Polyvinyl acetate (PVA, PVAc, poly(ethenyl ethanoate)), commonly known as wood glue, PVA glue, white glue, carpenter's glue, school glue, or
Elmer's glue in the US, is a widely available adhesive used for porous materials like wood, paper, and cloth. An
aliphatic
In organic chemistry, hydrocarbons ( compounds composed solely of carbon and hydrogen) are divided into two classes: aromatic compounds and aliphatic compounds (; G. ''aleiphar'', fat, oil). Aliphatic compounds can be saturated, like hexane, ...
rubber
Rubber, also called India rubber, latex, Amazonian rubber, ''caucho'', or ''caoutchouc'', as initially produced, consists of polymers of the organic compound isoprene, with minor impurities of other organic compounds. Thailand, Malaysia, an ...
y
synthetic polymer with the formula (C
4H
6O
2)
''n'', it belongs to the
polyvinyl ester family, with the general formula β
2">COOCHCH2. It is a type of
thermoplastic
A thermoplastic, or thermosoft plastic, is any plastic polymer material that becomes pliable or moldable at a certain elevated temperature and solidifies upon cooling.
Most thermoplastics have a high molecular weight. The polymer chains associate ...
.
Properties
The
degree of polymerization
The degree of polymerization, or DP, is the number of monomeric units in a macromolecule or polymer or oligomer molecule.
For a homopolymer, there is only one type of monomeric unit and the ''number-average'' degree of polymerization is given b ...
of polyvinyl acetate is typically 100 to 5000, while its
ester groups are sensitive to
base hydrolysis and slowly convert PVAc into
polyvinyl alcohol
Poly(vinyl alcohol) (PVOH, PVA, or PVAl) is a water-soluble synthetic polymer. It has the idealized formula H2CH(OH)sub>''n''. It is used in papermaking, textile warp sizing, as a thickener and emulsion stabilizer in polyvinyl acetate (PVAc) ...
and
acetic acid.
The
glass transition temperature of polyvinyl acetate is between 30 and 45 Β°C depending on the molecular weight.
PVAc dispersions such as
Elmer's Glue-All
Elmer's Products, or simply Elmer's is an American-based company that has a line of adhesive, craft, home repair, and office supply products. It is best known as the manufacturer of Elmer's Glue-All, a popular PVA-based synthetic glue, in ...
contain polyvinyl alcohol as a protective colloid. In alkaline conditions,
boron compounds such as
boric acid
Boric acid, more specifically orthoboric acid, is a compound of boron, oxygen, and hydrogen with formula . It may also be called hydrogen borate or boracic acid. It is usually encountered as colorless crystals or a white powder, that dissolve ...
or
borax
Borax is a salt ( ionic compound), a hydrated borate of sodium, with chemical formula often written . It is a colorless crystalline solid, that dissolves in water to make a basic solution. It is commonly available in powder or granular for ...
cause the polyvinyl alcohol to
cross-link
In chemistry and biology a cross-link is a bond or a short sequence of bonds that links one polymer chain to another. These links may take the form of covalent bonds or ionic bonds and the polymers can be either synthetic polymers or natural ...
, forming tackifying precipitates or toys, such as
Slime
Slime may refer to:
Biology
* Slime mold, a broad term often referring to roughly six groups of Eukaryotes
* Biofilm, an aggregate of microorganisms in which cells adhere to each other and/or to a surface
* Slimy (fish), also known as the pony ...
and
Flubber.
A number of microorganisms can degrade polyvinyl acetate. Most commonly, damage is caused by filamentous
fungi
A fungus ( : fungi or funguses) is any member of the group of eukaryotic organisms that includes microorganisms such as yeasts and molds, as well as the more familiar mushrooms. These organisms are classified as a kingdom, separately from ...
; however,
algae,
yeast
Yeasts are eukaryotic, single-celled microorganisms classified as members of the fungus kingdom. The first yeast originated hundreds of millions of years ago, and at least 1,500 species are currently recognized. They are estimated to constit ...
s,
lichens, and
bacteria
Bacteria (; singular: bacterium) are ubiquitous, mostly free-living organisms often consisting of one Cell (biology), biological cell. They constitute a large domain (biology), domain of prokaryotic microorganisms. Typically a few micrometr ...
can also degrade polyvinyl acetate.
Discovery
Polyvinyl acetate was discovered in
Germany
Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...
in 1912 by
Fritz Klatte
Fritz Klatte (28 March 1880, Diepholz – 11 February 1934) was a German chemist and the discoverer of polyvinyl acetate, with German patent (GP 281687 1912) for its preparation from acetylene gas.See:(1) Deutsche Reichs Patent no. 281687 (4 ...
.
The monomer,
vinyl acetate
Vinyl acetate is an organic compound with the formula CH3CO2CH=CH2. This colorless liquid is the precursor to polyvinyl acetate and ethene-vinyl acetate copolymers, important industrial polymers.
Production
The worldwide production capacity of v ...
, was first produced on an industrial scale by the addition of
acetic acid to
acetylene with a mercury(I) salt, but it is now primarily made by
palladium
Palladium is a chemical element with the symbol Pd and atomic number 46. It is a rare and lustrous silvery-white metal discovered in 1803 by the English chemist William Hyde Wollaston. He named it after the asteroid Pallas, which was itself na ...
-catalyzed oxidative addition of
acetic acid to
ethylene.
Preparation
PVA is a
vinyl polymer
In polymer chemistry, vinyl polymers are a group of polymers derived from substituted vinyl () monomers. Their backbone is an extended alkane chain . In popular usage, "vinyl" refers only to polyvinyl chloride (PVC).
Examples
Vinyl polymers ...
. Polyvinyl acetate is prepared by the
polymerization
In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks. There are many fo ...
of
vinyl acetate monomer
Vinyl acetate is an organic compound with the formula CH3CO2CH=CH2. This colorless liquid is the precursor to polyvinyl acetate and ethene-vinyl acetate copolymers, important industrial polymers.
Production
The worldwide production capacity of ...
(
free-radical
In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired valence electron.
With some exceptions, these unpaired electrons make radicals highly chemically reactive. Many radicals spon ...
vinyl polymerization of the
monomer
In chemistry, a monomer ( ; '' mono-'', "one" + ''-mer'', "part") is a molecule that can react together with other monomer molecules to form a larger polymer chain or three-dimensional network in a process called polymerization.
Classification
...
vinyl acetate).
Applications
As a
dispersion
Dispersion may refer to:
Economics and finance
* Dispersion (finance), a measure for the statistical distribution of portfolio returns
* Price dispersion, a variation in prices across sellers of the same item
*Wage dispersion, the amount of variat ...
in water (usually an emulsion), PVAc preparations are used as
adhesives for
porous
Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
materials, particularly for
wood
Wood is a porous and fibrous structural tissue found in the stems and roots of trees and other woody plants. It is an organic materiala natural composite of cellulose fibers that are strong in tension and embedded in a matrix of lignin ...
,
paper
Paper is a thin sheet material produced by mechanically or chemically processing cellulose fibres derived from wood, rags, grasses or other vegetable sources in water, draining the water through fine mesh leaving the fibre evenly distrib ...
, and
cloth
Textile is an umbrella term that includes various fiber-based materials, including fibers, yarns, filaments, threads, different fabric types, etc. At first, the word "textiles" only referred to woven fabrics. However, weaving is not the ...
, and as a consolidant for porous building stone, in particular
sandstone
Sandstone is a clastic sedimentary rock composed mainly of sand-sized (0.0625 to 2 mm) silicate grains. Sandstones comprise about 20–25% of all sedimentary rocks.
Most sandstone is composed of quartz or feldspar (both silicates ...
.
Uses:
* As
wood glue
Wood glue is an adhesive used to tightly bond pieces of wood together. Many substances have been used as glues.
Types Animal glue
Animal glue, especially hoof glue and hide glue, was the primary adhesive of choice for many types of woodworki ...
, PVAc is known as "white glue" and the yellow as "carpenter's glue".
* As paper adhesive during paper packaging conversion.
* In
bookbinding and book arts, due to its flexible strong bond and non-
acidic
In computer science, ACID ( atomicity, consistency, isolation, durability) is a set of properties of database transactions intended to guarantee data validity despite errors, power failures, and other mishaps. In the context of databases, a ...
nature (unlike many other polymers). The use of PVAc on the
Archimedes Palimpsest during the 20th century greatly hindered the task of disbinding the book and preserving and imaging the pages in the early 21st century, in part because the glue was stronger than the parchment it held together.
* In
handicrafts
A handicraft, sometimes more precisely expressed as artisanal handicraft or handmade, is any of a wide variety of types of work where useful and decorative objects are made completely by oneβs hand or by using only simple, non-automated re ...
.
* As
envelope
An envelope is a common packaging item, usually made of thin, flat material. It is designed to contain a flat object, such as a letter or card.
Traditional envelopes are made from sheets of paper cut to one of three shapes: a rhombus, a sh ...
adhesive.
* As
wallpaper adhesive.
* As a
primer for
drywall
Drywall (also called plasterboard, dry lining, wallboard, sheet rock, gypsum board, buster board, custard board, and gypsum panel) is a panel made of calcium sulfate dihydrate (gypsum), with or without additives, typically extruded between thic ...
and other substrates
* As a gum base in
chewing gum
Chewing gum is a soft, cohesive substance designed to be chewed without being swallowed. Modern chewing gum is composed of gum base, sweeteners, softeners/ plasticizers, flavors, colors, and, typically, a hard or powdered polyol coating. Its t ...
.
* As an adhesive for
cigarette paper
Rolling paper is a specialty paper used for making cigarettes (commercially manufactured filter cigarettes and individually made roll-your-own cigarettes). Rolling papers are packs of several cigarette-size sheets, often folded inside a cardboard ...
.
*As the coating layer on Gouda cheese.
The stiff
homopolymer
A polymer (; Greek '' poly-'', "many" + '' -mer'', "part")
is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic an ...
PVAc, but mostly the softer
copolymer
In polymer chemistry, a copolymer is a polymer derived from more than one species of monomer. The polymerization of monomers into copolymers is called copolymerization. Copolymers obtained from the copolymerization of two monomer species are some ...
, a combination of vinyl acetate and ethylene,
vinyl acetate ethylene (VAE), is also used in
paper
Paper is a thin sheet material produced by mechanically or chemically processing cellulose fibres derived from wood, rags, grasses or other vegetable sources in water, draining the water through fine mesh leaving the fibre evenly distrib ...
coatings,
paint and other industrial coatings, as a binder in
nonwoven
Nonwoven fabric is a fabric-like material made from staple fibre (short) and long fibres (continuous long), bonded together by chemical, mechanical, heat or solvent treatment. The term is used in the textile manufacturing industry to denote fabri ...
s in
glass fiber
Glass fiber ( or glass fibre) is a material consisting of numerous extremely fine fibers of glass.
Glassmakers throughout history have experimented with glass fibers, but mass manufacture of glass fiber was only made possible with the inventio ...
s,
sanitary napkins
A menstrual pad, or simply a pad, (also known as a sanitary pad, sanitary towel, sanitary napkin or feminine napkin) is an absorbent item worn by women in their underwear when menstruating, bleeding after giving birth, recovering from gynecolo ...
,
filter paper Filter paper is a semi-permeable paper barrier placed perpendicular to a liquid or air flow. It is used to separate fine solid particles from liquids or gases.
The raw materials are different Pulp (paper), paper pulps. The pulp may be made from soft ...
and in
textile finishing
In textile manufacturing, finishing refers to the processes that convert the woven or knitted cloth into a usable material and more specifically to any process performed after dyeing the yarn or fabric to improve the look, performance, or "hand" ...
.
Polyvinyl acetate is also the raw material to make other polymers like:
*
Polyvinyl alcohol
Poly(vinyl alcohol) (PVOH, PVA, or PVAl) is a water-soluble synthetic polymer. It has the idealized formula H2CH(OH)sub>''n''. It is used in papermaking, textile warp sizing, as a thickener and emulsion stabilizer in polyvinyl acetate (PVAc) ...
β
2">OCHCH2: Polyvinyl acetate is partially or completely
hydrolysed
Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution, elimination, and solvation reactions in which water is the nucleophile.
Biological hydrolysis ...
to give polyvinyl alcohol. This reversible saponification and esterification reaction was a strong hint for
Hermann Staudinger in the formulation of his theory of
macromolecules
A macromolecule is a very large molecule important to biophysical processes, such as a protein or nucleic acid. It is composed of thousands of covalently bonded atoms. Many macromolecules are polymers of smaller molecules called monomers. The ...
.
[H. Staudinger, K. Frey, W. Stark, Ber. Deut. Chem. Ges. 1927, 60, 1782.]
*
Polyvinyl acetate phthalate (PVAP): Polyvinyl acetate is partially hydrolyzed and then esterified with
phthalic acid
Phthalic acid is an aromatic dicarboxylic acid, with formula C6H4(CO2H)2. Although phthalic acid is of modest commercial importance, the closely related derivative phthalic anhydride is a commodity chemical produced on a large scale. Phthalic acid ...
.
See also
*
Ethylene vinyl acetate
Ethylene-vinyl acetate (EVA), also known as poly (ethylene-vinyl acetate) (PEVA), is the copolymer of ethylene and vinyl acetate. The weight percent of vinyl acetate usually varies from 10 to 40%, with the remainder being ethylene. There are thr ...
*
International Klein Blue
International Klein Blue (IKB) is a deep blue hue first mixed by the French artist Yves Klein. IKB's visual impact comes from its heavy reliance on ultramarine, as well as Klein's often thick and textured application of paint to canvas.
Histo ...
*
Elmer's Products
Elmer's Products, or simply Elmer's is an American-based company that has a line of adhesive, craft, home repair, and office supply products. It is best known as the manufacturer of Elmer's Glue-All, a popular PVA-based synthetic glue, i ...
References
{{Authority control
Adhesives
Household chemicals
Vinyl polymers
Woodworking adhesives
Wood finishing materials
Polymers
Acetate esters