Podsolisation is an extreme form of

leaching Leaching is the loss or extraction of certain materials from a carrier into a liquid (usually, but not always a solvent). and may refer to: * Leaching (agriculture), the loss of water-soluble plant nutrients from the soil; or applying a small amou ...

which causes the

eluviation In geology, eluvium or eluvial deposits are those geological deposits and soils that are derived by ''in situ'' weathering or weathering plus gravitational movement or accumulation. The process of removal of materials from geological or soil horiz ...

iron Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...

and

aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...

sesquioxide A sesquioxide is an oxide of an Chemical element, element (or Radical (chemistry), radical), where the ratio between the number of atoms of that element and the number of atoms of oxygen is 2:3. For example, aluminium oxide and phosphorus(III) oxi ...

s. The process generally occurs in areas where

precipitation In meteorology, precipitation is any product of the condensation of atmospheric water vapor that falls under gravitational pull from clouds. The main forms of precipitation include drizzle, rain, sleet, snow, ice pellets, graupel and hail. ...

is greater than

evapotranspiration Evapotranspiration (ET) is the combined processes by which water moves from the earth’s surface into the atmosphere. It covers both water evaporation (movement of water to the air directly from soil, canopies, and water bodies) and transpi ...

. The minerals are removed by a process known as

. When organic material is broken down nutrients are released, but at the same time organic acids are released. These organic acids are known as

chelating agents Chelation is a type of bonding of ions and molecules to metal ions. It involves the formation or presence of two or more separate coordinate bonds between a polydentate (multiple bonded) ligand and a single central metal atom. These ligands ar ...

. Many

podsol In soil science, podzols are the typical soils of coniferous or boreal forests and also the typical soils of eucalypt forests and heathlands in southern Australia. In Western Europe, podzols develop on heathland, which is often a construct of hum ...

soils form underneath

coniferous forests Conifers are a group of cone-bearing seed plants, a subset of gymnosperms. Scientifically, they make up the division Pinophyta (), also known as Coniferophyta () or Coniferae. The division contains a single extant class, Pinopsida. All exta ...

, the fact that pine trees are evergreen causes a very thin litter layer inhibiting the production of humus. As a result an acidic (pH 4.5) mor humus is produced which provides a greater amount of chelating agents.Rode A. A. To the problem of the degree of podzolization of soils // Studies in the genesis and geography of soils. M.: Acad. Sci. USSR, 1935. P. 55-70.

The A Horizon

In podsolisation, chelating agents break down clay and release minerals such as iron and aluminium. When iron and aluminium are hydrated they become sesquioxides. The sesquioxides are translocated from the A Horizon, a zone of out-washing, to the B Horizon, a zone of illuviation. Many bases such as

calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar t ...

and

potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosph ...

are also leached from the zone along with organic matter and

silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is ...

. Often minerals like

quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...

and silica are left behind in the A horizon. What is significantly different about podsols in comparison to other soils is that the bottom of A horizon is known as the AE horizon, which is an eluviated area which has lost sesquioxides. It tends to be an ash gray colour.

The B Horizon

The B Horizon has dark layer where minerals, organic matter and bases are being illuviated (washed in/accumulated). Below this is a red/orange layer of iron and aluminium sesquioxides deposit. Some bases remain in the soil, though others may be lost by

throughflow In hydrology, throughflow, a subtype of interflow (percolation), is the lateral unsaturated flow of water in the soil zone, typically through a highly permeable geologic unit overlying a less permeable one. Water thus returns to the surface, as ret ...

. In many podsols,

Iron Pans Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in fr ...

are created. This can cause water logging which may then saturate the A horizon leading to

mottling Mottle is a pattern of irregular marks, spots, streaks, blotches or patches of different shades or colours. It is commonly used to describe the surface of plants or the skin of animals. In plants, mottling usually consists of yellowish spots o ...

or a gleyed podsol. Also useful:

soil chemistry Soil chemistry is the study of the chemical characteristics of soil. Soil chemistry is affected by mineral composition, organic matter and environmental factors. In the early 1850s a consulting chemist to the Royal Agricultural Society in England ...

References

Soil chemistry {{Soil-sci-stub