?
,
91Br
, -
, β
−, 2n?
,
90Br
, -id=Selenium-92m
, style="text-indent:1em" ,
92mSe
, colspan="3" style="text-indent:2em" , 3072(2) keV
, 15.7(7) μs
, IT
,
92Se
, (9−)
,
,
, -id=Selenium-93
, rowspan=3,
93Se
, rowspan=3 style="text-align:right" , 34
, rowspan=3 style="text-align:right" , 59
, rowspan=3, 92.95614(43)#
, rowspan=3, 130# ms
300 ns, β
−?
,
93Br
, rowspan=3, 1/2+#
, rowspan=3,
, rowspan=3,
, -
, β
−, n?
,
92Br
, -
, β
−, 2n?
,
91Br
, -id=Selenium-93m
, style="text-indent:1em" ,
93mSe
, colspan="3" style="text-indent:2em" , 678.2(7) keV
, 420(100) ns
, IT
,
93Se
,
,
,
, -id=Selenium-94
, rowspan=3,
94Se
, rowspan=3 style="text-align:right" , 34
, rowspan=3 style="text-align:right" , 60
, rowspan=3, 93.96049(54)#
, rowspan=3, 50# ms
300 ns, β
−?
,
94Br
, rowspan=3, 0+
, rowspan=3,
, rowspan=3,
, -
, β
−, n?
,
93Br
, -
, β
−, 2n?
,
92Br
, -id=Selenium-94m
, style="text-indent:1em" ,
94mSe
, colspan="3" style="text-indent:2em" , 2430.0(6) keV
, 680(50) ns
, IT
,
94Se
, (7−)
,
,
, -id=Selenium-95
, rowspan=3,
95Se
, rowspan=3 style="text-align:right" , 34
, rowspan=3 style="text-align:right" , 61
, rowspan=3, 94.96730(54)#
, rowspan=3, 70# ms
400 ns, β
−?
,
95Br
, rowspan=3, 3/2+#
, rowspan=3,
, rowspan=3,
, -
, β
−, n?
,
94Br
, -
, β
−, 2n?
,
93Br
, -id=Selenium-96
,
96Se
, style="text-align:right" , 34
, style="text-align:right" , 62
,
,
,
,
,
,
,
, -id=Selenium-97
,
97Se
, style="text-align:right" , 34
, style="text-align:right" , 63
,
,
,
,
,
,
,
Use of radioisotopes
The isotope selenium-75 has
radiopharmaceutical
Radiopharmaceuticals, or medicinal radiocompounds, are a group of pharmaceutical drugs containing radioactive isotopes. Radiopharmaceuticals can be used as diagnostic and therapeutic agents. Radiopharmaceuticals emit radiation themselves, which ...
uses. For example, it is used in high-dose-rate endorectal
brachytherapy
Brachytherapy is a form of radiation therapy where a sealed radiation, radiation source is placed inside or next to the area requiring treatment. The word "brachytherapy" comes from the Ancient Greek, Greek word , meaning "short-distance" or "s ...
, as an alternative to
iridium-192
Iridium-192 (symbol 192Ir) is a radioactive isotope of iridium, with a half-life of 73.827 days. It decays by emitting beta (β) particles and gamma (γ) radiation. About 96% of 192Ir decays occur via emission of β and γ radiation, leading to ...
.
In paleobiogeochemistry, the ratio in amount of selenium-82 to selenium-76 (i.e, the value of δ
82/76Se) can be used to track down the
redox
Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is t ...
conditions on Earth during the
Neoproterozoic era
The Neoproterozoic Era is the last of the three geologic eras of the Proterozoic eon, spanning from 1 billion to 538.8 million years ago, and is the last era of the Precambrian "supereon". It is preceded by the Mesoproterozoic era and succeeded b ...
in order to gain a deeper understanding of the
rapid oxygenation that trigger the emergence of complex organisms.
See also
Daughter products other than selenium
*
Isotopes of krypton
There are 34 known isotopes of krypton (36Kr) with atomic mass numbers from 67 to 103. Naturally occurring krypton is made of five stable isotopes and one () which is slightly radioactive with an extremely long half-life, plus traces of radioisot ...
*
Isotopes of bromine
Bromine (35Br) has two stable isotopes, 79Br and 81Br, and 35 known radioisotopes, the most stable of which is 77Br, with a half-life of 57.036 hours.
Like the radioactive isotopes of iodine, radioisotopes of bromine, collectively radiobromine, c ...
*
Isotopes of arsenic
Arsenic (33As) has 32 known isotopes and at least 10 isomers. Only one of these isotopes, 75As, is stable; as such, it is considered a monoisotopic element. The longest-lived radioisotope is 73As with a half-life of 80 days.
List of isotopes
...
*
Isotopes of germanium
Germanium (32Ge) has five naturally occurring isotopes, 70Ge, 72Ge, 73Ge, 74Ge, and 76Ge. Of these, 76Ge is very slightly radioactive, decaying by double beta decay with a half-life of 1.78 × 1021 years (130 billion times the age of the ...
References
* Isotope masses from:
**
* Isotopic compositions and standard atomic masses from:
**
**
* Half-life, spin, and isomer data selected from the following sources.
**
**
**
{{Navbox element isotopes
Selenium
Selenium
Selenium is a chemical element; it has symbol (chemistry), symbol Se and atomic number 34. It has various physical appearances, including a brick-red powder, a vitreous black solid, and a grey metallic-looking form. It seldom occurs in this elem ...