Renewable Diesel
   HOME

TheInfoList



OR:

Vegetable oil can be used as an alternative fuel in diesel engines and in
heating oil Heating oil is any petroleum product or other oil used for heating; a fuel oil. Most commonly, it refers to low viscosity grades of fuel oil used for furnaces or boilers use for home heating and in other buildings. Home heating oil is often a ...
burners. When vegetable oil is used directly as a fuel, in either modified or unmodified equipment, it is referred to as straight vegetable oil (SVO) or pure plant oil (PPO). Conventional diesel engines can be modified to help ensure that the viscosity of the vegetable oil is low enough to allow proper
atomization Atomization refers to breaking bonds in some substance to obtain its constituent atoms in gas phase. By extension, it also means separating something into fine particles, for example: process of breaking bulk liquids into small droplets. Atomizati ...
of the fuel. This prevents incomplete combustion, which would damage the engine by causing a build-up of carbon. Straight vegetable oil can also be blended with conventional diesel or processed into biodiesel, HVO or bioliquids for use under a wider range of conditions.


History

Rudolf Diesel was the father of the engine which bears his name. His first attempts were to design an engine to run on coal dust, but he later designed his engine to run on vegetable oil. The idea, he hoped, would make his engines more attractive to farmers having a source of fuel readily available. In a 1912 presentation to the British Institute of Mechanical Engineers, he cited a number of efforts in this area and remarked, "The fact that fat oils from vegetable sources can be used may seem insignificant today, but such oils may perhaps become in course of time of the same importance as some natural mineral oils and the tar products are now." Periodic petroleum shortages spurred research into vegetable oil as a diesel substitute during the 1930s and 1940s, and again in the 1970s and early 1980s when straight vegetable oil enjoyed its highest level of scientific interest. The 1970s also saw the formation of the first commercial enterprise to allow consumers to run straight vegetable oil in their automobiles, Elsbett of West Germany. In the 1990s
Bougainville conflict The Bougainville conflict, also known as the Bougainville Civil War, was a multi-layered armed conflict fought from 1988 to 1998 in the North Solomons Province of Papua New Guinea (PNG) between PNG and the secessionist forces of the Bougainvill ...
, islanders cut off from oil supplies due to a blockade fueled their vehicles with
coconut oil frameless , right , alt = A cracked coconut and a bottle of coconut oil Coconut oil (or coconut butter) is an edible oil derived from the wick, meat, and milk of the coconut palm fruit. Coconut oil is a white solid fat; in warmer climates duri ...
.


Application and usability


Modified fuel systems

Most diesel car engines are suitable for the use of straight vegetable oil (SVO), also commonly called pure plant oil (PPO), with certain modifications. Principally, the viscosity and
surface tension Surface tension is the tendency of liquid surfaces at rest to shrink into the minimum surface area possible. Surface tension is what allows objects with a higher density than water such as razor blades and insects (e.g. water striders) to f ...
of the SVO/PPO must be reduced by preheating it, typically by using waste heat from the engine or electricity; otherwise, poor atomization, incomplete combustion, and carbonization may result. One common solution is to add a heat exchanger and an additional fuel tank for the petrodiesel or biodiesel blend and to switch between this additional tank and the main tank of SVO/PPO. The engine is started on diesel, switched over to vegetable oil as soon as it is warmed up, and switched back to diesel shortly before being switched off to ensure that no vegetable oil remains in the engine or fuel lines when it is started from cold again. In colder climates it is often necessary to heat the vegetable oil fuel lines and tank as it can become very viscous and even solidify. Single-tank conversions were developed largely in Germany and are now used throughout Europe. These conversions are designed to provide reliable operation with rapeseed oil that meets the German rapeseed oil fuel standard
DIN DIN or Din or din may refer to: People and language * Din (name), people with the name * Dīn, an Arabic word with three general senses: judgment, custom, and religion from which the name originates * Dinka language (ISO 639 code: din), spoken by ...
51605. Modifications to the engine's cold start regime assist combustion on start up and during the engine warm up phase. Suitably modified indirect injection (IDI) engines have proven to be operable with 100% PPO down to temperatures of . Direct injection (DI) engines generally have to be preheated with a block heater or diesel fired heater. The exception is the VW TDI ( Turbocharged Direct Injection) engine for which a number of German companies offer single-tank conversions. For long-term durability it has been found necessary to decrease the oil change interval and pay increased attention to engine maintenance.


Unmodified indirect injection engines

Many cars powered by indirect injection engines supplied by in-line injection pumps, or mechanical Bosch injection pumps are capable of running on pure SVO/PPO in all but winter temperatures. The most popular of these are the OM616 and OM617 engines found in the Mercedes-Benz W123 and W124 vehicles manufactured from 1980 through 1985. Indirect injection Mercedes-Benz vehicles with in-line injection pumps and cars featuring the PSA XUD engine tend to perform reasonably, especially as the latter is normally equipped with a coolant heated fuel filter. Engine reliability would depend on the condition of the engine. Attention to maintenance of the engine, particularly of the fuel injectors, cooling system and glow plugs will help to provide longevity. Ideally the engine would be converted.


Vegetable oil blending

The relatively high kinematic viscosity of vegetable oils must be reduced to make them compatible with conventional compression-ignition engines and fuel systems.
Cosolvent In chemistry, cosolvents are substances added to a primary solvent in small amounts to increase the solubility of a poorly-soluble Chemical compound, compound. Their use is most prevalent in chemical and biological research relating to pharmaceuti ...
blending is a low-cost and easy-to-adapt technology that reduces viscosity by diluting the vegetable oil with a low-molecular-weight solvent. This blending, or "cutting", has been done with diesel fuel, kerosene, and gasoline, among others; however, opinions vary as to the efficacy of this. Noted problems include higher rates of wear and failure in fuel pumps and piston rings when using blends.Pacific Islands Applied Geoscience Commission: "Coconut Oil Fuel Research in the Republic of the Marshall Islands"
/ref>


Home heating

When liquid fuels made from biomass are used for energy purposes other than transport, they are called bioliquids or biofuels. With often minimal modification, most residential furnaces and boilers that are designed to burn No. 2 heating oil can be made to burn either biodiesel or filtered, preheated waste vegetable oil (WVO). New standard oil burners are certified to operate on 20% biodiesel (B-20). Higher blends are possible with care, since biodiesel tends to liberate existing tarry deposits in fuel tank, which may tend to clog one or more filters. Conventional oil burners tend to clog and char if more than a smaller fraction of vegetable oil is mixed with conventional oil fuel. If the vegetable oil is cleaned at home by the consumer, WVO can result in considerable savings. Many restaurants will receive a minimal amount for their used cooking oil, and processing to a biofuel is fairly simple and inexpensive. Making the oil into biodiesel involves some toxic and hazardous chemical transformations. Burning filtered WVO directly is somewhat more problematic, since it is more viscous and has a higher ignition temperature; nonetheless, its burning can be accomplished with suitable preheating or burners designed to operate on it. WVO can thus be an economical heating option for those with the necessary mechanical and experimental aptitude.


Combined heat and power

A number of companies offer
compression ignition engine Compression may refer to: Physical science * Compression (physics), size reduction due to forces *Compression member, a structural element such as a column *Compressibility, susceptibility to compression *Gas compression * Compression ratio, of a ...
generators optimized to run on plant oils where the waste engine heat is recovered for heating.


Properties

The main form of SVO/PPO used in the UK is rapeseed oil (also known as canola oil, primarily in the United States and Canada) which has a freezing point of . However the use of sunflower oil, which gels at around , is currently being investigated as a means of improving cold-weather starting. However, oils with lower gelling points tend to be less saturated (leading to a higher iodine number) and polymerize more easily in the presence of atmospheric oxygen.


Material compatibility

Polymerization also has been consequentially linked to catastrophic component failures such as injection pump shaft seizure and breakage, injector tip failure leading to various and/or combustion chamber components damaged. Most metallurgical problems such as corrosion and electrolysis are related to water-based contamination or poor choices of plumbing (such as copper or zinc) which can cause gelling – even with petroleum-based fuels.


Temperature effects

Some Pacific island nations are using
coconut oil frameless , right , alt = A cracked coconut and a bottle of coconut oil Coconut oil (or coconut butter) is an edible oil derived from the wick, meat, and milk of the coconut palm fruit. Coconut oil is a white solid fat; in warmer climates duri ...
as fuel to reduce their expenses and their dependence on imported fuels while helping stabilize the coconut oil market. Coconut oil is only usable where temperatures do not drop below , unless two-tank SVO/PPO kits or other tank-heating accessories, etc. are used. The same techniques developed to use, for example, canola and other oils in cold climates can be implemented to make coconut oil usable in temperatures lower than


Availability


Recycled vegetable oil

Recycled vegetable oil, also termed used vegetable oil (UVO), waste vegetable oil (WVO), used cooking oil (UCO), or yellow grease (in
commodities In economics, a commodity is an economic good, usually a resource, that has full or substantial fungibility: that is, the market treats instances of the good as equivalent or nearly so with no regard to who produced them. The price of a comm ...
exchange), is recovered from businesses and industry that use the oil for cooking. , the United States was producing in excess of 11 billion liters (2.9 billion U.S. gallons) of recycled vegetable oil annually, mainly from industrial deep fryers in potato processing plants,
snack food A snack is a small portion of food generally Eating, eaten between meals. Snacks come in a variety of forms including packaged snack foods and other processed foods, as well as items made from fresh ingredients at home. Traditionally, snack ...
factories, and fast food restaurants. If all those 11 billion liters could be
recycled Recycling is the process of converting waste materials into new materials and objects. The recovery of energy from waste materials is often included in this concept. The recyclability of a material depends on its ability to reacquire the p ...
and used to replace the energy equivalent amount of petroleum (an ideal case), almost 1% of US oil consumption could be offset.See Greenhouse gas emissions by the United States Utilizing recycled vegetable oil as a replacement for standard petroleum-derived fuels like gasoline would reduce the price of gasoline by preserving the supply of petroleum.


Virgin vegetable oil

Virgin vegetable oil, also termed pure plant oil or straight vegetable oil, is extracted from plants solely for use as fuel. In contrast to used vegetable oil, is not a byproduct of other industries, and thus its prospects for use as fuel are not limited by the capacities of other industries. Production of vegetable oils for use as fuels is theoretically limited only by the agricultural capacity of a given economy. However, doing so detracts from the supply of other uses of pure vegetable oil.


Legal implications


Taxation of fuel

Taxation on SVO/PPO as a road fuel varies from country to country. It is possible that the revenue departments in many countries are even unaware of its use or consider it too insignificant to legislate. Germany used to have 0% taxation, resulting in it being a leader in most developments of the fuel use.


See also

*
Biodiesel by region This article describes the use and availability of biodiesel in various countries around the world. Argentina Argentina’s biodiesel industries are booming as a result of domestic demand along with strong export markets. Biodiesel production i ...
* Bioliquids *
Civic amenity site A civic amenity site (CA site) or household waste recycling centre (HWRC) (both terms are used in the United Kingdom) is a facility where the public can dispose of household waste and also often containing recycling points. Civic amenity sites ...
; collection point for waste vegetable oil *
Cooking oil Cooking oil is plant, animal, or synthetic liquid fat used in frying, baking, and other types of cooking. It is also used in food preparation and flavoring not involving heat, such as salad dressings and bread dips, and may be called edible oil. ...
*
Dimethyl ether Dimethyl ether (DME; also known as methoxymethane) is the organic compound with the formula CH3OCH3, (sometimes ambiguously simplified to C2H6O as it is an isomer of ethanol). The simplest ether, it is a colorless gas that is a useful precursor ...
: another diesel fuel alternative *
Food vs. fuel Food versus fuel is the dilemma regarding the risk of diverting farmland or crops for biofuels production to the detriment of the food supply. The biofuel and food price debate involves wide-ranging views, and is a long-standing, controversial ...
*
Greasestock Greasestock was an American event held yearly in Yorktown Heights, New York. Exhibitors showcase a variety of alternative energy vehicles, as well as exhibits with a sustainable lifestyle theme. Although it is illegal in New York to power a vehic ...
* Gutter oil (oil drainage or brown grease) * Issues relating to biofuels * The Big Green Bus * Vegetable oil recycling * Vegetable oil refining * Vegetable oils as alternative energy * Yellow grease *
Grand Canyon Railway 4960 Grand Canyon Railway 4960 is a class "O-1a" 2-8-2 "Mikado" type steam locomotive built by Baldwin Locomotive Works in Philadelphia, Pennsylvania in 1923 for the Chicago, Burlington and Quincy Railroad. Its primary use was freight service until 19 ...


References

{{Palm oil Biofuels DIY culture Food waste Vegetable oils