Peter L. Pauson
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Prof Peter Ludwig Israel Pauson
FRSE Fellowship of the Royal Society of Edinburgh (FRSE) is an award granted to individuals that the Royal Society of Edinburgh, Scotland's national academy of science and letters, judged to be "eminently distinguished in their subject". This soci ...
FRIC (1925–2013) was a German–Jewish emigrant who settled in Britain and who is remembered for his contributions to chemistry, most notably the
Pauson–Khand reaction The Pauson–Khand reaction (or PKR or PK-type reaction) is a chemical reaction described as a 2+2+1.html" ;"title="/nowiki>2+2+1">/nowiki>2+2+1/nowiki> cycloaddition between an alkyne, an alkene and carbon monoxide to form a α,β-cyclopentenone. ...
and as joint discoverer of
ferrocene Ferrocene is an organometallic compound with the formula . The molecule is a complex consisting of two cyclopentadienyl rings bound to a central iron atom. It is an orange solid with a camphor-like odor, that sublimes above room temperature, a ...
.


Life

He was born in
Bamberg Bamberg (, , ; East Franconian: ''Bambärch'') is a town in Upper Franconia, Germany, on the river Regnitz close to its confluence with the river Main. The town dates back to the 9th century, when its name was derived from the nearby ' castle. C ...
,
Germany Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...
on 30 July 1925, the son of Stefan Pauson and his wife, Helene Dorothea Herzfelder. His parents escaped to England in 1939 with Peter and his two sisters to flee the Nazi persecution of Jews. In 1942 the family moved to
Glasgow Glasgow ( ; sco, Glesca or ; gd, Glaschu ) is the most populous city in Scotland and the fourth-most populous city in the United Kingdom, as well as being the 27th largest city by population in Europe. In 2020, it had an estimated popul ...
and he began studying chemistry in the
University of Glasgow , image = UofG Coat of Arms.png , image_size = 150px , caption = Coat of arms Flag , latin_name = Universitas Glasguensis , motto = la, Via, Veritas, Vita , ...
under
Thomas Stevens Stevens Thomas Stevens Stevens FRS FRSE (1900 – 2000) was a 20th Scottish organic chemist. He was affectionately known as T.S.S. or Tommy Stevens. Life He was born in Renfrew on 8 October 1900, the only son of John Stevens and his wife, Jane Irving. ...
. After graduating in 1946, he moved to
Sheffield University , mottoeng = To discover the causes of things , established = – University of SheffieldPredecessor institutions: – Sheffield Medical School – Firth College – Sheffield Technical School – University College of Sheffield , type = Pu ...
as a postgraduate, studying under Robert Downs Haworth and receiving his doctorate in 1949. He then went to
Duquesne University Duquesne University of the Holy Spirit ( or ; Duquesne University or Duquesne) is a private Catholic research university in Pittsburgh, Pennsylvania. Founded by members of the Congregation of the Holy Spirit, Duquesne first opened as the Pittsbu ...
in
Pittsburgh Pittsburgh ( ) is a city in the Commonwealth (U.S. state), Commonwealth of Pennsylvania, United States, and the county seat of Allegheny County, Pennsylvania, Allegheny County. It is the most populous city in both Allegheny County and Wester ...
, Pennsylvania and pursued research on
tropolone Tropolone is an organic compound with the chemical formula . It is a pale yellow solid that is soluble in organic solvents. The compound has been of interest to research chemists because of its unusual electronic structure and its role as a ligan ...
s and other aromatic non-benzenoid molecules. His discovery of
ferrocene Ferrocene is an organometallic compound with the formula . The molecule is a complex consisting of two cyclopentadienyl rings bound to a central iron atom. It is an orange solid with a camphor-like odor, that sublimes above room temperature, a ...
with his student, Thomas J. Kealy, arose from an attempt to dimerize cyclopentadienylmagnesium bromide using
Iron(III) chloride Iron(III) chloride is the inorganic compound with the formula . Also called ferric chloride, it is a common compound of iron in the +3 oxidation state. The anhydrous compound is a crystalline solid with a melting point of 307.6 °C. The col ...
; the orange-yellow solid with formula C10H10Fe was described as a "molecular sandwich" in Pauson's note which was published in ''Nature'' in 1951. From 1951 to 1952 he studied at the
University of Chicago The University of Chicago (UChicago, Chicago, U of C, or UChi) is a private research university in Chicago, Illinois. Its main campus is located in Chicago's Hyde Park neighborhood. The University of Chicago is consistently ranked among the b ...
under
Morris Kharasch Morris Selig Kharasch (August 24, 1895 – October 9, 1957) was a pioneering organic chemist best known for his work with free radical additions and polymerizations. He defined the peroxide effect, explaining how an anti-Markovnikov orientation c ...
, then becoming a
DuPont DuPont de Nemours, Inc., commonly shortened to DuPont, is an American multinational chemical company first formed in 1802 by French-American chemist and industrialist Éleuthère Irénée du Pont de Nemours. The company played a major role in ...
Fellow at
Harvard University Harvard University is a private Ivy League research university in Cambridge, Massachusetts. Founded in 1636 as Harvard College and named for its first benefactor, the Puritan clergyman John Harvard, it is the oldest institution of higher le ...
. He then gained practical experience at the DuPont Laboratories in Wilmington. Returning to Britain, he became a lecturer at Sheffield University and in 1959 became Professor of Organic Chemistry at
Strathclyde University The University of Strathclyde ( gd, Oilthigh Shrath Chluaidh) is a public research university located in Glasgow, Scotland. Founded in 1796 as the Andersonian Institute, it is Glasgow's second-oldest university, having received its royal chart ...
. In 1964 he was elected a Fellow of the
Royal Society of Edinburgh The Royal Society of Edinburgh is Scotland's national academy of science and letters. It is a registered charity that operates on a wholly independent and non-partisan basis and provides public benefit throughout Scotland. It was established i ...
. Pauson and his postdoctoral assistant, Ihsan Khand, discovered the reaction now renowned as the
Pauson–Khand reaction The Pauson–Khand reaction (or PKR or PK-type reaction) is a chemical reaction described as a 2+2+1.html" ;"title="/nowiki>2+2+1">/nowiki>2+2+1/nowiki> cycloaddition between an alkyne, an alkene and carbon monoxide to form a α,β-cyclopentenone. ...
in 1971, though Pauson always referred to it as the "Khand reaction". In 1994, the University of Strathclyde established the
Merck Merck refers primarily to the German Merck family and three companies founded by the family, including: * the Merck Group, a German chemical, pharmaceutical and life sciences company founded in 1668 ** Merck Serono (known as EMD Serono in the Unite ...
Pauson Chair in Preparative Chemistry, funded by Merck, marking the contribution of Pauson to chemistry and to the university. Pauson retired in 1995 and died peacefully at home on 10 December 2013. He was cremated at
Clydebank Clydebank ( gd, Bruach Chluaidh) is a town in West Dunbartonshire, Scotland. Situated on the north bank of the River Clyde, it borders the village of Old Kilpatrick (with Bowling, West Dunbartonshire, Bowling and Milton, West Dunbartonshire, Mil ...
Crematorium. In his obituary, he is described as "''a gentleman of modesty, humility, and compassion … a fine man and a marvellous scientist''".


Family

He married Lai-Ngau Mary (née Wong) (1928 – March 18, 2010), having met her at a party hosted by
Enrico Fermi Enrico Fermi (; 29 September 1901 – 28 November 1954) was an Italian (later naturalized American) physicist and the creator of the world's first nuclear reactor, the Chicago Pile-1. He has been called the "architect of the nuclear age" and ...
when Pauson was at the University of Chicago in the early 1950s. They went on to have two children, Hilary and Alfred.


Selected publications

*''Organometallic Chemistry'' (1967) * * * * * * *


References

{{DEFAULTSORT:Pauson, Peter Ludwig Israel 1925 births 2013 deaths Jewish emigrants from Nazi Germany to the United Kingdom Organic chemists Alumni of the University of Sheffield Academics of the University of Sheffield Academics of the University of Strathclyde Fellows of the Royal Society of Edinburgh Duquesne University alumni