Sampson Flow
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Sampson flow is defined as fluid flow through an infinitely thin
orifice An orifice is any opening, mouth, hole or vent, as in a pipe, a plate, or a body * Body orifice, any opening in the body of a human or animal *Orifice plate, a restriction used to measure flow or to control pressure or flow, sometimes given specia ...
in the
viscous flow The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the inter ...
regime for low Reynolds number. It is derived from an analytical solution to the Navier-Stokes equations. The below equation can be used to calculate the total volumetric flowrate through such an orifice: :Q_S=\Delta P d^3 / 24 \mu Here, Q_S is the volumetric flowrate in m^3/sec, \Delta P is the pressure difference in Pa, d is the pore diameter in m, and \mu is the fluid's dynamic viscosity in Pa·s. The flow can also be expressed as a molecular flux as: :J_S=P_ \Delta P d/6\pi\mu k_BT Here, J_S is the molecular flux in atoms/m2·sec, P_ is the average of the pressures on either side of the orifice, k_B is the
Boltzmann constant The Boltzmann constant ( or ) is the proportionality factor that relates the average relative kinetic energy of particles in a gas with the thermodynamic temperature of the gas. It occurs in the definitions of the kelvin and the gas constant, ...
, (1.38\times10^ J/K), and T is the absolute temperature in K. Sampson flow is the macroscopic analog of
effusion In physics and chemistry, effusion is the process in which a gas escapes from a container through a hole of diameter considerably smaller than the mean free path of the molecules. Such a hole is often described as a ''pinhole'' and the escape ...
flow, which describes stochastic
diffusion Diffusion is the net movement of anything (for example, atoms, ions, molecules, energy) generally from a region of higher concentration to a region of lower concentration. Diffusion is driven by a gradient in Gibbs free energy or chemica ...
of molecules through an orifice much smaller than the mean-free-path of the gas molecules. For pore diameters on the order of the mean-free-path of the fluid, flow will occur with contributions from the molecular regime as well as the viscous regime, obeying the dusty gas model according to the following equation: :Q_=Q_S+Q_E Here, Q_ is the total volumetric flowrate and Q_E is the volumetric flowrate according to the law of
effusion In physics and chemistry, effusion is the process in which a gas escapes from a container through a hole of diameter considerably smaller than the mean free path of the molecules. Such a hole is often described as a ''pinhole'' and the escape ...
. As it turns out, for many gasses, we notice equal contributions from molecular and viscous regimes when the pore size is significantly larger than the mean-free-path of the fluid, for nitrogen this occurs at a pore diameter of 393 nm, 6.0× larger than the mean-free-path.


References

{{Reflist Fluid dynamics