Radiative Cooling
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In the study of
heat transfer Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy (heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, ...
, radiative cooling is the process by which a body loses
heat In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is al ...
by
thermal radiation Thermal radiation is electromagnetic radiation generated by the thermal motion of particles in matter. Thermal radiation is generated when heat from the movement of charges in the material (electrons and protons in common forms of matter) is ...
. As Planck's law describes, every
physical body In common usage and classical mechanics, a physical object or physical body (or simply an object or body) is a collection of matter within a defined contiguous boundary in three-dimensional space. The boundary must be defined and identified by t ...
spontaneously and continuously emits
electromagnetic radiation In physics, electromagnetic radiation (EMR) consists of waves of the electromagnetic field, electromagnetic (EM) field, which propagate through space and carry momentum and electromagnetic radiant energy. It includes radio waves, microwaves, inf ...
. Radiative cooling has been applied in various contexts throughout human history, including ice making in
India India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the seventh-largest country by area, the second-most populous country, and the most populous democracy in the world. Bounded by the Indian Ocean on the so ...
and
Iran Iran, officially the Islamic Republic of Iran, and also called Persia, is a country located in Western Asia. It is bordered by Iraq and Turkey to the west, by Azerbaijan and Armenia to the northwest, by the Caspian Sea and Turkmeni ...
,
heat shields In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is ...
for spacecrafts, and in architecture. In 2014, a scientific breakthrough in the use of
photonic metamaterials A photonic metamaterial (PM), also known as an optical metamaterial, is a type of electromagnetic metamaterial, that interacts with light, covering terahertz ( THz), infrared (IR) or visible wavelengths. The materials employ a periodic, cellul ...
made daytime radiative cooling possible. It has since been proposed as a strategy to mitigate local and
global warming In common usage, climate change describes global warming—the ongoing increase in global average temperature—and its effects on Earth's climate system. Climate change in a broader sense also includes previous long-term changes to E ...
caused by
greenhouse gas emissions Greenhouse gas emissions from human activities strengthen the greenhouse effect, contributing to climate change. Most is carbon dioxide from burning fossil fuels: coal, oil, and natural gas. The largest emitters include coal in China and lar ...
known as
passive daytime radiative cooling Passive daytime radiative cooling (PDRC) is a renewable cooling method proposed as a solution to global warming of enhancing terrestrial heat flow to outer space through the installation of thermally-emissive surfaces on Earth that require zer ...
.


Terrestrial radiative cooling


Mechanism

Infrared radiation can pass through dry, clear air in the wavelength range of 8–13 µm. Materials that can absorb energy and radiate it in those wavelengths exhibit a strong cooling effect. Materials that can also reflect 95% or more of sunlight in the 200 nanometres to 2.5 µm range can exhibit cooling even in direct sunlight.


Earth's energy budget

The Earth-atmosphere system uses radiative cooling to emit long-wave (
infrared Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from around ...
) radiation to balance the absorption of short-wave (visible light) energy from the sun. Convective transport of heat, and evaporative transport of latent heat are both important in removing heat from the surface and distributing it in the atmosphere. Pure radiative transport is more important higher up in the atmosphere. Diurnal and geographical variation further complicate the picture. The large-scale circulation of the
Earth's atmosphere The atmosphere of Earth is the layer of gases, known collectively as air, retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth protects life on Earth by creating pressure allowing for ...
is driven by the difference in absorbed solar radiation per square meter, as the sun heats the Earth more in the
Tropics The tropics are the regions of Earth surrounding the Equator. They are defined in latitude by the Tropic of Cancer in the Northern Hemisphere at N and the Tropic of Capricorn in the Southern Hemisphere at S. The tropics are also referred to ...
, mostly because of geometrical factors. The atmospheric and oceanic circulation redistributes some of this energy as
sensible heat Sensible heat is heat exchanged by a body or thermodynamic system in which the exchange of heat changes the temperature of the body or system, and some macroscopic variables of the body or system, but leaves unchanged certain other macroscopic vari ...
and
latent heat Latent heat (also known as latent energy or heat of transformation) is energy released or absorbed, by a body or a thermodynamic system, during a constant-temperature process — usually a first-order phase transition. Latent heat can be underst ...
partly via the mean flow and partly via eddies, known as
cyclone In meteorology, a cyclone () is a large air mass that rotates around a strong center of low atmospheric pressure, counterclockwise in the Northern Hemisphere and clockwise in the Southern Hemisphere as viewed from above (opposite to an anti ...
s in the atmosphere. Thus the tropics radiate less to space than they would if there were no circulation, and the poles radiate more; however in absolute terms the tropics radiate more energy to space.


Nocturnal surface cooling

Radiative cooling is commonly experienced on cloudless nights, when heat is radiated into space from the surface of the Earth, or from the skin of a human observer. The effect is well-known among
amateur astronomers Amateur astronomy is a hobby where participants enjoy observing or imaging celestial objects in the sky using the unaided eye, binoculars, or telescopes. Even though scientific research may not be their primary goal, some amateur astronomer ...
. The effect can be experienced by comparing skin temperature from looking straight up into a cloudless night sky for several seconds, to that after placing a sheet of paper between the face and the sky. Since outer space radiates at about a temperature of 3
kelvin The kelvin, symbol K, is the primary unit of temperature in the International System of Units (SI), used alongside its prefixed forms and the degree Celsius. It is named after the Belfast-born and University of Glasgow-based engineer and phys ...
s (−270
degrees Celsius The degree Celsius is the unit of temperature on the Celsius scale (originally known as the centigrade scale outside Sweden), one of two temperature scales used in the International System of Units (SI), the other being the Kelvin scale. The ...
or −450
degrees Fahrenheit The Fahrenheit scale () is a temperature scale based on one proposed in 1724 by the physicist Daniel Gabriel Fahrenheit (1686–1736). It uses the degree Fahrenheit (symbol: °F) as the unit. Several accounts of how he originally defined his ...
), and the sheet of paper radiates at about 300 kelvins (room temperature), the sheet of paper radiates more
heat In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is al ...
to the face than does the darkened cosmos. The effect is blunted by Earth's surrounding atmosphere, and particularly the water vapor it contains, so the apparent temperature of the sky is far warmer than outer space. The sheet does not block the cold; instead, the sheet reflects heat to the face and radiates the heat of the face that it just absorbed. The same radiative cooling mechanism can cause
frost Frost is a thin layer of ice on a solid surface, which forms from water vapor in an above-freezing atmosphere coming in contact with a solid surface whose temperature is below freezing, and resulting in a phase change from water vapor (a gas) ...
or
black ice Black ice, sometimes called clear ice, is a thin coating of glaze ice on a surface, especially on streets. The ice itself is not black, but visually transparent, allowing the often black road below to be seen through it. The typically low level ...
to form on surfaces exposed to the clear night sky, even when the
ambient temperature Colloquially, "room temperature" is a range of air temperatures that most people prefer for indoor settings. It feels comfortable to a person when they are wearing typical indoor clothing. Human comfort can extend beyond this range depending on ...
does not fall below freezing.


Kelvin's estimate of the Earth's age

The term radiative cooling is generally used for local processes, though the same principles apply to cooling over geological time, which was first used by Kelvin to estimate the age of the Earth (although his estimate ignored the substantial heat released by radioisotope decay, not known at the time, and the effects of convection in the mantle).


Astronomy

Radiative cooling is one of the few ways an object in space can give off energy. In particular,
white dwarf A white dwarf is a stellar core remnant composed mostly of electron-degenerate matter. A white dwarf is very dense: its mass is comparable to the Sun's, while its volume is comparable to the Earth's. A white dwarf's faint luminosity comes ...
stars are no longer generating energy by fusion or gravitational contraction, and have no solar wind. So the only way their temperature changes is by radiative cooling. This makes their temperature as a function of age very predictable, so by observing the temperature, astronomers can deduce the age of the star.


Applications


Climate change

The widespread application of
passive daytime radiative cooling Passive daytime radiative cooling (PDRC) is a renewable cooling method proposed as a solution to global warming of enhancing terrestrial heat flow to outer space through the installation of thermally-emissive surfaces on Earth that require zer ...
(PDRC) technologies that use the
infrared window The infrared atmospheric window refers to a region of the Infrared spectrum where there is relatively little absorption of terrestrial thermal radiation by atmospheric gases. The window plays an important role in the atmospheric greenhouse effec ...
(8–13 µm) to dissipate heat through longwave infrared (LWIR)
thermal radiation Thermal radiation is electromagnetic radiation generated by the thermal motion of particles in matter. Thermal radiation is generated when heat from the movement of charges in the material (electrons and protons in common forms of matter) is ...
heat transfer Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy (heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, ...
with
outer space Outer space, commonly shortened to space, is the expanse that exists beyond Earth and its atmosphere and between celestial bodies. Outer space is not completely empty—it is a near-perfect vacuum containing a low density of particles, pred ...
, has been proposed as a method of reducing temperature increases caused by
climate change In common usage, climate change describes global warming—the ongoing increase in global average temperature—and its effects on Earth's climate system. Climate change in a broader sense also includes previous long-term changes to E ...
. The installation of passive radiative heat emission technologies has been proposed as necessary to lower the temperature of Earth at a fast enough rate for human
survivability Survivability is the ability to remain alive or continue to exist. The term has more specific meaning in certain contexts. Ecological Following disruptive forces such as flood, fire, disease, war, or climate change some species of flora, fauna, ...
. Munday summarized the global implementation of such technologies:
Currently the Earth is absorbing ∼1 W/m2 more than it is emitting, which leads to an overall warming of the climate. By covering the Earth with a small fraction of thermally emitting materials, the heat flow away from the Earth can be increased, and the net radiative flux can be reduced to zero (or even made negative), thus stabilizing (or cooling) the Earth (...) If only 1%–2% of the Earth’s surface were instead made to radiate at this rate rather than its current average value, the total heat fluxes into and away from the entire Earth would be balanced and warming would cease.
PDRCs mimic the natural process of radiative cooling, in which the Earth cools itself by releasing heat to outer space (
Earth's energy budget Earth's energy budget accounts for the balance between the energy that Earth receives from the Sun and the energy the Earth loses back into outer space. Smaller energy sources, such as Earth's internal heat, are taken into consideration, but m ...
), although during the daytime, lowering ambient temperatures under direct solar intensity. On a clear day, solar irradiance can reach 1000 W/m2 with a diffuse component between 50-100 W/m2. The average PDRC has an estimated cooling power of ~100-150 W/m2. The cooling power of PDRCs is proportional to the exposed surface area of the installation.


Architecture

Cool roof Reflective surfaces or ground-based albedo modification (GBAM) is a solar radiation management method of enhancing the Earth's albedo (the ability to reflect the visible, infrared and ultraviolet wavelengths of the sun, reducing heat transfer to ...
s combine high solar reflectance with high infrared emittance, thereby simultaneously reducing heat gain from the sun and increasing heat removal through radiation. Radiative cooling thus offers potential for passive cooling for residential and commercial buildings. Traditional building surfaces, such as paint coatings, brick and concrete have high emittances of up to 0.96. They radiate heat into the sky to passively cool buildings at night. If made sufficiently reflective to sunlight, these materials can also achieve radiative cooling during the day. The most common radiative coolers found on buildings are white cool-roof paint coatings, which have solar reflectances of up to 0.94, and thermal emittances of up to 0.96. The solar reflectance of the paints arises from optical scattering by the dielectric pigments embedded in the polymer paint resin, while the thermal emittance arises from the polymer resin. However, because typical white pigments like titanium dioxide and zinc oxide absorb ultraviolet radiation, the solar reflectances of paints based on such pigments do not exceed 0.95. In 2014, researchers developed the first daytime radiative cooler using a multi-layer thermal photonic structure that selectively emits long wavelength infrared radiation into space, and can achieve 5 °C sub-ambient cooling under direct sunlight. Later researchers developed paintable porous polymer coatings, whose pores scatter sunlight to give solar reflectance of 0.96-0.99 and thermal emittance of 0.97. In experiments under direct sunlight, the coatings achieve 6 °C sub-ambient temperatures and cooling powers of 96 W/m2. Other notable radiative cooling strategies include dielectric films on metal mirrors, and polymer or polymer composites on silver or aluminum films. Silvered polymer films with solar reflectances of 0.97 and thermal emittance of 0.96, which remain 11 °C cooler than commercial white paints under the mid-summer sun, were reported in 2015. Researchers explored designs with dielectric
silicon dioxide Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
or
silicon carbide Silicon carbide (SiC), also known as carborundum (), is a hard chemical compound containing silicon and carbon. A semiconductor, it occurs in nature as the extremely rare mineral moissanite, but has been mass-produced as a powder and crystal sin ...
particles embedded in polymers that are translucent in the solar wavelengths and emissive in the infrared. In 2017, an example of this design with resonant polar silica microspheres randomly embedded in a polymeric matrix, was reported. The material is translucent to sunlight and has infrared
emissivity The emissivity of the surface of a material is its effectiveness in emitting energy as thermal radiation. Thermal radiation is electromagnetic radiation that most commonly includes both visible radiation (light) and infrared radiation, which is n ...
of 0.93 in the infrared atmospheric transmission window. When backed with silver coating, the material achieved a midday radiative cooling power of 93 W/m2 under direct sunshine along with high-throughput, economical roll-to-roll manufacturing.


Heat shields

High emissivity coatings that facilitate radiative cooling may be used in reusable thermal protection systems (RTPS) in spacecraft and
hypersonic In aerodynamics, a hypersonic speed is one that exceeds 5 times the speed of sound, often stated as starting at speeds of Mach 5 and above. The precise Mach number at which a craft can be said to be flying at hypersonic speed varies, since in ...
aircraft. In such heat shields a high emissivity material, such as
molybdenum disilicide Molybdenum disilicide (MoSi2, or molybdenum silicide), an intermetallic compound, a silicide of molybdenum, is a refractory ceramic with primary use in heating elements. It has moderate density, melting point 2030 °C, and is electrically co ...
(MoSi2) is applied on a thermally insulating ceramic substrate. In such heat shields high levels of total
emissivity The emissivity of the surface of a material is its effectiveness in emitting energy as thermal radiation. Thermal radiation is electromagnetic radiation that most commonly includes both visible radiation (light) and infrared radiation, which is n ...
, typically in the range 0.8 - 0.9, need to be maintained across a range of high temperatures. Planck's law dictates that at higher temperatures the radiative emission peak shifts to lower wavelengths (higher frequencies), influencing material selection as a function of operating temperature. In addition to effective radiative cooling, radiative thermal protection systems should provide damage tolerance and may incorporate self-healing functions through the formation of a viscous glass at high temperatures.


James Webb Space Telescope

The James Webb Space Telescope uses radiative cooling to reach its operation temperature of about 50 degrees K. To do this, its large reflective sunshield blocks radiation from the Sun, Earth, and Moon. The telescope structure, kept permanently in shadow by the sunshield, then cools by radiation.


Nocturnal ice making in early India and Iran

Before the invention of artificial refrigeration technology, ice making by nocturnal cooling was common in both India and Iran. Such apparatus consisted of a shallow ceramic tray with a thin layer of water, placed outdoors with a clear exposure to the night sky. The bottom and sides were insulated with a thick layer of hay. On a clear night the water would lose heat by radiation upwards. Provided the air was calm and not too far above freezing, heat gain from the surrounding air by
convection Convection is single or multiphase fluid flow that occurs spontaneously due to the combined effects of material property heterogeneity and body forces on a fluid, most commonly density and gravity (see buoyancy). When the cause of the convec ...
was low enough to allow the water to freeze.


See also

* Heat shield * Optical solar reflector, used for thermal control of spacecraft * Passive cooling *
Radiative forcing Radiative forcing (or climate forcing) is the change in energy flux in the atmosphere caused by natural or anthropogenic factors of climate change as measured by watts / metre2. It is a scientific concept used to quantify and compare the extern ...
*
Stefan–Boltzmann law The Stefan–Boltzmann law describes the power radiated from a black body in terms of its temperature. Specifically, the Stefan–Boltzmann law states that the total energy radiated per unit surface area of a black body across all wavelengths ...
* Terrestrial albedo effect *
Urban heat island An urban heat island (UHI) is an urban or metropolitan area that is significantly warmer than its surrounding rural areas due to human activities. The temperature difference is usually larger at night than during the day, and is most apparen ...
* Urban thermal plume


References

{{DEFAULTSORT:Radiative Cooling Thermodynamics Atmospheric radiation