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The iodine pit, also called the iodine hole or xenon pit, is a temporary disabling of a
nuclear reactor A nuclear reactor is a device used to initiate and control a fission nuclear chain reaction or nuclear fusion reactions. Nuclear reactors are used at nuclear power plants for electricity generation and in nuclear marine propulsion. Heat fr ...
due to buildup of short- lived
nuclear poison In applications such as nuclear reactors, a neutron poison (also called a neutron absorber or a nuclear poison) is a substance with a large neutron absorption cross-section. In such applications, absorbing neutrons is normally an undesirable eff ...
s in the
reactor core A nuclear reactor core is the portion of a nuclear reactor containing the nuclear fuel components where the nuclear reactions take place and the heat is generated. Typically, the fuel will be low-enriched uranium contained in thousands of indiv ...
. The main isotope responsible is 135Xe, mainly produced by natural
decay Decay may refer to: Science and technology * Bit decay, in computing * Software decay, in computing * Distance decay, in geography * Decay time (fall time), in electronics Biology * Decomposition of organic matter * Tooth decay (dental caries ...
of 135I. 135I is a weak
neutron absorber In applications such as nuclear reactors, a neutron poison (also called a neutron absorber or a nuclear poison) is a substance with a large neutron absorption cross-section. In such applications, absorbing neutrons is normally an undesirable eff ...
, while 135Xe is the strongest known neutron absorber. When 135Xe builds up in the
fuel rod Nuclear fuel is material used in nuclear power stations to produce heat to power turbines. Heat is created when nuclear fuel undergoes nuclear fission. Most nuclear fuels contain heavy fissile actinide elements that are capable of undergoing ...
s of a reactor, it significantly lowers their reactivity, by absorbing a significant amount of the neutrons that provide the nuclear reaction. The presence of 135I and 135Xe in the reactor is one of the main reasons for its power fluctuations in reaction to change of control rod positions. The buildup of short-lived fission products acting as nuclear poisons is called reactor poisoning, or xenon poisoning. Buildup of stable or long-lived neutron poisons is called reactor slagging.


Fission products decay and burnup

One of the common fission products is 135Te, which undergoes
beta decay In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which a beta particle (fast energetic electron or positron) is emitted from an atomic nucleus, transforming the original nuclide to an isobar of that nuclide. For ...
with
half-life Half-life (symbol ) is the time required for a quantity (of substance) to reduce to half of its initial value. The term is commonly used in nuclear physics to describe how quickly unstable atoms undergo radioactive decay or how long stable at ...
of 19 seconds to 135I. 135I itself is a weak neutron absorber. It builds up in the reactor in the rate proportional to the rate of fission, which is proportional to the reactor thermal power. 135I undergoes beta decay with half-life of 6.57 hours to 135Xe. The yield of 135Xe for uranium fission is 6.3%; about 95% of 135Xe originates from decay of 135I. 135Xe is the most powerful known
neutron absorber In applications such as nuclear reactors, a neutron poison (also called a neutron absorber or a nuclear poison) is a substance with a large neutron absorption cross-section. In such applications, absorbing neutrons is normally an undesirable eff ...
, with a
cross section Cross section may refer to: * Cross section (geometry) ** Cross-sectional views in architecture & engineering 3D *Cross section (geology) * Cross section (electronics) * Radar cross section, measure of detectability * Cross section (physics) **Abs ...
for
thermal neutron The neutron detection temperature, also called the neutron energy, indicates a free neutron's kinetic energy, usually given in electron volts. The term ''temperature'' is used, since hot, thermal and cold neutrons are moderated in a medium wi ...
s of 2.6×106 
barns A barn is an agricultural building usually on farms and used for various purposes. In North America, a barn refers to structures that house livestock, including cattle and horses, as well as equipment and fodder, and often grain.Allen G. ...
, so it acts as a " poison" that can slow or stop the
chain reaction A chain reaction is a sequence of reactions where a reactive product or by-product causes additional reactions to take place. In a chain reaction, positive feedback leads to a self-amplifying chain of events. Chain reactions are one way that sys ...
after a period of operation. This was discovered in the earliest nuclear reactors built by the
Manhattan Project The Manhattan Project was a research and development undertaking during World War II that produced the first nuclear weapons. It was led by the United States with the support of the United Kingdom and Canada. From 1942 to 1946, the project w ...
for
plutonium Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibi ...
production. As a result, the designers made provisions in the design to increase the reactor's reactivity (the number of neutrons per fission that go on to fission other atoms of nuclear fuel). 135Xe reactor poisoning played a major role in the Chernobyl disaster. By
neutron capture Neutron capture is a nuclear reaction in which an atomic nucleus and one or more neutrons collide and merge to form a heavier nucleus. Since neutrons have no electric charge, they can enter a nucleus more easily than positively charged protons, ...
, 135Xe is transformed ("burned") to 136Xe, which is effectively stable and does not significantly absorb neutrons. The burn rate is proportional to the
neutron flux The neutron flux, φ, is a scalar quantity used in nuclear physics and nuclear reactor physics. It is the total length travelled by all free neutrons per unit time and volume. Equivalently, it can be defined as the number of neutrons travellin ...
, which is proportional to the reactor power; a reactor running at twice the power will have twice the xenon burn rate. The production rate is also proportional to reactor power, but due to the half-life time of 135I, this rate depends on the ''average'' power over the past several hours. As a result, a reactor operating at constant power has a fixed steady-state equilibrium concentration, but when ''lowering'' reactor power, the 135Xe concentration can increase enough to effectively shut down the reactor. Without enough neutrons to offset their absorption by 135Xe, nor to burn the built-up xenon, the reactor has to be kept in shutdown state for 1–2 days until enough of the 135Xe decays. 135Xe beta-decays with half-life of 9.2 hours to 135Cs; a poisoned core will spontaneously recover after several half-lives. After about 3 days of shutdown, the core can be assumed to be free of 135Xe, without it introducing errors into the reactivity calculations. The inability of the reactor to be restarted in such state is called xenon precluded start up or dropping into an iodine pit; the duration of this situation is known as xenon dead time, poison outage, or iodine pit depth. Due to the risk of such situations, in the early Soviet nuclear industry, many servicing operations were performed on running reactors, as downtimes longer than an hour led to xenon buildup that could keep the reactor offline for significant time, lower the production of 239Pu, required for nuclear weapons, and would lead to investigations and punishment of the reactor operators.


Xenon-135 oscillations

The interdependence of 135Xe buildup and the neutron flux can lead to periodic power fluctuations. In large reactors, with little neutron flux coupling between their regions, flux nonuniformities can lead to formation of xenon oscillations, periodic local variations of reactor power moving through the core with a period of about 15 hours. A local variation of neutron flux causes increased burnup of 135Xe and production of 135I, depletion of 135Xe increases the reactivity in the core region. The local power density can change by a factor of three or more, while the average power of the reactor stays more or less unchanged. Strong negative
temperature coefficient A temperature coefficient describes the relative change of a physical property that is associated with a given change in temperature. For a property ''R'' that changes when the temperature changes by ''dT'', the temperature coefficient α is def ...
of reactivity causes
damping Damping is an influence within or upon an oscillatory system that has the effect of reducing or preventing its oscillation. In physical systems, damping is produced by processes that dissipate the energy stored in the oscillation. Examples in ...
of these oscillations, and is a desired reactor design feature.


Iodine pit behavior

The reactivity of the reactor after the shutdown first decreases, then increases again, having a shape of a pit; this gave the "iodine pit" its name. The degree of poisoning, and the depth of the pit and the corresponding duration of the outage, depends on the
neutron flux The neutron flux, φ, is a scalar quantity used in nuclear physics and nuclear reactor physics. It is the total length travelled by all free neutrons per unit time and volume. Equivalently, it can be defined as the number of neutrons travellin ...
before the shutdown. Iodine pit behavior is not observed in reactors with neutron flux density below 5×1016 neutrons m−2s−1, as the 135Xe is primarily removed by decay instead of neutron capture. As the core reactivity reserve is usually limited to 10% of Dk/k, thermal power reactors tend to use neutron flux at most about 5×1013 neutrons m−2s−1 to avoid restart problems after shutdown. The concentration changes of 135Xe in the reactor core after its shutdown is determined by the short-term
power history Power History refers to the power of a nuclear reactor over an extended period of time. Power history is important for calculations and operations that involve decay heat and fission product poisons and to avoid the iodine pit The iodine pit, ...
of the reactor (which determines the initial concentrations of 135I and 135Xe), and then by the half-life differences of the isotopes governing the rates of its production and removal; if the activity of 135I is higher than activity of 135Xe, the concentration of 135Xe will rise, and vice versa. During reactor operation at a given power level, a
secular equilibrium In nuclear physics, secular equilibrium is a situation in which the quantity of a radioactive isotope remains constant because its production rate (e.g., due to decay of a parent isotope) is equal to its decay rate. In radioactive decay Secular e ...
is established within 40–50 hours, when the production rate of iodine-135, its decay to xenon-135, and its burning to xenon-136 and decay to caesium-135 are keeping the xenon-135 amount in the reactor constant at a given power level. The equilibrium concentration of 135I is proportional to the neutron flux φ. The equilibrium concentration of 135Xe, however, depends very little on neutron flux for φ > 1017 neutrons m−2s−1. Increase of the reactor power, and the increase of neutron flux, causes a rise in production of 135I and consumption of 135Xe. At first, the concentration of xenon decreases, then slowly increases again to a new equilibrium level as now excess 135I decays. During typical power increases from 50 to 100%, the 135Xe concentration falls for about 3 hours.Xenon decay transient graph
/ref> Decrease of the reactor power lowers production of new 135I, but also lowers the burn rate of 135Xe. For a while 135Xe builds up, governed by the amount of available 135I, then its concentration decreases again to an equilibrium for the given reactor power level. The peak concentration of 135Xe occurs after about 11.1 hours after power decrease, and the equilibrium is reached after about 50 hours. A total shutdown of the reactor is an extreme case of power decrease.


Design precautions

If sufficient reactivity control authority is available, the reactor ''can'' be restarted, but a xenon burn-out transient must be carefully managed. As the control rods are extracted and criticality is reached,
neutron flux The neutron flux, φ, is a scalar quantity used in nuclear physics and nuclear reactor physics. It is the total length travelled by all free neutrons per unit time and volume. Equivalently, it can be defined as the number of neutrons travellin ...
increases many orders of magnitude and the 135Xe begins to absorb neutrons and be transmuted to 136Xe. The reactor ''burns off'' the nuclear poison. As this happens, the reactivity increases and the control rods must be gradually re-inserted or reactor power will increase. The time constant for this burn-off transient depends on the reactor design, power level history of the reactor for the past several days (therefore the 135Xe and 135I concentrations present), and the new power setting. For a typical step up from 50% power to 100% power, 135Xe concentration falls for about 3 hours. The first time 135Xe poisoning of a nuclear reactor occurred was on September 28th, 1944 in Pile 100-B at the Hanford Site. Reactor B was a Plutonium production reactor built by DuPont as part of the Manhattan Project. The reactor was started on September 27th, 1944 but the power dropped unexpectedly shortly after, leading to a complete shutdown on the evening of September 28th. Next morning the reaction restarted by itself. The physicist
John Archibald Wheeler John Archibald Wheeler (July 9, 1911April 13, 2008) was an American theoretical physicist. He was largely responsible for reviving interest in general relativity in the United States after World War II. Wheeler also worked with Niels Bohr in ...
, working for DuPont at the time, together with Enrico Fermi were able to identify that the drop in the neutron flux and the consequent shutdown was caused by the accumulation of 135Xe in the reactor fuel. Fortunately, the reactor was built with spare fuel channels that were then used to increase the normal operating levels of the reactor, thus increasing the burn-up rate of the accumulating 135Xe. Reactors with large physical dimensions, e.g. the
RBMK The RBMK (russian: реактор большой мощности канальный, РБМК; ''reaktor bolshoy moshchnosti kanalnyy'', "high-power channel-type reactor") is a class of graphite-moderated nuclear power reactor designed and buil ...
type, can develop significant nonuniformities of xenon concentration through the core. Control of such non-homogeneously poisoned cores, especially at low power, is a challenging problem. The Chernobyl disaster occurred after recovering Reactor 4 from a nonuniformly poisoned state. The reactor was significantly reduced in preparation for a test, to be followed by a scheduled shutdown. Just before the test, the power plummeted due to the accumulation of 135Xe as a result of the low burn-up rate at low power. Operators withdrew most of the control rods in an attempt to bring the power back up. Unbeknownst to the operators, these and other actions put the reactor in a state where it was exposed to a feedback loop of neutron power and steam production. A flawed shutdown system then caused a power surge that led to the explosion and destruction of reactor 4. The iodine pit effect has to be taken in account for reactor designs. High values of
power density Power density is the amount of power (time rate of energy transfer) per unit volume. In energy transformers including batteries, fuel cells, motors, power supply units etc., power density refers to a volume, where it is often called volum ...
, leading to high production rates of fission products and therefore higher iodine concentrations, require higher amount and enrichment of the nuclear fuel used to compensate. Without this reactivity reserve, a reactor shutdown would preclude its restart for several tens of hours until 135I/135Xe sufficiently decays, especially shortly before replacement of spent fuel (with high
burnup In nuclear power technology, burnup (also known as fuel utilization) is a measure of how much energy is extracted from a primary nuclear fuel source. It is measured as the fraction of fuel atoms that underwent fission in %FIMA (fissions per ini ...
and accumulated
nuclear poison In applications such as nuclear reactors, a neutron poison (also called a neutron absorber or a nuclear poison) is a substance with a large neutron absorption cross-section. In such applications, absorbing neutrons is normally an undesirable eff ...
s) with fresh one. Fluid fuel reactors cannot develop xenon inhomogeneity because the fuel is free to mix. Also, the
Molten Salt Reactor Experiment The Molten-Salt Reactor Experiment (MSRE) was an experimental molten salt reactor research reactor at the Oak Ridge National Laboratory (ORNL). This technology was researched through the 1960s, the reactor was constructed by 1964, it went critic ...
demonstrated that spraying the liquid fuel as droplets through a gas space during recirculation can allow xenon and krypton to leave the fuel salts. Removing 135Xe from neutron exposure also means that the reactor will produce more of the long-lived fission product 135Cs.


References

* {{cite web , author=C.R. Nave , url=http://hyperphysics.phy-astr.gsu.edu/hbase/nucene/xenon.html , title=Xenon Poisoning , work=HyperPhysics , publisher=Georgia State University , accessdate=2013-03-12 * Петунин В. П. Теплоэнергетика ядерных установок. — М.: Атомиздат, 1960. * Левин В. Е. Ядерная физика и ядерные реакторы. ''4-е изд.'' — М.: Атомиздат, 1979. Nuclear technology Neutron poisons Isotopes of xenon Isotopes of iodine