Plasma gasification is an extreme thermal process using

plasma Plasma or plasm may refer to: Science * Plasma (physics), one of the four fundamental states of matter * Plasma (mineral), a green translucent silica mineral * Quark–gluon plasma, a state of matter in quantum chromodynamics Biology * Blood pla ...

which converts

organic matter Organic matter, organic material, or natural organic matter refers to the large source of carbon-based compounds found within natural and engineered, terrestrial, and aquatic environments. It is matter composed of organic compounds that have c ...

into a

syngas Syngas, or synthesis gas, is a mixture of hydrogen and carbon monoxide, in various ratios. The gas often contains some carbon dioxide and methane. It is principly used for producing ammonia or methanol. Syngas is combustible and can be used as ...

(synthesis gas) which is primarily made up of

hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, an ...

and

carbon monoxide Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simple ...

. A

plasma torch A plasma torch (also known as a plasma arc, plasma gun, plasma cutter, or plasmatron) is a device for generating a directed flow of plasma. The plasma jet can be used for applications including plasma cutting, plasma arc welding, plasma spra ...

electric arc An electric arc, or arc discharge, is an electrical breakdown of a gas that produces a prolonged electrical discharge. The electric current, current through a normally Electrical conductance, nonconductive medium such as air produces a plasma (p ...

is used to ionize gas and

catalyze Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recyc ...

organic matter into

, with

slag Slag is a by-product of smelting (pyrometallurgical) ores and used metals. Broadly, it can be classified as ferrous (by-products of processing iron and steel), ferroalloy (by-product of ferroalloy production) or non-ferrous/base metals (by-prod ...

remaining as a byproduct. It is used commercially as a form of

waste treatment Waste treatment refers to the activities required to ensure that waste has the least practicable impact on the environment. In many countries various forms of waste treatment are required by law. Solid waste treatment The treatment of solid wastes ...

and has been tested for the gasification of

refuse-derived fuel Refuse-derived fuel (RDF) is a fuel produced from various types of waste such as municipal solid waste (MSW), industrial waste or commercial waste. The World Business Council for Sustainable Development provides a definition: ''"Selected wast ...

biomass Biomass is plant-based material used as a fuel for heat or electricity production. It can be in the form of wood, wood residues, energy crops, agricultural residues, and waste from industry, farms, and households. Some people use the terms bi ...

industrial waste Industrial waste is the waste produced by industrial activity which includes any material that is rendered useless during a manufacturing process such as that of factories, mills, and mining operations. Types of industrial waste include dirt and ...

hazardous waste Hazardous waste is waste that has substantial or potential threats to public health or the environment. Hazardous waste is a type of dangerous goods. They usually have one or more of the following hazardous traits: ignitability, reactivity, co ...

, and solid

hydrocarbons In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ex ...

, such as

coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when dea ...

oil sands Oil sands, tar sands, crude bitumen, or bituminous sands, are a type of unconventional petroleum deposit. Oil sands are either loose sands or partially consolidated sandstone containing a naturally occurring mixture of sand, clay, and wate ...

petcoke Petroleum coke, abbreviated coke or petcoke, is a final carbon-rich solid material that derives from oil refining, and is one type of the group of fuels referred to as cokes. Petcoke is the coke that, in particular, derives from a final cracki ...

and

oil shale Oil shale is an organic-rich fine-grained sedimentary rock containing kerogen (a solid mixture of organic chemical compounds) from which liquid hydrocarbons can be produced. In addition to kerogen, general composition of oil shales constitute ...

Process

Small plasma torches typically use an

inert gas An inert gas is a gas that does not readily undergo chemical reactions with other chemical substances and therefore does not readily form chemical compounds. The noble gases often do not react with many substances and were historically referred to ...

such as

argon Argon is a chemical element with the symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third-most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abu ...

where larger torches require

nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...

. The

electrode An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit (e.g. a semiconductor, an electrolyte, a vacuum or air). Electrodes are essential parts of batteries that can consist of a variety of materials de ...

s vary from

copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...

tungsten Tungsten, or wolfram, is a chemical element with the symbol W and atomic number 74. Tungsten is a rare metal found naturally on Earth almost exclusively as compounds with other elements. It was identified as a new element in 1781 and first isolat ...

hafnium Hafnium is a chemical element with the symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in many zirconium minerals. Its existence was predicted by Dmitri M ...

zirconium Zirconium is a chemical element with the symbol Zr and atomic number 40. The name ''zirconium'' is taken from the name of the mineral zircon, the most important source of zirconium. The word is related to Persian '' zargun'' (zircon; ''zar-gun'', ...

, along with various other

alloy An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, ...

s. A strong electric current under high voltage passes between the two electrodes as an

. Pressurized inert gas is

ionized Ionization, or Ionisation is the process by which an atom or a molecule acquires a negative or positive charge by gaining or losing electrons, often in conjunction with other chemical changes. The resulting electrically charged atom or molecule ...

passing through the plasma created by the arc. The torch's temperature ranges from . The temperature of the plasma reaction determines the structure of the plasma and forming gas. The waste is heated, melted and finally

vaporized Vaporization (or vaporisation) of an element or compound is a phase transition from the liquid phase to vapor. There are two types of vaporization: evaporation and boiling. Evaporation is a surface phenomenon, whereas boiling is a bulk phenom ...

. Only at these extreme conditions can molecular

dissociation Dissociation, in the wide sense of the word, is an act of disuniting or separating a complex object into parts. Dissociation may also refer to: * Dissociation (chemistry), general process in which molecules or ionic compounds (complexes, or salts ...

occur by breaking apart molecular bonds. Complex molecules are separated into individual

atoms Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas, an ...

. The resulting elemental components are in a gaseous phase (

). Molecular dissociation using plasma is referred to as "plasma

pyrolysis The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements ''py ...

Feedstocks

The feedstock for plasma waste treatment is most often

waste, or both. Feedstocks may also include

biomedical waste Biomedical waste or hospital waste is any kind of waste containing infectious (or potentially infectious) materials. It may also include waste associated with the generation of biomedical waste that visually appears to be of medical or laborator ...

and

hazardous materials Dangerous goods, abbreviated DG, are substances that when transported are a risk to health, safety, property or the environment. Certain dangerous goods that pose risks even when not being transported are known as hazardous materials ( syllabi ...

. Content and consistency of the waste directly impacts performance of a plasma facility. Pre-sorting to extract treatable material for the gasification provides consistency. Too much inorganic material such as metal and

construction waste Construction waste or debris is any kind of debris from the construction process. Different government agencies have clear definitions. For example, the United States Environmental Protection Agency EPA defines construction and demolition materi ...

increases slag production, which in turn decreases

production. However, a benefit is that the slag itself is chemically inert and safe to handle (certain materials may affect the content of the gas produced, however). Shredding waste to small uniform particles before entering the main chamber is generally required. This creates an efficient transfer of energy which enable sufficient breakdown of the materials. Steam is sometimes added into gasification processes to increase the generation of hydrogen (

steam reforming Steam reforming or steam methane reforming (SMR) is a method for producing syngas (hydrogen and carbon monoxide) by reaction of hydrocarbons with water. Commonly natural gas is the feedstock. The main purpose of this technology is hydrogen product ...

Yields

Pure highly calorific

synthesis gas Syngas, or synthesis gas, is a mixture of hydrogen and carbon monoxide, in various ratios. The gas often contains some carbon dioxide and methane. It is principly used for producing ammonia or methanol. Syngas is combustible and can be used as ...

consists predominantly of

(CO) and

(H₂).

Inorganic compound In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemist ...

s in the waste stream are not broken down but melted, which includes glass, ceramics, and various metals. The high temperature and lack of oxygen prevents the formation of many toxic compounds such as

furan Furan is a heterocyclic organic compound, consisting of a five-membered aromatic ring with four carbon atoms and one oxygen atom. Chemical compounds containing such rings are also referred to as furans. Furan is a colorless, flammable, highly ...

dioxins Dioxin may refer to: * 1,2-Dioxin or 1,4-Dioxin, two unsaturated heterocyclic 6-membered rings where two carbon atoms have been replaced by oxygen atoms, giving the molecular formula C4H4O2 *Dibenzo-1,4-dioxin, the parent compound also known as ...

nitrogen oxides Nitrogen oxide may refer to a binary compound of oxygen and nitrogen, or a mixture of such compounds: Charge-neutral *Nitric oxide (NO), nitrogen(II) oxide, or nitrogen monoxide *Nitrogen dioxide (), nitrogen(IV) oxide *Nitrogen trioxide (), or ni ...

, or

sulfur dioxide Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a toxic gas responsible for the odor of burnt matches. It is released naturally by volcanic activ ...

in the flame itself. However, dioxins are formed during cooling of the syngas. Metals resulting from plasma

can be recovered from the slag and eventually sold as a commodity. Inert slag produced from some processes is granulated and can be used in construction. A portion of the syngas produced feeds on-site turbines, which power the plasma torches and thus support the feed system.

Equipment

Some plasma gasification reactors operate at

negative pressure Negative pressure may refer to: * Negative value of a pressure variable * Negative room pressure, a ventilation technique used to avoid contaminating outside areas * Negative pressure ventilator, also known as an iron lung * Negative-pressure wou ...

, but most attempt to recover gaseous and/or solid resources.

Advantages

The main advantages of plasma torch technologies for waste treatment are: * Preventing hazardous waste from reaching landfills * Some processes are designed to recover fly ash, bottom ash, and most other particulates, for 95% or better diversion from landfills, and no harmful emissions of

toxic waste Toxic waste is any unwanted material in all forms that can cause harm (e.g. by being inhaled, swallowed, or absorbed through the skin). Mostly generated by industry, consumer products like televisions, computers, and phones contain toxic chemi ...

* Potential production of vitrified slag which could be used as construction material * Processing of

waste into combustible

for

electric power Electric power is the rate at which electrical energy is transferred by an electric circuit. The SI unit of power is the watt, one joule per second. Standard prefixes apply to watts as with other SI units: thousands, millions and billions o ...

and heat or for

synthesis Synthesis or synthesize may refer to: Science Chemistry and biochemistry *Chemical synthesis, the execution of chemical reactions to form a more complex molecule from chemical precursors ** Organic synthesis, the chemical synthesis of organ ...

into fuels or chemicals. * Production of

value-added In business, total value added is calculated by tabulating the unit value added (measured by summing unit profit sale price and production cost">Price.html" ;"title="he difference between Price">sale price and production cost], unit depreciatio ...

products (metals) from slag * Safe means to destroy both medical waste, medical and many other

s. * Gasification with starved combustion and rapid quenching of syngas from elevated temperatures can avoid the production of dioxins and furans that are common to incinerators * Air emissions can be cleaner than landfills and similar to that of incinerators.

Disadvantages

Main disadvantages of plasma torch technologies for waste treatment are: * Large initial investment costs relative to that of alternatives, including landfill and

incineration Incineration is a waste treatment process that involves the combustion of substances contained in waste materials. Industrial plants for waste incineration are commonly referred to as waste-to-energy facilities. Incineration and other high ...

. * Operational costs are high relative to that of incineration. * Wet feed stock results in less syngas production and higher energy consumption. * Frequent maintenance and limited plant availability.

Commercialization

Plasma torch gasification is used commercially for waste disposal at a total of five sites worldwide with a combined design capacity of 200 tonnes of waste per day, half of which is biomass waste. Energy recovery from waste streams using plasma gasification is currently implemented in a total of one (possibly two) installation representing a treatment capacity of 25-30 tonnes per day of waste.

Military use

The US Navy is employing Plasma Arc Waste Destruction System (PAWDS) on its latest generation ''Gerald R. Ford''-class aircraft carrier. The compact system being used will treat all combustible solid waste generated on board the ship. After having completed factory acceptance testing in Montreal, the system is scheduled to be shipped to the Huntington Ingalls shipyard for installation on the carrier.

References

External links

Gasification Technologies Council

Tetronics International

PEAT International

Advanced Plasma Power

Department of Trade and Industry - Using thermal plasma technology to create a valuable product from hazardous waste

PyroGenesis Canada Inc.

Responsible Energy Inc.

Plasma Power, LLC
{{DEFAULTSORT:Plasma Arc Waste Disposal Sustainable technologies Plasma processing Thermal treatment