Poly(3,4-ethylenedioxythiophene) (PEDOT or PEDT; ''IUPAC'' name poly(2,3-dihydrothieno ,4-''b''1,4]dioxane-5,7-diyl)) is a

conducting polymer Conductive polymers or, more precisely, intrinsically conducting polymers (ICPs) are organic polymers that conduct electricity. Such compounds may have metallic conductivity or can be semiconductors. The biggest advantage of conductive polymer ...

based on 3,4-ethylenedioxythiophene or EDOT. It was first reported by

Bayer AG Bayer AG (, commonly pronounced ; ) is a German multinational pharmaceutical and biotechnology company and one of the largest pharmaceutical companies in the world. Headquartered in Leverkusen, Bayer's areas of business include pharmaceutica ...

in 1989.

Polymer

PEDOT possesses many advantageous properties compared to earlier conducting polythiophenes like 3-alkylthiophenes. For example, the

polymer A polymer (; Greek '' poly-'', "many" + '' -mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...

is optically transparent in its

conducting Conducting is the art of directing a musical performance, such as an orchestral or choral concert. It has been defined as "the art of directing the simultaneous performance of several players or singers by the use of gesture." The primary duti ...

state and has high stability, moderate

band gap In solid-state physics, a band gap, also called an energy gap, is an energy range in a solid where no electronic states can exist. In graphs of the electronic band structure of solids, the band gap generally refers to the energy difference (i ...

, and low

redox potential Redox potential (also known as oxidation / reduction potential, ''ORP'', ''pe'', ''E_'', or E_) is a measure of the tendency of a chemical species to acquire electrons from or lose electrons to an electrode and thereby be reduced or oxidised respe ...

. Its major disadvantage is its poor

solubility In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution. The extent of the solubil ...

, which is partly circumvented by use of

composite material A composite material (also called a composition material or shortened to composite, which is the common name) is a material which is produced from two or more constituent materials. These constituent materials have notably dissimilar chemical or ...

s such as PEDOT:PSS and PEDOT-TMA. The polymer is generated by

oxidation Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a ...

. The process begins with production of the radical cation of EDOT monomer, ₂H₄O₂C₄H₂Ssup>+. This cation adds to a neutral EDOT followed by deprotonation. The idealized conversion using

peroxydisulfate The peroxydisulfate ion, , is an oxyanion, the anion of peroxydisulfuric acid. It is commonly referred to as persulfate, but this term also refers to the peroxomonosulfate ion, . It is also called ''peroxodisulfate''. Approximately 500,000 ton ...

is shown: :n C₂H₄O₂C₄H₂S + n (OSO₃)₂²⁻ → ₂H₄O₂C₄Ssub>n + 2n HOSO₃⁻ Polymerization is usually conducted in the presence of

polystyrene sulfonate Polystyrene sulfonates are a group of medications used to treat high blood potassium. Effects generally take hours to days. They are also used to remove potassium, calcium, and sodium from solutions in technical applications. Common side ef ...

(PSS), which acts as a template. PSS also provides a counter ion, which balances the charges in the reaction and hinders the formation of by-products such as 3,4-ethylenedioxy-2(5H)-thiophenone, and keeps the PEDOT

monomer In chemistry, a monomer ( ; '' mono-'', "one" + '' -mer'', "part") is a molecule that can react together with other monomer molecules to form a larger polymer chain or three-dimensional network in a process called polymerization. Classification ...

s dispersed in water or

aqueous An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, or sodium chloride (NaCl), in water would be r ...

solutions Solution may refer to: * Solution (chemistry), a mixture where one substance is dissolved in another * Solution (equation), in mathematics ** Numerical solution, in numerical analysis, approximate solutions within specified error bounds * Solut ...

. The resulting PEDOT:PSS composite can be deposited on a conductive support such as

platinum Platinum is a chemical element with the symbol Pt and atomic number 78. It is a dense, malleable, ductile, highly unreactive, precious, silverish-white transition metal. Its name originates from Spanish , a diminutive of "silver". Platin ...

gold Gold is a chemical element with the Symbol (chemistry), symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a Brightness, bright, slightly orange-yellow, dense, s ...

glassy carbon Glass-like carbon, often called glassy carbon or vitreous carbon, is a non-graphitizing, or nongraphitizable, carbon which combines glassy and ceramic properties with those of graphite. The most important properties are high temperature resis ...

, and

indium tin oxide Indium tin oxide (ITO) is a ternary composition of indium, tin and oxygen in varying proportions. Depending on the oxygen content, it can be described as either a ceramic or an alloy. Indium tin oxide is typically encountered as an oxygen-saturated ...

Uses

Applications of PEDOT include electrochromic displays and

antistatic An antistatic agent is a compound used for treatment of materials or their surfaces in order to reduce or eliminate buildup of static electricity. Static charge may be generated by the triboelectric effect or by a non-contact process using a high ...

s. PEDOT has also been proposed for

photovoltaic Photovoltaics (PV) is the conversion of light into electricity using semiconducting materials that exhibit the photovoltaic effect, a phenomenon studied in physics, photochemistry, and electrochemistry. The photovoltaic effect is commercially u ...

s, printed wiring, and sensors. PEDOT has been proposed for use in biocompatible interfaces.

References

{{Reflist Organic polymers Organic semiconductors Transparent electrodes Conductive polymers

Polymer

Uses

Further reading

References