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Rachid Yazami is a Moroccan scientist, engineer, and inventor. He is best known for his critical role in the development of the
graphite Graphite () is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on lar ...
anode An anode is an electrode of a polarized electrical device through which conventional current enters the device. This contrasts with a cathode, an electrode of the device through which conventional current leaves the device. A common mnemonic ...
(negative pole) for lithium-ion batteries and his research on fluoride ion batteries.


Education

Yazami graduated from the
Grenoble Institute of Technology The Grenoble Institute of Technology (Grenoble INP) (''Institut polytechnique de Grenoble'', ''Groupe Grenoble INP'' and before INPG) is a French technological university system consisting of eight engineering and management schools. Grenoble INP ...
in 1978. He also received a PhD. degree in 1985.


Battery research

Yazami's research project included a study of
graphite intercalation compound Graphite intercalation compounds are complex materials having a formula where the ion or is inserted ( intercalated) between the oppositely charged carbon layers. Typically ''m'' is much less than 1. These materials are deeply colored solids t ...
s for lithium battery applications. In 1985, he joined the
French National Centre for Scientific Research The French National Centre for Scientific Research (french: link=no, Centre national de la recherche scientifique, CNRS) is the French state research organisation and is the largest fundamental science agency in Europe. In 2016, it employed 31,63 ...
(CNRS) as a research associate. He was later promoted to the position of research director and professor in 1998. In 1980, Yazami was the first scientist to establish the reversible intercalation of
lithium Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid ...
into graphite in an
electrochemical Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference, as a measurable and quantitative phenomenon, and identifiable chemical change, with the potential difference as an outc ...
cell using a polymer electrolyte. Eventually, his discovery led to the lithium-graphite
anode An anode is an electrode of a polarized electrical device through which conventional current enters the device. This contrasts with a cathode, an electrode of the device through which conventional current leaves the device. A common mnemonic ...
which is now used in commercial lithium-ion batteries, a product with over $80 billion in market value. Yazami also worked on other forms of graphite materials for
cathode A cathode is the electrode from which a conventional current leaves a polarized electrical device. This definition can be recalled by using the mnemonic ''CCD'' for ''Cathode Current Departs''. A conventional current describes the direction in wh ...
applications in lithium batteries, including
graphite oxide Graphite oxide (GO), formerly called graphitic oxide or graphitic acid, is a compound of carbon, oxygen, and hydrogen in variable ratios, obtained by treating graphite with strong oxidizers and acids for resolving of extra metals. The maximally o ...
and
graphite fluoride Carbon monofluoride (CF, CFx, or (CF)n), also called polycarbon monofluoride (PMF), polycarbon fluoride, poly(carbon monofluoride), and graphite fluoride, is a material formed by high-temperature reaction of fluorine gas with graphite, charcoal ...
. In 2007, he founded a start-up company in California to develop and commercialize his patented discoveries, particularly on fluoride ion batteries (FIBs). While holding a research director position with the CNRS in France, Yazami served as a visiting associate at the
California Institute of Technology The California Institute of Technology (branded as Caltech or CIT)The university itself only spells its short form as "Caltech"; the institution considers other spellings such a"Cal Tech" and "CalTech" incorrect. The institute is also occasional ...
between 2000 and 2010. There, he conducted cooperative research on electrode materials, including
nanostructure A nanostructure is a structure of intermediate size between microscopic and molecular structures. Nanostructural detail is microstructure at nanoscale. In describing nanostructures, it is necessary to differentiate between the number of dimens ...
d materials like carbon nanotubes, nano-silicon, and nano-germanium anodes. His research on cathode materials included
thermodynamics Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of th ...
studies of phase transitions in lithiated transition metal oxides and phosphates. He also developed a new electrochemical technique based on thermodynamics measurements (ETM), which can be applied to assessing a battery's state of charge, state of health, and state of safety. Entropymetery applications include battery life extension owing to adaptive (smart) battery charging protocols and battery safety enhancement. In 2010, Yazami was appointed a Nanyang Visiting Professor. He was promoted in 2012 to the Cheng Tsang Man Chair Professor in Energy at the School of Materials Science and Engineering of the Nanyang Technological University (NTU) in Singapore. He served as the Director of Battery Programs at the Energy Research Institute (ERIAN) and as a Co-Principal Investigator in TUM Create Center of Electromobility lab. until 2017-18. While in Singapore, Yazami co-authored over 200 publications in peer-reviewed journals, in proceedings of international meetings, and as book chapters. He is the inventor involved in close to 180 patents according to the
WIPO The World Intellectual Property Organization (WIPO; french: link=no, Organisation mondiale de la propriété intellectuelle (OMPI)) is one of the 15 specialized agencies of the United Nations (UN). Pursuant to the 1967 Convention Establishin ...
site. From his recent experimental work, Yazami theorized that in a sealed rechargeable battery cell (closed system), such as a lithium-ion battery, two different states of charge of the battery cannot simultaneously share the same entropy and the same enthalpy values, a statement referred to as the "Yazami's Battery Theorem." The theorem can be expressed as: (∆S(x1)=∆S(x2)) and (∆H(x1)=∆H(x2))⇔ x1=x2 , where x1, x2 are two states of charge, ∆S= entropy, ∆H= enthalpy In fact, Yazami established a more universal (empirical) law that applies to primary and rechargeable batteries, that is the state of charge is a linear function of entropy and enthalpy. SOC=α+β∆S+γ∆H, in which α, β and γ coefficients depend on the cell' chemistry and state of health. This equation is reminiscent of
Gibbs free energy In thermodynamics, the Gibbs free energy (or Gibbs energy; symbol G) is a thermodynamic potential that can be used to calculate the maximum amount of work that may be performed by a thermodynamically closed system at constant temperature and ...
. Yazami also developed a new method based on entropymetry to detect an early stage of an internal short circuit within a battery cell, therefore making batteries safer. An internal short is the main root cause of a battery undergoing a thermal runaway involving fume, fire and explosion. More recently, Yazami invented a new method enabling ultra-fast charging (UFC) lithium ion batteries in 10 minutes and below. The method was coined by him as "Non-linear voltammetry" (NLV). UFC is critical for rapid deployment of electric vehicles.


Awards and writing

Yazami is the co-author involved in over 250 published papers and the co-inventor of about 160 patents related to lithium primary and rechargeable batteries and on new battery chemistry based on fluoride ion. He served as the President of the International Battery Association (IBA) and as a Member of the International Scientific Advisory Board of several international meetings, including the International Meetings on Lithium Batteries (IMLB). Yazami is the recipient of several research awards, including NATO (Science for Peace Award), NASA (two Technical Innovation Awards), IBA (Research Award), and the Hawaii Battery Conference. He is the main Founder of CFX Battery, Inc. (now Contour Energy Systems, Inc.) a Caltech-CNRS start-up company in Azusa, California and of KVI PTE LTD in Singapore. Yazami is the winner of 2012 Institute of Electrical and Electronics Engineers
IEEE Medal for Environmental and Safety Technologies The Institute of Electrical and Electronics Engineers (IEEE) is a 501(c)(3) professional association for electronic engineering and electrical engineering (and associated disciplines) with its corporate office in New York City and its operati ...
. In 2014, Rachid Yazami,
John Goodenough John Bannister Goodenough ( ; born July 25, 1922) is an American materials scientist, a solid-state physicist, and a Nobel laureate in chemistry. He is a professor of Mechanical, Materials Science, and Electrical Engineering at the University ...
, Yoshio Nishi, and
Akira Yoshino is a Japanese chemist. He is a fellow of Asahi Kasei Corporation and a professor at Meijo University in Nagoya. He created the first safe, production-viable lithium-ion battery which became used widely in cellular phones and notebook computer ...
were awarded the
Draper Prize The U.S. National Academy of Engineering annually awards the Draper Prize, which is given for the advancement of engineering and the education of the public about engineering. It is one of three prizes that constitute the "Nobel Prizes of Enginee ...
by The
National Academy of Engineering The National Academy of Engineering (NAE) is an American nonprofit, non-governmental organization. The National Academy of Engineering is part of the National Academies of Sciences, Engineering, and Medicine, along with the National Academy of ...
for pioneering and leading the groundwork for today’s lithium-ion battery. The prize, which was then in its 25th year, includes a $500,000 award. That same year, Yazami was a finalist of the Global Energy Award (Russia, 2014). In September 2014, Rachid Yazami was appointed by HM the King of Morocco a Corresponding Member of the Hassan II Academy of Sciences and Technologies of Morocco. Yazami received the Royal Medal (Wissam Malaki) of Intellectual Competency from HM the King of Morocco Mohamed VI, during Throne Day on 30 July 2014. In March 2016, Rachid Yazami received an award as a finalist of the Marius Lavet Prize of Inventing-Engineers in Paris, France. On 14 July 2016 Yazami was awarded the title of Chevalier de la Legion of honor of France. In March 2017, he received the Honors Award of the Moroccans of the World. In November 2018, Yazami was the recipient of the Takreem Award for Science and Technological Achievement considered as the Arab Scientist of the year. In September 2019, Yazami received the Arab Investor Award in the “Green Application” category. In February 2020, Yazami won the Mohammed bin Rashid Medal for Scientific Excellence in the UAE. In 2020 Yazami was offered the position of visiting professor at the Private University of Fes (Morocco) In 2021 Yazami was appointed a member of the New Energy Council of Reliance Industries Limited, India In 2021 Yazami was appointed President of the Scientific Board of the Moroccan Institute of Advanced Studies. In February 2022, Yazami was appointed a visiting scholar in chemistry at the California Institute of Technology.


Nobel Prize omission

In October 2019, his co-invention of the lithium-ion battery was honored with the 2019
Nobel Prize in Chemistry ) , image = Nobel Prize.png , alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then "M ...
. However, Yazami himself was omitted from the award, which was instead given to Stanley Whittingham, John Goodenough, and Akira Yoshino. The Royal Swedish Academy of Sciences awarded Goodenough and Whittingham for their cathodes and Yoshino for the first working prototype but omitted the importance of the working graphite anode invented by Yazami. Due to the
Nobel Prize The Nobel Prizes ( ; sv, Nobelpriset ; no, Nobelprisen ) are five separate prizes that, according to Alfred Nobel's will of 1895, are awarded to "those who, during the preceding year, have conferred the greatest benefit to humankind." Alfr ...
's limitation of up to three recipients, Yazami believes the committee had to make a difficult decision between Whittingham and himself. He nevertheless congratulated the three recipients of the prize.


References


External links

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Visiting Staff
{{DEFAULTSORT:Yazami, Rachid 20th-century French engineers Moroccan engineers Moroccan scientists Moroccan chemists 1953 births Living people Draper Prize winners Grenoble Institute of Technology alumni Moroccan emigrants to France 21st-century French scientists Research directors of the French National Centre for Scientific Research