Roald Hoffmann
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Roald Hoffmann (born Roald Safran; July 18, 1937) is a
Polish-American Polish Americans ( pl, Polonia amerykańska) are Americans who either have total or partial Poles, Polish ancestry, or are citizens of the Republic of Poland. There are an estimated 9.15 million self-identified Polish Americans, representing abou ...
theoretical chemist Theoretical chemistry is the branch of chemistry which develops theoretical generalizations that are part of the theoretical arsenal of modern chemistry: for example, the concepts of chemical bonding, chemical reaction, valence, the surface ...
who won the 1981
Nobel Prize in Chemistry ) , image = Nobel Prize.png , alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then "M ...
. He has also published plays and poetry. He is the Frank H. T. Rhodes Professor of Humane Letters, Emeritus, at
Cornell University Cornell University is a private statutory land-grant research university based in Ithaca, New York. It is a member of the Ivy League. Founded in 1865 by Ezra Cornell and Andrew Dickson White, Cornell was founded with the intention to teach an ...
, in
Ithaca, New York Ithaca is a city in the Finger Lakes region of New York, United States. Situated on the southern shore of Cayuga Lake, Ithaca is the seat of Tompkins County and the largest community in the Ithaca metropolitan statistical area. It is named a ...
.


Early life


Escape from the Holocaust

Hoffmann was born in
Złoczów Zolochiv ( uk, Золочів, pl, Złoczów, german: Solotschiw, yi, זלאָטשאָוו, ''Zlotshov'') is a small city of district significance in Lviv Oblast of Ukraine, the administrative center of Zolochiv Raion, Lviv Oblast, Zolochiv Rai ...
,
Second Polish Republic The Second Polish Republic, at the time officially known as the Republic of Poland, was a country in Central Europe, Central and Eastern Europe that existed between 1918 and 1939. The state was established on 6 November 1918, before the end of ...
(now Zolochiv,
Ukraine Ukraine ( uk, Україна, Ukraïna, ) is a country in Eastern Europe. It is the second-largest European country after Russia, which it borders to the east and northeast. Ukraine covers approximately . Prior to the ongoing Russian inv ...
), to a
Polish-Jewish The history of the Jews in Poland dates back at least 1,000 years. For centuries, Poland was home to the largest and most significant Ashkenazi Jewish community in the world. Poland was a principal center of Jewish culture, because of the lon ...
family, and was named in honor of the
Norwegian Norwegian, Norwayan, or Norsk may refer to: *Something of, from, or related to Norway, a country in northwestern Europe *Norwegians, both a nation and an ethnic group native to Norway *Demographics of Norway *The Norwegian language, including the ...
explorer
Roald Amundsen Roald Engelbregt Gravning Amundsen (, ; ; 16 July 1872 – ) was a Norwegian explorer of polar regions. He was a key figure of the period known as the Heroic Age of Antarctic Exploration. Born in Borge, Østfold, Norway, Amundsen bega ...
. His parents were Clara (Rosen), a teacher, and Hillel Safran, a civil engineer. After Germany invaded Poland and occupied the town, his family was placed in a labor camp where his father, who was familiar with much of the local infrastructure, was a valued prisoner. As the situation grew more dangerous, with prisoners being transferred to extermination camps, the family bribed guards to allow an escape. They arranged with a Ukrainian neighbor named Mykola Dyuk for Hoffmann, his mother, two uncles and an aunt to hide in the attic and a storeroom of the local schoolhouse, where they remained for eighteen months, from January 1943 to June 1944, while Hoffmann was aged 5 to 7. His father remained at the labor camp, but was able to occasionally visit, until he was tortured and killed by the Germans for his involvement in a plot to arm the camp prisoners. When she received the news, his mother attempted to contain her sorrow by writing down her feelings in a notebook her husband had been using to take notes on a relativity textbook he had been reading. While in hiding his mother kept Hoffmann entertained by teaching him to read and having him memorize geography from textbooks stored in the attic, then quizzing him on it. He referred to the experience as having been enveloped in a cocoon of love. Most of the rest of the family was killed in
the Holocaust The Holocaust, also known as the Shoah, was the genocide of European Jews during World War II. Between 1941 and 1945, Nazi Germany and its collaborators systematically murdered some six million Jews across German-occupied Europe; a ...
, though one grandmother and a few others survived. They migrated to the United States on the troop carrier ''Ernie Pyle'' in 1949. Hoffmann visited
Zolochiv Zolochiv, ( ua, Золочів) may refer to the following places in Ukraine: * Zolochiv, Lviv Oblast, city in Lviv Oblast * Zolochiv, Kharkiv Oblast, urban-type settlement in Ukraine {{set index, populated places in Ukraine ...
with his adult son (by then a parent of a five-year-old) in 2006 and found that the attic where he had hidden was still intact, but the storeroom had been incorporated, ironically enough, into a chemistry classroom. In 2009, a monument to Holocaust victims was built in
Zolochiv Zolochiv, ( ua, Золочів) may refer to the following places in Ukraine: * Zolochiv, Lviv Oblast, city in Lviv Oblast * Zolochiv, Kharkiv Oblast, urban-type settlement in Ukraine {{set index, populated places in Ukraine ...
on Hoffmann's initiative.


Personal life

Hoffmann married Eva Börjesson in 1960. They have two children, Hillel Jan and Ingrid Helena. He is an atheist.


Education and academic credentials

Hoffmann graduated in 1955 from New York City's
Stuyvesant High School Stuyvesant High School (pronounced ), commonly referred to among its students as Stuy (pronounced ), is a State school, public university-preparatory school, college-preparatory, Specialized high schools in New York City, specialized high school ...
, where he won a Westinghouse science scholarship. He received his
Bachelor of Arts Bachelor of arts (BA or AB; from the Latin ', ', or ') is a bachelor's degree awarded for an undergraduate program in the arts, or, in some cases, other disciplines. A Bachelor of Arts degree course is generally completed in three or four years ...
degree Degree may refer to: As a unit of measurement * Degree (angle), a unit of angle measurement ** Degree of geographical latitude ** Degree of geographical longitude * Degree symbol (°), a notation used in science, engineering, and mathematics ...
at
Columbia University Columbia University (also known as Columbia, and officially as Columbia University in the City of New York) is a private research university in New York City. Established in 1754 as King's College on the grounds of Trinity Church in Manhatt ...
(Columbia College) in 1958. He earned his
Master of Arts A Master of Arts ( la, Magister Artium or ''Artium Magister''; abbreviated MA, M.A., AM, or A.M.) is the holder of a master's degree awarded by universities in many countries. The degree is usually contrasted with that of Master of Science. Tho ...
degree in 1960 from
Harvard University Harvard University is a private Ivy League research university in Cambridge, Massachusetts. Founded in 1636 as Harvard College and named for its first benefactor, the Puritan clergyman John Harvard, it is the oldest institution of higher le ...
. He earned his
doctor of philosophy A Doctor of Philosophy (PhD, Ph.D., or DPhil; Latin: or ') is the most common Academic degree, degree at the highest academic level awarded following a course of study. PhDs are awarded for programs across the whole breadth of academic fields ...
degree from
Harvard University Harvard University is a private Ivy League research university in Cambridge, Massachusetts. Founded in 1636 as Harvard College and named for its first benefactor, the Puritan clergyman John Harvard, it is the oldest institution of higher le ...
while working under joint supervision of Martin Gouterman and subsequent 1976
Nobel Prize in Chemistry ) , image = Nobel Prize.png , alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then "M ...
winner William N. Lipscomb, Jr. Hoffman worked on the molecular orbital theory of polyhedral molecules. Under Lipscomb's direction the
Extended Hückel method The extended Hückel method is a semiempirical quantum chemistry method, developed by Roald Hoffmann since 1963. It is based on the Hückel method but, while the original Hückel method only considers pi orbitals, the extended method also includes ...
was developed by Lawrence Lohr and by Roald Hoffmann. This method was later extended by Hoffmann. He went to
Cornell Cornell University is a private statutory land-grant research university based in Ithaca, New York. It is a member of the Ivy League. Founded in 1865 by Ezra Cornell and Andrew Dickson White, Cornell was founded with the intention to teach an ...
in 1965 and has remained there, becoming professor emeritus.


Scientific research

Hoffmann's research and interests have been in the electronic structure of stable and unstable molecules, and in the study of transition states in reactions.Lipscomb WN. ''Boron Hydrides'', W. A. Benjamin Inc., New York, 1963, Chapter 3. He has investigated the structure and reactivity of both
organic Organic may refer to: * Organic, of or relating to an organism, a living entity * Organic, of or relating to an anatomical organ Chemistry * Organic matter, matter that has come from a once-living organism, is capable of decay or is the product ...
and
inorganic In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemist ...
molecules, and examined problems in organo-metallic and solid-state chemistry. Hoffman has developed semiempirical and nonempirical
computational Computation is any type of arithmetic or non-arithmetic calculation that follows a well-defined model (e.g., an algorithm). Mechanical or electronic devices (or, historically, people) that perform computations are known as ''computers''. An espe ...
tools and methods such as the
extended Hückel method The extended Hückel method is a semiempirical quantum chemistry method, developed by Roald Hoffmann since 1963. It is based on the Hückel method but, while the original Hückel method only considers pi orbitals, the extended method also includes ...
which he proposed in 1963 for determining molecular orbitals. With
Robert Burns Woodward Robert Burns Woodward (April 10, 1917 – July 8, 1979) was an American organic chemist. He is considered by many to be the most preeminent synthetic organic chemist of the twentieth century, having made many key contributions to the subject, e ...
he developed the
Woodward–Hoffmann rules The Woodward–Hoffmann rules (or the pericyclic selection rules), devised by Robert Burns Woodward and Roald Hoffmann, are a set of rules used to rationalize or predict certain aspects of the stereochemistry and activation energy of pericyclic reac ...
for elucidating
reaction mechanism In chemistry, a reaction mechanism is the step by step sequence of elementary reactions by which overall chemical change occurs. A chemical mechanism is a theoretical conjecture that tries to describe in detail what takes place at each stage of ...
s and their
stereochemistry Stereochemistry, a subdiscipline of chemistry, involves the study of the relative spatial arrangement of atoms that form the structure of molecules and their manipulation. The study of stereochemistry focuses on the relationships between stereois ...
. They realized that chemical transformations could be approximately predicted from subtle symmetries and asymmetries in the
electron orbitals An electron orbital may refer to: * An atomic orbital, describing the behaviour of an electron in an atom * A molecular orbital, describing the behaviour of an electron in a molecule See also * Electron configuration, the arrangement of electr ...
of complex molecules. Their rules predict differing outcomes, such as the types of products that will be formed when two compounds are activated by heat compared with those produced under activation by light. For this work Hoffmann received the 1981 Nobel Prize in chemistry, sharing it with Japanese chemist
Kenichi Fukui was a Japanese chemist, known as the first Asian person to be awarded the Nobel Prize in Chemistry. Fukui was co-recipient of the 1981 Nobel Prize in Chemistry with Roald Hoffmann, for their independent investigations into the mechanisms of ch ...
, who had independently resolved similar issues. (Woodward was not included in the prize, which is given only to living persons, although he had won the 1965 prize for other work.) In his Nobel Lecture, Hoffmann introduced the isolobal analogy for predicting the bonding properties of
organometallic compounds Organometallic chemistry is the study of organometallic compounds, chemical compounds containing at least one chemical bond between a carbon atom of an organic molecule and a metal, including alkali, alkaline earth, and transition metals, and so ...
. Some of Hoffman's most recent work, with
Neil Ashcroft Neil William Ashcroft (27 November 1938 – 15 March 2021) was a British solid-state physicist. Early life and education Ashcroft was born in London on 27 November 1938, and migrated to New Zealand in 1947. He was educated at Hutt Valley High Sc ...
and Vanessa Labet, examines bonding in matter under extreme high pressure.


Artistic interests


''The World Of Chemistry'' with Roald Hoffmann

In 1988 Hoffmann became the series host in a 26-program
PBS The Public Broadcasting Service (PBS) is an American public broadcasting, public broadcaster and Non-commercial activity, non-commercial, Terrestrial television, free-to-air television network based in Arlington, Virginia. PBS is a publicly fu ...
education series by Annenberg/CPB, '' The World of Chemistry'', opposite with series demonstrator
Don Showalter Donald L. Showalter is a professor emeritus and former chairman of the department of chemistry at the University of Wisconsin–Stevens Point. Born in Louisville, Kentucky, he attended Saint Xavier High School. Afterwards, he received his bache ...
. While Hoffmann introduced a series of concepts and ideas, Showalter provided a series of demonstrations and other visual representations to help students and viewers to better understand the information.


''Entertaining Science''

Since the spring of 2001, Hoffmann has been the host of the monthly series ''Entertaining Science'' at New York City's
Cornelia Street Cafe The Cornelia Street Cafe, was a restaurant & bar at 29 Cornelia Street in New York City's Greenwich Village, opened in July 1977. The cafe closed at the end of 2018, due to rising rents from the gentrification of the West Village; ending on its ho ...
, which explores the juncture between the arts and science.


Non-fiction

He has published books on the connections between art and science: ''Roald Hoffmann on the Philosophy, Art, and Science of Chemistry'' and ''Beyond the Finite: The Sublime in Art and Science''.


Poetry

Hoffmann is also a writer of
poetry Poetry (derived from the Greek ''poiesis'', "making"), also called verse, is a form of literature that uses aesthetic and often rhythmic qualities of language − such as phonaesthetics, sound symbolism, and metre − to evoke meanings i ...
. His collections include ''The Metamict State'' (1987, ), ''Gaps and Verges'' (1990, ), and ''Chemistry Imagined'', co-produced with artist Vivian Torrence.


Plays

He co-authored with
Carl Djerassi Carl Djerassi (October 29, 1923 – January 30, 2015) was an Austrian-born Bulgarian-American pharmaceutical chemist, novelist, playwright and co-founder of Djerassi Resident Artists Program with Diane Middlebrook, Diane Wood Middlebrook. He is b ...
the play ''Oxygen'', about the
discovery Discovery may refer to: * Discovery (observation), observing or finding something unknown * Discovery (fiction), a character's learning something unknown * Discovery (law), a process in courts of law relating to evidence Discovery, The Discovery ...
of
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as wel ...
and the experience of being a scientist. Hoffman's play, "Should've" (2006) about ethics in science and art, has been produced in workshops, as has a play based on his experiences in the holocaust, "We Have Something That Belongs to You" (2009), later retitled "Something That Belongs to You.


Honors and awards


Nobel Prize in Chemistry

In 1981, Hoffmann received the
Nobel Prize in Chemistry ) , image = Nobel Prize.png , alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then "M ...
, which he shared with
Kenichi Fukui was a Japanese chemist, known as the first Asian person to be awarded the Nobel Prize in Chemistry. Fukui was co-recipient of the 1981 Nobel Prize in Chemistry with Roald Hoffmann, for their independent investigations into the mechanisms of ch ...
"for their theories, developed independently, concerning the course of chemical reactions".The Nobel Prize in Chemistry 1981
. Nobelprize.org. Retrieved on April 2, 2014.


Other awards

Hoffmann has won many other awards, and is the recipient of more than 25 honorary degrees. *
ACS Award in Pure Chemistry The American Chemical Society Award in Pure Chemistry is awarded annually by the American Chemical Society (ACS) "to recognize and encourage fundamental research in pure chemistry carried out in North America by young men and women." "Young" me ...
, 1969 * Award of the
International Academy of Quantum Molecular Science The International Academy of Quantum Molecular Science (IAQMS) is an international scientific learned society covering all applications of quantum theory to chemistry and chemical physics. It was created in Menton in 1967. The founding members wer ...
, 1970, "pour sa methode de calcul des fonctions d'onde moleculaires et pour ses etudes theoriques des reactions chimiques" *Fellow of the American Academy of Arts and Sciences, elected 1971 *Elected member of the
National Academy of Sciences The National Academy of Sciences (NAS) is a United States nonprofit, non-governmental organization. NAS is part of the National Academies of Sciences, Engineering, and Medicine, along with the National Academy of Engineering (NAE) and the Nati ...
, elected 1972 *
Arthur C. Cope Award The Arthur C. Cope Award is a prize awarded for achievement in the field of organic chemistry research. It is sponsored by the Arthur C. Cope Fund, and has been awarded annually since 1973 by the American Chemical Society. It consists of $25,000, ...
in Organic Chemistry, 1973 (with
Robert B. Woodward Robert Burns Woodward (April 10, 1917 – July 8, 1979) was an American organic chemist. He is considered by many to be the most preeminent synthetic organic chemist of the twentieth century, having made many key contributions to the subject, e ...
) *
Nobel Prize in Chemistry ) , image = Nobel Prize.png , alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then "M ...
, 1981 *Inorganic Chemistry Award (American Chemical Society), 1982 (sponsored by Monsanto) *
National Medal of Science The National Medal of Science is an honor bestowed by the President of the United States to individuals in science and engineering who have made important contributions to the advancement of knowledge in the fields of behavioral and social scienc ...
, 1983 *Fellow of the American Philosophical Society, elected 1984 * Elected a Foreign Member of the Royal Society (ForMemRS) in 1984 *Foreign Member of the
Royal Swedish Academy of Sciences The Royal Swedish Academy of Sciences ( sv, Kungliga Vetenskapsakademien) is one of the Swedish Royal Academies, royal academies of Sweden. Founded on 2 June 1739, it is an independent, non-governmental scientific organization that takes special ...
, elected 1985 *
Priestley Medal The Priestley Medal is the highest honor conferred by the American Chemical Society (ACS) and is awarded for distinguished service in the field of chemistry. Established in 1922, the award is named after Joseph Priestley, the discoverer of oxygen ...
, 1990 *Harvard Centennial Medalist, 1994 *Pimentel Award in Chemical Education, 1996 * E.A. Wood Science Writing Award, 1997 *Literaturpreis of the Verband der Chemischen Industrie for his textbook ''The Same and Not The Same'', 1997 * Kolos Medal, 1998 *
American Institute of Chemists Gold Medal The American Institute of Chemists Gold Medal is the highest award of the American Institute of Chemists and has been awarded since 1926. It is presented annually to a person who has most encouraged the science of chemistry or the profession of ...
, 2006 *
James T. Grady-James H. Stack Award for Interpreting Chemistry The James T. Grady-James H. Stack Award for Interpreting Chemistry for the Public is awarded on a yearly basis by the American Chemical Society.Kosciuszko Foundation The Kosciuszko Foundation is a charitable foundation based in New York City. It was created by Stephen Mizwa to fund programs that promote Polish-American intellectual and artistic exchange. History The Polish American Scholarship Committee was ...
of Eminent Scientists of Polish Origin and Ancestry, 2014 * Ullyot Public Affairs Lecture,
Science History Institute The Science History Institute is an institution that preserves and promotes understanding of the history of science. Located in Philadelphia, Pennsylvania, it includes a library, museum, archive, research center and conference center. It was fo ...
, 2019 *
Marie Curie Medal The Marie Curie-Skłodowska Medal is a Polish annual science award conferred by the Polish Chemical Society (''Polskie Towarzystwo Chemiczne, PTCHEM'') to scientists working permanently abroad for contributions in the field of chemistry. Descrip ...
Hoffmann is a member of the
International Academy of Quantum Molecular Science The International Academy of Quantum Molecular Science (IAQMS) is an international scientific learned society covering all applications of quantum theory to chemistry and chemical physics. It was created in Menton in 1967. The founding members wer ...
and the Board of Sponsors of The
Bulletin of the Atomic Scientists The ''Bulletin of the Atomic Scientists'' is a nonprofit organization concerning science and global security issues resulting from accelerating technological advances that have negative consequences for humanity. The ''Bulletin'' publishes conte ...
. In August 2007, the
American Chemical Society The American Chemical Society (ACS) is a scientific society based in the United States that supports scientific inquiry in the field of chemistry. Founded in 1876 at New York University, the ACS currently has more than 155,000 members at all d ...
held a symposium at its biannual national meeting to honor Hoffmann's 70th birthday. In 2008, the
Göttingen Academy of Sciences and Humanities The Göttingen Academy of Sciences (german: Akademie der Wissenschaften zu Göttingen)Note that the German ''Wissenschaft'' has a wider meaning than the English "Science", and includes Social sciences and Humanities. is the second oldest of the se ...
awarded him its
Lichtenberg Medal The Lichtenberg Medal (German: Lichtenberg-Medaille) is the highest award of the Göttingen Academy of Sciences and Humanities. It was established in memory of the Göttingen scholar Georg Christoph Lichtenberg. It has been awarded since 2004 (eve ...
. In August 2017, another symposium was held at the 254th American Chemical Society National Meeting in Washington DC, to honor Hoffmann's 80th birthday. The
Hoffmann Institute of Advanced Materials The Hoffmann Institute of Advanced Materials (HIAM) is a science research institute affiliated to Shenzhen Polytechnic in Shenzhen, China. As the eighth institute at Shenzhen named after a Nobel laureate, it was founded in February 2018 under the ...
in Shenzhen, named after him, was founded in his honor in February 2018 and formally opened in his presence in May 2019.


References


External links

* {{DEFAULTSORT:Hoffmann, Roald 1937 births Living people Nobel laureates in Chemistry American Nobel laureates 21st-century American chemists Jewish American atheists Polish emigrants to the United States Brentwood High School (Brentwood, New York) alumni Columbia College (New York) alumni Cornell University faculty Harvard University alumni Jewish American scientists Jewish chemists Jews from Galicia (Eastern Europe) Eli Lilly and Company people Foreign Members of the Royal Society Members of the International Academy of Quantum Molecular Science Members of the Royal Swedish Academy of Sciences Members of the United States National Academy of Sciences Foreign Members of the Russian Academy of Sciences Foreign Fellows of the Indian National Science Academy National Medal of Science laureates Recipients of the Lomonosov Gold Medal People from Zolochiv, Lviv Oblast Polish Nobel laureates Polish chemists Stuyvesant High School alumni Survivors of World War II deportations to Transnistria Fellows of the American Chemical Society Theoretical chemists Computational chemists Stereochemists Sloan Research Fellows Scientists from New York (state) Fellows of the American Physical Society