Saponarin is a
flavone
Flavone is an organic compound with the formula . A white solid, flavone is a derivative of chromone with a phenyl (Ph) substituent adjacent to the ether group. The compound is of little direct practical importance, but susbstituted derivatives, t ...
glucoside
A glucoside is a glycoside that is derived from glucose. Glucosides are common in plants, but rare in animals. Glucose is produced when a glucoside is hydrolysed by purely chemical means, or decomposed by fermentation or enzymes.
The name was o ...
. It is found in ''
Saponaria officinalis
''Saponaria officinalis'' is a common perennial plant from the family Caryophyllaceae. This plant has many common names, including common soapwort, bouncing-bet, crow soap, wild sweet William, and soapweed. There are about 20 species of soapwor ...
'' and in ''
Strongylodon macrobotrys
''Strongylodon macrobotrys'', commonly known as jade vine, emerald vine''The Royal Horticultural Society A–Z Encyclopedia of Garden Plants'', ed. Christopher Brickell, Dorling Kindersley, London, 1996, , p987 or turquoise jade vine, is a specie ...
'' where it imparts the characteristic
jade color to the flower. This coloration has been shown to be an example of
copigmentation Copigmentation is a phenomenon where pigmentation due to anthocyanidins is reinforced by the presence of other colorless flavonoids known as cofactors or “copigments”. This occurs by the formation of a non-covalently-linked complex.
Examples
...
, a result of the presence of
malvin
Malvin is a naturally occurring chemical of the anthocyanin family.
Malvin reacts in the presence of H2O2 to form malvone. The ortho-benzoyloxyphenylacetic acid esters reaction product is dependant of the pH: it is obtained under acidic conditio ...
(an
anthocyanin
Anthocyanins (), also called anthocyans, are water-soluble vacuolar pigments that, depending on their pH, may appear red, purple, blue, or black. In 1835, the German pharmacist Ludwig Clamor Marquart gave the name Anthokyan to a chemical compo ...
) and saponarin in the ratio 1:9. Under the
alkali
In chemistry, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the saltwort) is a basic, ionic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a ...
ne conditions (
pH 7.9) found in the
sap
Sap is a fluid transported in xylem cells (vessel elements or tracheids) or phloem sieve tube elements of a plant. These cells transport water and nutrients throughout the plant.
Sap is distinct from latex, resin, or cell sap; it is a separa ...
of the
epidermal
The epidermis is the outermost of the three layers that comprise the skin, the inner layers being the dermis and hypodermis. The epidermis layer provides a barrier to infection from environmental pathogens and regulates the amount of water relea ...
cells, this combination produced a blue-green pigmentation; the pH of the colorless inner floral tissue was found to be lower, at pH 5.6. Experiments showed that saponarin produced a strong yellow colouring in slightly alkaline conditions, resulting in the greenish tone of the flower.
[Greenish blue flower colour of Strongylodon macrobotrys. Kosaku Takeda, Aki Fujii, Yohko Senda and Tsukasa Iwashina, Biochemical Systematics and Ecology, Volume 38, Issue 4, August 2010, Pages 630–633, ] It is also found in passion flowers (''
Passiflora
''Passiflora'', known also as the passion flowers or passion vines, is a genus of about 550 species of flowering plants, the type genus of the family Passifloraceae.
They are mostly tendril-bearing vines, with some being shrubs or trees. They ...
sp.'').
References
Flavone glucosides
C-glycoside natural phenols
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