![Rust on iron](https://upload.wikimedia.org/wikipedia/commons/a/a4/Rust_on_iron.jpg)
Rust is an
iron oxide
Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of whic ...
, a usually reddish-brown
oxide
An oxide () is a chemical compound that contains at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– (molecular) ion. with oxygen in the oxidation state of −2. Most of the E ...
formed by the reaction of
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
and
oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as wel ...
in the
catalytic
Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recyc ...
presence of
water
Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a ...
or
air moisture
(99.9839 °C)
, -
, Boiling point
,
, -
, specific gas constant
, 461.5 J/( kg·K)
, -
, Heat of vaporization
, 2.27 MJ/kg
, -
, Heat capacity
, 1.864 kJ/(kg·K)
Water vapor, water vapour or aqueous vapor is the gaseous phas ...
. Rust consists of
hydrous iron(III) oxides (Fe
2O
3·nH
2O) and
iron(III) oxide-hydroxide
Iron(III) oxide-hydroxide or ferric oxyhydroxideA. L. Mackay (1960): "β-Ferric Oxyhydroxide". ''Mineralogical Magazine'' (''Journal of the Mineralogical Society''), volume 32, issue 250, pages 545-557. is the chemical compound of iron, oxygen, ...
(FeO(OH), Fe(OH)
3), and is typically associated with the
corrosion
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...
of
refined iron
Pig iron, also known as crude iron, is an intermediate product of the iron industry in the production of steel which is obtained by smelting iron ore in a blast furnace. Pig iron has a high carbon content, typically 3.8–4.7%, along with sil ...
.
Given sufficient time, any iron mass, in the presence of water and oxygen, could eventually convert entirely to rust. Surface rust is commonly flaky and
friable
Friability ( ), the condition of being friable, describes the tendency of a solid substance to break into smaller pieces under duress or contact, especially by rubbing. The opposite of friable is indurate.
Substances that are designated hazardous, ...
, and provides no
passivational protection to the underlying iron, unlike the formation of
patina
Patina ( or ) is a thin layer that variously forms on the surface of copper, brass, bronze and similar metals and metal alloys (tarnish produced by oxidation or other chemical processes) or certain stones and wooden furniture (sheen produced b ...
on copper surfaces. ''Rusting'' is the common term for
corrosion
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...
of elemental iron and
its alloys such as
steel
Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant ty ...
. Many other
metal
A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ...
s undergo similar corrosion, but the resulting oxides are not commonly called "rust".
Several forms of rust are distinguishable both visually and by
spectroscopy
Spectroscopy is the field of study that measures and interprets the electromagnetic spectra that result from the interaction between electromagnetic radiation and matter as a function of the wavelength or frequency of the radiation. Matter wa ...
, and form under different circumstances. Other forms of rust include the result of reactions between iron and
chloride
The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride salts ...
in an environment deprived of oxygen.
Rebar
Rebar (short for reinforcing bar), known when massed as reinforcing steel or reinforcement steel, is a steel bar used as a Tension (physics), tension device in reinforced concrete and reinforced masonry structures to strengthen and aid the concr ...
used in underwater
concrete
Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most wi ...
pillars
A column or pillar in architecture and structural engineering is a structural element that transmits, through compression (physical), compression, the weight of the structure above to other structural elements below. In other words, a column i ...
, which generates
green rust
Green rust is a generic name for various green crystalline chemical compounds containing iron(II) and iron(III) cations, the hydroxide () anion, and another anion such as carbonate (), chloride (), or sulfate (), in a layered double hydroxide stru ...
, is an example. Although rusting is generally a negative aspect of iron, a particular form of rusting, known as ''stable rust'', causes the object to have a thin coating of rust over the top. If kept in low relative humidity, it makes the "stable" layer protective to the iron below, but not to the extent of other oxides such as
aluminium oxide on
aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
.
Chemical reactions
![RustyChainEdit1](https://upload.wikimedia.org/wikipedia/commons/5/52/RustyChainEdit1.jpg)
Rust is a general name for a complex of oxides and hydroxides of iron, which occur when iron or some alloys that contain iron are exposed to oxygen and moisture for a long period of time. Over time, the oxygen combines with the metal forming new compounds collectively called rust. Although rust may generally be termed as "oxidation", that term is much more general and describes a vast number of processes involving the loss of
electron
The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family,
and are generally thought to be elementary particles because they have no kn ...
s or increased oxidation state, as part of a
reaction
Reaction may refer to a process or to a response to an action, event, or exposure:
Physics and chemistry
*Chemical reaction
*Nuclear reaction
*Reaction (physics), as defined by Newton's third law
*Chain reaction (disambiguation).
Biology and me ...
. The best-known of these reactions involve
oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as wel ...
, hence the name "oxidation". The terms "rust" and "rusting" only mean oxidation of iron and its resulting products. Many other
oxidation reaction
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...
s exist which do not involve iron or produce rust. But only iron or alloys that contain iron can rust. However, other
metal
A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ...
s can corrode in similar ways.
The main catalyst for the rusting process is water. Iron or steel structures might appear to be solid, but water molecules can penetrate the microscopic
pits and cracks in any exposed metal. The hydrogen atoms present in water molecules can combine with other elements to form acids, which will eventually cause more metal to be exposed. If chloride ions are present, as is the case with saltwater, the corrosion is likely to occur more quickly. Meanwhile, the oxygen atoms combine with metallic atoms to form the destructive oxide compound. As the atoms combine, they weaken the metal, making the structure brittle and crumbly.
Oxidation of iron
When iron is in contact with water and oxygen, it rusts.
If
salt
Salt is a mineral composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of salts; salt in the form of a natural crystalline mineral is known as rock salt or halite. Salt is present in vast quantitie ...
is present, for example in
seawater
Seawater, or salt water, is water from a sea or ocean. On average, seawater in the world's oceans has a salinity of about 3.5% (35 g/L, 35 ppt, 600 mM). This means that every kilogram (roughly one liter by volume) of seawater has appro ...
or
salt spray
Salt is a mineral composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of salts; salt in the form of a natural crystalline mineral is known as rock salt or halite. Salt is present in vast quantitie ...
, the iron tends to rust more quickly, as a result of chemical reactions. Iron metal is relatively unaffected by pure water or by dry oxygen. As with other metals, like aluminium, a tightly adhering oxide coating, a
passivation layer, protects the bulk iron from further oxidation. The conversion of the passivating
ferrous oxide
Iron(II) oxide or ferrous oxide is the inorganic compound with the formula FeO. Its mineral form is known as wüstite. One of several iron oxides, it is a black-colored powder that is sometimes confused with rust, the latter of which consists of ...
layer to rust results from the combined action of two agents, usually oxygen and water.
Other degrading solutions are
sulfur dioxide
Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a toxic gas responsible for the odor of burnt matches. It is released naturally by volcanic activ ...
in water and
carbon dioxide
Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transpar ...
in water. Under these corrosive conditions,
iron hydroxide
Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of which ...
species are formed. Unlike ferrous oxides, the hydroxides do not adhere to the bulk metal. As they form and flake off from the surface, fresh iron is exposed, and the corrosion process continues until either all of the iron is consumed or all of the oxygen, water, carbon dioxide or sulfur dioxide in the system are removed or consumed.
When iron rusts, the oxides take up more volume than the original metal; this expansion can generate enormous forces, damaging structures made with iron. See ''
economic effect'' for more details.
Associated reactions
The rusting of iron is an electrochemical process that begins with the transfer of
electron
The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family,
and are generally thought to be elementary particles because they have no kn ...
s from iron to oxygen. The iron is the reducing agent (gives up electrons) while the oxygen is the oxidizing agent (gains electrons). The rate of corrosion is affected by water and accelerated by
electrolyte
An electrolyte is a medium containing ions that is electrically conducting through the movement of those ions, but not conducting electrons. This includes most soluble salts, acids, and bases dissolved in a polar solvent, such as water. Upon dis ...
s, as illustrated by the effects of
road salt
Sodium chloride , commonly known as salt (although sea salt also contains other chemical salts), is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. With molar masses of 22.99 and 35.45 g ...
on the corrosion of automobiles. The key reaction is the reduction of oxygen:
:O
2 + 4 + 2 → 4
Because it forms
hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. I ...
ion
An ion () is an atom or molecule with a net electrical charge.
The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...
s, this process is strongly affected by the presence of acid. Likewise, the corrosion of most metals by oxygen is accelerated at low
pH. Providing the electrons for the above reaction is the oxidation of iron that may be described as follows:
:Fe → Fe
2+ + 2
The following
redox reaction
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...
also occurs in the presence of water and is crucial to the formation of rust:
:4 Fe
2+ + O
2 → 4 Fe
3+ + 2 O
2−
In addition, the following multistep
acid–base reaction
An acid–base reaction is a chemical reaction that occurs between an acid and a base. It can be used to determine pH via titration. Several theoretical frameworks provide alternative conceptions of the reaction mechanisms and their applica ...
s affect the course of rust formation:
:Fe
2+ + 2 H
2O ⇌ Fe(OH)
2 + 2
:Fe
3+ + 3 H
2O ⇌ Fe(OH)
3 + 3
as do the following
dehydration
In physiology, dehydration is a lack of total body water, with an accompanying disruption of metabolic processes. It occurs when free water loss exceeds free water intake, usually due to exercise, disease, or high environmental temperature. Mil ...
equilibria:
:
Fe(OH)
2 ⇌ FeO +
:
Fe(OH)
3 ⇌ FeO(OH) +
:2 FeO(OH) ⇌ Fe
2O
3 +
From the above equations, it is also seen that the corrosion products are dictated by the availability of water and oxygen. With limited dissolved oxygen, iron(II)-containing materials are favoured, including
FeO
Iron(II) oxide or ferrous oxide is the inorganic compound with the formula FeO. Its mineral form is known as wüstite. One of several iron oxides, it is a black-colored powder that is sometimes confused with rust, the latter of which consists ...
and black
lodestone
Lodestones are naturally magnetized pieces of the mineral magnetite. They are naturally occurring magnets, which can attract iron. The property of magnetism was first discovered in antiquity through lodestones. Pieces of lodestone, suspen ...
or
magnetite
Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With the ...
(Fe
3O
4). High oxygen concentrations favour
ferric
In chemistry, iron(III) refers to the element iron in its +3 oxidation state. In ionic compounds (salts), such an atom may occur as a separate cation (positive ion) denoted by Fe3+.
The adjective ferric or the prefix ferri- is often used to spe ...
materials with the nominal formulae Fe(OH)
3−''x''O
. The nature of rust changes with time, reflecting the slow rates of the reactions of solids.
Furthermore, these complex processes are affected by the presence of other ions, such as
Ca2+, which serve as electrolytes which accelerate rust formation, or combine with the
hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. I ...
s and
oxide
An oxide () is a chemical compound that contains at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– (molecular) ion. with oxygen in the oxidation state of −2. Most of the E ...
s of iron to precipitate a variety of Ca, Fe, O, OH species.
The onset of rusting can also be detected in the laboratory with the use of
ferroxyl indicator solution
Ferroxyl indicator is a solution containing potassium hexacyanoferrate(III) and phenolphthalein. It turns blue in the presence of Fe2+ ions, and pink in the presence of hydroxide ions. It can be used to detect metal oxidation, and is often used to ...
. The solution detects both Fe
2+ ions and hydroxyl ions. Formation of Fe
2+ ions and hydroxyl ions are indicated by blue and pink patches respectively.
Prevention
![Uithuizermeeden de Boer 02](https://upload.wikimedia.org/wikipedia/commons/3/3e/Uithuizermeeden_de_Boer_02.JPG)
Because of the widespread use and importance of iron and steel products, the prevention or slowing of rust is the basis of major economic activities in a number of specialized technologies. A brief overview of methods is presented here; for detailed coverage, see the cross-referenced articles.
Rust is
permeable
Permeability, permeable, and semipermeable may refer to:
Chemistry
*Semipermeable membrane, a membrane which will allow certain molecules or ions to pass through it by diffusion
*Vascular permeability, the movement of fluids and molecules betwe ...
to air and water, therefore the interior metallic iron beneath a rust layer continues to corrode. Rust prevention thus requires coatings that preclude rust formation.
Rust-resistant alloys
Stainless steel forms a
passivation layer of
chromium(III) oxide
Chromium(III) oxide (or chromia) is an inorganic compound with the formula . It is one of the principal oxides of chromium and is used as a pigment. In nature, it occurs as the rare mineral eskolaite.
Structure and properties
has the corundum ...
. Similar passivation behavior occurs with
magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
,
titanium
Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...
,
zinc
Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
,
zinc oxide
Zinc oxide is an inorganic compound with the formula . It is a white powder that is insoluble in water. ZnO is used as an additive in numerous materials and products including cosmetics, food supplements, rubbers, plastics, ceramics, glass, cemen ...
s,
aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
,
polyaniline
Polyaniline (PANI) is a conducting polymer and organic semiconductor of the semi-flexible rod polymer family. The compound has been of interest since the 1980s because of its electrical conductivity and mechanical properties. Polyaniline is one of ...
, and other electroactive conductive polymers.
![Rust-AH-2022](https://upload.wikimedia.org/wikipedia/commons/3/36/Rust-AH-2022.jpg)
Special "
weathering steel
Weathering steel, often referred to by the genericised trademark COR-TEN steel and sometimes written without the hyphen as corten steel, is a group of steel alloys which were developed to eliminate the need for painting, and form a stable rus ...
" alloys such as Cor-Ten rust at a much slower rate than normal, because the rust adheres to the surface of the metal in a protective layer. Designs using this material must include measures that avoid worst-case exposures since the material still continues to rust slowly even under near-ideal conditions.
Galvanization
Galvanization consists of an application on the object to be protected of a layer of metallic
zinc
Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
by either
hot-dip galvanizing
Hot-dip galvanization is a form of galvanization. It is the process of coating iron and steel with zinc, which alloys with the surface of the base metal when immersing the metal in a bath of molten zinc at a temperature of around . When expose ...
or
electroplating
Electroplating, also known as electrochemical deposition or electrodeposition, is a process for producing a metal coating on a solid substrate through the reduction of cations of that metal by means of a direct electric current. The part to be ...
. Zinc is traditionally used because it is cheap, adheres well to steel, and provides
cathodic protection
Cathodic protection (CP; ) is a technique used to control the corrosion of a metal surface by making it the cathode of an electrochemical cell. A simple method of protection connects the metal to be protected to a more easily corroded "sacrific ...
to the steel surface in case of damage of the zinc layer. In more corrosive environments (such as salt water),
cadmium
Cadmium is a chemical element with the symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12, zinc and mercury. Like zinc, it demonstrates oxidation state +2 in most of ...
plating is preferred. Galvanization often fails at seams, holes, and joints where there are gaps in the coating. In these cases, the coating still provides some partial cathodic protection to iron, by acting as a
galvanic anode
A galvanic anode, or sacrificial anode, is the main component of a galvanic cathodic protection system used to protect buried or submerged metal structures from corrosion.
They are made from a metal alloy with a more "active" voltage (more n ...
and corroding itself instead of the underlying protected metal. The protective zinc layer is consumed by this action, and thus galvanization provides protection only for a limited period of time.
More modern coatings add aluminium to the coating as ''zinc-alume''; aluminium will migrate to cover scratches and thus provide protection for a longer period. These approaches rely on the aluminium and zinc oxides protecting a once-scratched surface, rather than oxidizing as a
sacrificial anode
A galvanic anode, or sacrificial anode, is the main component of a galvanic cathodic protection system used to protect buried or submerged metal structures from corrosion.
They are made from a metal alloy with a more "active" voltage (more n ...
as in traditional galvanized coatings. In some cases, such as very aggressive environments or long design life, both zinc and a
coating
A coating is a covering that is applied to the surface of an object, usually referred to as the Substrate (materials science), substrate. The purpose of applying the coating may be decorative, functional, or both. Coatings may be applied as liquid ...
are applied to provide enhanced corrosion protection.
Typical galvanization of steel products that are to be subjected to normal day-to-day weathering in an outside environment consists of a hot-dipped 85
µm zinc coating. Under normal weather conditions, this will deteriorate at a rate of 1 µm per year, giving approximately 85 years of protection.
Cathodic protection
Cathodic protection is a technique used to inhibit corrosion on buried or immersed structures by supplying an electrical charge that suppresses the electrochemical reaction. If correctly applied, corrosion can be stopped completely. In its simplest form, it is achieved by attaching a sacrificial anode, thereby making the iron or steel the cathode in the cell formed. The sacrificial anode must be made from something with a more negative
electrode potential
In electrochemistry, electrode potential is the electromotive force of a galvanic cell built from a standard reference electrode and another electrode to be characterized. By convention, the reference electrode is the standard hydrogen electrode (S ...
than the iron or steel, commonly zinc, aluminium, or magnesium. The sacrificial anode will eventually corrode away, ceasing its protective action unless it is replaced in a timely manner.
Cathodic protection can also be provided by using an applied electrical current. This would then be known as ICCP Impressed Current Cathodic Protection.
Coatings and painting
Rust formation can be controlled with coatings, such as
paint
Paint is any pigmented liquid, liquefiable, or solid mastic composition that, after application to a substrate in a thin layer, converts to a solid film. It is most commonly used to protect, color, or provide texture. Paint can be made in many ...
,
lacquer
Lacquer is a type of hard and usually shiny coating or finish applied to materials such as wood or metal. It is most often made from resin extracted from trees and waxes and has been in use since antiquity.
Asian lacquerware, which may be ca ...
,
varnish
Varnish is a clear transparent hard protective coating or film. It is not a stain. It usually has a yellowish shade from the manufacturing process and materials used, but it may also be pigmented as desired, and is sold commercially in various ...
, or wax tapes that isolate the iron from the environment. Large structures with enclosed box sections, such as ships and modern automobiles, often have a wax-based product (technically a "slushing oil") injected into these sections. Such treatments usually also contain rust inhibitors. Covering steel with concrete can provide some protection to steel because of the
alkaline
In chemistry, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the saltwort) is a base (chemistry), basic, ionic compound, ionic salt (chemistry), salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as ...
pH environment at the steel–concrete interface. However, rusting of steel in concrete can still be a problem, as expanding rust can fracture concrete from within.
As a closely related example, iron clamps were used to join
marble
Marble is a metamorphic rock composed of recrystallized carbonate minerals, most commonly calcite or Dolomite (mineral), dolomite. Marble is typically not Foliation (geology), foliated (layered), although there are exceptions. In geology, the ...
blocks during a restoration attempt of the
Parthenon
The Parthenon (; grc, Παρθενών, , ; ell, Παρθενώνας, , ) is a former temple on the Athenian Acropolis, Greece, that was dedicated to the goddess Athena during the fifth century BC. Its decorative sculptures are considere ...
in
Athens, Greece
Athens ( ; el, Αθήνα, Athína ; grc, Ἀθῆναι, Athênai (pl.) ) is both the capital and largest city of Greece. With a population close to four million, it is also the seventh largest city in the European Union. Athens dominates ...
, in 1898, but caused extensive damage to the marble by the rusting and swelling of unprotected iron. The ancient Greek builders had used a similar fastening system for the marble blocks during construction, however, they also poured molten
lead
Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...
over the iron joints for protection from seismic shocks as well as from corrosion. This method was successful for the 2500-year-old structure, but in less than a century the crude repairs were in imminent danger of collapse.
![Rust and dirt](https://upload.wikimedia.org/wikipedia/commons/b/bb/Rust_and_dirt.jpg)
When only temporary protection is needed for storage or transport, a thin layer of oil, grease or a special mixture such as
Cosmoline
Cosmoline is the genericized trademark for a common class of brown, wax-like petroleum-based corrosion inhibitors, typically conforming to United States Military Standard MIL-C-11796C Class 3. They are viscous when freshly applied, have a slight ...
can be applied to an iron surface. Such treatments are extensively used when "
mothballing" a steel ship, automobile, or other equipment for long-term storage.
Special anti-seize lubricant mixtures are available and are applied to metallic threads and other precision machined surfaces to protect them from rust. These compounds usually contain grease mixed with copper, zinc, or aluminium powder, and other proprietary ingredients.
Bluing
Bluing is a technique that can provide limited resistance to rusting for small steel items, such as firearms; for it to be successful, a water-displacing oil is rubbed onto the blued steel and other steel.
Inhibitors
Corrosion inhibitors, such as gas-phase or volatile inhibitors, can be used to prevent corrosion inside sealed systems. They are not effective when air circulation disperses them, and brings in fresh oxygen and moisture.
Humidity control
Rust can be avoided by controlling the moisture in the atmosphere.
An example of this is the use of
silica gel
Silica gel is an amorphous and porous form of silicon dioxide (silica), consisting of an irregular tridimensional framework of alternating silicon and oxygen atoms with nanometer-scale voids and pores. The voids may contain water or some other l ...
packets to control humidity in equipment shipped by sea.
Treatment
Rust removal from small iron or steel objects by
electrolysis
In chemistry and manufacturing, electrolysis is a technique that uses direct electric current (DC) to drive an otherwise non-spontaneous chemical reaction. Electrolysis is commercially important as a stage in the separation of elements from n ...
can be done in a home workshop using simple materials such as a plastic bucket filled with an electrolyte consisting of
washing soda
Sodium carbonate, , (also known as washing soda, soda ash and soda crystals) is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield moderately alkaline solutions ...
dissolved in
tap water
Tap water (also known as faucet water, running water, or municipal water) is water supplied through a tap, a water dispenser valve. In many countries, tap water usually has the quality of drinking water. Tap water is commonly used for drinking, ...
, a length of
rebar
Rebar (short for reinforcing bar), known when massed as reinforcing steel or reinforcement steel, is a steel bar used as a Tension (physics), tension device in reinforced concrete and reinforced masonry structures to strengthen and aid the concr ...
suspended vertically in the solution to act as an
anode
An anode is an electrode of a polarized electrical device through which conventional current enters the device. This contrasts with a cathode, an electrode of the device through which conventional current leaves the device. A common mnemonic is ...
, another laid across the top of the bucket to act as a support for suspending the object,
baling wire
Baling wire, otherwise known as bale wire, farm wire, haywire or soft wire, is a type of wire used in agriculture and industry for many uses such as mending fences or manually binding rectangular Hay#Small bales, bales of hay, straw bale, straw, ...
to suspend the object in the solution from the horizontal rebar, and a
battery charger
A battery charger, recharger, or simply charger is a device that stores energy in a battery by running an electric current through it. The charging protocol (how much voltage or current for how long, and what to do when charging is complete) depen ...
as a power source in which the positive terminal is clamped to the anode and the negative terminal is clamped to the object to be treated which becomes the
cathode
A cathode is the electrode from which a conventional current leaves a polarized electrical device. This definition can be recalled by using the mnemonic ''CCD'' for ''Cathode Current Departs''. A conventional current describes the direction in whi ...
.
Rust may be treated with commercial products known as
rust converter
Rust converters are chemical solutions or primers that can be applied directly to an iron or iron alloy surface to convert iron oxides (rust) into a protective chemical barrier. These compounds interact with iron oxides, especially iron(III) oxi ...
which contain
tannic acid
Tannic acid is a specific form of tannin, a type of polyphenol. Its weak acidity ( pKa around 6) is due to the numerous phenol groups in the structure. The chemical formula for commercial tannic acid is often given as C76H52O46, which correspon ...
or
phosphoric acid
Phosphoric acid (orthophosphoric acid, monophosphoric acid or phosphoric(V) acid) is a colorless, odorless phosphorus-containing solid, and inorganic compound with the chemical formula . It is commonly encountered as an 85% aqueous solution, w ...
which combines with rust; removed with organic acids like
citric acid
Citric acid is an organic compound with the chemical formula HOC(CO2H)(CH2CO2H)2. It is a colorless weak organic acid. It occurs naturally in citrus fruits. In biochemistry, it is an intermediate in the citric acid cycle, which occurs in t ...
and
vinegar
Vinegar is an aqueous solution of acetic acid and trace compounds that may include flavorings. Vinegar typically contains 5–8% acetic acid by volume. Usually, the acetic acid is produced by a double fermentation, converting simple sugars to et ...
or the stronger
hydrochloric acid
Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid
Acid strength is the tendency of an acid, symbol ...
; or removed with chelating agents as in some commercial formulations or even a solution of
molasses
Molasses () is a viscous substance resulting from refining sugarcane or sugar beets into sugar. Molasses varies in the amount of sugar, method of extraction and age of the plant. Sugarcane molasses is primarily used to sweeten and flavour foods ...
.
Economic effect
![Rust wedge](https://upload.wikimedia.org/wikipedia/commons/8/80/Rust_wedge.jpg)
Rust is associated with the degradation of iron-based tools and structures. As rust has a much higher volume than the originating mass of iron, its buildup can also cause failure by forcing apart adjacent parts — a phenomenon sometimes known as "rust packing". It was the cause of the collapse of the
Mianus river bridge in 1983, when the bearings rusted internally and pushed one corner of the road slab off its support.
Rust was an important factor in the
Silver Bridge
The Silver Bridge was an eyebar-chain suspension bridge built in 1928 and named for the color of its aluminum paint. The bridge carried U.S. Route 35 over the Ohio River, connecting Point Pleasant, West Virginia, and Gallipolis, Ohio.
On Dece ...
disaster of 1967 in
West Virginia
West Virginia is a state in the Appalachian, Mid-Atlantic and Southeastern regions of the United States.The Census Bureau and the Association of American Geographers classify West Virginia as part of the Southern United States while the Bur ...
, when a steel
suspension bridge
A suspension bridge is a type of bridge in which the deck (bridge), deck is hung below suspension wire rope, cables on vertical suspenders. The first modern examples of this type of bridge were built in the early 1800s. Simple suspension bridg ...
collapsed in less than a minute, killing 46 drivers and passengers on the bridge at the time. The
Kinzua Bridge
The Kinzua Bridge or the Kinzua Viaduct (, ) was a railroad trestle that spanned Kinzua Creek in McKean County in the U.S. state of Pennsylvania. The bridge was tall and long. Most of its structure collapsed during a tornado in July 2003.
Bi ...
in
Pennsylvania
Pennsylvania (; ( Pennsylvania Dutch: )), officially the Commonwealth of Pennsylvania, is a state spanning the Mid-Atlantic, Northeastern, Appalachian, and Great Lakes regions of the United States. It borders Delaware to its southeast, ...
was blown down by a
tornado
A tornado is a violently rotating column of air that is in contact with both the surface of the Earth and a cumulonimbus cloud or, in rare cases, the base of a cumulus cloud. It is often referred to as a twister, whirlwind or cyclone, altho ...
in 2003, largely because the central base bolts holding the structure to the ground had rusted away, leaving the bridge anchored by gravity alone.
Reinforced concrete
Reinforced concrete (RC), also called reinforced cement concrete (RCC) and ferroconcrete, is a composite material in which concrete's relatively low tensile strength and ductility are compensated for by the inclusion of reinforcement having hig ...
is also vulnerable to rust damage. Internal pressure caused by expanding corrosion of concrete-covered steel and iron can cause the concrete to
spall
Spall are fragments of a material that are broken off a larger solid body. It can be produced by a variety of mechanisms, including as a result of projectile impact, corrosion, weathering, cavitation, or excessive rolling pressure (as in a ball ...
, creating severe structural problems. It is one of the most common failure modes of reinforced concrete
bridge
A bridge is a structure built to span a physical obstacle (such as a body of water, valley, road, or rail) without blocking the way underneath. It is constructed for the purpose of providing passage over the obstacle, which is usually somethi ...
s and buildings.
File:Silver Bridge collapsed, Ohio side.jpg, The collapsed Silver Bridge
The Silver Bridge was an eyebar-chain suspension bridge built in 1928 and named for the color of its aluminum paint. The bridge carried U.S. Route 35 over the Ohio River, connecting Point Pleasant, West Virginia, and Gallipolis, Ohio.
On Dece ...
, as seen from the Ohio
Ohio () is a state in the Midwestern region of the United States. Of the fifty U.S. states, it is the 34th-largest by area, and with a population of nearly 11.8 million, is the seventh-most populous and tenth-most densely populated. The sta ...
side
File:Collapsed Kinzua Bridge.jpg, The Kinzua Bridge
The Kinzua Bridge or the Kinzua Viaduct (, ) was a railroad trestle that spanned Kinzua Creek in McKean County in the U.S. state of Pennsylvania. The bridge was tall and long. Most of its structure collapsed during a tornado in July 2003.
Bi ...
after it collapsed
File:Nandu River Iron Bridge corrosion - 03.jpg, Rusted and pitted struts of the 70-year-old Nandu River Iron Bridge
The Nandu River Iron Bridge (), also known as the Devil's Iron Bridge, Old Iron Bridge, and originally the Lu Palace Bridge (), is a partially collapsed, steel truss bridge over the Nandu River, in the north of Hainan Province, China. Opened to ...
File:Qew bruecke nf beton kaputt 23 von 46.jpg, Rusting rebar
Rebar (short for reinforcing bar), known when massed as reinforcing steel or reinforcement steel, is a steel bar used as a Tension (physics), tension device in reinforced concrete and reinforced masonry structures to strengthen and aid the concr ...
has expanded and spall
Spall are fragments of a material that are broken off a larger solid body. It can be produced by a variety of mechanisms, including as a result of projectile impact, corrosion, weathering, cavitation, or excessive rolling pressure (as in a ball ...
ed concrete off the surface of this reinforced concrete
Reinforced concrete (RC), also called reinforced cement concrete (RCC) and ferroconcrete, is a composite material in which concrete's relatively low tensile strength and ductility are compensated for by the inclusion of reinforcement having hig ...
support
Cultural symbolism
Rust is a commonly used
metaphor
A metaphor is a figure of speech that, for rhetorical effect, directly refers to one thing by mentioning another. It may provide (or obscure) clarity or identify hidden similarities between two different ideas. Metaphors are often compared wit ...
for slow decay due to neglect, since it gradually converts robust iron and steel metal into a soft crumbling powder. A wide section of the industrialized
American Midwest
The Midwestern United States, also referred to as the Midwest or the American Midwest, is one of four census regions of the United States Census Bureau (also known as "Region 2"). It occupies the northern central part of the United States. I ...
and
American Northeast
The Northeastern United States, also referred to as the Northeast, the East Coast, or the American Northeast, is a geographic region of the United States. It is located on the Atlantic coast of North America, with Canada to its north, the Southe ...
, once dominated by
steel foundries, the
automotive industry
The automotive industry comprises a wide range of company, companies and organizations involved in the design, Business development, development, manufacturing, marketing, and selling of motor vehicles. It is one of the world's largest industry ...
, and other manufacturers, has experienced harsh economic cutbacks that have caused the region to be dubbed the "
Rust Belt
The Rust Belt is a region of the United States that experienced industrial decline starting in the 1950s. The U.S. manufacturing sector as a percentage of the U.S. GDP peaked in 1953 and has been in decline since, impacting certain regions and ...
".
In music, literature, and art, rust is associated with images of faded glory, neglect, decay, and ruin.
See also
*
Corrosion engineering
Corrosion engineering is an engineering specialty that applies scientific, technical, engineering skills, and knowledge of natural laws and physical resources to design and implement materials, structures, devices, systems, and procedures to mana ...
References
Further reading
*
Waldman, J. (2015): ''Rust - the longest war.'' Simon & Schuster, New York.
*
*
* Corrosion - 2nd Edition (elsevier.com) Volume 1and 2; Editor: L L Shreir
{{Authority control
Corrosion
Iron