Pahoehoe Toe

Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or underwater, usually at temperatures from . The volcanic rock resulting from subsequent cooling is also often called ''lava''.

A lava flow is an outpouring of lava during an effusive eruption. (An explosive eruption, by contrast, produces a mixture of volcanic ash and other fragments called tephra, not lava flows.) The viscosity of most lava is about that of ketchup, roughly 10,000 to 100,000 times that of water. Even so, lava can flow great distances before cooling causes it to solidify, because lava exposed to air quickly develops a solid crust that insulates the remaining liquid lava, helping to keep it hot and inviscid enough to continue flowing.

The word ''lava'' comes from Italian and is probably derived from the Latin word ''labes'', which means a fall or slide. An early use of the word in connection with extrusion of magma from below the surface is found in a short account of the 1737 eruption of Vesuvius, written by Francesco Serao, who described "a flow of fiery lava" as an analogy to the flow of water and mud down the flanks of the volcano (a lahar) after heavy rain.

Properties of lava

Composition

Solidified lava on the Earth's crust is predominantly silicate minerals: mostly feldspars, feldspathoids, olivine, pyroxenes, amphiboles, micas and quartz. Rare nonsilicate lavas can be formed by local melting of nonsilicate mineral deposits or by separation of a magma into immiscible silicate and nonsilicate liquid phases.

Silicate lavas

Silicate lavas are molten mixtures dominated by oxygen and silicon, the most abundant elements of the Earth's crust, with smaller quantities of aluminium, calcium, magnesium, iron, sodium, and potassium and minor amounts of many other elements. Petrologists routinely express the composition of a silicate lava in terms of the weight or molar mass fraction of the oxides of the major elements (other than oxygen) present in the lava.

The physical behavior of silicate magmas is dominated by the silica component. Silicon ions in lava strongly bind to four oxygen ions in a tetrahedral arrangement. If an oxygen ion is bound to two silicon ions in the melt, it is described as a bridging oxygen, and lava with many clumps or chains of silicon ions connected by bridging oxygen ions is described as partially polymerized. Aluminium in combination with alkali metal oxides (sodium and potassium) also tends to polymerize the lava. Other cations, such as ferrous iron, calcium, and magnesium, bond much more weakly to oxygen and reduce the tendency to polymerize. Partial polymerization makes the lava viscous, so lava high in silica is much more viscous than lava low in silica.

Because of the role of silica in determining viscosity and because many other properties of a lava (such as its temperature) are observed to correlate with silica content, silicate lavas are divided into four chemical types based on silica content: ''felsic'', ''intermediate'', ''mafic'', and ''ultramafic''.

= Felsic lava

=
''Felsic'' or silicic lavas have a silica content greater than 63%. They include rhyolite and dacite lavas. With such a high silica content, these lavas are extremely viscous, ranging from 10⁸ cP (10⁵ Pa⋅s) for hot rhyolite lava at to 10¹¹ cP (10⁸ Pa⋅s) for cool rhyolite lava at . For comparison, water has a viscosity of about 1 cP (0.001 Pa⋅s). Because of this very high viscosity, felsic lavas usually erupt explosively to produce pyroclastic (fragmental) deposits. However, rhyolite lavas occasionally erupt effusively to form lava spines, lava domes or "coulees" (which are thick, short lava flows). The lavas typically fragment as they extrude, producing block lava flows. These often contain obsidian.

Felsic magmas can erupt at temperatures as low as . Unusually hot (>950 °C; >1,740 °F) rhyolite lavas, however, may flow for distances of many tens of kilometres, such as in the Snake River Plain of the northwestern United States.

= Intermediate lava

=
''Intermediate'' or andesitic lavas contain 52% to 63% silica, and are lower in aluminium and usually somewhat richer in magnesium and iron than felsic lavas. Intermediate lavas form andesite domes and block lavas and may occur on steep composite volcanoes, such as in the Andes. They are also commonly hotter than felsic lavas, in the range of . Because of their lower silica content and higher eruptive temperatures, they tend to be much less viscous, with a typical viscosity of 3.5 × 10⁶ cP (3,500 Pa⋅s) at . This is slightly greater than the viscosity of smooth peanut butter. Intermediate lavas show a greater tendency to form phenocrysts. Higher iron and magnesium tends to manifest as a darker groundmass, including amphibole or pyroxene phenocrysts.

= Mafic lava

=
''Mafic'' or basaltic lavas are typified by relatively high magnesium oxide and iron oxide content (whose molecular formulas provide the consonants in mafic) and have a silica content limited to a range 52% to 45%. They generally erupt at temperatures of and at relatively low viscosities, around 10⁴ to 10⁵ cP (10 to 100 Pa⋅s). This is similar to the viscosity of ketchup, although it is still many orders of magnitude higher than that of water. Mafic lavas tend to produce low-profile shield volcanoes or flood basalts, because the less viscous lava can flow for long distances from the vent. The thickness of a solidified basaltic lava flow, particularly on a low slope, may be much greater than the thickness of the moving molten lava flow at any one time, because basaltic lavas may "inflate" by a continued supply of lava and its pressure on a solidified crust. Most basaltic lavas are of ''ʻaʻā'' or ''pāhoehoe'' types, rather than block lavas. Underwater, they can form pillow lavas, which are rather similar to entrail-type pahoehoe lavas on land.

= Ultramafic lava

=
''Ultramafic'' lavas, such as komatiite and highly magnesian magmas that form boninite, take the composition and temperatures of eruptions to the extreme. All have a silica content under 45%. Komatiites contain over 18% magnesium oxide and are thought to have erupted at temperatures of . At this temperature there is practically no polymerization of the mineral compounds, creating a highly mobile liquid. Viscosities of komatiite magmas are thought to have been as low as 100 to 1000 cP (0.1 to 1 Pa⋅s), similar to that of light motor oil. Most ultramafic lavas are no younger than the Proterozoic, with a few ultramafic magmas known from the Phanerozoic in Central America that are attributed to a hot mantle plume. No modern komatiite lavas are known, as the Earth's mantle has cooled too much to produce highly magnesian magmas.

= Alkaline lavas

=
Some silicate lavas have an elevated content of alkali metal oxides (sodium and potassium), particularly in regions of continental rifting, areas overlying deeply subducted plates, or at intraplate hotspots. Their silica content can range from ultramafic (nephelinites, basanites and tephrites) to felsic (trachytes). They are more likely to be generated at greater depths in the mantle than subalkaline magmas. Olivine nephelinite lavas are both ultramafic and highly alkaline, and are thought to have come from much deeper in the mantle of the Earth than other lavas.

Non-silicate lavas

Some lavas of unusual composition have erupted onto the surface of the Earth. These include:
* Carbonatite and natrocarbonatite lavas are known from Ol Doinyo Lengai volcano in Tanzania, which is the sole example of an active carbonatite volcano. Carbonatites in the geologic record are typically 75% carbonate minerals, with lesser amounts of silica-undersaturated silicate minerals (such as micas and olivine), apatite, magnetite, and pyrochlore. This may not reflect the original composition of the lava, which may have included sodium carbonate that was subsequently removed by hydrothermal activity, though laboratory experiments show that a calcite-rich magma is possible. Carbonatite lavas show stable isotope ratios indicating they are derived from the highly alkaline silicic lavas with which they are always associated, probably by separation of an immiscible phase. Natrocarbonatite lavas of Ol Doinyo Lengai are composed mostly of sodium carbonate, with about half as much calcium carbonate and half again as much potassium carbonate, and minor amounts of halides, fluorides, and sulphates. The lavas are extremely fluid, with viscosities only slightly greater than water, and are very cool, with measured temperatures of .
* Iron oxide lavas are thought to be the source of the iron ore at Kiruna, Sweden which formed during the Proterozoic. Iron oxide lavas of Pliocene

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