Praseodymium(III) Perchlorate
   HOME

TheInfoList



OR:

Praseodymium(III) perchlorate is the
perchlorate A perchlorate is a chemical compound containing the perchlorate ion, . The majority of perchlorates are commercially produced salts. They are mainly used as oxidizers for pyrotechnic devices and to control static electricity in food packaging. Per ...
salt of praseodymium, with the
chemical formula In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, ...
of Pr(ClO4)3.


Preparation

Praseodymium(III) perchlorate can be prepared from
praseodymium(III,IV) oxide Praseodymium(III,IV) oxide is the inorganic compound with the formula that is insoluble in water. It has a cubic fluorite structure. It is the most stable form of praseodymium oxide at ambient temperature and pressure. Properties and structure ...
. Dissolving praseodymium(III,IV) oxide in a slight excess of
hydrochloric acid Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid Acid strength is the tendency of an acid, symbol ...
and adding a small amount of
hydrogen peroxide Hydrogen peroxide is a chemical compound with the formula . In its pure form, it is a very pale blue liquid that is slightly more viscous than water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution (3%†...
can prepare praseodymium perchlorate.


Chemical properties

Praseodymium perchlorate can form two complexes with crown ether
18-crown-6 18-Crown-6 is an organic compound with the formula 2H4O and the IUPAC name of 1,4,7,10,13,16-hexaoxacyclooctadecane. It is a white, hygroscopic crystalline solid with a low melting point. Like other crown ethers, 18-crown-6 functions as a li ...
in stoichiometric ratios of 1:1 and 1:2., and can form complexes with L-
proline Proline (symbol Pro or P) is an organic acid classed as a proteinogenic amino acid (used in the biosynthesis of proteins), although it does not contain the amino group but is rather a secondary amine. The secondary amine nitrogen is in the prot ...
,
glutamic acid Glutamic acid (symbol Glu or E; the ionic form is known as glutamate) is an α-amino acid that is used by almost all living beings in the biosynthesis of proteins. It is a non-essential nutrient for humans, meaning that the human body can synt ...
, mandelic acid, penicillamine. It can also form complexes with
imidazole Imidazole (ImH) is an organic compound with the formula C3N2H4. It is a white or colourless solid that is soluble in water, producing a mildly alkaline solution. In chemistry, it is an aromatic heterocycle, classified as a diazole Diazole refers ...
and alanine.


References

{{Authority control Praseodymium(III) compounds Perchlorates