''Quantities, Units and Symbols in Physical Chemistry'', also known as the ''Green Book'', is a compilation of terms and symbols widely used in the field of
physical chemistry
Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mecha ...
. It also includes a table of
physical constant
A physical constant, sometimes fundamental physical constant or universal constant, is a physical quantity that is generally believed to be both universal in nature and have constant value in time. It is contrasted with a mathematical constant, ...
s, tables listing the properties of
elementary particle
In particle physics, an elementary particle or fundamental particle is a subatomic particle that is not composed of other particles. Particles currently thought to be elementary include electrons, the fundamental fermions ( quarks, leptons, an ...
s,
chemical element
A chemical element is a species of atoms that have a given number of protons in their nuclei, including the pure substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler sub ...
s, and
nuclide
A nuclide (or nucleide, from nucleus, also known as nuclear species) is a class of atoms characterized by their number of protons, ''Z'', their number of neutrons, ''N'', and their nuclear energy state.
The word ''nuclide'' was coined by Truman ...
s, and information about conversion factors that are commonly used in physical chemistry. The ''Green Book'' is published by the
International Union of Pure and Applied Chemistry
The International Union of Pure and Applied Chemistry (IUPAC ) is an international federation of National Adhering Organizations working for the advancement of the chemical sciences, especially by developing nomenclature and terminology. It is ...
(IUPAC) and is based on published, citeable sources. Information in the ''Green Book'' is synthesized from recommendations made by IUPAC, the
International Union of Pure and Applied Physics
The International Union of Pure and Applied Physics (IUPAP ) is an international non-governmental organization whose mission is to assist in the worldwide development of physics, to foster international cooperation in physics, and to help in the ...
(IUPAP) and the
International Organization for Standardization
The International Organization for Standardization (ISO ) is an international standard development organization composed of representatives from the national standards organizations of member countries. Membership requirements are given in Ar ...
(ISO), including recommendations listed in the IUPAP Red Book ''Symbols, Units, Nomenclature and Fundamental Constants in Physics'' and in the
ISO 31
ISO 31 (Quantities and units, International Organization for Standardization, 1992) is a superseded international standard concerning physical quantities, units of measurement, their interrrelationships and their presentation. It was revised and ...
standards.
History, list of editions, and translations to non-English languages
The third edition of the ''Green Book'' () was first published by IUPAC in 2007. A second printing of the third edition was released in 2008; this printing made several minor revisions to the 2007 text. A third printing of the third edition was released in 2011. The text of the third printing is identical to that of the second printing.
A Japanese translation of the third edition of the ''Green Book'' () was published in 2009. A French translation of the third edition of the ''Green Book'' () was published in 2012.
Portuguese translation(Brazilian Portuguese and European Portuguese) of the third edition of the ''Green Book'' () was published in 2018, with updated values of the physical constants and atomic weights; it is referred to as the "Livro Verde".
A concise four-page summary of the most important material in the ''Green Book'' was published in the July–August 2011 issue of ''Chemistry International'', the IUPAC news magazine.
The second edition of the ''Green Book'' () was first published in 1993. It was reprinted in 1995, 1996, and 1998.
The ''Green Book'' is a direct successor of the ''Manual of Symbols and Terminology for Physicochemical Quantities and Units'', originally prepared for publication on behalf of IUPAC's Physical Chemistry Division by M. L. McGlashen in 1969. A full history of the Green Book's various editions is provided in the historical introduction to the third edition.
The second edition and the third edition (second printing) of the ''Green Book'' have both been made available online as PDF files; the PDF version of the third edition is fully searchable. The four-page concise summary is also available online as a PDF file.
External Links (below).
Handy content
In addition to the obvious data on quantities, units and symbols, the compilation contains some less obvious but very useful information on related topics.
Quantity calculus
Unit conversion is a notorious source of errors. Many people apply individual rules, e.g. "to obtain length in centimeters multiply the length in inches by 2.54", but combining several such conversions is laborious and prone to mistakes. A better way is to use the
factor-label method, which is closely related to
dimensional analysis
In engineering and science, dimensional analysis is the analysis of the relationships between different physical quantities by identifying their base quantities (such as length, mass, time, and electric current) and units of measure (such as m ...
, and
quantity calculus Quantity calculus is the formal method for describing the mathematical relations between ''abstract'' physical quantities. (Here the term ''calculus'' should be understood in its broader sense of "a system of computation", rather than in the sense o ...
explained in sections 1.1 and 7.1 of this compilation.
Scientific typography
Section 1.3 explains the rules for writing scientific symbols and names, for example, where to use capital letters or italics, and where their use is incorrect. The typographical rules are extensive, including even such detail as whether "20°C" or "20 °C" is the correct form.
Atomic units
Section 3.8 introduces
atomic units
The Hartree atomic units are a system of natural units of measurement which is especially convenient for atomic physics and computational chemistry calculations. They are named after the physicist Douglas Hartree. By definition, the following f ...
and gives a table of atomic units of various physical quantities and the conversion factor to the
SI units
The International System of Units, known by the international abbreviation SI in all languages and sometimes Pleonasm#Acronyms and initialisms, pleonastically as the SI system, is the modern form of the metric system and the world's most wid ...
. Section 7.3(v) gives a concise but clear tutorial on practical use of atomic units, in particular how to understand equations "written in atomic units".
See also
* ''
Nomenclature of Organic Chemistry
''Nomenclature of Organic Chemistry'', commonly referred to by chemists as the ''Blue Book'', is a collection of recommendations on organic chemical nomenclature published at irregular intervals by the International Union of Pure and Applied C ...
'' (the ''Blue Book'')
* ''
Nomenclature of Inorganic Chemistry
In chemical nomenclature, the IUPAC nomenclature of inorganic chemistry is a systematic method of naming inorganic chemical compounds, as recommended by the International Union of Pure and Applied Chemistry (IUPAC). It is published in '' Nomencla ...
'' (the ''Red Book'')
* ''
Compendium of Chemical Terminology
The International Union of Pure and Applied Chemistry publishes many books which contain its complete list of definitions. The definitions are divided into seven "colour books": Gold, Green, Blue, Purple, Orange, White, and Red. There is also an e ...
'' (the ''Gold Book'')
* ''
Compendium of Analytical Nomenclature
The ''Compendium of Analytical Nomenclature'' is an IUPAC nomenclature book published by the International Union of Pure and Applied Chemistry (IUPAC) containing internationally accepted definitions for terms in analytical chemistry. It has traditi ...
'' (the ''Orange Book'')
External links
''Quantities, Units and Symbols in Physical Chemistry'', IUPAC ''Green Book'', third edition( E.R. Cohen, T. Cvitas, J.G. Frey, B. Holmström, K. Kuchitsu, R. Marquardt, I. Mills, F. Pavese, M. Quack, J. Stohner, H.L. Strauss, M. Takami, and A.J. Thor, ''Quantities, Units and Symbols in Physical Chemistry'', IUPAC ''Green Book'', Third Edition, Second Printing, IUPAC & RSC Publishing, Cambridge (2008))
Concise four-page summary of the ''Green Book''{{'s third editionSecond edition of the ''Green Book''(commonly known as the "''Colour Books''")
IUPAC official website Chemistry reference works
Chemical nomenclature
Units of chemical measurement