surface science Surface science is the study of physical and chemical phenomena that occur at the interface of two phases, including solid–liquid interfaces, solid–gas interfaces, solid–vacuum interfaces, and liquid–gas interfaces. It includes the fiel ...

, selective adsorption is the effect when minima associated with bound-state resonances occur in specular intensity in atom-surface

scattering Scattering is a term used in physics to describe a wide range of physical processes where moving particles or radiation of some form, such as light or sound, are forced to deviate from a straight trajectory by localized non-uniformities (including ...

. In crystal growth, selective adsorption refers to the phenomenon where adsorbing molecules attach preferentially to certain crystal faces. An example of selective adsorption can be demonstrated in the growth of Rochelle salt crystals. If copper ions are added to solution during the growth process, some crystal faces will slow down as copper apparently becomes a barrier to adsorption. However, by then adding sodium hydroxide to the solution, the preferred crystal faces will change once again.

Discovery

Pronounced intensity minima were first observed in 1930 by

Theodor Estermann Theodor Estermann (5 February 1902 – 29 November 1991) was a German-born American mathematician, working in the field of analytic number theory. The Estermann measure, a measure of the central symmetry of a convex set in the Euclidean plane ...

Otto Frisch Otto Robert Frisch FRS (1 October 1904 – 22 September 1979) was an Austrian-born British physicist who worked on nuclear physics. With Lise Meitner he advanced the first theoretical explanation of nuclear fission (coining the term) and first ...

, and Otto Stern, during a series of gas-surface interaction experiments attempting to demonstrate the wave nature of atoms and molecules. The phenomenon has been explained in 1936 by John Lennard-Jones and Devonshire in terms of resonant transitions to bound surface states.

Significance

The selective adsorption binding energies can supply information on the gas-surface interaction potentials by yielding the vibrational energy spectrum of the gas atom bound to the surface. Starting from the 1970s, it has been extensively studied, both theoretically and experimentally. Energy levels measured with this technique are available for many systems.

References

* * Surface science {{Physical-chemistry-stub