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A waveplate or retarder is an
optical Optics is the branch of physics that studies the behaviour and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behaviour of visible, ultravio ...
device that alters the polarization state of a
light Light, visible light, or visible radiation is electromagnetic radiation that can be visual perception, perceived by the human eye. Visible light spans the visible spectrum and is usually defined as having wavelengths in the range of 400– ...
wave travelling through it. Two common types of waveplates are the ''half-wave plate'', which rotates the polarization direction of linearly polarized light, and the ''quarter-wave plate'', which converts between different elliptical polarizations (such as the special case of converting from linearly polarized light to circularly polarized light and vice versa.) Waveplates are constructed out of a
birefringent Birefringence, also called double refraction, is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are described as birefring ...
material (such as
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
or
mica Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into fragile elastic plates. This characteristic is described as ''perfect basal cleavage''. Mica is co ...
, or even plastic), for which the
index of refraction In optics, the refractive index (or refraction index) of an optical medium is the ratio of the apparent speed of light in the air or vacuum to the speed in the medium. The refractive index determines how much the path of light is bent, or refrac ...
is different for light that is linearly polarized along one or the other of two certain perpendicular crystal axes. The behavior of a waveplate (that is, whether it is a half-wave plate, a quarter-wave plate, etc.) depends on the thickness of the crystal, the
wavelength In physics and mathematics, wavelength or spatial period of a wave or periodic function is the distance over which the wave's shape repeats. In other words, it is the distance between consecutive corresponding points of the same ''phase (waves ...
of light, and the variation of the index of refraction. By appropriate choice of the relationship between these parameters, it is possible to introduce a controlled phase shift between the two polarization components of a light wave, thereby altering its polarization. With an engineered combination of two birefringent materials, an achromatic waveplate can be manufactured such that the spectral response of its phase retardance can be nearly flat. A common use of waveplates—particularly the sensitive-tint (full-wave) and quarter-wave plates—is in
optical mineralogy Optical mineralogy is the study of minerals and Rock (geology), rocks by measuring their optics, optical properties. Most commonly, rock and mineral samples are prepared as thin sections or grain mounts for study in the laboratory with a petrog ...
. Addition of plates between the
polarizer A polarizer or polariser is an optical filter that lets light waves of a specific polarization (waves), polarization pass through while attenuation, blocking light waves of other polarizations. It can filter a beam of light of undefined or mixed ...
s of a
petrographic microscope A petrographic microscope is a type of optical microscope used to identify Rock (geology), rocks and minerals in thin sections. The microscope is used in optical mineralogy and petrography, a branch of petrology which focuses on detailed descr ...
makes the optical identification of
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
s in
thin section In optical mineralogy and petrography, a thin section (or petrographic thin section) is a thin slice of a rock or mineral sample, prepared in a laboratory, for use with a polarizing petrographic microscope, electron microscope and electron ...
s of rocks easier, in particular by allowing deduction of the shape and orientation of the optical indicatrices within the visible crystal sections. This alignment can allow discrimination between minerals which otherwise appear very similar in plane polarized and cross polarized light.


Principles of operation

A waveplate works by shifting the
phase Phase or phases may refer to: Science *State of matter, or phase, one of the distinct forms in which matter can exist *Phase (matter), a region of space throughout which all physical properties are essentially uniform *Phase space, a mathematica ...
between two perpendicular polarization components of the light wave. A typical waveplate is simply a
birefringent Birefringence, also called double refraction, is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are described as birefring ...
crystal with a carefully chosen orientation and thickness. The crystal is cut into a plate, with the orientation of the cut chosen so that the
optic axis An optical axis is an imaginary line that passes through the geometrical center of an optical system such as a camera lens, microscope or telescopic sight. Lens elements often have rotational symmetry about the axis. The optical axis defines th ...
of the crystal is parallel to the surfaces of the plate. This results in two axes in the plane of the cut: the ''ordinary axis'', with index of refraction ''n''o, and the ''extraordinary axis'', with index of refraction ''n''e. The ordinary axis is perpendicular to the optic axis. The extraordinary axis is parallel to the optic axis. For a light wave normally incident upon the plate, the polarization component along the ordinary axis travels through the crystal with a speed ''v''o = ''c''/''n''o, while the polarization component along the extraordinary axis travels with a speed ''v''e = ''c''/''n''e. This leads to a phase difference between the two components as they exit the crystal. When ''n''e < ''n''o, as in
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
, the extraordinary axis is called the ''fast axis'' and the ordinary axis is called the ''slow axis''. For ''n''e > ''n''o the situation is reversed. Depending on the thickness of the crystal, light with polarization components along both axes will emerge in a different polarization state. The waveplate is characterized by the amount of relative phase, Γ, that it imparts on the two components, which is related to the birefringence Δ''n'' and the thickness ''L'' of the crystal by the formula :\Gamma = \frac, where λ0 is the vacuum wavelength of the light. Waveplates in general, as well as
polarizer A polarizer or polariser is an optical filter that lets light waves of a specific polarization (waves), polarization pass through while attenuation, blocking light waves of other polarizations. It can filter a beam of light of undefined or mixed ...
s, can be described using the Jones matrix formalism, which uses a vector to represent the polarization state of light and a matrix to represent the linear transformation of a waveplate or polarizer. Although the birefringence Δ''n'' may vary slightly due to dispersion, this is negligible compared to the variation in phase difference according to the wavelength of the light due to the fixed path difference (λ0 in the denominator in the above equation). Waveplates are thus manufactured to work for a particular range of wavelengths. The phase variation can be minimized by stacking two waveplates that differ by a tiny amount in thickness back-to-back, with the slow axis of one along the fast axis of the other. With this configuration, the relative phase imparted can be, for the case of a quarter-wave plate, one-fourth a wavelength rather than three-fourths or one-fourth plus an integer. This is called a ''zero-order waveplate''. For a single waveplate changing the wavelength of the light introduces a linear error in the phase. Tilt of the waveplate enters via a factor of 1/cos θ (where θ is the angle of tilt) into the path length and thus only quadratically into the phase. For the extraordinary polarization the tilt also changes the refractive index to the ordinary via a factor of cos θ, so combined with the path length, the phase shift for the extraordinary light due to tilt is zero. A polarization-independent phase shift of zero order needs a plate with thickness of one wavelength. For calcite the refractive index changes in the first decimal place, so that a true zero order plate is ten times as thick as one wavelength. For
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
and magnesium fluoride the refractive index changes in the second decimal place and true zero order plates are common for wavelengths above 1 μm.


Plate types


Half-wave plate

For a half-wave plate, the relationship between ''L'', Δ''n'', and λ0 is chosen so that the phase shift between polarization components is Γ = π. Now suppose a linearly polarized wave with polarization vector \mathbf is incident on the crystal. Let θ denote the angle between \mathbf and \mathbf, where \mathbf is the vector along the waveplate's fast axis. Let ''z'' denote the propagation axis of the wave. The electric field of the incident wave is \mathbf\,\mathrm^ = E\, \mathbf\,\mathrm^ = E (\cos\theta\, \mathbf + \sin\theta\, \mathbf) \mathrm^, where \mathbf lies along the waveplate's slow axis. The effect of the half-wave plate is to introduce a phase shift term e''i''Γ = e''i''π = −1 between the ''f'' and ''s'' components of the wave, so that upon exiting the crystal the wave is now given by E (\cos\theta\, \mathbf - \sin\theta\, \mathbf) \mathrm^ = E cos(-\theta) \mathbf + \sin(-\theta) \mathbf\mathrm^. If \mathbf' denotes the polarization vector of the wave exiting the waveplate, then this expression shows that the angle between \mathbf' and \mathbf is −θ. Evidently, the effect of the half-wave plate is to mirror the wave's polarization vector through the plane formed by the vectors \mathbf and \mathbf. For linearly polarized light, this is equivalent to saying that the effect of the half-wave plate is to rotate the polarization vector through an angle 2θ; however, for elliptically polarized light the half-wave plate also has the effect of inverting the light's
handedness In human biology, handedness is an individual's preferential use of one hand, known as the dominant hand, due to and causing it to be stronger, faster or more Fine motor skill, dextrous. The other hand, comparatively often the weaker, less dext ...
.


Quarter-wave plate

For a quarter-wave plate, the relationship between ''L'', Δ''n'', and λ0 is chosen so that the phase shift between polarization components is Γ = π/2. Now suppose a linearly polarized wave is incident on the crystal. This wave can be written as :(E_f \mathbf + E_s \mathbf)\mathrm^, where the ''f'' and ''s'' axes are the quarter-wave plate's fast and slow axes, respectively, the wave propagates along the ''z'' axis, and ''Ef'' and ''Es'' are real. The effect of the quarter-wave plate is to introduce a phase shift term e''i''Γ =e''i''π/2 = ''i'' between the ''f'' and ''s'' components of the wave, so that upon exiting the crystal the wave is now given by :(E_f \mathbf + i E_s \mathbf)\mathrm^. The wave is now elliptically polarized. If the axis of polarization of the incident wave is chosen so that it makes a 45° with the fast and slow axes of the waveplate, then ''Ef'' = ''Es'' ≡ ''E'', and the resulting wave upon exiting the waveplate is :E(\mathbf+i\mathbf)\mathrm^, and the wave is circularly polarized. If the axis of polarization of the incident wave is chosen so that it makes a 0° with the fast or slow axes of the waveplate, then the polarization will not change, so remains linear. If the angle is in between 0° and 45° the resulting wave has an elliptical polarization. A circulating polarization can be visualized as the sum of two linear polarizations with a phase difference of 90°. The output depends on the polarization of the input. Suppose polarization axes x and y parallel with the slow and fast axis of the waveplate: The polarization of the incoming photon (or beam) can be resolved as two polarizations on the x and y axis. If the input polarization is parallel to the fast or slow axis, then there is no polarization of the other axis, so the output polarization is the same as the input (only the phase more or less delayed). If the input polarization is 45° to the fast and slow axis, the polarization on those axes are equal. But the phase of the output of the slow axis will be delayed 90° with the output of the fast axis. If not the amplitude but both sine values are displayed, then x and y combined will describe a circle. With other angles than 0° or 45° the values in fast and slow axis will differ and their resultant output will describe an ellipse.


Full-wave, or sensitive-tint plate

A full-wave plate introduces a phase difference of exactly one wavelength between the two polarization directions, for one wavelength of light. In
optical mineralogy Optical mineralogy is the study of minerals and Rock (geology), rocks by measuring their optics, optical properties. Most commonly, rock and mineral samples are prepared as thin sections or grain mounts for study in the laboratory with a petrog ...
, it is common to use a full-wave plate designed for green light (a wavelength near 540 nm). Linearly polarized white light which passes through the plate becomes elliptically polarized, except for that green light wavelength, which will remain linear. If a linear polarizer oriented perpendicular to the original polarization is added, this green wavelength is fully extinguished but elements of the other colors remain. This means that under these conditions the plate will appear an intense shade of red-violet, sometimes known as "sensitive tint". This gives rise to this plate's alternative names, the ''sensitive-tint plate'' or (less commonly) ''red-tint plate''. These plates are widely used in mineralogy to aid in identification of
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
s in
thin section In optical mineralogy and petrography, a thin section (or petrographic thin section) is a thin slice of a rock or mineral sample, prepared in a laboratory, for use with a polarizing petrographic microscope, electron microscope and electron ...
s of rocks.


Multiple-order vs. zero-order waveplates

A multiple-order waveplate is made from a single birefringent crystal that produces an integer multiple of the rated retardance (for example, a multiple-order half-wave plate may have an absolute retardance of 37λ/2). By contrast, a zero-order waveplate produces exactly the specified retardance. This can be accomplished by combining two multiple-order wave plates such that the difference in their retardances yields the net (true) retardance of the waveplate. Zero-order waveplates are less sensitive to temperature and wavelength shifts, but are more expensive than multiple-order ones. Stacking a series of different-order waveplates with polarization filters between them yields a Lyot filter. Either the filters can be rotated, or the waveplates can be replaced with
liquid crystal Liquid crystal (LC) is a state of matter whose properties are between those of conventional liquids and those of solid crystals. For example, a liquid crystal can flow like a liquid, but its molecules may be oriented in a common direction as i ...
layers, to obtain a widely tunable pass band in optical transmission spectrum.


Use in mineralogy and optical petrology

The sensitive-tint (full-wave) and quarter-wave plates are widely used in the field of
optical mineralogy Optical mineralogy is the study of minerals and Rock (geology), rocks by measuring their optics, optical properties. Most commonly, rock and mineral samples are prepared as thin sections or grain mounts for study in the laboratory with a petrog ...
. Addition of plates between the polarizers of a
petrographic microscope A petrographic microscope is a type of optical microscope used to identify Rock (geology), rocks and minerals in thin sections. The microscope is used in optical mineralogy and petrography, a branch of petrology which focuses on detailed descr ...
makes easier the optical identification of
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
s in
thin section In optical mineralogy and petrography, a thin section (or petrographic thin section) is a thin slice of a rock or mineral sample, prepared in a laboratory, for use with a polarizing petrographic microscope, electron microscope and electron ...
s of rocks, in particular by allowing deduction of the shape and orientation of the optical indicatrices within the visible crystal sections. In practical terms, the plate is inserted between the perpendicular polarizers at an angle of 45 degrees. This allows two different procedures to be carried out to investigate the mineral under the crosshairs of the microscope. Firstly, in ordinary cross polarized light, the plate can be used to distinguish the orientation of the optical indicatrix relative to crystal elongation – that is, whether the mineral is "length slow" or "length fast" – based on whether the visible interference colors increase or decrease by one order when the plate is added. Secondly, a slightly more complex procedure allows for a tint plate to be used in conjunction with interference figure techniques to allow measurement of the ''optic angle'' of the mineral. The optic angle (often notated as "2V") can both be diagnostic of mineral type, as well as in some cases revealing information about the variation of chemical composition within a single mineral type.


See also

*
Crystal optics Crystal optics is the branch of optics that describes the behaviour of light in ''anisotropic media'', that is, media (such as crystals) in which light behaves differently depending on which direction the light is propagating. The index of refrac ...
*
Fresnel rhomb A Fresnel rhomb is an optical prism that introduces a 90° phase difference between two perpendicular components of polarization, by means of two total internal reflections. If the incident beam is linearly polarized at 45° to the plane of in ...
* Photoelastic modulator * Polarization rotator * Q-plate *
Spatial light modulator A spatial light modulator (SLM) is a device that can control the intensity, phase, or polarization of light in a spatially varying manner. A simple example is an overhead projector transparency. Usually when the term SLM is used, it means that ...
* Zone plate


References


External links


Waveplates
RP photonics ''Encyclopedia of Laser Physics and Technology''
Polarizers and Waveplates
{{Webarchive, url=https://web.archive.org/web/20160317052935/http://optics.byu.edu/animation/polarwav.mov , date=2016-03-17 Animation Optical mineralogy Polarization (waves) Optical components