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Tyrian purple ( grc, πορφύρα ''porphúra''; la, purpura), also known as Phoenician red, Phoenician purple, royal purple, imperial purple, or imperial dye, is a reddish-
purple Purple is any of a variety of colors with hue between red and blue. In the RGB color model used in computer and television screens, purples are produced by mixing red and blue light. In the RYB color model historically used by painters ...
natural dye Natural dyes are dyes or colorants derived from plants, invertebrates, or minerals. The majority of natural dyes are vegetable dyes from plant sources— roots, berries, bark, leaves, and wood—and other biological sources such as fungi. Ar ...
. The name Tyrian refers to
Tyre, Lebanon Tyre (; ar, صور, translit=Ṣūr; phn, 𐤑𐤓, translit=Ṣūr, Greek language, Greek ''Tyros'', Τύρος) is a city in Lebanon, one of the List of oldest continuously inhabited cities, oldest continually inhabited cities in the world, t ...
. It is secreted by several species of predatory
sea snail Sea snail is a common name for slow-moving marine gastropod molluscs, usually with visible external shells, such as whelk or abalone. They share the taxonomic class Gastropoda with slugs, which are distinguished from snails primarily by the a ...
s in the family
Muricidae Muricidae is a large and varied taxonomic family of small to large predatory sea snails, marine gastropod mollusks, commonly known as murex snails or rock snails. With about 1,600 living species, the Muricidae represent almost 10% of the Neoga ...
, rock snails originally known by the name 'Murex'. In ancient times, extracting this dye involved tens of thousands of snails and substantial labor, and as a result, the dye was highly valued. The colored compound is 6,6′-dibromoindigo.


History

Biological pigment Biological pigments, also known simply as pigments or biochromes, are substances produced by living organisms that have a color resulting from selective color absorption. Biological pigments include plant pigments and flower pigments. Many biol ...
s were often difficult to acquire, and the details of their production were kept secret by the manufacturers. Tyrian purple is a pigment made from the
mucus Mucus ( ) is a slippery aqueous secretion produced by, and covering, mucous membranes. It is typically produced from cells found in mucous glands, although it may also originate from mixed glands, which contain both serous and mucous cells. It ...
of several species of Murex snail. Production of Tyrian purple for use as a
fabric Textile is an umbrella term that includes various fiber-based materials, including fibers, yarns, filaments, threads, different fabric types, etc. At first, the word "textiles" only referred to woven fabrics. However, weaving is not ...
dye began as early as 1200 BCE by the
Phoenicia Phoenicia () was an ancient thalassocratic civilization originating in the Levant region of the eastern Mediterranean, primarily located in modern Lebanon. The territory of the Phoenician city-states extended and shrank throughout their his ...
ns, and was continued by the
Greeks The Greeks or Hellenes (; el, Έλληνες, ''Éllines'' ) are an ethnic group and nation indigenous to the Eastern Mediterranean and the Black Sea regions, namely Greece, Cyprus, Albania, Italy, Turkey, Egypt, and, to a lesser extent, ot ...
and
Romans Roman or Romans most often refers to: *Rome, the capital city of Italy * Ancient Rome, Roman civilization from 8th century BC to 5th century AD *Roman people, the people of ancient Rome *''Epistle to the Romans'', shortened to ''Romans'', a lette ...
until 1453 CE, with the
fall of Constantinople The Fall of Constantinople, also known as the Conquest of Constantinople, was the capture of the capital of the Byzantine Empire by the Ottoman Empire. The city fell on 29 May 1453 as part of the culmination of a 53-day siege which had begun o ...
. The pigment was expensive and complex to produce, and items colored with it became associated with power and wealth. The color of textiles from this period provides insight into socio-cultural relationships within ancient societies, in addition to providing insight to technological achievements, fashion, social stratification, agriculture and trade connections. Text was copied from this source, which is available under
Creative Commons Attribution 4.0 International License
Despite their value to archaeological research, textiles are rare in the archaeological record. Like any perishable organic material, they are usually subject to rapid decomposition and their preservation requires special conditions to prevent destruction by microorganisms. Tyrian purple may first have been used by the ancient
Phoenicia Phoenicia () was an ancient thalassocratic civilization originating in the Levant region of the eastern Mediterranean, primarily located in modern Lebanon. The territory of the Phoenician city-states extended and shrank throughout their his ...
ns as early as 1570 BCE. It has been suggested that the name Phoenicia itself means 'land of purple'. The
dye A dye is a colored substance that chemically bonds to the substrate to which it is being applied. This distinguishes dyes from pigments which do not chemically bind to the material they color. Dye is generally applied in an aqueous solution and ...
was greatly prized in antiquity because the colour did not easily fade, but instead became brighter with weathering and sunlight. It came in various shades, the most prized being that of black-tinted clotted blood. Because it was extremely difficult to make, Tyrian purple was expensive: the 4th century BCE
historian A historian is a person who studies and writes about the past and is regarded as an authority on it. Historians are concerned with the continuous, methodical narrative and research of past events as relating to the human race; as well as the st ...
Theopompus Theopompus ( grc-gre, Θεόπομπος, ''Theópompos''; c. 380 BCc. 315 BC) was an ancient Greek historian and rhetorician. Biography Theopompus was born on the Aegean island of Chios. In early youth, he seems to have spent some time at Athen ...
reported, "Purple for dyes fetched its weight in silver at Colophon" in
Asia Minor Anatolia, tr, Anadolu Yarımadası), and the Anatolian plateau, also known as Asia Minor, is a large peninsula in Western Asia and the westernmost protrusion of the Asian continent. It constitutes the major part of modern-day Turkey. The re ...
. The expense meant that purple-dyed textiles became
status symbol A status symbol is a visible, external symbol of one's social position, an indicator of economic or social status. Many luxury goods are often considered status symbols. ''Status symbol'' is also a sociological term – as part of social and soc ...
s, whose use was restricted by
sumptuary law Sumptuary laws (from Latin ''sūmptuāriae lēgēs'') are laws that try to regulate consumption. ''Black's Law Dictionary'' defines them as "Laws made for the purpose of restraining luxury or extravagance, particularly against inordinate expendi ...
s. The most senior
Roman magistrate The Roman magistrates were elected officials in Ancient Rome. During the period of the Roman Kingdom, the King of Rome was the principal executive magistrate.Abbott, 8 His power, in practice, was absolute. He was the chief priest, lawgiver, ...
s wore a ''
toga praetexta The toga (, ), a distinctive garment of ancient Rome, was a roughly semicircular cloth, between in length, draped over the shoulders and around the body. It was usually woven from white wool, and was worn over a tunic. In Roman historiography, ...
'', a white
toga The toga (, ), a distinctive garment of ancient Rome, was a roughly semicircular cloth, between in length, draped over the shoulders and around the body. It was usually woven from white wool, and was worn over a tunic. In Roman historical tra ...
edged with a stripe of Tyrian purple. The even more sumptuous ''
toga picta The toga (, ), a distinctive garment of ancient Rome, was a roughly semicircular cloth, between in length, draped over the shoulders and around the body. It was usually woven from white wool, and was worn over a tunic. In Roman historical tra ...
'', solid Tyrian purple with a gold stripe, was worn by generals celebrating a
Roman triumph The Roman triumph (') was a civil ceremony and religious rite of ancient Rome, held to publicly celebrate and sanctify the success of a military commander who had led Roman forces to victory in the service of the state or in some historical tra ...
. By the fourth century CE, sumptuary laws in Rome had been tightened so much that only the Roman emperor was permitted to wear Tyrian purple. As a result, 'purple' is sometimes used as a
metonym Metonymy () is a figure of speech in which a concept is referred to by the name of something closely associated with that thing or concept. Etymology The words ''metonymy'' and ''metonym'' come from grc, μετωνυμία, 'a change of name' ...
for the office (e.g. the phrase 'donned the purple' means 'became emperor'). The production of Tyrian purple was tightly controlled in the succeeding
Byzantine Empire The Byzantine Empire, also referred to as the Eastern Roman Empire or Byzantium, was the continuation of the Roman Empire primarily in its eastern provinces during Late Antiquity and the Middle Ages, when its capital city was Constantinopl ...
and subsidized by the imperial court, which restricted its use for the colouring of imperial silks. Later (9th century) a child born to a reigning emperor was said to be ''
porphyrogenitos Traditionally, born in the purple (sometimes "born to the purple") was a category of members of royal families born during the reign of their parent. This notion was later loosely expanded to include all children born of prominent or high-ranking ...
'', "
born in the purple Traditionally, born in the purple (sometimes "born to the purple") was a category of members of royal families born during the reign of their parent. This notion was later loosely expanded to include all children born of prominent or high-ranking ...
".It is also possible that the term ''
porphyrogenitos Traditionally, born in the purple (sometimes "born to the purple") was a category of members of royal families born during the reign of their parent. This notion was later loosely expanded to include all children born of prominent or high-ranking ...
'' may refer to the purple-red rock known as ''porphyry'' that walled the imperial birthing apartment.
Some speculate that the dye extracted from the ''
Bolinus brandaris ''Bolinus brandaris'' (originally called ''Murex brandaris'' by Linnaeus and also Haustellum brandaris), and commonly known as the purple dye murex or the spiny dye-murex, is a species of medium-sized predatory sea snail, an edible marine gastro ...
'' is known as () in
Biblical Hebrew Biblical Hebrew (, or , ), also called Classical Hebrew, is an archaic form of the Hebrew language, a language in the Canaanite branch of Semitic languages spoken by the Israelites in the area known as the Land of Israel, roughly west of t ...
. Another dye extracted from a related sea snail, ''
Hexaplex trunculus ''Hexaplex trunculus'' (previously known as ''Murex trunculus'', ''Phyllonotus trunculus'', or the banded dye-murex) is a medium-sized sea snail, a marine gastropod mollusk in the family Muricidae, the murex shells or rock snails. It is included ...
'', produced a blue colour after light exposure which could be the one known as (), used in garments worn for ritual purposes.


Production from sea snails

The dye substance is a mucous secretion from the
hypobranchial gland The hypobranchial gland is a glandular structure which is part of the anatomy of many mollusks, including several different families of gastropods, and also many protobranch bivalves. This gland produces mucus as well as biologically active compo ...
of one of several species of medium-sized predatory
sea snail Sea snail is a common name for slow-moving marine gastropod molluscs, usually with visible external shells, such as whelk or abalone. They share the taxonomic class Gastropoda with slugs, which are distinguished from snails primarily by the a ...
s that are found in the eastern
Mediterranean Sea The Mediterranean Sea is a sea connected to the Atlantic Ocean, surrounded by the Mediterranean Basin and almost completely enclosed by land: on the north by Western and Southern Europe and Anatolia, on the south by North Africa, and on ...
, and off the Atlantic coast of Morocco. These are the
marine Marine is an adjective meaning of or pertaining to the sea or ocean. Marine or marines may refer to: Ocean * Maritime (disambiguation) * Marine art * Marine biology * Marine debris * Marine habitats * Marine life * Marine pollution Military ...
gastropod The gastropods (), commonly known as snails and slugs, belong to a large taxonomic class of invertebrates within the phylum Mollusca called Gastropoda (). This class comprises snails and slugs from saltwater, from freshwater, and from land. T ...
s ''
Bolinus brandaris ''Bolinus brandaris'' (originally called ''Murex brandaris'' by Linnaeus and also Haustellum brandaris), and commonly known as the purple dye murex or the spiny dye-murex, is a species of medium-sized predatory sea snail, an edible marine gastro ...
'' the spiny dye-murex (originally known as ''Murex brandaris'' Linnaeus, 1758), the banded dye-murex ''
Hexaplex trunculus ''Hexaplex trunculus'' (previously known as ''Murex trunculus'', ''Phyllonotus trunculus'', or the banded dye-murex) is a medium-sized sea snail, a marine gastropod mollusk in the family Muricidae, the murex shells or rock snails. It is included ...
'', the rock-shell ''
Stramonita haemastoma ''Stramonita haemastoma'', common name the red-mouthed rock shell or the Florida dog winkle, is a species of predatory sea snail, a marine gastropod mollusc in the family Muricidae, the rock snails. Subspecies ''Stramonita haemastoma'' contains ...
'', 284 pp incl 192 figs. & 32 pls. and less commonly a number of other species such as ''
Bolinus cornutus ''Bolinus cornutus'', or horned murex, is a predatory species of sea snail, a marine gastropod mollusk in the family Muricidae, the murex or rock snails. This species is common along the west coast of Africa, where it prefers moderately shallow ...
''. The dye is an organic compound of
bromine Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest element in group 17 of the periodic table ( halogens) and is a volatile red-brown liquid at room temperature that evaporates readily to form a simi ...
(i.e., an
organobromine compound Organobromine compounds, also called organobromides, are organic compounds that contain carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons avai ...
), a class of compounds often found in algae and in some other sea life, but much more rarely found in the biology of land animals. This dye is in contrast to the cheaper imitation purple that was commonly produced using cheaper materials than the dyes from the sea snail. In nature, the snails use the secretion as part of their predatory behavior to sedate prey and as an
antimicrobial An antimicrobial is an agent that kills microorganisms or stops their growth. Antimicrobial medicines can be grouped according to the microorganisms they act primarily against. For example, antibiotics are used against bacteria, and antifungals ar ...
lining on egg masses.Because of research by Benkendorff et al. (1999), the Tyrian purple precursor tyrindoleninone is being investigated as a potential antimicrobial agent with uses against
multidrug-resistant bacteria Multidrug-resistant bacteria (MDR bacteria) are bacteria that are resistant to three or more classes of antimicrobial drugs. MDR bacteria have seen an increase in prevalence in recent years and pose serious risks to public health. MDR bacteria c ...
.
The snail also secretes this substance when it is attacked by predators, or physically antagonized by humans (e.g., poked). Therefore, the dye can be collected either by "milking" the snails, which is more labor-intensive but is a
renewable resource A renewable resource, also known as a flow resource, is a natural resource which will replenish to replace the portion depleted by usage and consumption, either through natural reproduction or other recurring processes in a finite amount of ti ...
, or by collecting and destructively crushing the snails. David Jacoby remarks that "twelve thousand snails of ''
Murex brandaris ''Bolinus brandaris'' (originally called ''Murex brandaris'' by Linnaeus and also Haustellum brandaris), and commonly known as the purple dye murex or the spiny dye-murex, is a species of medium-sized predatory sea snail, an edible marine gastrop ...
'' yield no more than 1.4 g of pure dye, enough to colour only the trim of a single garment." Through the snail harvesting process which includes the extraction of the hypobranchial gland (located under the mollusk's mantle) the dye is collected which required advanced knowledge of biology. Murex-based dyeing must take place close to the site from which the snails originate, because the freshness of the material has a significant effect on the results, the colors yielded based on the long process of biochemical, enzymatic and photochemical reactions, and requires reduction and oxidation processes that probably took several days. Many other species worldwide within the family Muricidae, for example ''
Plicopurpura pansa ''Plicopurpura pansa'' is a species of sea snail, a marine gastropod mollusk in the family Muricidae Muricidae is a large and varied taxonomic family of small to large predatory sea snails, marine gastropod mollusks, commonly known as mur ...
'', from the tropical eastern Pacific, and '' Plicopurpura patula'' from the Caribbean zone of the western
Atlantic The Atlantic Ocean is the second-largest of the world's five oceans, with an area of about . It covers approximately 20% of Earth's surface and about 29% of its water surface area. It is known to separate the " Old World" of Africa, Europe ...
, can also produce a similar substance (which turns into an enduring purple dye when exposed to sunlight) and this ability has sometimes also been historically exploited by local inhabitants in the areas where these snails occur. (Some other predatory gastropods, such as some
wentletrap Wentletraps are small, often white, very high-spired, predatory or ectoparasitic sea snails, marine gastropod mollusks in the family Epitoniidae.Gofas, S. (2010). Epitoniidae. In: Bouchet, P.; Gofas, S.; Rosenberg, G. (2010) World Marine Mollusc ...
s in the family
Epitoniidae Wentletraps are small, often white, very high-spired, predatory or ectoparasitic sea snails, marine gastropod mollusks in the family Epitoniidae.Gofas, S. (2010). Epitoniidae. In: Bouchet, P.; Gofas, S.; Rosenberg, G. (2010) World Marine Mollusc ...
, seem to also produce a similar substance, although this has not been studied or exploited commercially.) The
dog whelk The dog whelk, dogwhelk, or Atlantic dogwinkle (''Nucella lapillus'') is a species of predatory sea snail, a carnivorous marine gastropod in the family Muricidae, the rock snails. ''Nucella lapillus'' was originally described by Carl Linnaeus i ...
''Nucella lapillus'', from the North Atlantic, can also be used to produce red-purple and violet dyes.


Royal blue

The Phoenicians also made a deep blue-colored dye, sometimes referred to as ''royal blue'' or ''hyacinth purple'', which was made from a closely related species of marine snail. The Phoenicians established an ancillary production facility on the
Iles Purpuraires Iles Purpuraires are a set of small islands off the western coast of Morocco at the bay located at Essaouira, the largest of which is Mogador Island. These islands were settled in antiquity by the Phoenicians, chiefly to exploit certain marine re ...
at
Mogador Essaouira ( ; ar, الصويرة, aṣ-Ṣawīra; shi, ⵜⴰⵚⵚⵓⵔⵜ, Taṣṣort, formerly ''Amegdul''), known until the 1960s as Mogador, is a port city in the western Moroccan region of Marakesh-Safi, on the Atlantic coast. It ...
, in
Morocco Morocco (),, ) officially the Kingdom of Morocco, is the westernmost country in the Maghreb region of North Africa. It overlooks the Mediterranean Sea to the north and the Atlantic Ocean to the west, and has land borders with Algeria to A ...
. The sea snail harvested at this western Moroccan dye production facility was ''
Hexaplex trunculus ''Hexaplex trunculus'' (previously known as ''Murex trunculus'', ''Phyllonotus trunculus'', or the banded dye-murex) is a medium-sized sea snail, a marine gastropod mollusk in the family Muricidae, the murex shells or rock snails. It is included ...
'' also known by the older name ''
Murex trunculus ''Hexaplex trunculus'' (previously known as ''Murex trunculus'', ''Phyllonotus trunculus'', or the banded dye-murex) is a medium-sized sea snail, a marine gastropod mollusk in the family Muricidae, the murex shells or rock snails. It is includ ...
''. This second species of dye murex is found today on the Mediterranean and Atlantic coasts of Europe and Africa (Spain, Portugal, Morocco).


Background

The colour-fast (non-fading) dye was an item of luxury trade, prized by
Romans Roman or Romans most often refers to: *Rome, the capital city of Italy * Ancient Rome, Roman civilization from 8th century BC to 5th century AD *Roman people, the people of ancient Rome *''Epistle to the Romans'', shortened to ''Romans'', a lette ...
, who used it to colour ceremonial robes. Used as a dye, the color shifts from blue (peak absorption at 590 nm, which is yellow-orange) to reddish-purple (peak absorption at 520 nm, which is green). It is believed that the intensity of the purple hue improved rather than faded as the dyed cloth aged.
Vitruvius Vitruvius (; c. 80–70 BC – after c. 15 BC) was a Roman architect and engineer during the 1st century BC, known for his multi-volume work entitled '' De architectura''. He originated the idea that all buildings should have three attribut ...
mentions the production of Tyrian purple from shellfish. In his ''
History of Animals ''History of Animals'' ( grc-gre, Τῶν περὶ τὰ ζῷα ἱστοριῶν, ''Ton peri ta zoia historion'', "Inquiries on Animals"; la, Historia Animalium, "History of Animals") is one of the major Aristotle's biology, texts on biolo ...
'',
Aristotle Aristotle (; grc-gre, Ἀριστοτέλης ''Aristotélēs'', ; 384–322 BC) was a Greek philosopher and polymath during the Classical period in Ancient Greece. Taught by Plato, he was the founder of the Peripatetic school of ...
described the shellfish from which Tyrian purple was obtained and the process of extracting the tissue that produced the dye.
Pliny the Elder Gaius Plinius Secundus (AD 23/2479), called Pliny the Elder (), was a Roman author, naturalist and natural philosopher, and naval and army commander of the early Roman Empire, and a friend of the emperor Vespasian. He wrote the encyclopedic ' ...
described the production of Tyrian purple in his '' Natural History'':The problem with Tyrian purple is that the precursor reacts very quickly with air and light to form an insoluble dye. (Hence Pliny says: "... ''when
he shellfish He or HE may refer to: Language * He (pronoun), an English pronoun * He (kana), the romanization of the Japanese kana へ * He (letter), the fifth letter of many Semitic alphabets * He (Cyrillic), a letter of the Cyrillic script called ''He'' ...
have once discharged their waxy secretion, their juices have no consistency''. ...") The cumbersome process that Pliny describes is necessary to reverse the oxidation and to restore the water-soluble precursor so that large masses of wool can be dyed. See: See also: C. J. Cooksey (2001) "Tyrian purple: 6,6’-Dibromoindigo and Related Compounds," ''Molecules'', 6 (9) : 736–769, especially page 761. Indigo, which is chemically very similar to Tyrian purple, behaves similarly. See: http://www.indigopage.com/chemistry.htm
The most favourable season for taking these hellfishis after the rising of the Dog-star, or else before spring; for when they have once discharged their waxy secretion, their juices have no consistency: this, however, is a fact unknown in the dyers' workshops, although it is a point of primary importance. After it is taken, the vein .e. hypobranchial glandis extracted, which we have previously spoken of, to which it is requisite to add salt, a sextarius bout 20 fl. oz.to every hundred pounds of juice. It is sufficient to leave them to steep for a period of three days, and no more, for the fresher they are, the greater virtue there is in the liquor. It is then set to boil in vessels of tin r lead and every hundred amphorae ought to be boiled down to five hundred pounds of dye, by the application of a moderate heat; for which purpose the vessel is placed at the end of a long funnel, which communicates with the furnace; while thus boiling, the liquor is skimmed from time to time, and with it the flesh, which necessarily adheres to the veins. About the tenth day, generally, the whole contents of the cauldron are in a liquefied state, upon which a fleece, from which the grease has been cleansed, is plunged into it by way of making trial; but until such time as the colour is found to satisfy the wishes of those preparing it, the liquor is still kept on the boil. The tint that inclines to red is looked upon as inferior to that which is of a blackish hue. The wool is left to lie in soak for five hours, and then, after carding it, it is thrown in again, until it has fully imbibed the colour.
Archaeological data from Tyre indicate that the snails were collected in large vats and left to decompose. This produced a hideous stench that was actually mentioned by ancient authors. Not much is known about the subsequent steps, and the actual ancient method for mass-producing the two murex dyes has not yet been successfully reconstructed; this special "blackish clotted blood" colour, which was prized above all others, is believed to be achieved by double-dipping the cloth, once in the indigo dye of ''H. trunculus'' and once in the purple-red dye of ''B. brandaris''. The Roman mythographer
Julius Pollux Julius Pollux ( el, Ἰούλιος Πολυδεύκης, ''Ioulios Polydeukes''; fl. 2nd century) was a Greek scholar and rhetorician from Naucratis, Ancient Egypt.Andrew Dalby, ''Food in the Ancient World: From A to Z'', p.265, Routledge, 2003 E ...
, writing in the 2nd century CE, asserted (''Onomasticon'' I, 45–49) that the purple dye was first discovered by the philosopher Heracles of Tyre, or rather, by his dog, whose mouth was stained purple from chewing on snails along the coast at Tyre. This story was depicted by
Peter Paul Rubens Sir Peter Paul Rubens (; ; 28 June 1577 – 30 May 1640) was a Flemish artist and diplomat from the Duchy of Brabant in the Southern Netherlands (modern-day Belgium). He is considered the most influential artist of the Flemish Baroque tradit ...
in his painting ''
Hercules' Dog Discovers Purple Dye ''Hercules's Dog Discovers Purple Dye'' or ''The Discovery of Purple by Hercules's Dog'' is an oil painting by Flemish artist Peter Paul Rubens painted circa 1636, towards the end of his career. It depicts the mythical discovery of Tyrian purple ...
''. According to
John Malalas John Malalas ( el, , ''Iōánnēs Malálas'';  – 578) was a Byzantine chronicler from Antioch (now Antakya, Turkey). Life Malalas was of Syrian descent, and he was a native speaker of Syriac who learned how to write in Greek later ...
, the incident happened during the reign of the legendary King Phoenix of Tyre, the eponymous progenitor of the Phoenicians, and therefore he was the first ruler to wear Tyrian purple and legislate on its use. Recently, the archaeological discovery of substantial numbers of Murex shells on
Crete Crete ( el, Κρήτη, translit=, Modern: , Ancient: ) is the largest and most populous of the Greek islands, the 88th largest island in the world and the fifth largest island in the Mediterranean Sea, after Sicily, Sardinia, Cyprus, ...
suggests that the Minoans may have pioneered the extraction of Imperial purple centuries before the Tyrians. Dating from collocated pottery suggests the dye may have been produced during the Middle Minoan period in the 20th–18th century BC. Accumulations of crushed murex shells from a hut at the site of Coppa Nevigata in southern Italy may indicate production of purple dye there from at least the 18th century BCE. Additional archaeological evidence can be found from samples originating from excavations at the extensive Iron Age copper smelting site of “Slaves’ Hill” (Site 34), which is tightly dated by radiocarbon to the late 11th–early 10th centuries BC. Findings from this site include evidence of the use of purple dye found in stains used on pot shards. Evidence of the use of dye in pottery are found in most cases on the upper part of ceramic basins, on the inside surface, the areas in which the reduced dye-solution was exposed to air, and underwent oxidation that turned it purple. The production of ''Murex'' purple for the Byzantine court came to an abrupt end with the sack of Constantinople in 1204, the critical episode of the
Fourth Crusade The Fourth Crusade (1202–1204) was a Latin Christian armed expedition called by Pope Innocent III. The stated intent of the expedition was to recapture the Muslim-controlled city of Jerusalem, by first defeating the powerful Egyptian Ayyubid S ...
. David Jacoby concludes that "no Byzantine emperor nor any Latin ruler in former Byzantine territories could muster the financial resources required for the pursuit of murex purple production. On the other hand, murex fishing and dyeing with genuine purple are attested for Egypt in the tenth to 13th centuries." By contrast, Jacoby finds that there are no mentions of purple fishing or dyeing, nor trade in the colorant in any Western source, even in the Frankish Levant. The European West turned instead to
vermilion Vermilion (sometimes vermillion) is a color, color family, and pigment most often made, since antiquity until the 19th century, from the powdered mineral cinnabar (a form of mercury sulfide, which is toxic) and its corresponding color. It i ...
provided by the insect ''
Kermes vermilio ''Kermes vermilio'' is a species of '' Kermes'' so which feeds on trees. Some of the species are used by humans to make vermilion; though an at-similar-time-of-discovery mineral form in many cultures is cinnabar (HgS, Mercury Sulphide, crystalli ...
'', known as ''grana'', or
crimson Crimson is a rich, deep red color, inclining to purple. It originally meant the color of the kermes dye produced from a scale insect, '' Kermes vermilio'', but the name is now sometimes also used as a generic term for slightly bluish-red co ...
. In 1909, Harvard anthropologist
Zelia Nuttall Zelia Maria Magdalena Nuttall (6 September 1857 – 12 April 1933) was an American archaeologist and anthropologist specialised in pre-Aztec Mexican cultures and pre-Columbian manuscripts. She discovered two forgotten manuscripts of this type in ...
compiled an intensive comparative study on the historical production of the purple dye produced from the carnivorous murex snail, source of the royal purple dye valued higher than gold in the ancient Near East and ancient Mexico. Not only did the people of ancient Mexico use the same methods of production as the Phoenicians, they also valued murex-dyed cloth above all others, as it appeared in codices as the attire of nobility. "Nuttall noted that the Mexican murex-dyed cloth bore a "disagreeable … strong fishy smell, which appears to be as lasting as the color itself." Likewise, the ancient Egyptian ''Papyrus of Anastasi'' laments: "The hands of the dyer reek like rotting fish ..." So pervasive was this stench that the
Talmud The Talmud (; he, , Talmūḏ) is the central text of Rabbinic Judaism and the primary source of Jewish religious law ('' halakha'') and Jewish theology. Until the advent of modernity, in nearly all Jewish communities, the Talmud was the ce ...
specifically granted women the right to divorce any husband who became a dyer after marriage. In 2021, archaeologists found surviving wool fibers dyed with royal purple in the
Timna Valley The Timna Valley (תִּמְנָע, ) is located in southern Israel in the southwestern Arava/Arabah, approximately north of the Gulf of Aqaba and the city of Eilat. The area is rich in copper ore and has been mined since the 5th millennium ...
in Israel. The find, which was dated to c. 1000 BCE, constituted the first direct evidence of fabric dyed with the pigment from antiquity.


Murex purple production in North Africa

Murex purple was a very important industry in many Phoenician territories and
Carthage Carthage was the capital city of Ancient Carthage, on the eastern side of the Lake of Tunis in what is now Tunisia. Carthage was one of the most important trading hubs of the Ancient Mediterranean and one of the most affluent cities of the classi ...
was no exception. Traces of this once very lucrative industry are still visible in many Punic sites such as
Kerkouane Kerkouane or Kerkuane ( ar, كركوان, ''Karkwān'') is the site of an ancient Punic city in north-eastern Tunisia, near Cape Bon. Kerkouane was one of the most important Punic cities, with Carthage, Hadrumetum (modern Sousse), and Utica. This ...
, Zouchis,
Djerba Djerba (; ar, جربة, Jirba, ; it, Meninge, Girba), also transliterated as Jerba or Jarbah, is a Tunisian island and the largest island of North Africa at , in the Gulf of Gabès, off the coast of Tunisia. It had a population of 139,544 ...
and even in Carthage itself. According to Pliny, Meninx (today's Djerba) produced the best purple in Africa which was also ranked second only after Tyre's. It was found also at
Essaouira Essaouira ( ; ar, الصويرة, aṣ-Ṣawīra; shi, ⵜⴰⵚⵚⵓⵔⵜ, Taṣṣort, formerly ''Amegdul''), known until the 1960s as Mogador, is a port city in the western Moroccan region of Marakesh-Safi, on the Atlantic coast. It ha ...
(
Morocco Morocco (),, ) officially the Kingdom of Morocco, is the westernmost country in the Maghreb region of North Africa. It overlooks the Mediterranean Sea to the north and the Atlantic Ocean to the west, and has land borders with Algeria to A ...
). The Royal purple or Imperial purple was probably used until the time of
Augustine of Hippo Augustine of Hippo ( , ; la, Aurelius Augustinus Hipponensis; 13 November 354 – 28 August 430), also known as Saint Augustine, was a theologian and philosopher of Berber origin and the bishop of Hippo Regius in Numidia, Roman North Afr ...
(354–430 CE) and before the demise of the Roman Empire.


Dye chemistry

Variations in colors of "Tyrian purple" from different snails are related to the presence of indigo dye (blue), 6-bromoindigo (purple), and the red 6,6′-dibromoindigo. Additional changes in color can be induced by debromination from light exposure (as is the case for
Tekhelet ''Tekhelet'' ( he, תְּכֵלֶת ''təḵēleṯ''; alternate spellings include ''tekheleth'', ''t'chelet'', ''techelet'' and ''techeiles'') is a "blue-violet", "blue", or "turquoise" dye highly prized by ancient Mediterranean civilizations. I ...
) or by heat processing. The final shade of purple is decided by chromatogram, which can be idenfitied by
HPLC High-performance liquid chromatography (HPLC), formerly referred to as high-pressure liquid chromatography, is a technique in analytical chemistry used to separate, identify, and quantify each component in a mixture. It relies on pumps to p ...
analysis in a single measurement: indigotin (IND) and indirubin (INR). The two are found in plant sources such as
woad ''Isatis tinctoria'', also called woad (), dyer's woad, or glastum, is a flowering plant in the family Brassicaceae (the mustard family) with a documented history of use as a blue dye and medicinal plant. Its genus name, Isatis, derives from ...
(''Isatis tinctoria L''.) and the
indigo plant ''Indigofera'' is a large genus of over 750 species of flowering plants belonging to the pea family Fabaceae. They are widely distributed throughout the tropical and subtropical regions of the world. Description Species of ''Indigofera'' are mos ...
(''Indigofera tinctoria L''), as well as in several species of shellfish. In 1998, by means of a lengthy trial and error process, a process for dyeing with Tyrian purple was rediscovered. This finding built on reports from the 15th century to the 18th century and explored the biotechnology process behind
woad ''Isatis tinctoria'', also called woad (), dyer's woad, or glastum, is a flowering plant in the family Brassicaceae (the mustard family) with a documented history of use as a blue dye and medicinal plant. Its genus name, Isatis, derives from ...
fermentation. It is hypothesized that an alkaline fermenting vat was necessary. An incomplete ancient recipe for Tyrian purple recorded by Pliny the Elder was also consulted. By altering the percentage of sea salt in the dye vat and adding
potash Potash () includes various mined and manufactured salts that contain potassium in water- soluble form.
, he was able to successfully dye wool a deep purple colour. Recent research in
organic electronics Organic electronics is a field of materials science concerning the design, synthesis, characterization, and application of organic molecules or polymers that show desirable electronic properties such as conductivity. Unlike conventional inorgan ...
has shown that Tyrian purple is an ambipolar organic semiconductor. Transistors and circuits based on this material can be produced from sublimed thin-films of the dye. The good semiconducting properties of the dye originate from strong intermolecular hydrogen bonding that reinforces
pi stacking In chemistry, pi stacking (also called π–π stacking) refers to the presumptive attractive, noncovalent pi interactions ( orbital overlap) between the pi bonds of aromatic rings. However this is a misleading description of the phenomena since ...
necessary for transport.


Modern hue rendering

True Tyrian purple, like most high- chroma
pigment A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compou ...
s, cannot be accurately rendered on a standard RGB computer monitor. Ancient reports are also not entirely consistent, but these swatches give a rough indication of the likely range in which it appeared. _________
_________ The lower one is the
sRGB sRGB is a standard RGB (red, green, blue) color space that HP and Microsoft created cooperatively in 1996 to use on monitors, printers, and the World Wide Web. It was subsequently standardized by the International Electrotechnical Commission ...
colour #990024, intended for viewing on an output device with a
gamma Gamma (uppercase , lowercase ; ''gámma'') is the third letter of the Greek alphabet. In the system of Greek numerals it has a value of 3. In Ancient Greek, the letter gamma represented a voiced velar stop . In Modern Greek, this letter r ...
of 2.2 . It is a representation of RHS colour code 66A, which has been equated to "Tyrian red", a term which is often used as a synonym for Tyrian purple.


Philately

The colour name "Tyrian plum" is popularly given to a British postage stamp that was prepared, but never released to the public, shortly before the death of King Edward VII in 1910.


Gallery

File:Cuneiform tablet BM62788.jpg, alt=cuneiform tablet,
Cuneiform Cuneiform is a logo- syllabic script that was used to write several languages of the Ancient Middle East. The script was in active use from the early Bronze Age until the beginning of the Common Era. It is named for the characteristic wedge- ...
tablet, dated 600–500 BCE, with instructions for dyeing wool purple and blue. Ref.. File:Heb cover hi.jpg, A set of ''
Tzitzit ''Tzitzit'' ( he, ''ṣīṣīṯ'', ; plural ''ṣīṣiyyōṯ'', Ashkenazi: '; and Samaritan: ') are specially knotted ritual fringes, or tassels, worn in antiquity by Israelites and today by observant Jews and Samaritans. are usual ...
'', four tassels or "fringes" with
tekhelet ''Tekhelet'' ( he, תְּכֵלֶת ''təḵēleṯ''; alternate spellings include ''tekheleth'', ''t'chelet'', ''techelet'' and ''techeiles'') is a "blue-violet", "blue", or "turquoise" dye highly prized by ancient Mediterranean civilizations. I ...
(purple-blue) threads produced from a ''Hexaplex trunculus'' based dye. File:Contemporary portrayal of a toga picta.jpg, Painting of a man wearing an all-purple ''toga picta'', from an Etruscan tomb (about 350 BCE). File:Compitalia fresco.jpg, Roman men wearing ''togae praetextae'' with reddish-purple stripes during a religious procession (1st century BCE). File:Empress Theodora.jpg, The Empress Theodora, the wife of the Emperor Justinian, dressed in Tyrian purple. (6th century). File:Karl den store krons av leo III.jpg, A medieval depiction of the coronation of the Emperor
Charlemagne Charlemagne ( , ) or Charles the Great ( la, Carolus Magnus; german: Karl der Große; 2 April 747 – 28 January 814), a member of the Carolingian dynasty, was King of the Franks from 768, King of the Lombards from 774, and the first E ...
in 800 CE wearing royal blue. The bishops and cardinals wear Tyrian purple, and the Pope wears white. File:Shroud of Charlemagne manufactured in Constantinople 814.jpg, A fragment of the shroud in which the Emperor
Charlemagne Charlemagne ( , ) or Charles the Great ( la, Carolus Magnus; german: Karl der Große; 2 April 747 – 28 January 814), a member of the Carolingian dynasty, was King of the Franks from 768, King of the Lombards from 774, and the first E ...
was buried in 814 CE. It was made of gold and Tyrian purple from Constantinople. File:Tyrian purple on grayscale.jpg, 6,6'-dibromoindigo, the major component of Tyrian purple


See also

* * * *


Explanatory notes


References


External links

* * * * * {{DEFAULTSORT:Tyrian Purple Animal dyes Organic pigments Mollusc products Organobromides Halogen-containing natural products Shades of violet Byzantine culture Byzantine clothing Bromine-containing natural products