The Planck relation
[French & Taylor (1978), pp. 24, 55.][Cohen-Tannoudji, Diu & Laloë (1973/1977), pp. 10–11.] (referred to as Planck's energy–frequency relation,
[Schwinger (2001), p. 203.] the Planck relation, Planck equation, and Planck formula, though the latter might also refer to
Planck's law
In physics, Planck's law describes the spectral density of electromagnetic radiation emitted by a black body in thermal equilibrium at a given temperature , when there is no net flow of matter or energy between the body and its environment.
At ...
) is a fundamental equation in
quantum mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, ...
which states that the energy of a
photon
A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they always ...
, , known as
photon energy
Photon energy is the energy carried by a single photon. The amount of energy is directly proportional to the photon's electromagnetic frequency and thus, equivalently, is inversely proportional to the wavelength. The higher the photon's frequency, ...
, is proportional to its
frequency
Frequency is the number of occurrences of a repeating event per unit of time. It is also occasionally referred to as ''temporal frequency'' for clarity, and is distinct from ''angular frequency''. Frequency is measured in hertz (Hz) which is eq ...
, :
The
constant of proportionality
In mathematics, two sequences of numbers, often experimental data, are proportional or directly proportional if their corresponding elements have a constant ratio, which is called the coefficient of proportionality or proportionality constant ...
, , is known as the
Planck constant
The Planck constant, or Planck's constant, is a fundamental physical constant of foundational importance in quantum mechanics. The constant gives the relationship between the energy of a photon and its frequency, and by the mass-energy equivale ...
. Several equivalent forms of the relation exist, including in terms of
angular frequency
In physics, angular frequency "''ω''" (also referred to by the terms angular speed, circular frequency, orbital frequency, radian frequency, and pulsatance) is a scalar measure of rotation rate. It refers to the angular displacement per unit tim ...
, :
where
. The relation accounts for the
quantized nature of light and plays a key role in understanding phenomena such as the
photoelectric effect
The photoelectric effect is the emission of electrons when electromagnetic radiation, such as light, hits a material. Electrons emitted in this manner are called photoelectrons. The phenomenon is studied in condensed matter physics, and solid st ...
and
black-body radiation
Black-body radiation is the thermal electromagnetic radiation within, or surrounding, a body in thermodynamic equilibrium with its environment, emitted by a black body (an idealized opaque, non-reflective body). It has a specific, continuous spect ...
(where the related
Planck postulate The Planck postulate (or Planck's postulate), one of the fundamental principles of quantum mechanics, is the postulate that the energy of oscillators in a black body is quantized, and is given by
:E=nh\nu\,,
where ''n'' is an integer (1, 2, 3, ...), ...
can be used to derive
Planck's law
In physics, Planck's law describes the spectral density of electromagnetic radiation emitted by a black body in thermal equilibrium at a given temperature , when there is no net flow of matter or energy between the body and its environment.
At ...
).
Spectral forms
Light can be characterized using several
spectral
''Spectral'' is a 2016 3D military science fiction, supernatural horror fantasy and action-adventure thriller war film directed by Nic Mathieu. Written by himself, Ian Fried, and George Nolfi from a story by Fried and Mathieu. The film stars J ...
quantities, such as
frequency
Frequency is the number of occurrences of a repeating event per unit of time. It is also occasionally referred to as ''temporal frequency'' for clarity, and is distinct from ''angular frequency''. Frequency is measured in hertz (Hz) which is eq ...
,
wavelength
In physics, the wavelength is the spatial period of a periodic wave—the distance over which the wave's shape repeats.
It is the distance between consecutive corresponding points of the same phase on the wave, such as two adjacent crests, tro ...
,
wavenumber
In the physical sciences, the wavenumber (also wave number or repetency) is the ''spatial frequency'' of a wave, measured in cycles per unit distance (ordinary wavenumber) or radians per unit distance (angular wavenumber). It is analogous to temp ...
, and their angular equivalents (
angular frequency
In physics, angular frequency "''ω''" (also referred to by the terms angular speed, circular frequency, orbital frequency, radian frequency, and pulsatance) is a scalar measure of rotation rate. It refers to the angular displacement per unit tim ...
,
angular wavelength
In physics, the wavelength is the spatial period of a periodic wave—the distance over which the wave's shape repeats.
It is the distance between consecutive corresponding points of the same phase on the wave, such as two adjacent crests, tro ...
, and
angular wavenumber
In the physical sciences, the wavenumber (also wave number or repetency) is the ''spatial frequency'' of a wave, measured in cycles per unit distance (ordinary wavenumber) or radians per unit distance (angular wavenumber). It is analogous to temp ...
). These quantities are related through
so the Planck relation can take the following 'standard' forms
as well as the following 'angular' forms,
The standard forms make use of the
Planck constant
The Planck constant, or Planck's constant, is a fundamental physical constant of foundational importance in quantum mechanics. The constant gives the relationship between the energy of a photon and its frequency, and by the mass-energy equivale ...
. The angular forms make use of the
reduced Planck constant
The Planck constant, or Planck's constant, is a fundamental physical constant of foundational importance in quantum mechanics. The constant gives the relationship between the energy of a photon and its frequency, and by the mass-energy equivale ...
. Here is the
speed of light
The speed of light in vacuum, commonly denoted , is a universal physical constant that is important in many areas of physics. The speed of light is exactly equal to ). According to the special theory of relativity, is the upper limit ...
.
de Broglie relation
The de Broglie relation,
[Weinberg (1995), p. 3.] also known as the de Broglie's momentum–wavelength relation,
generalizes the Planck relation to
matter wave
Matter waves are a central part of the theory of quantum mechanics, being an example of wave–particle duality. All matter exhibits wave-like behavior. For example, a beam of electrons can be diffracted just like a beam of light or a water wave ...
s.
Louis de Broglie
Louis Victor Pierre Raymond, 7th Duc de Broglie (, also , or ; 15 August 1892 – 19 March 1987) was a French physicist and aristocrat who made groundbreaking contributions to quantum theory. In his 1924 PhD thesis, he postulated the wave na ...
argued that if
particles had a wave nature, the relation would also apply to them, and postulated that particles would have a wavelength equal to . Combining de Broglie's postulate with the Planck–Einstein relation leads to
or
The de Broglie's relation is also often encountered in
vector
Vector most often refers to:
*Euclidean vector, a quantity with a magnitude and a direction
*Vector (epidemiology), an agent that carries and transmits an infectious pathogen into another living organism
Vector may also refer to:
Mathematic ...
form
where is the momentum vector, and is the
angular wave vector
In physics, a wave vector (or wavevector) is a vector used in describing a wave, with a typical unit being cycle per metre. It has a magnitude and direction. Its magnitude is the wavenumber of the wave (inversely proportional to the wavelength), ...
.
Bohr's frequency condition
Bohr's frequency condition states that the frequency of a photon absorbed or emitted during an
electronic transition
A quantum jump is the abrupt transition of a quantum system (atom, molecule, atomic nucleus) from one quantum state to another, from one energy level to another. When the system absorbs energy, there is a transition to a higher energy level (exc ...
is related to the energy difference () between the two
energy level
A quantum mechanical system or particle that is bound—that is, confined spatially—can only take on certain discrete values of energy, called energy levels. This contrasts with classical particles, which can have any amount of energy. The te ...
s involved in the transition:
[van der Waerden (1967), p. 5.]
This is a direct consequence of the Planck–Einstein relation.
See also
*
Compton wavelength
The Compton wavelength is a quantum mechanical property of a particle. The Compton wavelength of a particle is equal to the wavelength of a photon whose energy is the same as the rest energy of that particle (see mass–energy equivalence). It was ...
References
Cited bibliography
*
Cohen-Tannoudji, C., Diu, B., Laloë, F. (1973/1977). ''Quantum Mechanics'', translated from the French by S.R. Hemley, N. Ostrowsky, D. Ostrowsky, second edition, volume 1, Wiley, New York, .
*
French, A.P.,
Taylor, E.F. (1978). ''An Introduction to Quantum Physics'', Van Nostrand Reinhold, London, .
*Griffiths, D.J. (1995). ''Introduction to Quantum Mechanics'', Prentice Hall, Upper Saddle River NJ, .
*
Landé, A. (1951). ''Quantum Mechanics'', Sir Isaac Pitman & Sons, London.
*Landsberg, P.T. (1978). ''Thermodynamics and Statistical Mechanics'', Oxford University Press, Oxford UK, .
*
Messiah, A. (1958/1961)
''Quantum Mechanics'' volume 1, translated from the French by G.M. Temmer, North-Holland, Amsterdam.
*
Schwinger, J. (2001). ''Quantum Mechanics: Symbolism of Atomic Measurements'', edited by
B.-G. Englert, Springer, Berlin, .
*
van der Waerden, B.L. (1967). ''Sources of Quantum Mechanics'', edited with a historical introduction by B.L. van der Waerden, North-Holland Publishing, Amsterdam.
*
Weinberg, S. (1995). ''The Quantum Theory of Fields'', volume 1, ''Foundations'', Cambridge University Press, Cambridge UK, .
*
Weinberg, S. (2013). ''Lectures on Quantum Mechanics'', Cambridge University Press, Cambridge UK, .
*Flowers, P., Theopold,K., Langley, R. (n.d.). ''Chemistry'', chapter 6, ''Electronic Structure and Periodic Properties of Elements'', OpenStax, https://opentextbc.ca/chemistry/chapter/6-2-the-bohr-model/.
{{DEFAULTSORT:Planck-Einstein relation
Foundational quantum physics
Max Planck