A rechargeable battery, storage battery, or secondary cell (formally a type of energy accumulator), is a type of

electrical battery An electric battery is a source of electric power consisting of one or more electrochemical cells with external connections for powering electrical devices. When a battery is supplying power, its positive terminal is the cathode and its negati ...

which can be charged, discharged into a load, and recharged many times, as opposed to a disposable or

primary battery A primary battery or primary cell is a battery (a galvanic cell) that is designed to be used once and discarded, and not recharged with electricity and reused like a secondary cell (rechargeable battery). In general, the electrochemical reaction ...

, which is supplied fully charged and discarded after use. It is composed of one or more

electrochemical cell An electrochemical cell is a device capable of either generating electrical energy from chemical reactions or using electrical energy to cause chemical reactions. The electrochemical cells which generate an electric current are called voltaic o ...

s. The term "accumulator" is used as it accumulates and stores energy through a reversible

electrochemical Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference, as a measurable and quantitative phenomenon, and identifiable chemical change, with the potential difference as an outco ...

reaction Reaction may refer to a process or to a response to an action, event, or exposure: Physics and chemistry *Chemical reaction *Nuclear reaction *Reaction (physics), as defined by Newton's third law *Chain reaction (disambiguation). Biology and me ...

. Rechargeable batteries are produced in many different shapes and sizes, ranging from button cells to megawatt systems connected to stabilize an electrical distribution network. Several different combinations of

electrode An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit (e.g. a semiconductor, an electrolyte, a vacuum or air). Electrodes are essential parts of batteries that can consist of a variety of materials de ...

material Material is a substance or mixture of substances that constitutes an object. Materials can be pure or impure, living or non-living matter. Materials can be classified on the basis of their physical and chemical properties, or on their geologi ...

s and

electrolyte An electrolyte is a medium containing ions that is electrically conducting through the movement of those ions, but not conducting electrons. This includes most soluble salts, acids, and bases dissolved in a polar solvent, such as water. Upon dis ...

s are used, including lead–acid, zinc–air, nickel–cadmium (NiCd), nickel–metal hydride (NiMH),

lithium-ion A lithium-ion or Li-ion battery is a type of rechargeable battery which uses the reversible reduction of lithium ions to store energy. It is the predominant battery type used in portable consumer electronics and electric vehicles. It also sees ...

(Li-ion),

lithium iron phosphate Lithium iron phosphate or lithium ferro-phosphate (LFP) is an inorganic compound with the formula . It is a gray, red-grey, brown or black solid that is insoluble in water. The material has attracted attention as a component of lithium iron phosp ...

(LiFePO4), and

lithium-ion polymer A lithium polymer battery, or more correctly lithium-ion polymer battery (abbreviated as LiPo, LIP, Li-poly, lithium-poly and others), is a rechargeable battery of lithium-ion battery, lithium-ion technology using a polymer electrolyte instead o ...

(Li-ion polymer). Rechargeable batteries typically initially cost more than disposable batteries, but have a much lower

total cost of ownership Total cost of ownership (TCO) is a financial estimate intended to help buyers and owners determine the direct and indirect costs of a product or service. It is a management accounting concept that can be used in full cost accounting or even ecolog ...

and

environmental impact Environmental issues are effects of human activity on the biophysical environment, most often of which are harmful effects that cause environmental degradation. Environmental protection is the practice of protecting the natural environment on t ...

, as they can be recharged inexpensively many times before they need replacing. Some rechargeable battery types are available in the same

sizes Size in general is the magnitude or dimensions of a thing. More specifically, ''geometrical size'' (or ''spatial size'') can refer to linear dimensions (length, width, height, diameter, perimeter), area, or volume. Size can also be measu ...

and voltages as disposable types, and can be used interchangeably with them. Billions of dollars in research are being invested around the world for improving batteries and industry also focuses on building better batteries.

Applications

Devices which use rechargeable batteries include automobile starters, portable consumer devices, light vehicles (such as motorized wheelchairs,

golf carts A golf cart (alternatively known as a golf buggy or golf car) is a small motorized vehicle designed originally to carry two golfers and their golf clubs around a golf course with less effort than walking. Over time, variants were introduced t ...

electric bicycles An electric bicycle (e-bike, eBike, etc.) is a motorized bicycle with an integrated electric motor used to assist propulsion. Many kinds of e-bikes are available worldwide, but they generally fall into two broad categories: bikes that assist ...

, and electric

forklifts A forklift (also called lift truck, jitney, hi-lo, fork truck, fork hoist, and forklift truck) is a powered industrial truck used to lift and move materials over short distances. The forklift was developed in the early 20th century by various ...

), road vehicles (cars, vans, trucks, motorbikes), trains, small airplanes, tools,

uninterruptible power supplies An uninterruptible power supply or uninterruptible power source (UPS) is an electrical apparatus that provides emergency power to a load when the input power source or mains power fails. A UPS differs from an auxiliary or emergency power system ...

, and

battery storage power station A battery storage power station is a type of energy storage power station that uses a group of batteries to store electrical energy. Battery storage is the fastest responding dispatchable source of power on electric grids, and it is used to sta ...

s. Emerging applications in hybrid internal combustion-battery and

electric vehicles An electric vehicle (EV) is a vehicle that uses one or more electric motors for propulsion. It can be powered by a collector system, with electricity from extravehicular sources, or it can be powered autonomously by a battery (sometimes cha ...

drive the technology to reduce cost, weight, and size, and increase lifetime. Older rechargeable batteries

self-discharge Self-discharge is a phenomenon in batteries in which internal chemical reactions reduce the stored charge of the battery without any connection between the electrodes or any external circuit. Self-discharge decreases the shelf life Shelf life ...

relatively rapidly, and require charging before first use; some newer low self-discharge NiMH batteries hold their charge for many months, and are typically sold factory-charged to about 70% of their rated capacity.

Battery storage power station A battery storage power station is a type of energy storage power station that uses a group of batteries to store electrical energy. Battery storage is the fastest responding dispatchable source of power on electric grids, and it is used to sta ...

s use rechargeable batteries for load-leveling (storing electric energy at times of low demand for use during peak periods) and for

renewable energy Renewable energy is energy that is collected from renewable resources that are naturally replenished on a human timescale. It includes sources such as sunlight, wind, the movement of water, and geothermal heat. Although most renewable energy ...

uses (such as storing power generated from

photovoltaic array A photovoltaic system, also PV system or solar power system, is an electric power system designed to supply usable solar power by means of photovoltaics. It consists of an arrangement of several components, including solar panels to absorb and co ...

s during the day to be used at night). Load-leveling reduces the maximum power which a plant must be able to generate, reducing capital cost and the need for

peaking power plant Peaking power plants, also known as peaker plants, and occasionally just "peakers", are power plants that generally run only when there is a high demand, known as peak demand, for electricity. Because they supply power only occasionally, the power ...

s. According to a report from Research and Markets, the analysts forecast the global rechargeable battery market to grow at a CAGR of 8.32% during the period 2018–2022. Small rechargeable batteries can power portable

electronic device The field of electronics is a branch of physics and electrical engineering that deals with the emission, behaviour and effects of electrons using electronic devices. Electronics uses active devices to control electron flow by amplification ...

s, power tools, appliances, and so on. Heavy-duty batteries power

electric vehicle An electric vehicle (EV) is a vehicle that uses one or more electric motors for propulsion. It can be powered by a collector system, with electricity from extravehicular sources, or it can be powered autonomously by a battery (sometimes cha ...

s, ranging from scooters to

locomotives A locomotive or engine is a rail transport vehicle that provides the motive power for a train. If a locomotive is capable of carrying a payload, it is usually rather referred to as a multiple unit, motor coach, railcar or power car; the u ...

and

ship A ship is a large watercraft that travels the world's oceans and other sufficiently deep waterways, carrying cargo or passengers, or in support of specialized missions, such as defense, research, and fishing. Ships are generally distinguished ...

s. They are used in distributed electricity generation and in stand-alone power systems.

Charging and discharging

During charging, the positive active material is

oxidized Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...

, producing

electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no kn ...

s, and the negative material is reduced, consuming electrons. These electrons constitute the

current Currents, Current or The Current may refer to: Science and technology * Current (fluid), the flow of a liquid or a gas ** Air current, a flow of air ** Ocean current, a current in the ocean *** Rip current, a kind of water current ** Current (stre ...

flow in the external circuit. The

may serve as a simple buffer for internal

ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...

flow between the

s, as in

and nickel-cadmium cells, or it may be an active participant in the

reaction, as in lead–acid cells. The energy used to charge rechargeable batteries usually comes from a

battery charger A battery charger, recharger, or simply charger is a device that stores energy in a battery by running an electric current through it. The charging protocol (how much voltage or current for how long, and what to do when charging is complete) depen ...

using AC

mains electricity Mains electricity or utility power, power grid, domestic power, and wall power, or in some parts of Canada as hydro, is a general-purpose alternating-current (AC) electric power supply. It is the form of electrical power that is delivered to h ...

, although some are equipped to use a vehicle's 12-volt DC power outlet. The voltage of the source must be higher than that of the battery to force current to flow into it, but not too much higher or the battery may be damaged. Chargers take from a few minutes to several hours to charge a battery. Slow "dumb" chargers without voltage or temperature-sensing capabilities will charge at a low rate, typically taking 14 hours or more to reach a full charge. Rapid chargers can typically charge cells in two to five hours, depending on the model, with the fastest taking as little as fifteen minutes. Fast chargers must have multiple ways of detecting when a cell reaches full charge (change in terminal voltage, temperature, etc.) to stop charging before harmful overcharging or overheating occurs. The fastest chargers often incorporate cooling fans to keep the cells from overheating. Battery packs intended for rapid charging may include a temperature sensor that the charger uses to protect the pack; the sensor will have one or more additional electrical contacts. Different battery chemistries require different charging schemes. For example, some battery types can be safely recharged from a constant voltage source. Other types need to be charged with a regulated current source that tapers as the battery reaches fully charged voltage. Charging a battery incorrectly can damage a battery; in extreme cases, batteries can overheat, catch fire, or explosively vent their contents. Charge discharge secondary batterie

Rate of discharge

Battery charging and discharging rates are often discussed by referencing a "C" rate of current. The C rate is that which would theoretically fully charge or discharge the battery in one hour. For example,

trickle charging Trickle charging means charging a fully charged battery at a rate equal to its self-discharge rate, thus enabling the battery to remain at its fully charged level; this state occurs almost exclusively when the battery is not loaded, as trickle char ...

might be performed at C/20 (or a "20-hour" rate), while typical charging and discharging may occur at C/2 (two hours for full capacity). The available capacity of electrochemical cells varies depending on the discharge rate. Some energy is lost in the internal resistance of cell components (plates, electrolyte, interconnections), and the rate of discharge is limited by the speed at which chemicals in the cell can move about. For lead-acid cells, the relationship between time and discharge rate is described by

Peukert's law Peukert's law, presented by the German scientist in 1897, expresses approximately the change in capacity of rechargeable lead–acid batteries at different rates of discharge. As the rate of discharge increases, the battery's available capacity ...

; a lead-acid cell that can no longer sustain a usable terminal voltage at a high current may still have usable capacity, if discharged at a much lower rate. Data sheets for rechargeable cells often list the discharge capacity on 8-hour or 20-hour or other stated time; cells for

uninterruptible power supply An uninterruptible power supply or uninterruptible power source (UPS) is an electrical apparatus that provides emergency power to a load when the input power source or mains power fails. A UPS differs from an auxiliary or emergency power system ...

systems may be rated at 15-minute discharge. The terminal voltage of the battery is not constant during charging and discharging. Some types have relatively constant voltage during discharge over much of their capacity. Non-rechargeable alkaline and zinc–carbon cells output 1.5V when new, but this voltage drops with use. Most NiMH AA and AAA cells are rated at 1.2 V, but have a flatter

discharge curve Discharge may refer to Expel or let go * Discharge, the act of firing a gun * Discharge, or termination of employment, the end of an employee's duration with an employer * Military discharge, the release of a member of the armed forces from serv ...

than alkalines and can usually be used in equipment designed to use

alkaline batteries An alkaline battery (IEC code: L) is a type of primary battery where the electrolyte (most commonly potassium hydroxide) has a pH value above 7. Typically these batteries derive energy from the reaction between zinc metal and manganese dioxi ...

. Battery manufacturers' technical notes often refer to voltage per cell (VPC) for the individual cells that make up the battery. For example, to charge a 12 V lead-acid battery (containing 6 cells of 2 V each) at 2.3 VPC requires a voltage of 13.8 V across the battery's terminals.

Damage from cell reversal

Subjecting a discharged cell to a current in the direction which tends to discharge it further to the point the positive and negative terminals switch polarity causes a condition called '. Generally, pushing current through a discharged cell in this way causes undesirable and irreversible chemical reactions to occur, resulting in permanent damage to the cell. Cell reversal can occur under a number of circumstances, the two most common being: * When a battery or cell is connected to a charging circuit the wrong way around. * When a battery made of several cells connected in series is deeply discharged. In the latter case, the problem occurs due to the different cells in a battery having slightly different capacities. When one cell reaches discharge level ahead of the rest, the remaining cells will force the current through the discharged cell. Many battery-operated devices have a low-voltage cutoff that prevents deep discharges from occurring that might cause cell reversal. A

smart battery A smart battery or a smart battery pack is a rechargeable battery pack with a built-in battery management system (BMS), usually designed for use in a portable computer such as a laptop. In addition to the usual positive and negative terminals, ...

has voltage monitoring circuitry built inside. Cell reversal can occur to a weakly charged cell even before it is fully discharged. If the battery drain current is high enough, the cell's internal resistance can create a resistive voltage drop that is greater than the cell's forward emf. This results in the reversal of the cell's polarity while the current is flowing. The higher the required discharge rate of a battery, the better matched the cells should be, both in the type of cell and state of charge, in order to reduce the chances of cell reversal. In some situations, such as when correcting NiCd batteries that have been previously overcharged, it may be desirable to fully discharge a battery. To avoid damage from the cell reversal effect, it is necessary to access each cell separately: each cell is individually discharged by connecting a load clip across the terminals of each cell, thereby avoiding cell reversal.

Damage during storage in fully discharged state

If a multi-cell battery is fully discharged, it will often be damaged due to the cell reversal effect mentioned above. It is possible however to fully discharge a battery without causing cell reversal—either by discharging each cell separately, or by allowing each cell's internal leakage to dissipate its charge over time. Even if a cell is brought to a fully discharged state without reversal, however, damage may occur over time simply due to remaining in the discharged state. An example of this is the sulfation that occurs in lead-acid batteries that are left sitting on a shelf for long periods. For this reason it is often recommended to charge a battery that is intended to remain in storage, and to maintain its charge level by periodically recharging it. Since damage may also occur if the battery is overcharged, the optimal level of charge during storage is typically around 30% to 70%.

Depth of discharge

Depth of discharge (DOD) is normally stated as a percentage of the nominal ampere-hour capacity; 0% DOD means no discharge. As the usable capacity of a battery system depends on the rate of discharge and the allowable voltage at the end of discharge, the depth of discharge must be qualified to show the way it is to be measured. Due to variations during manufacture and aging, the DOD for complete discharge can change over time or number of

charge cycle A charge cycle is the process of charging a rechargeable battery and discharging it as required into a load. The term is typically used to specify a battery's expected life, as the number of charge cycles affects life more than the mere passage of ...

s. Generally a rechargeable battery system will tolerate more charge/discharge cycles if the DOD is lower on each cycle. Lithium batteries can discharge to about 80 to 90% of their nominal capacity. Lead-acid batteries can discharge to about 50–60%. While flow batteries can discharge 100%.

Lifespan and cycle stability

If batteries are used repeatedly even without mistreatment, they lose capacity as the number of charge cycles increases, until they are eventually considered to have reached the end of their useful life. Different battery systems have differing mechanisms for wearing out. For example, in lead-acid batteries, not all the active material is restored to the plates on each charge/discharge cycle; eventually enough material is lost that the battery capacity is reduced. In lithium-ion types, especially on deep discharge, some reactive lithium metal can be formed on charging, which is no longer available to participate in the next discharge cycle. Sealed batteries may lose moisture from their liquid electrolyte, especially if overcharged or operated at high temperature. This reduces the cycling life.

Recharging time

Recharging time is an important parameter to the user of a product powered by rechargeable batteries. Even if the charging power supply provides enough power to operate the device as well as recharge the battery, the device is attached to an external power supply during the charging time. For electric vehicles used industrially, charging during off-shifts may be acceptable. For highway electric vehicles, rapid charging is necessary for charging in a reasonable time. A rechargeable battery cannot be recharged at an arbitrarily high rate. The internal resistance of the battery will produce heat, and excessive temperature rise will damage or destroy a battery. For some types, the maximum charging rate will be limited by the speed at which active material can diffuse through a liquid electrolyte. High charging rates may produce excess gas in a battery, or may result in damaging side reactions that permanently lower the battery capacity. Very roughly, and with many exceptions and caveats, restoring a battery's full capacity in one hour or less is considered fast charging. A battery charger system will include more complex control-circuit- and charging strategies for fast charging, than for a charger designed for slower recharging.

Active components

The active components in a secondary cell are the chemicals that make up the positive and negative active materials, and the

. The positive and negative

electrodes An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit (e.g. a semiconductor, an electrolyte, a vacuum or air). Electrodes are essential parts of batteries that can consist of a variety of materials de ...

are made up of different materials, with the positive exhibiting a reduction potential and the negative having an

oxidation Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...

potential. The sum of the potentials from these half-reactions is the standard cell potential or

voltage Voltage, also known as electric pressure, electric tension, or (electric) potential difference, is the difference in electric potential between two points. In a static electric field, it corresponds to the work needed per unit of charge to m ...

. In

primary cell A primary battery or primary cell is a battery (a galvanic cell) that is designed to be used once and discarded, and not recharged with electricity and reused like a secondary cell (rechargeable battery). In general, the electrochemical reaction ...

s the positive and negative electrodes are known as the

cathode A cathode is the electrode from which a conventional current leaves a polarized electrical device. This definition can be recalled by using the mnemonic ''CCD'' for ''Cathode Current Departs''. A conventional current describes the direction in whi ...

and

anode An anode is an electrode of a polarized electrical device through which conventional current enters the device. This contrasts with a cathode, an electrode of the device through which conventional current leaves the device. A common mnemonic is ...

, respectively. Although this convention is sometimes carried through to rechargeable systems—especially with

cells, because of their origins in primary lithium cells—this practice can lead to confusion. In rechargeable cells the positive electrode is the cathode on discharge and the anode on charge, and vice versa for the negative electrode.

Types

Commercial types

The

lead–acid battery The lead–acid battery is a type of rechargeable battery first invented in 1859 by French physicist Gaston Planté. It is the first type of rechargeable battery ever created. Compared to modern rechargeable batteries, lead–acid batteries have ...

, invented in 1859 by French physicist

Gaston Planté Gaston Planté (22 April 1834 – 21 May 1889) was a French physicist who invented the lead–acid battery in 1859. This type battery was developed as the first rechargeable electric battery marketed for commercial use and it is widely used in aut ...

, is the oldest type of rechargeable battery. Despite having a very low energy-to-weight ratio and a low energy-to-volume ratio, its ability to supply high

surge current Inrush current, input surge current, or switch-on surge is the maximal instantaneous input current drawn by an electrical device when first turned on. Alternating-current electric motors and transformers may draw several times their normal full-lo ...

s means that the cells have a relatively large

power-to-weight ratio Power-to-weight ratio (PWR, also called specific power, or power-to-mass ratio) is a calculation commonly applied to engines and mobile power sources to enable the comparison of one unit or design to another. Power-to-weight ratio is a measuremen ...

. These features, along with the low cost, makes it attractive for use in motor vehicles to provide the high current required by automobile starter motors. The

nickel–cadmium battery The nickel–cadmium battery (Ni–Cd battery or NiCad battery) is a type of rechargeable battery using nickel oxide hydroxide and metallic cadmium as electrodes. The abbreviation ''Ni-Cd'' is derived from the chemical symbols of nickel (Ni) and ...

(NiCd) was invented by

Waldemar Jungner Ernst Waldemar Jungner (19 June 1869 – 30 August 1924) was a Swedish inventor and engineer. In 1898 he invented the nickel-iron electric storage battery (NiFe), the nickel-cadmium battery (NiCd), and the rechargeable alkaline silver-cadmium ...

of Sweden in 1899. It uses

nickel oxide hydroxide Nickel oxide hydroxide is the inorganic compound with the chemical formula NiO(OH). It is a black solid that is insoluble in all solvents but attacked by base and acid. It is a component of the nickel-metal hydride battery and of the nickel–iro ...

and metallic

cadmium Cadmium is a chemical element with the symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12, zinc and mercury. Like zinc, it demonstrates oxidation state +2 in most of ...

s. Cadmium is a toxic element, and was banned for most uses by the European Union in 2004. Nickel–cadmium batteries have been almost completely superseded by nickel–metal hydride (NiMH) batteries. The

nickel–iron battery The nickel–iron battery (NiFe battery) is a rechargeable battery having nickel(III) oxide-hydroxide positive plates and iron negative plates, with an electrolyte of potassium hydroxide. The active materials are held in nickel-plated steel tub ...

(NiFe) was also developed by Waldemar Jungner in 1899; and commercialized by Thomas Edison in 1901 in the United States for electric vehicles and

railway signalling Railway signalling (), also called railroad signaling (), is a system used to control the movement of railway traffic. Trains move on fixed rails, making them uniquely susceptible to collision. This susceptibility is exacerbated by the enormou ...

. It is composed of only non-toxic elements, unlike many kinds of batteries that contain toxic mercury, cadmium, or lead. The

nickel–metal hydride battery A nickel metal hydride battery (NiMH or Ni–MH) is a type of rechargeable battery. The chemical reaction at the positive electrode is similar to that of the nickel–cadmium cell (NiCd), with both using nickel oxide hydroxide (NiOOH). How ...

(NiMH) became available in 1989. These are now a common consumer and industrial type. The battery has a hydrogen-absorbing

alloy An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, ...

for the negative

instead of

. The

lithium-ion battery A lithium-ion or Li-ion battery is a type of rechargeable battery which uses the reversible reduction of lithium ions to store energy. It is the predominant battery type used in portable consumer electronics and electric vehicles. It also se ...

was introduced in the market in 1991, is the choice in most consumer electronics, having the best

energy density In physics, energy density is the amount of energy stored in a given system or region of space per unit volume. It is sometimes confused with energy per unit mass which is properly called specific energy or . Often only the ''useful'' or extract ...

and a very slow loss of charge when not in use. It does have drawbacks too, particularly the risk of unexpected ignition from the heat generated by the battery. Such incidents are rare and according to experts, they can be minimized "via appropriate design, installation, procedures and layers of safeguards" so the risk is acceptable.

Lithium-ion polymer batteries A lithium polymer battery, or more correctly lithium-ion polymer battery (abbreviated as LiPo, LIP, Li-poly, lithium-poly and others), is a rechargeable battery of lithium-ion technology using a polymer electrolyte instead of a liquid electrol ...

(LiPo) are light in weight, offer slightly higher energy density than Li-ion at slightly higher cost, and can be made in any shape. They are available but have not displaced Li-ion in the market. A primary use is for LiPo batteries is in powering remote-controlled cars, boats and airplanes. LiPo packs are readily available on the consumer market, in various configurations, up to 44.4v, for powering certain R/C vehicles and helicopters or drones. Some test reports warn of the risk of fire when the batteries are not used in accordance with the instructions. Independent reviews of the technology discuss the risk of fire and explosion from Lithium-ion batteries under certain conditions because they use liquid electrolytes.

Other experimental types

‡ citations are needed for these parameters ;Notes * ^a Nominal cell

in V. * ^b

Energy density In physics, energy density is the amount of energy stored in a given system or region of space per unit volume. It is sometimes confused with energy per unit mass which is properly called specific energy or . Often only the ''useful'' or extract ...

= energy/weight or energy/size, given in three different units * ^c

Specific power Power-to-weight ratio (PWR, also called specific power, or power-to-mass ratio) is a calculation commonly applied to engines and mobile power sources to enable the comparison of one unit or design to another. Power-to-weight ratio is a measuremen ...

= power/weight in W/kg * ^e Energy/consumer price in W·h/

US$ The United States dollar (symbol: $; code: USD; also abbreviated US$ or U.S. Dollar, to distinguish it from other dollar-denominated currencies; referred to as the dollar, U.S. dollar, American dollar, or colloquially buck) is the official ...

(approximately) * ^f Self-discharge rate in %/month * ^g Cycle durability in number of cycles * ^h Time durability in years * ⁱ

VRLA A valve regulated lead–acid (VRLA) battery, commonly known as a sealed lead–acid (SLA) battery, is a type of lead–acid battery characterized by a limited amount of electrolyte ("starved" electrolyte) absorbed in a plate separator or formed ...

or recombinant includes

gel batteries A valve regulated lead–acid (VRLA) battery, commonly known as a sealed lead–acid (SLA) battery, is a type of lead–acid battery characterized by a limited amount of electrolyte ("starved" electrolyte) absorbed in a plate separator or formed ...

and absorbed glass mats * ^p Pilot production The

lithium–sulfur battery The lithium–sulfur battery (Li–S battery) is a type of rechargeable battery. It is notable for its high specific energy. The low atomic weight of lithium and moderate atomic weight of sulfur means that Li–S batteries are relatively light ( ...

was developed by Sion Power in 1994. The company claims superior energy density to other lithium technologies. The thin-film battery (TFB) is a refinement of lithium ion technology by Excellatron. The developers claim a large increase in recharge cycles to around 40,000 and higher charge and discharge rates, at least 5 ''C'' charge rate. Sustained 60 ''C'' discharge and 1000''C'' peak discharge rate and a significant increase in specific energy, and energy density.

Lithium iron phosphate battery The lithium iron phosphate battery (LFP (lithium ferro-phosphate), or Li-IP) is a type of lithium-ion battery using lithium iron phosphate () as the cathode material, and a graphitic carbon electrode with a metallic backing as the anode. Becaus ...

is used in some applications.

UltraBattery UltraBattery (commonly sold as Lead-Carbon batteries) is a hybrid energy storage device invented by Australia's Commonwealth Scientific and Industrial Research Organisation (CSIRO). UltraBattery combines ultracapacitor technology with lead-acid ...

, a hybrid lead–acid battery and ultracapacitor invented by Australia's national science organisation

CSIRO The Commonwealth Scientific and Industrial Research Organisation (CSIRO) is an Australian Government The Australian Government, also known as the Commonwealth Government, is the national government of Australia, a federal parliamentar ...

, exhibits tens of thousands of partial state of charge cycles and has outperformed traditional lead-acid, lithium, and NiMH-based cells when compared in testing in this mode against variability management power profiles. UltraBattery has kW and MW-scale installations in place in Australia, Japan, and the U.S.A. It has also been subjected to extensive testing in hybrid electric vehicles and has been shown to last more than 100,000 vehicle miles in on-road commercial testing in a courier vehicle. The technology is claimed to have a lifetime of 7 to 10 times that of conventional lead-acid batteries in high rate partial state-of-charge use, with safety and environmental benefits claimed over competitors like lithium-ion. Its manufacturer suggests an almost 100% recycling rate is already in place for the product. The

potassium-ion battery A potassium-ion battery or K-ion battery (abbreviated as KIB) is a type of battery and analogue to lithium-ion batteries, using potassium ions for charge transfer instead of lithium ions. It was invented by the Iranian/American chemist Ali Eftekhar ...

delivers around a million cycles, due to the extraordinary electrochemical stability of potassium insertion/extraction materials such as

Prussian blue Prussian blue (also known as Berlin blue, Brandenburg blue or, in painting, Parisian or Paris blue) is a dark blue pigment produced by oxidation of ferrous ferrocyanide salts. It has the chemical formula Fe CN)">Cyanide.html" ;"title="e(Cyani ...

. The

sodium-ion battery The sodium-ion battery (NIB or SIB) is a type of rechargeable battery that uses sodium ions (Na+) as its Electric charge, charge carriers. Its Lithium-ion battery#Electrochemistry, working principle and Lithium-ion battery#Design, cell constructio ...

is meant for stationary storage and competes with lead–acid batteries. It aims at a low total cost of ownership per kWh of storage. This is achieved by a long and stable lifetime. The effective number of cycles is above 5000 and the battery is not damaged by deep discharge. The energy density is rather low, somewhat lower than lead–acid.

Alternatives

A rechargeable battery is only one of several types of rechargeable energy storage systems. Several alternatives to rechargeable batteries exist or are under development. For uses such as portable radios, rechargeable batteries may be replaced by clockwork mechanisms which are wound up by hand, driving dynamos, although this system may be used to charge a battery rather than to operate the radio directly.

Flashlight A flashlight ( US, Canada) or torch ( UK, Australia) is a portable hand-held electric lamp. Formerly, the light source typically was a miniature incandescent light bulb, but these have been displaced by light-emitting diodes (LEDs) since the ...

s may be driven by a dynamo directly. For transportation,

systems and laboratories,

flywheel energy storage Flywheel energy storage (FES) works by accelerating a rotor (flywheel) to a very high speed and maintaining the energy in the system as rotational energy. When energy is extracted from the system, the flywheel's rotational speed is reduced as a c ...

systems store energy in a spinning rotor for conversion to electric power when needed; such systems may be used to provide large pulses of power that would otherwise be objectionable on a common electrical grid.

Ultracapacitor A supercapacitor (SC), also called an ultracapacitor, is a high-capacity capacitor, with a capacitance value much higher than other capacitors but with lower voltage limits. It bridges the gap between electrolytic capacitors and rechargeable b ...

s capacitors of extremely high value are also used; an electric screwdriver which charges in 90 seconds and will drive about half as many screws as a device using a rechargeable battery was introduced in 2007, and similar flashlights have been produced. In keeping with the concept of ultracapacitors, betavoltaic batteries may be utilized as a method of providing a trickle-charge to a secondary battery, greatly extending the life and energy capacity of the battery system being employed; this type of arrangement is often referred to as a "hybrid betavoltaic power source" by those in the industry. Ultracapacitors are being developed for transportation, using a large capacitor to store energy instead of the rechargeable battery banks used in

hybrid vehicles A hybrid vehicle is one that uses two or more distinct types of power, such as submarines that use diesel when surfaced and batteries when submerged. Other means to store energy include pressurized fluid in hydraulic hybrids. The basic princip ...

. One drawback of capacitors compared to batteries is that the terminal voltage drops rapidly; a capacitor that has 25% of its initial energy left in it will have one-half of its initial voltage. By contrast, battery systems tend to have a terminal voltage that does not decline rapidly until nearly exhausted. This terminal voltage drop complicates the design of power electronics for use with ultracapacitors. However, there are potential benefits in cycle efficiency, lifetime, and weight compared with rechargeable systems. China started using ultracapacitors on two commercial bus routes in 2006; one of them is route 11 in

Shanghai Shanghai (; , , Standard Mandarin pronunciation: ) is one of the four direct-administered municipalities of the People's Republic of China (PRC). The city is located on the southern estuary of the Yangtze River, with the Huangpu River flow ...

. 超级电容公交车专题 (Super capacitor buses topics)
52Bus.com website, August 2006 (in Chinese, archived page).

Flow batteries A flow battery, or redox flow battery (after reduction–oxidation), is a type of electrochemical cell where chemical energy is provided by two chemical components dissolved in liquids that are pumped through the system on separate sides of a ...

, used for specialized applications, are recharged by replacing the electrolyte liquid. A flow battery can be considered to be a type of rechargeable

fuel cell A fuel cell is an electrochemical cell that converts the chemical energy of a fuel (often hydrogen) and an oxidizing agent (often oxygen) into electricity through a pair of redox reactions. Fuel cells are different from most batteries in requ ...

Research

Rechargeable battery research includes development of new electrochemical systems as well as improving the life span and capacity of current types.