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Robert Culbertson West Jr. (March 18, 1928 – October 12, 2022) was an American chemist. West was an E. G. Rochow Professor of Chemistry Emeritus at the
University of Wisconsin–Madison A university () is an educational institution, institution of higher education, higher (or Tertiary education, tertiary) education and research which awards academic degrees in several Discipline (academia), academic disciplines. Universities ty ...
; Director of the Organosilicon Research Center, University of Wisconsin–Madison 1999–20??; President, Silatronix, Inc. (2007–20??); Distinguished Professor,
Yonsei University Yonsei University (; ) is a private research university in Seoul, South Korea. As a member of the "SKY" universities, Yonsei University is deemed one of the three most prestigious institutions in the country. It is particularly respected in the ...
, 2007–2011. He died in Madison, Wisconsin on October 12, 2022, at the age of 94.


Education

West received his Bachelor of Arts in Chemistry from
Cornell University Cornell University is a private statutory land-grant research university based in Ithaca, New York. It is a member of the Ivy League. Founded in 1865 by Ezra Cornell and Andrew Dickson White, Cornell was founded with the intention to teach an ...
in 1950, proceeding on to
Harvard University Harvard University is a private Ivy League research university in Cambridge, Massachusetts. Founded in 1636 as Harvard College and named for its first benefactor, the Puritan clergyman John Harvard, it is the oldest institution of higher le ...
where he received his Master of Arts in 1952 and Ph.D. in 1954. At Cornell, he was a member of the
Quill and Dagger Quill and Dagger is a senior honor society at Cornell University. It is often recognized as one of the most prominent societies of its type, along with Skull and Bones and Scroll and Key at Yale University. In 1929, ''The New York Times'' stated t ...
society.


Notable work

West was a chemist best known for his groundbreaking research in
silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic tab ...
chemistry as well as for his work with oxocarbons and
organolithium compound In organometallic chemistry, organolithium reagents are chemical compounds that contain carbon–lithium (C–Li) bonds. These reagents are important in organic synthesis, and are frequently used to transfer the organic group or the lithium atom ...
s. In 2004, West was listed as one of the most cited scientists during the period 1981-1999, according to a citation survey by Thomson ISI. West's most well-known discovery was the synthesis of the first ever silicon-silicon double bond in 1981, a feat which broke the so-called "double-bond rule" (which stated that main group elements below row two of the periodic table could not form double bonds). West later discovered the first example of a stable
silylene Silylene is a chemical compound with the formula SiH2. It is the silicon analog of methylene, the simplest carbene. Silylene is a stable molecule as a gas but rapidly reacts in a bimolecular manner when condensed. Unlike carbenes, which can exis ...
, a form of divalent silicon, acting as the silicon analog to the now catalytically important
carbene In organic chemistry, a carbene is a molecule containing a neutral carbon atom with a valence of two and two unshared valence electrons. The general formula is or where the R represents substituents or hydrogen atoms. The term "carbene" ma ...
. West also developed a new model for understanding rotations in
polymers A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic an ...
. West's numerous other discoveries include a siloxane-based
electrolyte An electrolyte is a medium containing ions that is electrically conducting through the movement of those ions, but not conducting electrons. This includes most soluble salts, acids, and bases dissolved in a polar solvent, such as water. Upon dis ...
which has made possible revolutionary rechargeable implantable batteries for biomedical applications including the treatment of spinal injuries and nerve damage. His later interests included the synthesis of silicon-containing anticancer drugs, and the study of silicon and germanium compounds by
muon A muon ( ; from the Greek letter mu (μ) used to represent it) is an elementary particle similar to the electron, with an electric charge of −1 '' e'' and a spin of , but with a much greater mass. It is classified as a lepton. As wi ...
resonance spectroscopy.


Other interests

West was an instrument-rated pilot with over 2500 hours as pilot-in-command. He was a
mountaineer Mountaineering or alpinism, is a set of outdoor activities that involves ascending tall mountains. Mountaineering-related activities include traditional outdoor climbing, skiing, and traversing via ferratas. Indoor climbing, sport climbing, an ...
, with over 50 first ascents in the mountains of
British Columbia British Columbia (commonly abbreviated as BC) is the westernmost province of Canada, situated between the Pacific Ocean and the Rocky Mountains. It has a diverse geography, with rugged landscapes that include rocky coastlines, sandy beaches, ...
. He was known for his eccentric lifestyle, liberal political views, and activism for women's reproductive rights both in the US and internationally. In 1972, along with
Anne Nicol Gaylor Anne Nicol Gaylor (November 25, 1926 – June 14, 2015) was an American atheism, atheist and reproductive rights advocate. She co-founded the Freedom from Religion Foundation and an abortion fund for Wisconsin women. She wrote the book ''Abortio ...
, he co-founded the Women's Medical Fund to help
Wisconsin Wisconsin () is a state in the upper Midwestern United States. Wisconsin is the 25th-largest state by total area and the 20th-most populous. It is bordered by Minnesota to the west, Iowa to the southwest, Illinois to the south, Lake M ...
women pay for
abortion Abortion is the termination of a pregnancy by removal or expulsion of an embryo or fetus. An abortion that occurs without intervention is known as a miscarriage or "spontaneous abortion"; these occur in approximately 30% to 40% of pregn ...
s. His international interests led to extensive collaborative research with chemistry departments in major universities in countries including Austria, Brazil, Canada, Germany, Hungary, Israel, Japan, Korea, Lebanon, Mexico, Norway and Russia. Many of his over 600 publications were in collaboration with scientists in countries outside the USA.


References


External links


University of Wisconsin faculty biography

New battery technology helps stimulate nerves
University of Wisconsin news {{DEFAULTSORT:West, Robert 1928 births 2022 deaths 21st-century American chemists Cornell University alumni Harvard University alumni University of Wisconsin–Madison faculty People from Glen Ridge, New Jersey