Pseudomorphosis
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In
mineralogy Mineralogy is a subject of geology specializing in the scientific study of the chemistry, crystal structure, and physical (including optical) properties of minerals and mineralized artifacts. Specific studies within mineralogy include the proces ...
, a pseudomorph is a
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
or mineral compound that appears in an atypical form (
crystal system In crystallography, a crystal system is a set of point groups (a group of geometric symmetries with at least one fixed point). A lattice system is a set of Bravais lattices. Space groups are classified into crystal systems according to their po ...
), resulting from a substitution process in which the appearance and dimensions remain constant, but the original mineral is replaced by another. The name literally means "false form". Terminology for pseudomorphs is "''replacer'' after ''original''", as in ''brookite'' after ''rutile''.


Substitution pseudomorph

An infiltration pseudomorph, or substitution pseudomorph is a pseudomorph in which one mineral or other material is replaced by another. The original shape of the mineral remains unchanged, but color, hardness, and other properties change to those of the replacing mineral. An example of this process is the replacement of wood by
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
(
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
or
opal Opal is a hydrated amorphous form of silica (SiO2·''n''H2O); its water content may range from 3 to 21% by weight, but is usually between 6 and 10%. Due to its amorphous property, it is classified as a mineraloid, unlike crystalline forms ...
) to form
petrified wood Petrified wood, also known as petrified tree (from Ancient Greek meaning 'rock' or 'stone'; literally 'wood turned into stone'), is the name given to a special type of ''fossilized wood'', the fossilized remains of terrestrial vegetation. ''P ...
in which the substitution may be so perfect as to retain the original cellular structure of the wood. An example of mineral-to-mineral substitution is replacement of
aragonite Aragonite is a carbonate mineral, one of the three most common naturally occurring crystal forms of calcium carbonate, (the other forms being the minerals calcite and vaterite). It is formed by biological and physical processes, including prec ...
twin Twins are two offspring produced by the same pregnancy.MedicineNet > Definition of TwinLast Editorial Review: 19 June 2000 Twins can be either ''monozygotic'' ('identical'), meaning that they develop from one zygote, which splits and forms two em ...
crystals by
native copper Native copper is an uncombined form of copper that occurs as a natural mineral. Copper is one of the few metallic elements to occur in native form, although it most commonly occurs in oxidized states and mixed with other elements. Native coppe ...
, as occurs at the
Corocoro United Copper Mines The Corocoro United Copper Mines, Ltd. was the largest copper mine in Bolivia, an honor previously held by Compania Corocoro de Bolivia. The corporate office was at 151 Finsbury Pavement House, London, England, while the mine office was at Coro ...
of Coro Coro,
Bolivia , image_flag = Bandera de Bolivia (Estado).svg , flag_alt = Horizontal tricolor (red, yellow, and green from top to bottom) with the coat of arms of Bolivia in the center , flag_alt2 = 7 × 7 square p ...
. A variety of infiltration or substitution pseudomorphism is called alteration, in which only partial replacement occurs. This happens typically when a mineral of one composition changes by chemical reaction to another of similar composition, retaining the original crystalline shape. An example is a change from
galena Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It cryst ...
(lead sulfide) to
anglesite Anglesite is a lead sulfate mineral with the chemical formula PbSO4. It occurs as an oxidation product of primary lead sulfide ore, galena. Anglesite occurs as prismatic orthorhombic crystals and earthy masses, and is isomorphous with barite and ...
(lead sulfate). The resulting pseudomorph may contain an unaltered core of galena surrounded by anglesite that has the cubic crystal shape of galena.


Paramorph

A paramorph (also called allomorph) is a mineral changed on the molecular level only. It has the same chemical composition, but with a different structure. The mineral looks identical to the original unaltered form. This occurs, as an example, in the
aragonite Aragonite is a carbonate mineral, one of the three most common naturally occurring crystal forms of calcium carbonate, (the other forms being the minerals calcite and vaterite). It is formed by biological and physical processes, including prec ...
to
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
change.


Epimorph and incrustation pseudomorph

An incrustation pseudomorph, also called epimorph, results from a process by which a mineral is coated by another and the encased mineral dissolves. The encasing mineral remains intact, and retains the shape of the original mineral or material. Alternatively, another mineral may fill the space (the mold) previously occupied by some other mineral or material.


In other fields

Pseudomorphs are also common in
paleontology Paleontology (), also spelled palaeontology or palæontology, is the scientific study of life that existed prior to, and sometimes including, the start of the Holocene epoch (roughly 11,700 years before present). It includes the study of fossi ...
.
Fossil A fossil (from Classical Latin , ) is any preserved remains, impression, or trace of any once-living thing from a past geological age. Examples include bones, shells, exoskeletons, stone imprints of animals or microbes, objects preserved ...
s are often formed by pseudomorphic replacement of the remains by mineral matter. Examples include petrified wood and pyritized
gastropod The gastropods (), commonly known as snails and slugs, belong to a large taxonomic class of invertebrates within the phylum Mollusca called Gastropoda (). This class comprises snails and slugs from saltwater, from freshwater, and from land. T ...
shells. In
biology Biology is the scientific study of life. It is a natural science with a broad scope but has several unifying themes that tie it together as a single, coherent field. For instance, all organisms are made up of cells that process hereditary i ...
, a pseudomorph is a cloud of mucus-rich ink released by many species of
cephalopod A cephalopod is any member of the molluscan class Cephalopoda (Greek plural , ; "head-feet") such as a squid, octopus, cuttlefish, or nautilus. These exclusively marine animals are characterized by bilateral body symmetry, a prominent head ...
. The name refers to the similarity in appearance between the cephalopod that released it and the cloud itself, in this context meaning literally "false body". This behaviour often allows the cephalopod to escape from predation unharmed, and is often performed as part of what is known as the blanch-ink-jet maneuver. In
philosophy Philosophy (from , ) is the systematized study of general and fundamental questions, such as those about existence, reason, knowledge, values, mind, and language. Such questions are often posed as problems to be studied or resolved. Some ...
, the concept of pseudomorphosis was used by the German philosopher
Oswald Spengler Oswald Arnold Gottfried Spengler (; 29 May 1880 – 8 May 1936) was a German historian and philosopher of history whose interests included mathematics, science, and art, as well as their relation to his organic theory of history. He is best known ...
to describe how the forms of an older, more widely dispersed culture condition the expression forms of a younger, emerging culture, leading the latter to develop into forms that are fundamentally alien to its own world-feeling, and thereby preventing it from fully developing its own self-consciousness. In
archaeology Archaeology or archeology is the scientific study of human activity through the recovery and analysis of material culture. The archaeological record consists of artifacts, architecture, biofacts or ecofacts, sites, and cultural landscap ...
, organic pseudomorphs are impressions of organic material that can accumulate on the surface of metal artifacts as they corrode. They may occur when metal artifacts are buried in contact with organics under damp soil.0. de Alarcon, "Of Daggers and Scabbards: Evidence of Organic Pseudomorphs and X-Radiography." Penn Museum Blog. 16 April 2016. https://www.penn.museum/blog/collection/conservation/of-daggers-and-scabbards-evidence-from-organic-pseudomorphs-and-x-radiography


See also

*
Polymorphism (materials science) In materials science, polymorphism describes the existence of a solid material in more than one form or crystal structure. Polymorphism is a form of isomerism. Any crystalline material can exhibit the phenomenon. Allotropy refers to polymorphism ...


References

* ''Dana's Manual of Mineralogy'' by Cornelis S. Hurlbut, Eighteenth Edition, (1971, John Wiley & Sons, Inc.) {{ISBN, 0-471-42225-8 Mineralogy