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Red beds (or redbeds) are
sedimentary rocks
Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles t ...
, typically consisting of
sandstone
Sandstone is a clastic sedimentary rock composed mainly of sand-sized (0.0625 to 2 mm) silicate grains. Sandstones comprise about 20–25% of all sedimentary rocks.
Most sandstone is composed of quartz or feldspar (both silicates) ...
,
siltstone
Siltstone, also known as aleurolite, is a clastic sedimentary rock that is composed mostly of silt. It is a form of mudrock with a low clay mineral content, which can be distinguished from shale by its lack of fissility.Blatt ''et al.'' 1980, p ...
, and
shale
Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...
, that are predominantly red in color due to the presence of
ferric oxide
Iron(III) oxide or ferric oxide is the inorganic compound with the formula Fe2O3. It is one of the three main oxides of iron, the other two being iron(II) oxide (FeO), which is rare; and iron(II,III) oxide (Fe3O4), which also occurs naturally a ...
s. Frequently, these red-colored sedimentary strata locally contain thin beds of
conglomerate,
marl
Marl is an earthy material rich in carbonate minerals, clays, and silt. When hardened into rock, this becomes marlstone. It is formed in marine or freshwater environments, often through the activities of algae.
Marl makes up the lower part o ...
,
limestone
Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
, or some combination of these sedimentary rocks. The ferric oxides, which are responsible for the red color of red beds, typically occur as a coating on the grains of sediments comprising red beds. Classic examples of red beds are the
Permian
The Permian ( ) is a geologic period and stratigraphic system which spans 47 million years from the end of the Carboniferous Period million years ago (Mya), to the beginning of the Triassic Period 251.9 Mya. It is the last period of the Paleoz ...
and
Triassic
The Triassic ( ) is a geologic period and system which spans 50.6 million years from the end of the Permian Period 251.902 million years ago ( Mya), to the beginning of the Jurassic Period 201.36 Mya. The Triassic is the first and shortest period ...
strata of the western United States and the
Devonian
The Devonian ( ) is a geologic period and system of the Paleozoic era, spanning 60.3 million years from the end of the Silurian, million years ago (Mya), to the beginning of the Carboniferous, Mya. It is named after Devon, England, whe ...
Old Red Sandstone
The Old Red Sandstone is an assemblage of rocks in the North Atlantic region largely of Devonian age. It extends in the east across Great Britain, Ireland and Norway, and in the west along the northeastern seaboard of North America. It also exte ...
facies
In geology, a facies ( , ; same pronunciation and spelling in the plural) is a body of rock with specified characteristics, which can be any observable attribute of rocks (such as their overall appearance, composition, or condition of formatio ...
of Europe.
Primary red beds
Primary red beds may be formed by the erosion and redeposition of red soils or older red beds, but a fundamental problem with this hypothesis is the relative scarcity of red-colored source sediments of suitable age close to an area of red-bed sediments in
Cheshire
Cheshire ( ) is a ceremonial and historic county in North West England, bordered by Wales to the west, Merseyside and Greater Manchester to the north, Derbyshire to the east, and Staffordshire and Shropshire to the south. Cheshire's county t ...
, England. Primary red beds may also form by in situ (early
diagenetic
Diagenesis () is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a ...
) reddening of the sediment by the dehydration of brown or drab colored ferric hydroxides. These ferric hydroxides commonly include
goethite
Goethite (, ) is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the "α" polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient t ...
(FeO-OH) and so-called "amorphous ferric hydroxide" or
limonite
Limonite () is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as FeO(OH)·H2O, although this is not entirely accurate as the ratio of oxide to hydroxid ...
. Much of this material may be the mineral
ferrihydrite
Ferrihydrite (Fh) is a widespread hydrous ferric oxyhydroxide mineral at the Earth's surface, and a likely constituent in extraterrestrial materials. It forms in several types of environments, from freshwater to marine systems, aquifers to hydro ...
(Fe
2O
3 H
2O).
This dehydration or "aging" process has been found to be intimately associated with
pedogenesis
Soil formation, also known as pedogenesis, is the process of soil genesis as regulated by the effects of place, environment, and history. Biogeochemical processes act to both create and destroy order (anisotropy) within soils. These alterations l ...
in
alluvial
Alluvium (from Latin ''alluvius'', from ''alluere'' 'to wash against') is loose clay, silt, sand, or gravel that has been deposited by running water in a stream bed, on a floodplain, in an alluvial fan or beach, or in similar settings. Alluv ...
floodplain
A floodplain or flood plain or bottomlands is an area of land adjacent to a river which stretches from the banks of its channel to the base of the enclosing valley walls, and which experiences flooding during periods of high discharge.Goudi ...
s and
desert
A desert is a barren area of landscape where little precipitation occurs and, consequently, living conditions are hostile for plant and animal life. The lack of vegetation exposes the unprotected surface of the ground to denudation. About on ...
environments.
Goethite
Goethite (, ) is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the "α" polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient t ...
(ferric hydroxide) is normally unstable relative to
hematite
Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
and, in the absence of water or at elevated temperature, will readily dehydrate according to the reaction:
:2FeOOH (goethite)→ Fe
2O
3 (hematite) +H
2O
The
Gibbs free energy
In thermodynamics, the Gibbs free energy (or Gibbs energy; symbol G) is a thermodynamic potential that can be used to calculate the maximum amount of work that may be performed by a thermodynamically closed system at constant temperature and pr ...
(G) for the reaction goethite → hematite (at 250 °C) is −2.76 kJ/mol and G becomes increasingly negative with smaller particle size. Thus detrital ferric hydroxides, including goethite and ferrihydrite, will spontaneously transform into red-colored hematite pigment with time. This process not only accounts for the progressive reddening of alluvium but also the fact that older desert dune sands are more intensely reddened than their younger equivalents.
Diagenetic red beds
Red beds may form during
diagenesis
Diagenesis () is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a ...
. The key to this mechanism is the
intrastratal alteration of
ferromagnesian silicates
In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is al ...
by oxygenated
groundwater
Groundwater is the water present beneath Earth's surface in rock and soil pore spaces and in the fractures of rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit of rock or an unconsolidate ...
s during burial. Walker's studies show that the
hydrolysis
Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution reaction, substitution, elimination reaction, elimination, and solvation reactions in which water ...
of
hornblende
Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks ...
and other iron-bearing detritus follows
Goldich dissolution series The Goldich dissolution series is a method of predicting the relative stability or weathering rate of common igneous minerals on the Earth's surface, with minerals that form at higher temperatures and pressures less stable on the surface than minera ...
. This is controlled by the
Gibbs free energy
In thermodynamics, the Gibbs free energy (or Gibbs energy; symbol G) is a thermodynamic potential that can be used to calculate the maximum amount of work that may be performed by a thermodynamically closed system at constant temperature and pr ...
of the particular reaction. For example, the most easily altered material would be
olivine
The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers quickl ...
: e.g.
:Fe
2SiO
4 (fayalite) + O
2 → Fe
2O
3 (hematite) + SiO
2 (quartz) with E = -27.53 kJ/mol
A key feature of this process, and exemplified by the reaction, is the production of a suite of by-products which are precipitated as
authigenic
Authigenesis is the process whereby a mineral or sedimentary rock deposit is generated where it is found or observed. Such deposits are described as authigenic. Authigenic sedimentary minerals form during sedimentation by precipitation or recrys ...
phases. These include mixed layer clays (
illite
Illite is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandwich of silica tetrahedron (T) – alumina ...
–
montmorillonite
Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite group, ...
),
quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
,
potassium feldspar Potassium feldspar refers to a number of minerals in the feldspar group, and containing potassium:
*Orthoclase (endmember formula K Al Si3 O8), an important tectosilicate mineral that forms igneous rock
*Microcline, chemically the same as orthoclas ...
and
carbonates
A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate g ...
as well as the pigmentary
ferric oxide
Iron(III) oxide or ferric oxide is the inorganic compound with the formula Fe2O3. It is one of the three main oxides of iron, the other two being iron(II) oxide (FeO), which is rare; and iron(II,III) oxide (Fe3O4), which also occurs naturally a ...
s. Reddening progresses as the diagenetic alteration becomes more advanced, and is thus a time-dependent mechanism. The other implication is that reddening of this type is not specific to a particular
depositional environment
In geology, depositional environment or sedimentary environment describes the combination of physical, chemical, and biological processes associated with the deposition of a particular type of sediment and, therefore, the rock types that will be ...
. However, the favourable conditions for diagenetic red bed formation i.e. positive
Eh and neutral-alkaline
pH are most commonly found in hot, semi-arid areas, and this is why red beds are traditionally associated with such climates.
Secondary red beds
Secondary red beds are characterized by irregular color zonation, often related to sub-
unconformity
An unconformity is a buried erosional or non-depositional surface separating two rock masses or strata of different ages, indicating that sediment deposition was not continuous. In general, the older layer was exposed to erosion for an interval o ...
weathering
Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement), ...
profiles. The color boundaries may cross-cut lithological contacts and show more intense reddening adjacent to unconformities. Secondary reddening phases might be superimposed on earlier formed primary red beds in the
Carboniferous
The Carboniferous ( ) is a geologic period and system of the Paleozoic that spans 60 million years from the end of the Devonian Period million years ago ( Mya), to the beginning of the Permian Period, million years ago. The name ''Carbonifero ...
of the southern
North Sea
The North Sea lies between Great Britain, Norway, Denmark, Germany, the Netherlands and Belgium. An epeiric sea on the European continental shelf, it connects to the Atlantic Ocean through the English Channel in the south and the Norwegian S ...
. Post-diagenetic alteration may take place through reactions such as
pyrite
The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral.
Pyrite's metallic Luster (mineralogy), lust ...
oxidation:
:3O
2 + 4FeS
2→ Fe
2O
3 (hematite) + 8S E = −789 kJ/mol
and
siderite
Siderite is a mineral composed of iron(II) carbonate (FeCO3). It takes its name from the Greek word σίδηρος ''sideros,'' "iron". It is a valuable iron mineral, since it is 48% iron and contains no sulfur or phosphorus. Zinc, magnesium and ...
oxidation:
:O
2 + 4FeCO
3 → 2Fe
2O
3 (hematite) + 4CO
2 E = −346 kJ/mol
Secondary red beds formed in this way are an excellent example of
telodiagenesis. They are linked to the
uplift
Uplift may refer to: Science
* Geologic uplift, a geological process
** Tectonic uplift, a geological process
* Stellar uplift, the theoretical prospect of moving a stellar mass
* Uplift mountains
* Llano Uplift
* Nemaha Uplift
Business
* Uplif ...
, erosion and surface weathering of previously deposited sediments and require conditions similar to primary and diagenetic red beds for their formation.
See also
*
Red Beds of Texas and Oklahoma
The Red Beds of Texas and Oklahoma are a group of Early Permian-age geologic strata in the southwestern United States cropping out in north-central Texas and south-central Oklahoma. They comprise several stratigraphic Group (stratigraphy), groups i ...
*
Chugwater Formation
The Chugwater Formation is a mapped bedrock unit consisting primarily of red sandstone, in the states of Wyoming, Montana, and Colorado in the United States. It is recognized as a geologic formation in Colorado and Montana, but as a Group (set of ...
*
Red Hills, Kansas
The Red Hills, also referred to as Gypsum Hills, is the name of a physiographic region located mostly in Clark, Comanche and Barber counties in southern and central Kansas. This undulating terrain of red-tinted sediments, a product of the under ...
*
Old Red Sandstone
The Old Red Sandstone is an assemblage of rocks in the North Atlantic region largely of Devonian age. It extends in the east across Great Britain, Ireland and Norway, and in the west along the northeastern seaboard of North America. It also exte ...
*
New Red Sandstone
The New Red Sandstone, chiefly in British geology, is composed of beds of red sandstone and associated rocks laid down throughout the Permian (300 million years ago) to the end of the Triassic (about 200 million years ago), that under ...
References
{{reflist
External links
Pictures of Permo-Triassic red beds in Palo Duro Canyon
Sedimentary rocks