The room-temperature densification method was developed for Li
2MoO
4 ceramic
A ceramic is any of the various hard, brittle, heat-resistant and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcelai ...
s and is based on the
water-solubility of
Li2MoO4. It can be used for the fabrication of Li
2MoO
4 ceramics instead of conventional thermal
sintering
Clinker nodules produced by sintering
Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction.
Sintering happens as part of a manufacturing ...
. The method utilizes a small amount of aqueous phase formed by moistening the Li
2MoO
4 powder. The densification occurs during sample pressing as the solution incorporates the pores between the powder particles and
recrystallizes. The contact points of the
particles
In the physical sciences, a particle (or corpuscule in older texts) is a small localized object which can be described by several physical or chemical properties, such as volume, density, or mass.
They vary greatly in size or quantity, from ...
provide a high pressure zone, where
solubility
In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution.
The extent of the solub ...
is increased, whereas the pores act as a suitable place for the
precipitation
In meteorology, precipitation is any product of the condensation of atmospheric water vapor that falls under gravitational pull from clouds. The main forms of precipitation include drizzle, rain, sleet, snow, ice pellets, graupel and hai ...
of the solution. Any residual water is removed by post-processing typically at 120 °C. The method is suitable also for Li
2MoO
4 composite ceramics with up to 30 volume-% of filler material, enabling the optimization of the
dielectric
In electromagnetism, a dielectric (or dielectric medium) is an electrical insulator that can be polarised by an applied electric field. When a dielectric material is placed in an electric field, electric charges do not flow through the m ...
properties.
References
{{DEFAULTSORT:Room-temperature densification method
Ceramic engineering
Ceramic materials
Materials science