Radioluminescence is the phenomenon by which light is produced in a material by bombardment with ionizing radiation such as

alpha particle Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay, but may also be pr ...

s, beta particles, or

gamma ray A gamma ray, also known as gamma radiation (symbol γ or \gamma), is a penetrating form of electromagnetic radiation arising from the radioactive decay of atomic nuclei. It consists of the shortest wavelength electromagnetic waves, typically ...

s. Radioluminescence is used as a low level light source for night illumination of instruments or signage. Radioluminescent paint is occasionally used for clock hands and instrument dials, enabling them to be read in the dark. Radioluminescence is also sometimes seen around high-power radiation sources, such as

nuclear reactor A nuclear reactor is a device used to initiate and control a fission nuclear chain reaction or nuclear fusion reactions. Nuclear reactors are used at nuclear power plants for electricity generation and in nuclear marine propulsion. Heat fr ...

s and

radioisotopes A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess nuclear energy, making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferr ...

Mechanism

Radioluminescence occurs when an incoming particle of ionizing radiation collides with an atom or molecule, exciting an orbital electron to a higher energy level. The particle usually comes from the radioactive decay of an atom of a

radioisotope A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess nuclear energy, making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferr ...

, an

isotope Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numb ...

of an element which is radioactive. The electron then returns to its ground energy level by emitting the extra energy as a

photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they a ...

of light. A chemical that releases light of a particular color when struck by ionizing radiation is called a phosphor. Radioluminescent light sources usually consist of a radioactive substance mixed with, or in proximity to, a phosphor.

Applications

Since radioactivity was discovered around the turn of the 20th century, the main application of radioluminescence has been in

radioluminescent paint Luminous paint or luminescent paint is paint that exhibits luminescence. In other words, it gives off visible light through fluorescence, phosphorescence, or radioluminescence. There are three types of luminous paints: fluorescent paint, phosp ...

, used on

watch A watch is a portable timepiece intended to be carried or worn by a person. It is designed to keep a consistent movement despite the motions caused by the person's activities. A wristwatch is designed to be worn around the wrist, attached b ...

and

compass A compass is a device that shows the cardinal directions used for navigation and geographic orientation. It commonly consists of a magnetized needle or other element, such as a compass card or compass rose, which can pivot to align itself wit ...

dials, gunsights, aircraft flight instrument faces, and other instruments, to allow them to be seen in the dark. Radioluminescent paint consists of a mixture of a chemical containing a

with a radioluminescent chemical ( phosphor). The continuous radioactive decay of the isotope's atoms releases radiation particles which strike the molecules of the phosphor, causing them to give off light. The constant bombardment by radioactive particles causes the chemical breakdown of many types of phosphor, so radioluminescent paints lose some of their luminosity over their working life. Radioluminescent materials may also be used in the construction of an

optoelectric nuclear battery An optoelectric nuclear battery (also radiophotovoltaic device, radioluminescent nuclear battery or radioisotope photovoltaic generator) is a type of nuclear battery in which nuclear energy is converted into light, which is then used to generate ...

, a type of

radioisotope generator An atomic battery, nuclear battery, radioisotope battery or radioisotope generator is a device which uses energy from the decay of a radioactive isotope to generate electricity. Like nuclear reactors, they generate electricity from nuclear en ...

in which nuclear energy is converted into light.

Radium

The first use of radioluminescence was in luminous paint containing

radium Radium is a chemical element with the symbol Ra and atomic number 88. It is the sixth element in group 2 of the periodic table, also known as the alkaline earth metals. Pure radium is silvery-white, but it readily reacts with nitrogen (rathe ...

, a natural

. Beginning in 1908, luminous paint containing a mixture of

and

copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...

- doped

zinc sulfide Zinc sulfide (or zinc sulphide) is an inorganic compound with the chemical formula of ZnS. This is the main form of zinc found in nature, where it mainly occurs as the mineral sphalerite. Although this mineral is usually black because of various ...

was used to paint watch faces and instrument dials, giving a greenish glow. Phosphors containing

-doped zinc sulfide (ZnS:Cu) yield blue-green light; copper and

manganese Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...

-doped zinc sulfide (), yielding yellow-orange light, are also used. Radium-based luminescent paint is no longer used due to the radiation hazard posed to those manufacturing the dials. These phosphors are not suitable for use in layers thicker than 25 mg/cm², as the self-absorption of the light then becomes a problem. Furthermore, zinc sulfide undergoes degradation of its crystal lattice structure, leading to gradual loss of brightness significantly faster than the depletion of radium. ZnS:Ag coated

spinthariscope A spinthariscope () is a device for observing individual nuclear disintegrations caused by the interaction of ionizing radiation with a phosphor (see radioluminescence) or scintillator. Invention The spinthariscope was invented by William Crook ...

screens were used by

Ernest Rutherford Ernest Rutherford, 1st Baron Rutherford of Nelson, (30 August 1871 – 19 October 1937) was a New Zealand physicist who came to be known as the father of nuclear physics. ''Encyclopædia Britannica'' considers him to be the greatest ...

in his experiments discovering the

atomic nucleus The atomic nucleus is the small, dense region consisting of protons and neutrons at the center of an atom, discovered in 1911 by Ernest Rutherford based on the 1909 Geiger–Marsden gold foil experiment. After the discovery of the neutron ...

. Radium was used in luminous paint until the 1960s, when it was replaced with the other radioisotopes above due to health concerns. In addition to alpha and beta particles, radium emits penetrating

s, which can pass through the metal and glass of a watch dial, and skin. A typical older radium wristwatch dial has a radioactivity of 3–10 kBq and could expose its wearer to an annual dose of 24 millisieverts if worn continuously. Another health hazard is its decay product, the radioactive gas

radon Radon is a chemical element with the symbol Rn and atomic number 86. It is a radioactive, colourless, odourless, tasteless noble gas. It occurs naturally in minute quantities as an intermediate step in the normal radioactive decay chains through ...

, which constitutes a significant risk even at extremely low concentrations when inhaled. Radium's long

half-life Half-life (symbol ) is the time required for a quantity (of substance) to reduce to half of its initial value. The term is commonly used in nuclear physics to describe how quickly unstable atoms undergo radioactive decay or how long stable at ...

of 1600 years means that surfaces coated with radium paint, such as watch faces and hands, remain a health hazard long after their useful life is over. There are still millions of luminous radium clock, watch, and compass faces and aircraft instrument dials owned by the public. The case of the " Radium Girls", workers in watch factories in the early 1920s who painted watch faces with radium paint and later contracted fatal cancer through ingesting radium when they pointed their brushes with their lips, increased public awareness of the hazards of radioluminescent materials, and radioactivity in general.

Promethium

In the second half of the 20th century, radium was progressively replaced with paint containing promethium-147. Promethium is a low-energy beta-emitter, which, unlike alpha emitters like radium, does not degrade the phosphor lattice, so the luminosity of the material will not degrade so quickly. It also does not emit the penetrating

s which radium does. The half-life of ¹⁴⁷Pm is only 2.62 years, so in a decade the radioactivity of a promethium dial will decline to only 1/16 of its original value, making it safer to dispose of, compared to radium with its half life of 1600 years. However, this short half-life meant that the luminosity of promethium dials also dropped by half every 2.62 years, giving them a short useful life, which led to promethium's replacement by tritium. Promethium-based paint was used to illuminate Apollo Lunar Module electrical switch tips and painted on control panels of the Lunar Roving Vehicle.

Tritium

The latest generation of radioluminescent materials is based on

tritium Tritium ( or , ) or hydrogen-3 (symbol T or H) is a rare and radioactive isotope of hydrogen with half-life about 12 years. The nucleus of tritium (t, sometimes called a ''triton'') contains one proton and two neutrons, whereas the nucleus of ...

, a radioactive isotope of

hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...

with half-life of 12.32 years that emits very low-energy beta radiation. It is used on

wristwatch A watch is a portable timepiece intended to be carried or worn by a person. It is designed to keep a consistent movement despite the motions caused by the person's activities. A wristwatch is designed to be worn around the wrist, attached by ...

faces, gun sights, and emergency exit signs. The tritium gas is contained in a small glass tube, coated with a phosphor on the inside.

Beta particles A beta particle, also called beta ray or beta radiation (symbol β), is a high-energy, high-speed electron or positron emitted by the radioactive decay of an atomic nucleus during the process of beta decay. There are two forms of beta decay, β ...

emitted by the tritium strike the phosphor coating and cause it to

fluoresce Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, tha ...

, emitting light, usually yellow-green. Tritium is used because it is believed to pose a negligible threat to human health, in contrast to the previous radioluminescent source, radium, which proved to be a significant radiological hazard. The low-energy 5.7 keV beta particles emitted by tritium cannot pass through the enclosing glass tube. Even if they could, they are not able to penetrate human skin. Tritium is only a health threat if ingested. Since tritium is a gas, if a tritium tube breaks, the gas dissipates in the air and is diluted to safe concentrations. Tritium has a half-life of 12.32 years, so the brightness of a tritium light source will decline to half its initial value in that time.

Infrared radiofluorescence

Infrared radiofluorescence (sometimes spelt radio-fluorescence) is a

dating Dating is a stage of romantic relationships in which two individuals engage in an activity together, most often with the intention of evaluating each other's suitability as a partner in a future intimate relationship. It falls into the categor ...

technique involving the

infrared Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from around ...

(~ 880 nm) luminescence signal of

orthoclase Orthoclase, or orthoclase feldspar ( endmember formula K Al Si3 O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture," because its two cleavage planes are at right angles ...

from exposure to ionizing radiation. It can reveal the last time of daylight exposure of sediments, e.g., a layer of sand exposed to light before deposition.

References

{{Reflist Luminescence