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Stil de grain yellow or sap green is a
pigment A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compo ...
derived from berries of the
buckthorn ''Rhamnus'' is a genus of about 110 accepted species of shrubs or small trees, commonly known as buckthorns, in the family Rhamnaceae. Its species range from tall (rarely to ) and are native mainly in east Asia and North America, but found thr ...
species '' Rhamnus saxatilis'', which are commonly called
Avignon Avignon (, ; ; oc, Avinhon, label=Provençal dialect, Provençal or , ; la, Avenio) is the Prefectures in France, prefecture of the Vaucluse Departments of France, department in the Provence-Alpes-Côte d'Azur Regions of France, region of So ...
berries or
Persia Iran, officially the Islamic Republic of Iran, and also called Persia, is a country located in Western Asia. It is bordered by Iraq and Turkey to the west, by Azerbaijan and Armenia to the northwest, by the Caspian Sea and Turkmeni ...
n berries after two historical areas of supply; latterly Italy was a major source. The color, whose principal chemical component is rhamnetin, was formerly called pink (or pinke); latterly, to distinguish it from light red "pink", the yellow "pink" was qualified as Dutch pink, brown pink, English pink, Italian pink, or French pink — the first three also applied to similar
quercitron Quercitron is a yellow natural dye obtained from the bark of the Eastern Black Oak (''Quercus velutina''), a forest tree indigenous in North America. It was formerly called Dutch pink, English pink, or Italian pink. The name is a shortened fo ...
dyes from the American
eastern black oak ''Quercus velutina'', the black oak, is a species of oak in the red oak group (''Quercus'' sect. ''Lobatae''), native and widespread in eastern and central North America. It is sometimes called the eastern black oak. ''Quercus velutina'' was pre ...
, ''Quercus velutina''. Other names are Persian berries lake, yellow berries and buckthorn berries.


Manufacture

Traditional sap green is made from both ripe and unripe buckthorn berries, and prepared in different ways. Berry harvest time, varietal, preparation method and time period of use influence the common name used to refer to that particular hue, color, recipe or chemical composition. Extracting the coloring principle through boiling water allows one to add different
mordant A mordant or dye fixative is a substance used to set (i.e. bind) dyes on fabrics by forming a coordination complex with the dye, which then attaches to the fabric (or tissue). It may be used for dyeing fabrics or for intensifying stains in ...
s, such as
alum An alum () is a type of chemical compound, usually a hydrated double salt, double sulfate salt (chemistry), salt of aluminium with the general chemical formula, formula , where is a valence (chemistry), monovalent cation such as potassium or a ...
or
soda Soda or SODA may refer to: Chemistry * Some chemical compounds containing sodium ** Sodium carbonate, washing soda or soda ash ** Sodium bicarbonate, baking soda ** Sodium hydroxide, caustic soda ** Sodium oxide, an alkali metal oxide * Sod ...
, each resulting in a different hue of this color. Unripe berries ( it, rhamni immaturi) produces a pigment that is dark brown in bulk and turns to bright yellow in a thin layer. It has a low
lightfastness Lightfastness is a property of a colourant such as dye or pigment that describes its resistance to fading when exposed to light. Dyes and pigments are used for example for dyeing of fabrics, plastics or other materials and manufacturing paints or ...
rating of about 4. Ripe berries ( it, rhamni maturi) produce a color called yellow
madder ''Rubia'' is the type genus of the Rubiaceae family of flowering plants, which also contains coffee. It contains around 80 species of perennial scrambling or climbing herbs and subshrubs native to the Old World. The genus and its best-known spe ...
, ''stil de grain'', or yellow lake. It is not permanent and was often used for
decorative painting A house painter and decorator is a tradesman responsible for the painting and decorating of buildings, and is also known as a decorator or house painter.''The Modern Painter and Decorator'' volume 1 1921 Caxton The purpose of painting is to imp ...
. Most often when called ''sap green'' the color is in the form of a
dyestuff A dye is a colored substance that chemically bonds to the substrate to which it is being applied. This distinguishes dyes from pigments which do not chemically bind to the material they color. Dye is generally applied in an aqueous solution and ...
, either direct from berry juice or as a
lake A lake is an area filled with water, localized in a basin, surrounded by land, and distinct from any river or other outlet that serves to feed or drain the lake. Lakes lie on land and are not part of the ocean, although, like the much large ...
precipitated with alum. In lake form, this color is considered to fade rapidly.


History

For use in medieval
illuminated manuscript An illuminated manuscript is a formally prepared document where the text is often supplemented with flourishes such as borders and miniature illustrations. Often used in the Roman Catholic Church for prayers, liturgical services and psalms, the ...
s, the color was sold in dried sheep
bladder The urinary bladder, or simply bladder, is a hollow organ in humans and other vertebrates that stores urine from the kidneys before disposal by urination. In humans the bladder is a distensible organ that sits on the pelvic floor. Urine enters ...
s in a liquid form that resembled a dense syrup, instead of being dried and sold as powder. The first recorded use of ''pinke'' as a color name in English for this yellow pigment was in 1598. The names ''stil de grain yellow'' and ''yellow madder'' came into use as the name for this yellow pigment in the early to mid-18th century, replacing the former name ''pinke''. In the 17th century, the word ''pink'' or ''pinke'' was used to describe a yellowish pigment, which was mixed with blue colors to yield greenish colors.
Thomas Jenner Sir Thomas Jenner (1637–1707) was an English barrister, Baron of the Exchequer and Justice of the Common Pleas, closely associated with the Stuart kings Charles II and James II of England. Life He was born at Mayfield, Sussex, eldest son of ...
's ''A Book of Drawing, Limning, Washing'' (1652) categorizes "Pink & blew
bice Bice, from the French ''bis'', originally meaning dark-coloured, is a green or blue pigment. In French the terms ''vert bis'' and ''azur bis'' mean dark green and dark blue respectively. Bice pigments were generally prepared from basic copper carb ...
" amongst the greens (p. 38), and specifies several admixtures of greenish colors made with pink—e.g. "Grasse-green is made of Pink and Bice, it is shadowed with
Indigo Indigo is a deep color close to the color wheel blue (a primary color in the RGB color space), as well as to some variants of ultramarine, based on the ancient dye of the same name. The word "indigo" comes from the Latin word ''indicum'', m ...
and Pink ... French-green of Pink and Indico hadowed withIndico" (pp. 38–40). In
William Salmon William Salmon (1644–1713) was an English empiric doctor and a writer of medical texts. He advertised himself as a "Professor of Physick". Salmon held an equivocal place in the medical community. He led apothecaries in opposing attempts by ...
's ''Polygraphice'' (1673), "Pink yellow" is mentioned amongst the chief yellow pigments (p. 96), and the reader is instructed to mix it with either saffron or
ceruse Venetian ceruse, also known as ''blanc de ceruse de Venise'' and Spirits of Saturn, was a 16th-century cosmetic used as a skin whitener. It was in great demand and considered the best available at the time, supposedly containing the best qualit ...
for "sad" or "light" shades thereof, respectively (p. 98). The pigment was used widely in the 18th century in France and England.


Modern use

Although it is used widely by name, it is rare to find a pre-made fine artist product that contains this pure pigment. Berries, ripe or unripe, and different versions of the lake are obtainable in powdered pigment form, although it is costly compared to its substitutes. It is fugitive and therefore not ideally suited for oil color, but has survived well in manuscript form due to the natural protections from light and moisture that a book offers. In contemporary art supplies the term "sap green" often indicates a mixture intending to resemble the traditional sap green or stil de grain yellow. Contemporary oil colors often use
coal tar Coal tar is a thick dark liquid which is a by-product of the production of coke and coal gas from coal. It is a type of creosote. It has both medical and industrial uses. Medicinally it is a topical medication applied to skin to treat psoriasi ...
lakes as a substitute. In 2006 Golden Artist Colors' line of "historical colors"
acrylic paint Acrylic paint is a fast-drying paint made of pigment suspended in acrylic polymer emulsion and plasticizers, silicone oils, defoamers, stabilizers, or metal soaps. Most acrylic paints are water-based, but become water-resistant when dry. Depe ...
included one named "sap green", made of synthetic
iron oxide Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of whic ...
, nickel complex azo, brominated and chlorinated
copper phthalocyanine Copper phthalocyanine (CuPc), also called phthalocyanine blue, phthalo blue and many other names, is a bright, crystalline, synthetic blue pigment from the group of phthalocyanine dyes. Its brilliant blue is frequently used in paints and dyes ...
and nearly pure amorphous carbon. A modern authority for this as a color is the ISCC-NBS Dictionary of Color Names (1955)—Color Sample of Stil de Grain Yellow (color sample #83).


See also

* List of colors


References


Sources

* *


Citations

{{DEFAULTSORT:Stil De Grain Yellow Shades of yellow Natural dyes