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A refinery is a production facility composed of a group of chemical engineering
unit processes A ''unit process'' is one or more grouped operations in a manufacturing system that can be defined and separated from others. In life-cycle assessment (LCA) and ISO 14040, a unit process is defined as "smallest element considered in the life cycle ...
and unit operations
refining {{Unreferenced, date=December 2009 Refining (also perhaps called by the mathematical term affining) is the process of purification of a (1) substance or a (2) form. The term is usually used of a natural resource that is almost in a usable form, b ...
certain materials or converting
raw material A raw material, also known as a feedstock, unprocessed material, or primary commodity, is a basic material that is used to produce goods, finished goods, energy, or intermediate materials that are feedstock for future finished products. As feedst ...
into products of value.


Types of refineries

Different types of refineries are as follows: * Petroleum oil refinery, which converts
crude oil Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crude ...
into high-octane motor spirit ( gasoline/petrol),
diesel oil Diesel fuel , also called diesel oil, is any liquid fuel specifically designed for use in a diesel engine, a type of internal combustion engine in which fuel ignition takes place without a spark as a result of compression of the inlet air and t ...
,
liquefied petroleum gas Liquefied petroleum gas (LPG or LP gas) is a fuel gas which contains a flammable mixture of hydrocarbon gases, specifically propane, propylene, butylene, isobutane and n-butane. LPG is used as a fuel gas in heating appliances, cooking e ...
es (LPG), kerosene, heating
fuel oil Fuel oil is any of various fractions obtained from the distillation of petroleum (crude oil). Such oils include distillates (the lighter fractions) and residues (the heavier fractions). Fuel oils include heavy fuel oil, marine fuel oil (MFO), bun ...
s, hexane,
lubricating oil A lubricant (sometimes shortened to lube) is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, t ...
s,
bitumen Asphalt, also known as bitumen (, ), is a sticky, black, highly viscous liquid or semi-solid form of petroleum. It may be found in natural deposits or may be a refined product, and is classed as a pitch. Before the 20th century, the term a ...
and petroleum coke * Edible oil refinery which converts
cooking oil Cooking oil is plant, animal, or synthetic liquid fat used in frying, baking, and other types of cooking. It is also used in food preparation and flavoring not involving heat, such as salad dressings and bread dips, and may be called edible oil. ...
into a product that is uniform in taste, smell and appearance, and stability *
Natural gas processing Natural-gas processing is a range of industrial processes designed to purify raw natural gas by removing impurities, contaminants and higher molecular mass hydrocarbons to produce what is known as ''pipeline quality'' dry natural gas. Natural gas ...
plant, which purifies and converts raw natural gas into residential, commercial and industrial fuel gas, and also recovers natural gas liquids (NGL) such as ethane,
propane Propane () is a three-carbon alkane with the molecular formula . It is a gas at standard temperature and pressure, but compressible to a transportable liquid. A by-product of natural gas processing and petroleum refining, it is commonly used a ...
,
butane Butane () or ''n''-butane is an alkane with the formula C4H10. Butane is a gas at room temperature and atmospheric pressure. Butane is a highly flammable, colorless, easily liquefied gas that quickly vaporizes at room temperature. The name but ...
s and
pentane Pentane is an organic compound with the formula C5H12—that is, an alkane with five carbon atoms. The term may refer to any of three structural isomers, or to a mixture of them: in the IUPAC nomenclature, however, pentane means exclusively the ' ...
s * Sugar refinery, which converts
sugar Sugar is the generic name for sweet-tasting, soluble carbohydrates, many of which are used in food. Simple sugars, also called monosaccharides, include glucose, fructose, and galactose. Compound sugars, also called disaccharides or double ...
cane and sugar beets into crystallized sugar and sugar syrups *
Salt refinery Salt is a mineral composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of salts; salt in the form of a natural crystalline mineral is known as rock salt or halite. Salt is present in vast quantitie ...
, which cleans common salt ( NaCl), produced by the solar evaporation of sea water, followed by washing and re-crystallization * Metal refineries refining metals such as alumina, copper, gold, lead, nickel, silver, uranium, zinc, magnesium and cobalt * Iron refining, a stage of refining pig iron (typically grey cast iron to white cast iron), before fining, which converts pig iron into bar iron or steel


A typical oil refinery

The image below is a schematic flow diagram of a typical oil refinery depicting various unit processes and the flow of intermediate products between the inlet
crude oil feedstock Crude can refer to: * Crude oil or simply crude, the unprocessed form of petroleum * Crude (2007 film), ''Crude'' (2007 film), an Australian documentary about the geology and economics of crude oil * Crude (2009 film), ''Crude'' (2009 film), an Am ...
and the final products. The diagram depicts only one of the hundreds of different configurations. It does not include any of the usual facilities providing utilities such as steam, cooling water, and electric power as well as
storage tank Storage tanks are containers that hold liquids, compressed gases (gas tank; or in U.S.A "pressure vessel", which is not typically labeled or regulated as a storage tank) or mediums used for the short- or long-term storage of heat or cold. The t ...
s for crude oil feedstock and for intermediate products and end products.


Natural gas processing plant

The image below is a schematic block flow diagram of a typical natural gas processing plant. It shows various unit processes converting raw natural gas into gas pipelined to end users. The block flow diagram also shows how processing of the raw natural gas yields byproduct sulfur, byproduct ethane, and natural gas liquids (NGL) propane, butanes and natural gasoline (denoted as pentanes +).


Sugar refining

Sugar is generally produced from
sugarcane Sugarcane or sugar cane is a species of (often hybrid) tall, Perennial plant, perennial grass (in the genus ''Saccharum'', tribe Andropogoneae) that is used for sugar Sugar industry, production. The plants are 2–6 m (6–20 ft) tall with ...
or
sugar beet A sugar beet is a plant whose root contains a high concentration of sucrose and which is grown commercially for sugar production. In plant breeding, it is known as the Altissima cultivar group of the common beet (''Beta vulgaris''). Together wi ...
s. As the global production of sugar from sugarcane is at least twice the production from sugar beets, this section focuses on sugarcane.


Milling

Sugarcane is traditionally refined into sugar in two stages. In the first stage, raw sugar is produced by the milling of harvested sugarcane. In a sugar mill, sugarcane is washed, chopped, and shredded by revolving knives. The shredded cane is mixed with water and crushed. The juices (containing 10-15 percent
sucrose Sucrose, a disaccharide, is a sugar composed of glucose and fructose subunits. It is produced naturally in plants and is the main constituent of white sugar. It has the molecular formula . For human consumption, sucrose is extracted and refined ...
) are collected and mixed with lime to adjust pH to 7, prevent decay into glucose and
fructose Fructose, or fruit sugar, is a Ketose, ketonic monosaccharide, simple sugar found in many plants, where it is often bonded to glucose to form the disaccharide sucrose. It is one of the three dietary monosaccharides, along with glucose and galacto ...
, and precipitate impurities. The lime and other suspended solids are settled out, and the clarified juice is concentrated in a
multiple-effect evaporator A multiple-effect evaporator, as defined in chemical engineering, is an apparatus for efficiently using the heat from steam to evaporate water. Water is boiled in a sequence of vessels, each held at a lower pressure than the last. Because the ...
to make a syrup with about 60 weight percent sucrose. The syrup is further concentrated under vacuum until it becomes
supersaturated In physical chemistry, supersaturation occurs with a solution when the concentration of a solute exceeds the concentration specified by the value of solubility at equilibrium. Most commonly the term is applied to a solution of a solid in a liqu ...
and is then seeded with crystalline sugar. Upon cooling, sugar crystallizes out of the syrup. Centrifuging then separates the sugar from the remaining liquid (molasses). Raw sugar has a yellow to brown color. Sugar is sometimes consumed locally at this stage but usually undergoes further purification.
Sulfur dioxide Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a toxic gas responsible for the odor of burnt matches. It is released naturally by volcanic activ ...
is bubbled through the cane juice subsequent to crystallization in a process known as "sulfitation." This process inhibits color forming reactions and stabilizes the sugar juices to produce “mill white” or “plantation white” sugar. The fibrous solids, called ''bagasse'', remaining after the crushing of the shredded sugarcane are burned for fuel which helps a sugar mill to become self-sufficient in energy. Any excess bagasse can be used for animal feed, to produce paper, or burned to generate electricity for the local power grid.


Refining

The second stage is often executed in heavy sugar-consuming regions such as
North America North America is a continent in the Northern Hemisphere and almost entirely within the Western Hemisphere. It is bordered to the north by the Arctic Ocean, to the east by the Atlantic Ocean, to the southeast by South America and the Car ...
, Europe, and
Japan Japan ( ja, 日本, or , and formally , ''Nihonkoku'') is an island country in East Asia. It is situated in the northwest Pacific Ocean, and is bordered on the west by the Sea of Japan, while extending from the Sea of Okhotsk in the north ...
. In the second stage, white sugar is produced that is more than 99 percent pure
sucrose Sucrose, a disaccharide, is a sugar composed of glucose and fructose subunits. It is produced naturally in plants and is the main constituent of white sugar. It has the molecular formula . For human consumption, sucrose is extracted and refined ...
. In such refineries, raw sugar is further purified by
fractional crystallization Fractional crystallization may refer to: * Fractional crystallization (chemistry), a process to separate different solutes from a solution * Fractional crystallization (geology) Fractional crystallization, or crystal fractionation, is one of the ...
.


References

{{Authority control Chemical processes Industrial buildings