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A potentiometer is an instrument for measuring
voltage Voltage, also known as electric pressure, electric tension, or (electric) potential difference, is the difference in electric potential between two points. In a static electric field, it corresponds to the work needed per unit of charge to ...
or 'potential difference' by comparison of an unknown voltage with a known reference
voltage Voltage, also known as electric pressure, electric tension, or (electric) potential difference, is the difference in electric potential between two points. In a static electric field, it corresponds to the work needed per unit of charge to ...
. If a sensitive indicating instrument is used, very little current is drawn from the source of the unknown voltage. Since the reference voltage can be produced from an accurately calibrated voltage divider, a potentiometer can provide high precision in measurement. The method was described by
Johann Christian Poggendorff Johann Christian Poggendorff (29 December 1796 – 24 January 1877), was a German physicist born in Hamburg. By far the greater and more important part of his work related to electricity and magnetism. Poggendorff is known for his electrostatic ...
around 1841 and became a standard laboratory measuring technique. In this arrangement, a fraction of a known voltage from a resistive slide wire is compared with an unknown voltage by means of a
galvanometer A galvanometer is an electromechanical measuring instrument for electric current. Early galvanometers were uncalibrated, but improved versions, called ammeters, were calibrated and could measure the flow of current more precisely. A galvan ...
. The sliding contact or wiper of the potentiometer is adjusted and the galvanometer briefly connected between the sliding contact and the unknown voltage. The deflection of the galvanometer is observed and the sliding tap adjusted until the galvanometer no longer deflects from zero. At that point the galvanometer draws no current from the unknown source, and the magnitude of voltage can be calculated from the position of the sliding contact. This null balance measuring method is still important in electrical
metrology Metrology is the scientific study of measurement. It establishes a common understanding of units, crucial in linking human activities. Modern metrology has its roots in the French Revolution's political motivation to standardise units in Fran ...
and standards work and is also used in other areas of electronics. Measurement potentiometers are divided into four main classes listed below.


Principle of operation

The principle of a potentiometer is that the potential dropped across a segment of a wire of uniform cross-section carrying a constant current is directly proportional to its length. The potentiometer is a simple device used to measure the electrical potentials (or compare the e.m.f of a cell). One form of potentiometer is a uniform high-resistance wire attached to an insulating support, marked with a linear measuring scale. In use, an adjustable regulated voltage source E, of greater magnitude than the potential to be measured, is connected across the wire so as to pass a steady current through it. Between the end of the wire and any point along it will be a potential proportional to the length of wire to that point. By comparing the potential at points along the wire with an unknown potential, the magnitude of the unknown potential can be determined. The instrument used for comparison must be sensitive, but need not be particularly well-calibrated or accurate so long as its deflection from zero position can be easily detected.


Constant current potentiometer

In this circuit, the ends of a uniform resistance wire R1 are connected to a regulated DC supply VS for use as a voltage divider. The potentiometer is first calibrated by positioning the wiper (arrow) at the spot on the R1 wire that corresponds to the voltage of a standard cell so that = A standard
electrochemical cell An electrochemical cell is a device capable of either generating electrical energy from chemical reactions or using electrical energy to cause chemical reactions. The electrochemical cells which generate an electric current are called voltaic o ...
is used whose emf is known (e.g. 1.0183 volts for a Weston standard cell). The supply voltage VS is then adjusted until the
galvanometer A galvanometer is an electromechanical measuring instrument for electric current. Early galvanometers were uncalibrated, but improved versions, called ammeters, were calibrated and could measure the flow of current more precisely. A galvan ...
shows zero, indicating the voltage on R2 is equal to the standard cell voltage. An unknown DC voltage, in series with the galvanometer, is then connected to the sliding wiper, across a variable-length section R3 of the resistance wire. The wiper is moved until no current flows into or out of the source of unknown voltage, as indicated by the galvanometer in series with the unknown voltage. The voltage across the selected R3 section of wire is then equal to the unknown voltage. The final step is to calculate the unknown voltage from the fraction of the length of the resistance wire that was connected to the unknown voltage. The galvanometer does not need to be calibrated, as its only function is to read zero or not zero. When measuring an unknown voltage and the galvanometer reads zero, no current is drawn from the unknown voltage and so the reading is independent of the source's internal resistance, as if by a
voltmeter A voltmeter is an instrument used for measuring electric potential difference between two points in an electric circuit. It is connected in parallel. It usually has a high resistance so that it takes negligible current from the circuit. ...
of
infinite Infinite may refer to: Mathematics * Infinite set, a set that is not a finite set *Infinity, an abstract concept describing something without any limit Music *Infinite (group), a South Korean boy band *''Infinite'' (EP), debut EP of American m ...
resistance. Because the resistance wire can be made very uniform in cross-section and resistivity, and the position of the wiper can be measured easily, this method can be used to measure unknown DC voltages greater than or less than a calibration voltage produced by a standard cell without drawing any
current Currents, Current or The Current may refer to: Science and technology * Current (fluid), the flow of a liquid or a gas ** Air current, a flow of air ** Ocean current, a current in the ocean *** Rip current, a kind of water current ** Current (stre ...
from the standard cell. If the potentiometer is attached to a constant voltage DC supply such as a
lead–acid battery The lead–acid battery is a type of rechargeable battery first invented in 1859 by French physicist Gaston Planté. It is the first type of rechargeable battery ever created. Compared to modern rechargeable batteries, lead–acid batteries have ...
, then a second variable resistor (not shown) can be used to calibrate the potentiometer by varying the current through the R1 resistance wire. If the length of the R1 resistance wire is AB, where A is the (-) end and B is the (+) end, and the movable wiper is at point X at a distance AX on the R3 portion of the resistance wire when the galvanometer gives a zero reading for an unknown voltage, the distance AX is measured or read from a pre-printed scale next to the resistance wire. The unknown voltage can then be calculated: V_U = (Calibration \ Cell \ Voltage)


Constant resistance potentiometer

The constant resistance potentiometer is a variation of the basic idea in which a variable current is fed through a fixed resistor. These are used primarily for measurements in the millivolt and microvolt range.


Microvolt potentiometer

This is a form of the constant resistance potentiometer described above but designed to minimize the effects of contact resistance and thermal emf. This equipment is satisfactorily used down to readings of 1000 nV or so.


Thermocouple potentiometer

Another development of the standard types was the 'thermocouple potentiometer' especially adapted for temperature measurement with
thermocouple A thermocouple, also known as a "thermoelectrical thermometer", is an electrical device consisting of two dissimilar electrical conductors forming an electrical junction. A thermocouple produces a temperature-dependent voltage as a result of th ...
s. Potentiometers for use with thermocouples also measure the temperature at which the thermocouple wires are connected, so that cold-junction compensation may be applied to correct the apparent measured EMF to the standard cold-junction temperature of 0 degrees C.


Analytical chemistry

To make a potentiometric determination of an analyte in a solution, the potential of the cell is measured. This measurement must be corrected for the reference and junction potentials. It can also be used in standardisation methods. The concentration of the analyte can then be calculated from the
Nernst Equation In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction ( half-cell or full cell reaction) from the standard electrode potential, absolute tempe ...
. Many varieties of this basic principle exist for quantitative measurements.


Metre bridge

A metre bridge is a simple type of potentiometer which may be used in school science laboratories to demonstrate the principle of resistance measurement by potentiometric means. A resistance wire is laid along the length of a metre rule and contact with the wire is made through a
galvanometer A galvanometer is an electromechanical measuring instrument for electric current. Early galvanometers were uncalibrated, but improved versions, called ammeters, were calibrated and could measure the flow of current more precisely. A galvan ...
by a slider. When the galvanometer reads zero, the ratio between the lengths of wire to the left and right of the slider is equal to the ratio between the values of a known and an unknown resistor in a parallel circuit.


See also

* Potentiometer (voltage divider) *
Wheatstone bridge A Wheatstone bridge is an electrical circuit used to measure an unknown electrical resistance by balancing two legs of a bridge circuit, one leg of which includes the unknown component. The primary benefit of the circuit is its ability to provid ...


References


External links


Pictures of measuring potentiometers


{{Electroanalytical Voltmeters Electrical meters Measuring instruments