The Río Tinto (, ''
red
Red is the color at the long wavelength end of the visible spectrum of light, next to orange and opposite violet. It has a dominant wavelength of approximately 625–740 nanometres. It is a primary color in the RGB color model and a secondar ...
river'' or Tinto River) is a
river
A river is a natural flowing watercourse, usually freshwater, flowing towards an ocean, sea, lake or another river. In some cases, a river flows into the ground and becomes dry at the end of its course without reaching another body of wate ...
in southwestern
Spain
, image_flag = Bandera de España.svg
, image_coat = Escudo de España (mazonado).svg
, national_motto = ''Plus ultra'' (Latin)(English: "Further Beyond")
, national_anthem = (English: "Royal March")
, i ...
that rises in the
Sierra Morena
The Sierra Morena is one of the main systems of mountain ranges in Spain. It stretches for 450 kilometres from east to west across the south of the Iberian Peninsula, forming the southern border of the ''Meseta Central'' plateau and providi ...
mountains of
Andalusia
Andalusia (, ; es, Andalucía ) is the southernmost Autonomous communities of Spain, autonomous community in Peninsular Spain. It is the most populous and the second-largest autonomous community in the country. It is officially recognised as a ...
. It flows generally south-southwest, reaching the
Gulf of Cádiz
The Gulf of Cádiz ( es, Golfo de Cádiz, pt, Golfo de Cádis) is the arm of the Atlantic Ocean between Cabo de Santa Maria, the southernmost point of mainland Portugal and Cape Trafalgar at the western end of the Strait of Gibraltar. Two maj ...
at
Huelva
Huelva (, ) is a city in southwestern Spain, the capital of the province of Huelva in the autonomous community of Andalusia. It is between two short rias though has an outlying spur including nature reserve on the Gulf of Cádiz coast. The rias ...
. The Rio Tinto river has a unique red and orange colour derived from its chemical makeup that is extremely acidic and with very high levels of
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
and
heavy metals
upright=1.2, Crystals of osmium, a heavy metal nearly twice as dense as lead">lead.html" ;"title="osmium, a heavy metal nearly twice as dense as lead">osmium, a heavy metal nearly twice as dense as lead
Heavy metals are generally defined as ...
.
The river maintains its colour for an approximate length of 50 kilometres.
After the 50 kilometre mark, the chemistry that makes the Rio Tinto river so unique appears to slowly decline, as does the odd colouring. The location where the chemistry of the river is altered is near a town called
Niebla.
The river's chemistry begins to significantly change following the town of Niebla owing to the fact that the Rio Tinto blends itself with other streams that are connected to the
Atlantic Ocean
The Atlantic Ocean is the second-largest of the world's five oceans, with an area of about . It covers approximately 20% of Earth's surface and about 29% of its water surface area. It is known to separate the " Old World" of Africa, Europe ...
.
The river is approximately long and is located within the
Iberian Pyrite Belt
The Iberian Pyrite Belt is a vast geographical area with particular geological features that stretches along much of the south of the Iberian Peninsula, from Portugal to Spain. It is about 250 km long and 30–50 km wide, running northwe ...
.
This area has large amounts of
ore
Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 April 2 ...
and
sulfide
Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds lar ...
deposits.
The Rio Tinto area has been the source of approximately 5,000 years of
ore
Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 April 2 ...
mining
Mining is the extraction of valuable minerals or other geological materials from the Earth, usually from an ore body, lode, vein, seam, reef, or placer deposit. The exploitation of these deposits for raw material is based on the economic via ...
,
including
copper
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
,
silver
Silver is a chemical element with the Symbol (chemistry), symbol Ag (from the Latin ', derived from the Proto-Indo-European wikt:Reconstruction:Proto-Indo-European/h₂erǵ-, ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, whi ...
,
gold
Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile met ...
, and other minerals,
[
] extracted as far as 20 kilometres from the river shores.
As a possible result of the mining, the Río Tinto is notable for being very
acid
In computer science, ACID ( atomicity, consistency, isolation, durability) is a set of properties of database transactions intended to guarantee data validity despite errors, power failures, and other mishaps. In the context of databases, a sequ ...
ic (
pH 2) and its deep reddish hue is due to
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
dissolved in the water.
Acid mine drainage
Acid mine drainage, acid and metalliferous drainage (AMD), or acid rock drainage (ARD) is the outflow of acidic water from metal mines or coal mines.
Acid rock drainage occurs naturally within some environments as part of the rock weathering ...
from the mines leads to severe
environmental
A biophysical environment is a biotic and abiotic surrounding of an organism or population, and consequently includes the factors that have an influence in their survival, development, and evolution. A biophysical environment can vary in scale f ...
problems because the acidity (low pH) dissolves
heavy metals into the water. It is not clear how much acid drainage has come from natural processes and how much has come from mining. There are severe environmental concerns over the pollution in the river.
Although the river represents a harsh environment for life, some
microorganism
A microorganism, or microbe,, ''mikros'', "small") and ''organism'' from the el, ὀργανισμός, ''organismós'', "organism"). It is usually written as a single word but is sometimes hyphenated (''micro-organism''), especially in olde ...
s classified as
extremophile
An extremophile (from Latin ' meaning "extreme" and Greek ' () meaning "love") is an organism that is able to live (or in some cases thrive) in extreme environments, i.e. environments that make survival challenging such as due to extreme temper ...
s do thrive in these conditions. Such life forms include certain species of
bacteria
Bacteria (; singular: bacterium) are ubiquitous, mostly free-living organisms often consisting of one biological cell. They constitute a large domain of prokaryotic microorganisms. Typically a few micrometres in length, bacteria were among ...
,
algae
Algae (; singular alga ) is an informal term for a large and diverse group of photosynthetic eukaryotic organisms. It is a polyphyletic grouping that includes species from multiple distinct clades. Included organisms range from unicellular mic ...
and
heterotroph
A heterotroph (; ) is an organism that cannot produce its own food, instead taking nutrition from other sources of organic carbon, mainly plant or animal matter. In the food chain, heterotrophs are primary, secondary and tertiary consumers, but ...
s.
History
The
ore
Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 April 2 ...
body was deposited during the
Carboniferous
The Carboniferous ( ) is a geologic period and system of the Paleozoic that spans 60 million years from the end of the Devonian Period million years ago ( Mya), to the beginning of the Permian Period, million years ago. The name ''Carbonifero ...
period (300–350
Ma) by
hydrothermal
Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
activities on the sea floor. The history of
mining
Mining is the extraction of valuable minerals or other geological materials from the Earth, usually from an ore body, lode, vein, seam, reef, or placer deposit. The exploitation of these deposits for raw material is based on the economic via ...
in the Rio Tinto area traces back to the
Tartessans and the
Iberians
The Iberians ( la, Hibērī, from el, Ἴβηρες, ''Iberes'') were an ancient people settled in the eastern and southern coasts of the Iberian peninsula, at least from the 6th century BC. They are described in Greek and Roman sources (among ...
starting mining in 3000 BC, followed by the
Phoenicia
Phoenicia () was an ancient thalassocratic civilization originating in the Levant region of the eastern Mediterranean, primarily located in modern Lebanon. The territory of the Phoenician city-states extended and shrank throughout their histor ...
ns,
Greeks
The Greeks or Hellenes (; el, Έλληνες, ''Éllines'' ) are an ethnic group and nation indigenous to the Eastern Mediterranean and the Black Sea regions, namely Greece, Cyprus, Albania, Italy, Turkey, Egypt, and, to a lesser extent, oth ...
,
Romans
Roman or Romans most often refers to:
*Rome, the capital city of Italy
*Ancient Rome, Roman civilization from 8th century BC to 5th century AD
*Roman people, the people of ancient Rome
*''Epistle to the Romans'', shortened to ''Romans'', a letter ...
,
Visigoths
The Visigoths (; la, Visigothi, Wisigothi, Vesi, Visi, Wesi, Wisi) were an early Germanic people who, along with the Ostrogoths, constituted the two major political entities of the Goths within the Roman Empire in late antiquity, or what is ...
, and
Moors
The term Moor, derived from the ancient Mauri, is an exonym first used by Christian Europeans to designate the Muslim inhabitants of the Maghreb, the Iberian Peninsula, Sicily and Malta during the Middle Ages.
Moors are not a distinct or ...
. The Rio Tinto region has been the source of approximately 5,000 years of
ore
Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 April 2 ...
extraction,
and
chemical refinement primarily for
copper
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
,
silver
Silver is a chemical element with the Symbol (chemistry), symbol Ag (from the Latin ', derived from the Proto-Indo-European wikt:Reconstruction:Proto-Indo-European/h₂erǵ-, ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, whi ...
and
gold
Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile met ...
, and later for
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
,
manganese
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...
and other minerals.
This long standing mining activity has vastly modified the topography of the region.
After a period of abandonment and disuse, the mines were rediscovered in 1556 and the Spanish government began operating them once again in 1724.
In the 19th century, companies from the
United Kingdom
The United Kingdom of Great Britain and Northern Ireland, commonly known as the United Kingdom (UK) or Britain, is a country in Europe, off the north-western coast of the continental mainland. It comprises England, Scotland, Wales and North ...
started large-scale mining operations. In 1873, the
Rio Tinto Company
Rio Tinto Group is an Anglo-Australian multinational company that is the world's second-largest metals and mining corporation (behind BHP). The company was founded in 1873 when of a group of investors purchased a mine complex on the Rio Tinto, ...
was formed to operate the mines. Production declined after the peak of production in 1930, and it ended in 1986 for copper mining and in 1996 for
silver
Silver is a chemical element with the Symbol (chemistry), symbol Ag (from the Latin ', derived from the Proto-Indo-European wikt:Reconstruction:Proto-Indo-European/h₂erǵ-, ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, whi ...
and
gold
Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile met ...
mining. All mining ended in 2001.
Increased copper prices in the 2010s led to efforts by EMED Mining to reopen the mine, but difficulties in acquiring all necessary property rights, environmental concerns, and obtaining regulatory approval delayed reopening. The mine, which employed as many as 20,000 in the past, would employ 350 people during its startup phase. Environmental concerns are centered on long disused water reservoirs which might not be able to withstand the stress of renewed waste inputs.
Controversy on its nature
Due to the extreme conditions of the river, there is very little in the way of life, with the exception of small amounts of
microorganism
A microorganism, or microbe,, ''mikros'', "small") and ''organism'' from the el, ὀργανισμός, ''organismós'', "organism"). It is usually written as a single word but is sometimes hyphenated (''micro-organism''), especially in olde ...
s, including
algae
Algae (; singular alga ) is an informal term for a large and diverse group of photosynthetic eukaryotic organisms. It is a polyphyletic grouping that includes species from multiple distinct clades. Included organisms range from unicellular mic ...
. The presence of
anaerobic bacteria
An anaerobic organism or anaerobe is any organism that does not require molecular oxygen for growth. It may react negatively or even die if free oxygen is present. In contrast, an aerobic organism (aerobe) is an organism that requires an oxygenate ...
in the sediments is thought to contribute somewhat to the river's famously low
pH (acidity), that in turn increases the concentration of dissolved
heavy metals
upright=1.2, Crystals of osmium, a heavy metal nearly twice as dense as lead">lead.html" ;"title="osmium, a heavy metal nearly twice as dense as lead">osmium, a heavy metal nearly twice as dense as lead
Heavy metals are generally defined as ...
. The waters from the Rio Tinto, high in metal sulfides, provide an ideal environment for
chemolithoautotrophic A lithoautotroph is an organism which derives energy from reactions of reduced compounds of mineral (inorganic) origin. Two types of lithoautotrophs are distinguished by their energy source; photolithoautotrophs derive their energy from light while ...
microorganisms, with the sulfides acting as a food source. The product of metal sulfide metabolism through oxidization is
ferric iron
In chemistry, iron(III) refers to the element iron in its +3 oxidation state. In ionic compounds (salts), such an atom may occur as a separate cation (positive ion) denoted by Fe3+.
The adjective ferric or the prefix ferri- is often used to s ...
and secretion of acidic liquid. The continuation of this process for an extended period of time is thought by some scientists to be responsible for keeping the river's
pH between 2 and 2.5 in most areas. Even in the extremely acidic water, both red and green algae have been observed to thrive in relatively high concentrations. Despite algae levels in the Rio Tinto accounting for over half of the total
biomass
Biomass is plant-based material used as a fuel for heat or electricity production. It can be in the form of wood, wood residues, energy crops, agricultural residues, and waste from industry, farms, and households. Some people use the terms bi ...
in the river, algae is understood to have minimal effects on the characteristics of the complex ecosystem.
The discovery of multiple oxide terraces mediated by microorganisms at up to 60 meters above the current water level, and as far away as 20 kilometers from the current river's path, may suggest that the unusual ecosystem is a natural phenomenon since before human mining activities started in this region.
On the other hand, it is known that toxic water emanates from these vast underground and open pit mines and chemical
ore refinement that had been active off and on for thousands of years. While it is still undetermined if the unique water chemistry of the Rio Tinto developed as a result of thousands of years of mining or by natural causes, it is possible that the river's chemical makeup is due to the combination of both natural causes and
acid mine drainage
Acid mine drainage, acid and metalliferous drainage (AMD), or acid rock drainage (ARD) is the outflow of acidic water from metal mines or coal mines.
Acid rock drainage occurs naturally within some environments as part of the rock weathering ...
.
[Rio Tinto and the Mines: The long-dormant site of Spain's first environmental protest in 1888, revisited]
Adam Lederer and Vicky Azcoitia. ''Natural History Magazine''. May 2017. The river drains an area with huge deposits of sulfides which was formed more than 350 million years ago. When sulfides are exposed to air, water, and microorganisms, drainage from acidic rocks flows into surface and ground water. Mining, however, greatly increases exposed areas.
Astrobiology
This river has gained recent scientific interest due to the presence of
extremophile
An extremophile (from Latin ' meaning "extreme" and Greek ' () meaning "love") is an organism that is able to live (or in some cases thrive) in extreme environments, i.e. environments that make survival challenging such as due to extreme temper ...
anaerobic
Anaerobic means "living, active, occurring, or existing in the absence of free oxygen", as opposed to aerobic which means "living, active, or occurring only in the presence of oxygen." Anaerobic may also refer to:
* Anaerobic adhesive, a bonding a ...
bacteria
Bacteria (; singular: bacterium) are ubiquitous, mostly free-living organisms often consisting of one biological cell. They constitute a large domain of prokaryotic microorganisms. Typically a few micrometres in length, bacteria were among ...
that dwell in the acidic water. The subsurface
rock
Rock most often refers to:
* Rock (geology), a naturally occurring solid aggregate of minerals or mineraloids
* Rock music, a genre of popular music
Rock or Rocks may also refer to:
Places United Kingdom
* Rock, Caerphilly, a location in Wales ...
s on the
river bed
A stream bed or streambed is the bottom of a stream or river (bathymetry) or the physical confine of the normal water flow (channel). The lateral confines or channel margins are known as the stream banks or river banks, during all but flood st ...
contain iron and
sulfide
Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds lar ...
mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
s on which the bacteria feed. The extreme conditions in the river may be analogous to other locations in the
Solar System
The Solar SystemCapitalization of the name varies. The International Astronomical Union, the authoritative body regarding astronomical nomenclature, specifies capitalizing the names of all individual astronomical objects but uses mixed "Solar S ...
thought to contain liquid water, such as
groundwater on Mars
During past ages, there was rain and snow on Mars; especially in the Noachian and early Hesperian epochs. Some moisture entered the ground and formed aquifers. That is, the water went into the ground, seeped down until it reached a formation tha ...
. Scientists have also directly compared the
chemistry
Chemistry is the science, scientific study of the properties and behavior of matter. It is a natural science that covers the Chemical element, elements that make up matter to the chemical compound, compounds made of atoms, molecules and ions ...
of the water in which the Mars rocks of
Meridiani Planum
The Meridiani Planum (alternately Meridiani plain, Meridiani plains, Terra Meridiani, or Terra Meridiani plains) is either a large plain straddling the equator of Mars and covered with a vast number of spherules containing a lot of iron oxide or ...
were deposited in the past with the Río Tinto.
Likewise, the moon
Europa
Europa may refer to:
Places
* Europe
* Europa (Roman province), a province within the Diocese of Thrace
* Europa (Seville Metro), Seville, Spain; a station on the Seville Metro
* Europa City, Paris, France; a planned development
* Europa Cliff ...
contains an acidic ocean of water underneath its ice surface, thus the Rio Tinto river is of interest to
astrobiologists studying the environmental limits of life and
planetary habitability
Planetary habitability is the measure of a planet's or a natural satellite's potential to develop and maintain environments hospitable to life. Life may be generated directly on a planet or satellite endogenously or be transferred to it from ...
.
See also
*
Acid mine drainage
Acid mine drainage, acid and metalliferous drainage (AMD), or acid rock drainage (ARD) is the outflow of acidic water from metal mines or coal mines.
Acid rock drainage occurs naturally within some environments as part of the rock weathering ...
*
Environmental impact of mining
Environmental effects of mining can occur at local, regional, and global scales through direct and indirect mining practices. The effects can result in erosion, sinkholes, loss of biodiversity, or the contamination of soil, groundwater, and su ...
*
List of rivers of Spain
This is an incomplete list of rivers that are at least partially in Spain. The rivers flowing into the sea are sorted along the coast. Rivers flowing into other rivers are listed by the rivers they flow into. Rivers in the mainland Iberian Peninsu ...
References
External links
Mars Analog Research and Technology Experiment FAQProtected Landscape Río TintoMining Park of Rio TintoWith link t
The Ernest Lluch mining Museum, RioTinto the fairly new mining museum of the area, containing a permanent exhibition on the history of mining, and geological information.
{{DEFAULTSORT:Tinto, Rio
Rivers of Spain
Rivers of Andalusia
Environmental impact of mining
Environmental issues in Spain
Mining in Spain