Rhyolite ( ) is the most
silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
-rich of
volcanic rock
Volcanic rock (often shortened to volcanics in scientific contexts) is a rock formed from lava erupted from a volcano. In other words, it differs from other igneous rock by being of volcanic origin. Like all rock types, the concept of volcanic r ...
s. It is generally
glass
Glass is a non-crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling (quenching) of ...
y or fine-grained (
aphanitic
Aphanites (adj. ''aphanitic''; ) are igneous rocks that are so fine-grained that their component mineral crystals are not visible to the naked eye (in contrast to phanerites, in which the crystals are visible to the unaided eye). This geologic ...
) in
texture
Texture may refer to:
Science and technology
* Surface texture, the texture means smoothness, roughness, or bumpiness of the surface of an object
* Texture (roads), road surface characteristics with waves shorter than road roughness
* Texture (c ...
, but may be
porphyritic
Porphyritic is an adjective used in geology to describe igneous rocks with a distinct difference in the size of mineral crystals, with the larger crystals known as phenocrysts. Both extrusive and intrusive rocks can be porphyritic, meaning all ...
, containing larger mineral
crystal
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...
s (
phenocrysts
300px, feldspathic phenocrysts. This granite, from the Switzerland">Swiss side of the Mont Blanc massif, has large white plagioclase phenocrysts, triclinic minerals that give trapezoid shapes when cut through). 1 euro coins, 1 euro coin (diameter ...
) in an otherwise fine-grained
groundmass
The matrix or groundmass of a rock is the finer-grained mass of material in which larger grains, crystals, or clasts are embedded.
The matrix of an igneous rock consists of finer-grained, often microscopic, crystals in which larger crystals, ca ...
. The
mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
assemblage is predominantly
quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
,
sanidine
Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal system ...
, and
plagioclase
Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more prope ...
. It is the
extrusive
Extrusive rock refers to the mode of igneous volcanic rock formation in which hot magma from inside the Earth flows out (extrudes) onto the surface as lava or explodes violently into the atmosphere to fall back as pyroclastics or tuff. In contras ...
equivalent to
granite
Granite () is a coarse-grained (phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies undergro ...
.
Rhyolitic
magma
Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural sa ...
is extremely
viscous
The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water.
Viscosity quantifies the inter ...
, due to its high silica content. This favors
explosive eruption
In volcanology, an explosive eruption is a volcanic eruption of the most violent type. A notable example is the 1980 eruption of Mount St. Helens. Such eruptions result when sufficient gas has dissolved under pressure within a viscous magma such ...
s over
effusive eruption
An effusive eruption is a type of volcanic eruption in which lava steadily flows out of a volcano onto the ground.
Overview
There are two major groupings of eruptions: effusive and explosive. Effusive eruption differs from explosive eruption, ...
s, so this type of magma is more often erupted as
pyroclastic rock
Pyroclastic rocks (derived from the el, πῦρ, links=no, meaning fire; and , meaning broken) are clastic rocks composed of rock fragments produced and ejected by explosive volcanic eruptions. The individual rock fragments are known as pyrocl ...
than as
lava flow
Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or und ...
s. Rhyolitic ash-flow
tuff
Tuff is a type of rock made of volcanic ash ejected from a vent during a volcanic eruption. Following ejection and deposition, the ash is lithified into a solid rock. Rock that contains greater than 75% ash is considered tuff, while rock cont ...
s are among the most voluminous of continental
igneous rock
Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main The three types of rocks, rock types, the others being Sedimentary rock, sedimentary and metamorphic rock, metamorphic. Igneous rock ...
formations.
Rhyolitic tuff has been extensively used for construction.
Obsidian
Obsidian () is a naturally occurring volcanic glass formed when lava extrusive rock, extruded from a volcano cools rapidly with minimal crystal growth. It is an igneous rock.
Obsidian is produced from felsic lava, rich in the lighter elements s ...
, which is rhyolitic
volcanic glass
Volcanic glass is the amorphous (uncrystallized) product of rapidly cooling magma. Like all types of glass, it is a state of matter intermediate between the closely packed, highly ordered array of a crystal and the highly disordered array of liqu ...
, has been used for tools from prehistoric times to the present day because it can be shaped to an extremely sharp edge. Rhyolitic
pumice
Pumice (), called pumicite in its powdered or dust form, is a volcanic rock that consists of highly vesicular rough-textured volcanic glass, which may or may not contain crystals. It is typically light-colored. Scoria is another vesicular vol ...
finds use as an
abrasive
An abrasive is a material, often a mineral, that is used to shape or finish a workpiece through rubbing which leads to part of the workpiece being worn away by friction. While finishing a material often means polishing it to gain a smooth, reflec ...
, in
concrete
Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most wi ...
, and as a
soil amendment
A soil conditioner is a product which is added to soil to improve the soil’s physical qualities, usually its fertility (ability to provide nutrition for plants) and sometimes its mechanics. In general usage, the term "soil conditioner" is often ...
.
Description
![TAS-Diagramm-rhyolite](https://upload.wikimedia.org/wikipedia/commons/e/e9/TAS-Diagramm-rhyolite.png)
Rhyolite is an
extrusive
Extrusive rock refers to the mode of igneous volcanic rock formation in which hot magma from inside the Earth flows out (extrudes) onto the surface as lava or explodes violently into the atmosphere to fall back as pyroclastics or tuff. In contras ...
igneous rock, formed from magma rich in
silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
that is extruded from a volcanic vent to cool quickly on the surface rather than slowly in the subsurface. It is generally light in color due to its low content of
mafic
A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks include ...
minerals, and it is typically very fine-grained (
aphanitic
Aphanites (adj. ''aphanitic''; ) are igneous rocks that are so fine-grained that their component mineral crystals are not visible to the naked eye (in contrast to phanerites, in which the crystals are visible to the unaided eye). This geologic ...
) or
glassy.
An extrusive igneous rock is classified as rhyolite when
quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
constitutes 20% to 60% by volume of its total content of quartz,
alkali feldspar
Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldspa ...
, and
plagioclase
Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more prope ...
(
QAPF) and alkali feldspar makes up 35% to 90% of its total feldspar content.
Feldspathoid
The feldspathoids are a group of tectosilicate minerals which resemble feldspars but have a different structure and much lower silica content. They occur in rare and unusual types of igneous rocks, and are usually not found in rocks containing prim ...
s are not present. This makes rhyolite the extrusive equivalent of granite. However, while the
IUGS
The International Union of Geological Sciences (IUGS) is an international non-governmental organization devoted to international cooperation in the field of geology.
About
The IUGS was founded in 1961 and is a Scientific Union member of the Inte ...
recommends classifying volcanic rocks on the basis of their mineral composition whenever possible, volcanic rocks are often glassy or so fine-grained that mineral identification is impractical. The rock must then be classified chemically based on its content of silica and
alkali metal oxide
The alkali metals react with oxygen to form several different compounds: suboxides, oxides, peroxides, sesquioxides, superoxides, and ozonides. They all react violently with water.
Alkali metal suboxides
* Hexarubidium monoxide (Rb6O) h
* Non ...
s (
K2O plus
Na2O). Rhyolite is high in silica and total alkali metal oxides, placing it in the R field of the
TAS diagram
The TAS classification can be used to assign names to many common types of volcanic rocks based upon the relationships between the combined alkali content and the silica content. These chemical parameters are useful, because the relative proportion ...
.
The alkali feldspar in rhyolites is
sanidine
Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal system ...
or, less commonly,
orthoclase
Orthoclase, or orthoclase feldspar (endmember formula K Al Si3 O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture," because its two cleavage planes are at right angles t ...
. It is rarely
anorthoclase
The mineral anorthoclase ((Na,K)AlSi3O8) is a crystalline solid solution in the alkali feldspar series, in which the sodium-aluminium silicate member exists in larger proportion. It typically consists of between 10 and 36 percent of KAlSi3O8 and ...
. These feldspar minerals sometimes are present as phenocrysts. The plagioclase is usually
sodium
Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable iso ...
-rich (
oligoclase
Oligoclase is a rock-forming mineral belonging to the plagioclase feldspars. In chemical composition and in its crystallographic and physical characters it is intermediate between albite ( Na Al Si3 O8) and anorthite ( CaAl2Si2O8). The albite:an ...
or
andesine
Andesine is a silicate mineral, a member of the plagioclase feldspar solid solution series. Its chemical formula is ( Ca, Na)( Al, Si)4 O8, where Ca/(Ca + Na) (% anorthite) is between 30–50%. The formula may be written as Na0.7-0.5Ca0.3-0.5A ...
).
Cristobalite
Cristobalite is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, SiO2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members of the ...
and
trydimite
Tridymite is a high-temperature polymorph of silica and usually occurs as minute tabular white or colorless pseudo-hexagonal crystals, or scales, in cavities in felsic volcanic rocks. Its chemical formula is Si O2. Tridymite was first described ...
are sometimes present along with the quartz.
Biotite
Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron-endmember annite, and the magnesium-endmember phlogopite; more alumino ...
,
augite
Augite is a common rock-forming pyroxene mineral with formula . The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees.
Characteristics
Augite is a solid solution in the pyroxene group. ...
,
fayalite
Fayalite (, commonly abbreviated to Fa) is the iron-rich end-member of the olivine solid-solution series. In common with all minerals in the olivine group, fayalite crystallizes in the orthorhombic system (space group ''Pbnm'') with cell para ...
, and
hornblende
Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks ...
are common accessory minerals.
Geology
Due to their high content of silica and low
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
and
magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
contents, rhyolitic
magmas
Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural sa ...
form highly viscous
lava
Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or un ...
s.
As a result, many eruptions of rhyolite are highly explosive, and rhyolite occurs more frequently as
pyroclastic rock
Pyroclastic rocks (derived from the el, πῦρ, links=no, meaning fire; and , meaning broken) are clastic rocks composed of rock fragments produced and ejected by explosive volcanic eruptions. The individual rock fragments are known as pyrocl ...
than as
lava flow
Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or und ...
s.
Rhyolitic ash flow tuffs are the only volcanic product with volumes rivaling those of
flood basalt
A flood basalt (or plateau basalt) is the result of a giant volcanic eruption or series of eruptions that covers large stretches of land or the ocean floor with basalt lava. Many flood basalts have been attributed to the onset of a hotspot reach ...
s.
Rhyolites also occur as
breccia
Breccia () is a rock composed of large angular broken fragments of minerals or rocks cemented together by a fine-grained matrix.
The word has its origins in the Italian language, in which it means "rubble". A breccia may have a variety of di ...
s or in
lava dome
In volcanology, a lava dome is a circular mound-shaped protrusion resulting from the slow extrusion of viscous lava from a volcano. Dome-building eruptions are common, particularly in convergent plate boundary settings. Around 6% of eruptions on ...
s,
volcanic plug
A volcanic plug, also called a volcanic neck or lava neck, is a volcanic object created when magma hardens within a vent on an active volcano. When present, a plug can cause an extreme build-up of high gas pressure if rising volatile-charged mag ...
s, and
dikes
Dyke (UK) or dike (US) may refer to:
General uses
* Dyke (slang), a slang word meaning "lesbian"
* Dike (geology), a subvertical sheet-like intrusion of magma or sediment
* Dike (mythology), ''Dikē'', the Greek goddess of moral justice
* Dikes, ...
.
Rhyolitic lavas erupt at a relatively low temperature of , significantly cooler than basaltic lavas, which typically erupt at temperatures of .
Rhyolites that cool too quickly to grow
crystals
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macrosc ...
form a natural glass or vitrophyre, also called
obsidian
Obsidian () is a naturally occurring volcanic glass formed when lava extrusive rock, extruded from a volcano cools rapidly with minimal crystal growth. It is an igneous rock.
Obsidian is produced from felsic lava, rich in the lighter elements s ...
. Slower cooling forms microscopic crystals in the lava and results in textures such as flow
foliations
Foliation may refer to:
* Foliation, a geometric device used to study manifolds
* Foliation (geology), a property of certain rocks
* A pagination system in book production
* Vernation, the growth and arrangement of leaves
* In architecture, an orn ...
,
spherulitic,
nodular, and
lithophysa
A lithophysa (plural lithophysae, from Greek ''lithos'' "stone" + ''physan'' "to blow") is a felsic volcanic rock with a spherulitic structure and interior cavity with concentric chambers. Its outer shape is spherical or lenticular. They vary in ...
l structures. Some rhyolite is highly
vesicular pumice
Pumice (), called pumicite in its powdered or dust form, is a volcanic rock that consists of highly vesicular rough-textured volcanic glass, which may or may not contain crystals. It is typically light-colored. Scoria is another vesicular vol ...
.
Peralkaline
Peralkaline rocks include those igneous rocks which have a deficiency of aluminium such that sodium and potassium are in excess of that needed for feldspar. The presence of aegerine (sodium pyroxene) and riebeckite (sodium amphibole) are indicative ...
rhyolites (rhyolites unusually rich in alkali metals) include
comendite
Comendite is a hard, peralkaline igneous rock, a type of light blue grey rhyolite. Phenocrysts are sodic sanidine with minor albite and bipyramidal quartz. Iddings, Joseph Paxson, 1913, ''Igneous rocks: composition, texture and classification'', v ...
and
pantellerite
Pantellerite is a type of volcanic rock, specifically a peralkaline rhyolite. It has a higher iron and lower aluminium composition than comendite. It is named after Pantelleria, a volcanic island in the Strait of Sicily and the type location for ...
. Peralkalinity has significant effects on
lava flow morphology and
mineralogy
Mineralogy is a subject of geology specializing in the scientific study of the chemistry, crystal structure, and physical (including optical) properties of minerals and mineralized artifacts. Specific studies within mineralogy include the proces ...
, such that peralkaline rhyolites can be 10–30 times more fluid than typical
calc-alkaline
The calc-alkaline magma series is one of two main subdivisions of the subalkaline magma series, the other subalkaline magma series being the tholeiitic series. A magma series is a series of compositions that describes the evolution of a mafic mag ...
rhyolites. As a result of their increased fluidity, they are able to form small-scale flow folds,
lava tube
A lava tube, or pyroduct, is a natural conduit formed by flowing lava from a volcanic vent that moves beneath the hardened surface of a lava flow. If lava in the tube empties, it will leave a cave.
Formation
A lava tube is a type of lava ca ...
s and thin dikes. Peralkaline rhyolites erupt at relatively high temperatures of more than . They comprise
bimodal
In statistics, a multimodal distribution is a probability distribution with more than one mode (statistics), mode. These appear as distinct peaks (local maxima) in the probability density function, as shown in Figures 1 and 2. Categorical, ...
shield volcano
A shield volcano is a type of volcano named for its low profile, resembling a warrior's shield lying on the ground. It is formed by the eruption of highly fluid (low viscosity) lava, which travels farther and forms thinner flows than the more v ...
es at
hotspots and
rift
In geology, a rift is a linear zone where the lithosphere is being pulled apart and is an example of extensional tectonics.
Typical rift features are a central linear downfaulted depression, called a graben, or more commonly a half-grabe ...
s (e.g.
Rainbow Range,
Ilgachuz Range
The Ilgachuz Range is a name given to an extinct shield volcano in British Columbia, Canada. It is not a mountain range in the normal sense, because it was formed as a single volcano that has been eroded for the past 5 million years. It lies on ...
and
Level Mountain
Level Mountain is a large volcanic complex in the Northern Interior of British Columbia, Canada. It is located north-northwest of Telegraph Creek and west of Dease Lake on the Nahlin Plateau. With a maximum elevation of , it is the second-hig ...
in
British Columbia
British Columbia (commonly abbreviated as BC) is the westernmost province of Canada, situated between the Pacific Ocean and the Rocky Mountains. It has a diverse geography, with rugged landscapes that include rocky coastlines, sandy beaches, ...
, Canada).
Eruptions of rhyolite lava are relatively rare compared to eruptions of less felsic lavas. Only four eruptions of rhyolite have been recorded since the start of the 20th century: at the
St. Andrew Strait
St. Andrew Strait is a volcano in Papua New Guinea that has had eruptions in historical times. The volcano is not linked to any tectonic plates, the volcano is also in an area of very few earthquakes, suggesting that St. Andrew Strait is an Intrapl ...
volcano in
Papua New Guinea
Papua New Guinea (abbreviated PNG; , ; tpi, Papua Niugini; ho, Papua Niu Gini), officially the Independent State of Papua New Guinea ( tpi, Independen Stet bilong Papua Niugini; ho, Independen Stet bilong Papua Niu Gini), is a country i ...
and
Novarupta
Novarupta (meaning "newly erupted" in Latin) is a volcano that was formed in 1912, located on the Alaska Peninsula on a slope of Trident Volcano in Katmai National Park and Preserve, about southwest of Anchorage. Formed during the largest volca ...
volcano in
Alaska
Alaska ( ; russian: Аляска, Alyaska; ale, Alax̂sxax̂; ; ems, Alas'kaaq; Yup'ik: ''Alaskaq''; tli, Anáaski) is a state located in the Western United States on the northwest extremity of North America. A semi-exclave of the U.S., ...
as well as at
Chaitén
Chaitén (, ) is a Chilean town, commune and former capital of the Palena Province in Los Lagos Region. The town is north of the mouth of Yelcho River, on the east coast of the Gulf of Corcovado. The town is strategically close to the northern end ...
and
Cordón Caulle
Cordón is a central ''barrio'' (neighbourhood or district) of Montevideo, Uruguay, located East of the Centro. Its main avenue is 18 de Julio Avenue.
History
Cordón was the first neighborhood to be created outside the walls of the old Citade ...
volcanoes in southern
Chile
Chile, officially the Republic of Chile, is a country in the western part of South America. It is the southernmost country in the world, and the closest to Antarctica, occupying a long and narrow strip of land between the Andes to the east a ...
.
The eruption of Novarupta in 1912 was the largest volcanic eruption of the 20th century,
and began with explosive volcanism that later transitioned to effusive volcanism and the formation of a rhyolite dome in the vent.
Petrogenesis
Rhyolite magmas can be produced by
igneous differentiation
In geology, igneous differentiation, or magmatic differentiation, is an umbrella term for the various processes by which magmas undergo bulk chemical change during the partial melting process, cooling, emplacement, or eruption. The sequence of (u ...
of a more mafic (silica-poor) magma, through
fractional crystallization Fractional crystallization may refer to:
* Fractional crystallization (chemistry), a process to separate different solutes from a solution
* Fractional crystallization (geology)
Fractional crystallization, or crystal fractionation, is one of the ...
or by assimilation of melted crustal rock (
anatexis
Anatexis (via Latin from Greek roots meaning "to melt down") is the partial melting of rocks. Traditionally, anatexis is used specifically to discuss the partial melting of crustal rocks, while the generic term "partial melting" refers to the part ...
). Associations of
andesite
Andesite () is a volcanic rock of intermediate composition. In a general sense, it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predomi ...
s,
dacite
Dacite () is a volcanic rock formed by rapid solidification of lava that is high in silica and low in alkali metal oxides. It has a fine-grained (aphanitic) to porphyritic texture and is intermediate in composition between andesite and rhyolite. ...
s, and rhyolites in similar tectonic settings and with similar chemistry suggests that the rhyolite members were formed by differentiation of mantle-derived
basalt
Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
ic magmas at shallow depths. In other cases, the rhyolite appears to be a product of melting of crustal sedimentary rock.
Water vapor plays an important role in lowering the melting point of silicic rock,
and some rhyolitic magmas may have a water content as high as 7–8 weight percent.
High-silica rhyolite (HSR), with a silica content of 75 to 77·8% , forms a distinctive subgroup within the rhyolites. HSRs are the most
evolved
Evolution is change in the heritable characteristics of biological populations over successive generations. These characteristics are the expressions of genes, which are passed on from parent to offspring during reproduction. Variation t ...
of all igneous rocks, with a composition very close to the water-saturated granite
eutectic and with extreme enrichment in most
incompatible element In petrology and geochemistry, an incompatible element is one that is unsuitable in size and/or charge to the cation sites of the minerals of which it is included. It is defined by the partition coefficient between rock-forming minerals and melt b ...
s. However, they are highly depleted in
strontium
Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is ex ...
,
barium
Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element.
Th ...
, and
europium
Europium is a chemical element with the symbol Eu and atomic number 63. Europium is the most reactive lanthanide by far, having to be stored under an inert fluid to protect it from atmospheric oxygen or moisture. Europium is also the softest lanth ...
. They are interpreted as products of repeated melting and freezing of granite in the subsurface. HSRs typically erupt in large
caldera
A caldera ( ) is a large cauldron-like hollow that forms shortly after the emptying of a magma chamber in a volcano eruption. When large volumes of magma are erupted over a short time, structural support for the rock above the magma chamber is ...
eruptions.
Occurrence
Rhyolite is common along
convergent plate boundaries
A convergent boundary (also known as a destructive boundary) is an area on Earth where two or more lithospheric plates collide. One plate eventually slides beneath the other, a process known as subduction. The subduction zone can be defined by a ...
, where a slab of
oceanic lithosphere
A lithosphere () is the rigid, outermost rocky shell of a terrestrial planet or natural satellite. On Earth, it is composed of the crust (geology), crust and the portion of the upper mantle (geology), mantle that behaves elastically on time sca ...
is being
subducted
Subduction is a geological process in which the oceanic lithosphere is recycled into the Earth's mantle at convergent boundaries. Where the oceanic lithosphere of a tectonic plate converges with the less dense lithosphere of a second plate, the ...
into the
Earth's mantle
Earth's mantle is a layer of silicate rock between the crust and the outer core. It has a mass of 4.01 × 1024 kg and thus makes up 67% of the mass of Earth. It has a thickness of making up about 84% of Earth's volume. It is predominantly sol ...
beneath overriding oceanic or
continental lithosphere
A lithosphere () is the rigid, outermost rocky shell of a terrestrial planet or natural satellite. On Earth, it is composed of the crust and the portion of the upper mantle that behaves elastically on time scales of up to thousands of years o ...
. It can sometimes be the predominant igneous rock type in these settings. Rhyolite is more common when the overriding lithosphere is continental rather than oceanic. The thicker continental crust gives the rising magma more opportunity to differentiate and assimilate crustal rock.
Rhyolite has been found on islands far from land, but such oceanic occurrences are rare.
[Farndon, John (2007) ''The Illustrated Encyclopedia of Rocks of the World''. Southwater. p. 54. ] The
tholeiitic magmas erupted at volcanic ocean islands, such as
Iceland
Iceland ( is, Ísland; ) is a Nordic island country in the North Atlantic Ocean and in the Arctic Ocean. Iceland is the most sparsely populated country in Europe. Iceland's capital and largest city is Reykjavík, which (along with its s ...
, can sometimes differentiate all the way to rhyolite, and about 8% of the volcanic rock in Iceland is rhyolite. However, this is unusual, and the
Hawaiian Islands
The Hawaiian Islands ( haw, Nā Mokupuni o Hawai‘i) are an archipelago of eight major islands, several atolls, and numerous smaller islets in the North Pacific Ocean, extending some from the island of Hawaii in the south to northernmost Kur ...
(for example) have no known occurrences of rhyolite. The
alkaline magmas of volcanic ocean islands will very occasionally differentiate all the way to peralkaline rhyolites, but differentiation usually ends with
trachyte
Trachyte () is an extrusive igneous rock composed mostly of alkali feldspar. It is usually light-colored and aphanitic (fine-grained), with minor amounts of mafic minerals, and is formed by the rapid cooling of lava enriched with silica and al ...
.
Small volumes of rhyolite are sometimes erupted in association with
flood basalt
A flood basalt (or plateau basalt) is the result of a giant volcanic eruption or series of eruptions that covers large stretches of land or the ocean floor with basalt lava. Many flood basalts have been attributed to the onset of a hotspot reach ...
s, late in their history and where central volcanic complexes develop.
Name
The name rhyolite was introduced into
geology
Geology () is a branch of natural science concerned with Earth and other astronomical objects, the features or rocks of which it is composed, and the processes by which they change over time. Modern geology significantly overlaps all other Ear ...
in 1860 by the German traveler and geologist
Ferdinand von Richthofen
Baron Ferdinand Freiherr von Richthofen (5 May 18336 October 1905), better known in English as was a German traveller, geographer, and scientist. He is noted for coining the terms "Seidenstraße" and "Seidenstraßen" = "Silk Road(s)" or "Silk ...
from the Greek word ''rhýax'' ("a stream of lava") and the rock name suffix "-lite".
Uses
In
North American pre-historic times, rhyolite was quarried extensively in what is now eastern
Pennsylvania
Pennsylvania (; ( Pennsylvania Dutch: )), officially the Commonwealth of Pennsylvania, is a state spanning the Mid-Atlantic, Northeastern, Appalachian, and Great Lakes regions of the United States. It borders Delaware to its southeast, ...
. Among the leading quarries was the
Carbaugh Run Rhyolite Quarry Site in
Adams County. Rhyolite was mined there starting 11,500 years ago.
Tons of rhyolite were traded across the
Delmarva Peninsula
The Delmarva Peninsula, or simply Delmarva, is a large peninsula and proposed state on the East Coast of the United States, occupied by the vast majority of the state of Delaware and parts of the Eastern Shore regions of Maryland and Virginia ...
,
[ because the rhyolite kept a sharp point when ]knapped
Knapping is the shaping of flint, chert, obsidian, or other conchoidal fracturing stone through the process of lithic reduction to manufacture stone tools, strikers for flintlock firearms, or to produce flat-faced stones for building or facing w ...
and was used to make spear points and arrowheads.
Obsidian is usually of rhyolitic composition, and it has been used for tools since prehistoric times. Obsidian scalpels have been investigated for use in delicate surgery. Pumice, also typically of rhyolitic composition, finds important uses as an abrasive
An abrasive is a material, often a mineral, that is used to shape or finish a workpiece through rubbing which leads to part of the workpiece being worn away by friction. While finishing a material often means polishing it to gain a smooth, reflec ...
, in concrete
Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most wi ...
, and as a soil amendment
A soil conditioner is a product which is added to soil to improve the soil’s physical qualities, usually its fertility (ability to provide nutrition for plants) and sometimes its mechanics. In general usage, the term "soil conditioner" is often ...
. Rhyolitic tuff was used extensively for construction in ancient Rome and has been used in construction in modern Europe.
See also
*
*
References
External links
Geology.com - Rhyolite
Gemstones.com - guide and properties chart - Rhyolite
{{Volcanoes
Aphanitic rocks
Felsic rocks
Porphyritic rocks
Volcanic rocks
Subvolcanic rocks
Volcanology